JPS6118736A - 不飽和側鎖を持つ芳香族化合物の製法 - Google Patents
不飽和側鎖を持つ芳香族化合物の製法Info
- Publication number
- JPS6118736A JPS6118736A JP13941284A JP13941284A JPS6118736A JP S6118736 A JPS6118736 A JP S6118736A JP 13941284 A JP13941284 A JP 13941284A JP 13941284 A JP13941284 A JP 13941284A JP S6118736 A JPS6118736 A JP S6118736A
- Authority
- JP
- Japan
- Prior art keywords
- compound
- formula
- reactive zinc
- alcohol
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 5
- 150000001491 aromatic compounds Chemical group 0.000 title claims description 8
- -1 aromatic allyl compound Chemical group 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 3
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims abstract 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims abstract 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract 2
- 125000005843 halogen group Chemical group 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 17
- 238000006243 chemical reaction Methods 0.000 abstract description 15
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 abstract description 11
- 238000009835 boiling Methods 0.000 abstract description 9
- 239000002904 solvent Substances 0.000 abstract description 9
- 239000000203 mixture Substances 0.000 abstract description 7
- 150000001875 compounds Chemical class 0.000 abstract description 5
- 239000003054 catalyst Substances 0.000 abstract description 4
- 238000005695 dehalogenation reaction Methods 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 229910052736 halogen Inorganic materials 0.000 abstract description 3
- 150000002367 halogens Chemical class 0.000 abstract description 3
- 238000003786 synthesis reaction Methods 0.000 abstract description 3
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 229920000642 polymer Polymers 0.000 abstract description 2
- 239000007858 starting material Substances 0.000 abstract 2
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
- 239000000428 dust Substances 0.000 abstract 1
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 abstract 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 abstract 1
- 235000019441 ethanol Nutrition 0.000 description 13
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 8
- 229930015698 phenylpropene Natural products 0.000 description 6
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000010521 absorption reaction Methods 0.000 description 4
- 235000005074 zinc chloride Nutrition 0.000 description 4
- 239000011592 zinc chloride Substances 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 238000004817 gas chromatography Methods 0.000 description 3
- NGKSKVYWPINGLI-UHFFFAOYSA-N prop-2-ynylbenzene Chemical group C#CCC1=CC=CC=C1 NGKSKVYWPINGLI-UHFFFAOYSA-N 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004508 fractional distillation Methods 0.000 description 1
- 238000005338 heat storage Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13941284A JPS6118736A (ja) | 1984-07-05 | 1984-07-05 | 不飽和側鎖を持つ芳香族化合物の製法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13941284A JPS6118736A (ja) | 1984-07-05 | 1984-07-05 | 不飽和側鎖を持つ芳香族化合物の製法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6118736A true JPS6118736A (ja) | 1986-01-27 |
| JPS6319488B2 JPS6319488B2 (enrdf_load_html_response) | 1988-04-22 |
Family
ID=15244632
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13941284A Granted JPS6118736A (ja) | 1984-07-05 | 1984-07-05 | 不飽和側鎖を持つ芳香族化合物の製法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6118736A (enrdf_load_html_response) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS63182991U (enrdf_load_html_response) * | 1987-05-20 | 1988-11-25 |
-
1984
- 1984-07-05 JP JP13941284A patent/JPS6118736A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6319488B2 (enrdf_load_html_response) | 1988-04-22 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Krespan et al. | Perfluoroallyl fluorosulfate, a reactive new perfluoroallylating agent | |
| JPS6118736A (ja) | 不飽和側鎖を持つ芳香族化合物の製法 | |
| JPS6118738A (ja) | 不飽和側鎖を持つ芳香族化合物の製造方法 | |
| JPS6118737A (ja) | 不飽和側鎖を有する芳香族化合物の製造方法 | |
| JPS61122240A (ja) | ハロゲン化された３，３‐ジメチル‐５‐ヘキセン‐２‐オンの製造方法 | |
| JPS61130258A (ja) | １―ブロモエチルヒドロカルボニルカーボネートの製造方法 | |
| JPS62178537A (ja) | ５−ブロム−１−ペンタナ−ル化合物またはそのアセタ−ル誘導体の製造法 | |
| Kira et al. | Photochemically Induced Exchange of Fluorine and. BETA.-Silyl Moieties in 2-Fluorophenyldisilanes. | |
| JPS5852247A (ja) | オキソカルボン酸エステルの製造法 | |
| JPS62120327A (ja) | フルオロアルキル化方法 | |
| JPS6043067B2 (ja) | ２‐アルコキシインドリジン誘導体およびその製法 | |
| JPH045283A (ja) | アミノプロピオフェノン誘導体又はその塩の製造方法 | |
| JPH0324056A (ja) | インドール類の製造法 | |
| JP4001978B2 (ja) | 不飽和アルデヒドの製造方法 | |
| JPS63183543A (ja) | α−ヒドロキシケトン類の製造法 | |
| JPH023672A (ja) | ２，６‐ジエチルアニリン誘導体およびその製法 | |
| JPS5877876A (ja) | ２−ヘキシル−５−メチルフランの製造法 | |
| JPS58126829A (ja) | ベンゾフエノン誘導体の製造方法 | |
| JPH0291064A (ja) | プロピオフエノン誘導体の製法 | |
| JPS59172432A (ja) | １−フエニル−２−アルコキシアルカン類の製法 | |
| JPS6345654B2 (enrdf_load_html_response) | ||
| JPH01272559A (ja) | ２，６‐ジエチルアニリン誘導体及びその製造法 | |
| JPS5888358A (ja) | ９−ハイドロパ−オキシ−９−置換フルオレンの製造法 | |
| JPS6169781A (ja) | トリ有機錫シラトラン誘導体の製造法 | |
| JPS60112732A (ja) | 炭化水素系化合物の製造法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |