JPS61174286A - シツフ塩基コバルト錯体の酸素吸脱着剤としての使用方法 - Google Patents
シツフ塩基コバルト錯体の酸素吸脱着剤としての使用方法Info
- Publication number
- JPS61174286A JPS61174286A JP60014506A JP1450685A JPS61174286A JP S61174286 A JPS61174286 A JP S61174286A JP 60014506 A JP60014506 A JP 60014506A JP 1450685 A JP1450685 A JP 1450685A JP S61174286 A JPS61174286 A JP S61174286A
- Authority
- JP
- Japan
- Prior art keywords
- oxygen
- solvent
- cobalt complex
- polar solvent
- desorption agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title claims description 39
- 239000001301 oxygen Substances 0.000 title claims description 39
- 229910052760 oxygen Inorganic materials 0.000 title claims description 39
- 239000003463 adsorbent Substances 0.000 title abstract description 6
- 238000003795 desorption Methods 0.000 title abstract description 6
- 239000002798 polar solvent Substances 0.000 claims abstract description 16
- 239000002904 solvent Substances 0.000 claims abstract description 7
- 239000002262 Schiff base Substances 0.000 claims description 15
- -1 Schiff base cobalt complex Chemical class 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 6
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- 238000006467 substitution reaction Methods 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 1
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract description 22
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 abstract description 6
- 150000001875 compounds Chemical class 0.000 abstract description 4
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 abstract description 3
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 abstract description 3
- IXWOUPGDGMCKGT-UHFFFAOYSA-N 2,3-dihydroxybenzaldehyde Chemical compound OC1=CC=CC(C=O)=C1O IXWOUPGDGMCKGT-UHFFFAOYSA-N 0.000 abstract description 2
- 239000007787 solid Substances 0.000 abstract description 2
- 239000000725 suspension Substances 0.000 abstract description 2
- 239000000843 powder Substances 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 description 14
- 239000002585 base Substances 0.000 description 6
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 6
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 150000004753 Schiff bases Chemical class 0.000 description 3
- 150000004700 cobalt complex Chemical class 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 150000002926 oxygen Chemical class 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001868 cobalt Chemical class 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000001816 cooling Methods 0.000 description 2
- 238000007872 degassing Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical class CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 2
- 239000003446 ligand Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 230000002441 reversible effect Effects 0.000 description 2
- 238000002336 sorption--desorption measurement Methods 0.000 description 2
- KMBSSXSNDSJXCG-UHFFFAOYSA-N 1-[2-(2-hydroxyundecylamino)ethylamino]undecan-2-ol Chemical compound CCCCCCCCCC(O)CNCCNCC(O)CCCCCCCCC KMBSSXSNDSJXCG-UHFFFAOYSA-N 0.000 description 1
- VEUMANXWQDHAJV-UHFFFAOYSA-N 2-[2-[(2-hydroxyphenyl)methylideneamino]ethyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCN=CC1=CC=CC=C1O VEUMANXWQDHAJV-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 102000001554 Hemoglobins Human genes 0.000 description 1
- 108010054147 Hemoglobins Proteins 0.000 description 1
- 102000036675 Myoglobin Human genes 0.000 description 1
- 108010062374 Myoglobin Proteins 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- ZBYYWKJVSFHYJL-UHFFFAOYSA-L cobalt(2+);diacetate;tetrahydrate Chemical compound O.O.O.O.[Co+2].CC([O-])=O.CC([O-])=O ZBYYWKJVSFHYJL-UHFFFAOYSA-L 0.000 description 1
- 238000000921 elemental analysis Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Gas Separation By Absorption (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60014506A JPS61174286A (ja) | 1985-01-30 | 1985-01-30 | シツフ塩基コバルト錯体の酸素吸脱着剤としての使用方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60014506A JPS61174286A (ja) | 1985-01-30 | 1985-01-30 | シツフ塩基コバルト錯体の酸素吸脱着剤としての使用方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61174286A true JPS61174286A (ja) | 1986-08-05 |
| JPH0324402B2 JPH0324402B2 (enrdf_load_stackoverflow) | 1991-04-03 |
Family
ID=11862950
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60014506A Granted JPS61174286A (ja) | 1985-01-30 | 1985-01-30 | シツフ塩基コバルト錯体の酸素吸脱着剤としての使用方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61174286A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0248014A (ja) * | 1988-08-05 | 1990-02-16 | Agency Of Ind Science & Technol | 混合気体の分離方法 |
| CN102924488A (zh) * | 2012-08-30 | 2013-02-13 | 山东轻工业学院 | 一类含银的吡嗪西弗碱配合物的结构、制备和用途 |
| CN103073510A (zh) * | 2013-03-01 | 2013-05-01 | 山东轻工业学院 | 一类吡嗪基新西弗碱化合物的结构、制备和用途 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS594439A (ja) * | 1982-06-30 | 1984-01-11 | Nippon Sanso Kk | 不活性ガスの精製方法 |
-
1985
- 1985-01-30 JP JP60014506A patent/JPS61174286A/ja active Granted
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS594439A (ja) * | 1982-06-30 | 1984-01-11 | Nippon Sanso Kk | 不活性ガスの精製方法 |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0248014A (ja) * | 1988-08-05 | 1990-02-16 | Agency Of Ind Science & Technol | 混合気体の分離方法 |
| CN102924488A (zh) * | 2012-08-30 | 2013-02-13 | 山东轻工业学院 | 一类含银的吡嗪西弗碱配合物的结构、制备和用途 |
| CN103073510A (zh) * | 2013-03-01 | 2013-05-01 | 山东轻工业学院 | 一类吡嗪基新西弗碱化合物的结构、制备和用途 |
| CN103073510B (zh) * | 2013-03-01 | 2014-12-17 | 齐鲁工业大学 | 一类吡嗪基西弗碱化合物的结构、制备和用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0324402B2 (enrdf_load_stackoverflow) | 1991-04-03 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |