JPS61229891A - メシチル亜ホスホン酸ジクロリドの製造方法 - Google Patents
メシチル亜ホスホン酸ジクロリドの製造方法Info
- Publication number
- JPS61229891A JPS61229891A JP7032485A JP7032485A JPS61229891A JP S61229891 A JPS61229891 A JP S61229891A JP 7032485 A JP7032485 A JP 7032485A JP 7032485 A JP7032485 A JP 7032485A JP S61229891 A JPS61229891 A JP S61229891A
- Authority
- JP
- Japan
- Prior art keywords
- solution
- reacting
- bromomesitylene
- phosphorus trichloride
- lithiomesitylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- RWCXNEMDSPWVPM-UHFFFAOYSA-N dichloro-(2,4,6-trimethylphenyl)phosphane Chemical compound CC1=CC(C)=C(P(Cl)Cl)C(C)=C1 RWCXNEMDSPWVPM-UHFFFAOYSA-N 0.000 title 1
- FAIAAWCVCHQXDN-UHFFFAOYSA-N phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 claims abstract description 6
- RRTLQRYOJOSPEA-UHFFFAOYSA-N 2-bromo-1,3,5-trimethylbenzene Chemical group CC1=CC(C)=C(Br)C(C)=C1 RRTLQRYOJOSPEA-UHFFFAOYSA-N 0.000 claims abstract description 5
- 238000010992 reflux Methods 0.000 claims abstract description 4
- 239000011261 inert gas Substances 0.000 claims abstract description 3
- 229910052744 lithium Inorganic materials 0.000 claims abstract 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims abstract 2
- 238000010438 heat treatment Methods 0.000 claims abstract 2
- -1 alkyl lithium Chemical compound 0.000 claims description 10
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 239000002244 precipitate Substances 0.000 claims description 3
- 239000000706 filtrate Substances 0.000 claims description 2
- 239000002904 solvent Substances 0.000 claims description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 claims description 2
- 238000001914 filtration Methods 0.000 claims 1
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 abstract description 6
- MZRVEZGGRBJDDB-UHFFFAOYSA-N N-Butyllithium Chemical compound [Li]CCCC MZRVEZGGRBJDDB-UHFFFAOYSA-N 0.000 abstract description 5
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- KWGKDLIKAYFUFQ-UHFFFAOYSA-M lithium chloride Chemical compound [Li+].[Cl-] KWGKDLIKAYFUFQ-UHFFFAOYSA-M 0.000 abstract description 4
- 239000000126 substance Substances 0.000 abstract description 4
- 238000001816 cooling Methods 0.000 abstract description 3
- 239000011541 reaction mixture Substances 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract 2
- 238000003756 stirring Methods 0.000 abstract 1
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- MXZIJBADTFIUMO-UHFFFAOYSA-N phenylphosphonous acid dihydrochloride Chemical compound Cl.Cl.OP(O)C1=CC=CC=C1 MXZIJBADTFIUMO-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- AUHZEENZYGFFBQ-UHFFFAOYSA-N mesitylene Substances CC1=CC(C)=CC(C)=C1 AUHZEENZYGFFBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001827 mesitylenyl group Chemical group [H]C1=C(C(*)=C(C([H])=C1C([H])([H])[H])C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7032485A JPS61229891A (ja) | 1985-04-03 | 1985-04-03 | メシチル亜ホスホン酸ジクロリドの製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP7032485A JPS61229891A (ja) | 1985-04-03 | 1985-04-03 | メシチル亜ホスホン酸ジクロリドの製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61229891A true JPS61229891A (ja) | 1986-10-14 |
| JPH0415795B2 JPH0415795B2 (https=) | 1992-03-19 |
Family
ID=13428149
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP7032485A Granted JPS61229891A (ja) | 1985-04-03 | 1985-04-03 | メシチル亜ホスホン酸ジクロリドの製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61229891A (https=) |
-
1985
- 1985-04-03 JP JP7032485A patent/JPS61229891A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0415795B2 (https=) | 1992-03-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313111 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
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| EXPY | Cancellation because of completion of term |