JPS61126103A - 重合体の製造法 - Google Patents
重合体の製造法Info
- Publication number
- JPS61126103A JPS61126103A JP59244545A JP24454584A JPS61126103A JP S61126103 A JPS61126103 A JP S61126103A JP 59244545 A JP59244545 A JP 59244545A JP 24454584 A JP24454584 A JP 24454584A JP S61126103 A JPS61126103 A JP S61126103A
- Authority
- JP
- Japan
- Prior art keywords
- monomer
- aqueous solution
- dissolved oxygen
- polymerization
- inert gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920000642 polymer Polymers 0.000 title claims abstract description 18
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000000178 monomer Substances 0.000 claims abstract description 57
- 239000007864 aqueous solution Substances 0.000 claims abstract description 44
- 239000012530 fluid Substances 0.000 claims abstract description 26
- 239000011261 inert gas Substances 0.000 claims abstract description 23
- 239000000243 solution Substances 0.000 claims abstract description 21
- 238000006116 polymerization reaction Methods 0.000 claims description 35
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 41
- 239000001301 oxygen Substances 0.000 abstract description 41
- 229910052760 oxygen Inorganic materials 0.000 abstract description 41
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract description 11
- PQUXFUBNSYCQAL-UHFFFAOYSA-N 1-(2,3-difluorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(F)=C1F PQUXFUBNSYCQAL-UHFFFAOYSA-N 0.000 abstract description 9
- 239000003505 polymerization initiator Substances 0.000 abstract description 9
- 229940047670 sodium acrylate Drugs 0.000 abstract description 9
- 229910001873 dinitrogen Inorganic materials 0.000 abstract description 7
- 239000000203 mixture Substances 0.000 abstract description 3
- 238000000034 method Methods 0.000 description 7
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000000017 hydrogel Substances 0.000 description 2
- 238000002347 injection Methods 0.000 description 2
- 239000007924 injection Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229920003176 water-insoluble polymer Polymers 0.000 description 2
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- TURITJIWSQEMDB-UHFFFAOYSA-N 2-methyl-n-[(2-methylprop-2-enoylamino)methyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCNC(=O)C(C)=C TURITJIWSQEMDB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229940048053 acrylate Drugs 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- -1 alkali metal salts Chemical class 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011437 continuous method Methods 0.000 description 1
- 229920006037 cross link polymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 230000003670 easy-to-clean Effects 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000008394 flocculating agent Substances 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 230000001706 oxygenating effect Effects 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/06—Treatment of polymer solutions
- C08F6/10—Removal of volatile materials, e.g. solvents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/10—Aqueous solvent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D19/00—Degasification of liquids
- B01D19/0005—Degasification of liquids with one or more auxiliary substances
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polymerisation Methods In General (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Priority Applications (7)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59244545A JPS61126103A (ja) | 1984-11-21 | 1984-11-21 | 重合体の製造法 |
| US06/799,025 US4656232A (en) | 1984-11-21 | 1985-11-18 | Method for production of polymer |
| DE3540994A DE3540994C2 (de) | 1984-11-21 | 1985-11-19 | Verfahren zur Herstellung eines Polymers |
| FR858517256A FR2573431B1 (fr) | 1984-11-21 | 1985-11-21 | Procede de production d'un polymere |
| CN85109197.0A CN1003590B (zh) | 1984-11-21 | 1985-11-21 | 聚合物制备方法 |
| KR1019850008724A KR910002464B1 (ko) | 1984-11-21 | 1985-11-21 | 중합체의 제조법 |
| GB08528677A GB2173203B (en) | 1984-11-21 | 1985-11-21 | Polymerization of unsaturated monomers |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59244545A JPS61126103A (ja) | 1984-11-21 | 1984-11-21 | 重合体の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61126103A true JPS61126103A (ja) | 1986-06-13 |
| JPH0214362B2 JPH0214362B2 (enExample) | 1990-04-06 |
Family
ID=17120289
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59244545A Granted JPS61126103A (ja) | 1984-11-21 | 1984-11-21 | 重合体の製造法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4656232A (enExample) |
| JP (1) | JPS61126103A (enExample) |
| KR (1) | KR910002464B1 (enExample) |
| CN (1) | CN1003590B (enExample) |
| DE (1) | DE3540994C2 (enExample) |
| FR (1) | FR2573431B1 (enExample) |
| GB (1) | GB2173203B (enExample) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08171234A (ja) * | 1995-06-26 | 1996-07-02 | Canon Inc | 画像形成方法 |
| WO2002081608A3 (en) * | 2001-04-02 | 2003-03-06 | Nippon Catalytic Chem Ind | Method for producing chemical reactive substance and polycarboxylic acid produced thereby |
| JP2009507119A (ja) * | 2005-09-07 | 2009-02-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 重合法 |
| JP2009507117A (ja) * | 2005-09-07 | 2009-02-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 重合法 |
| JP2009507118A (ja) * | 2005-09-07 | 2009-02-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 重合法 |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2002016A1 (en) * | 1988-11-21 | 1990-05-21 | Koji Miyake | Manufacturing method, continuous manufacturing method, product and manufacturing apparatus of absorbent composite |
| DE3842184A1 (de) * | 1988-12-15 | 1990-06-21 | Basf Ag | Verfahren zur steuerung der teilchengroesse bei der herstellung von pulverfoermigen polymerisaten |
| US5126381A (en) * | 1988-12-19 | 1992-06-30 | Dow Corning Corporation | Bead processor |
| US6291605B1 (en) | 1990-06-06 | 2001-09-18 | Clarence S. Freeman | Polymerization process with spraying step |
| US6130304A (en) * | 1996-05-14 | 2000-10-10 | Sanyo Chemical Industries, Ltd. | Water-absorbent or water-retention material and production method thereof |
| US6107358A (en) * | 1996-08-23 | 2000-08-22 | Nippon Shokubai Co., Ltd. | Water-absorbent resin and method for production thereof |
| DE19938574A1 (de) | 1999-08-17 | 2001-02-22 | Stockhausen Chem Fab Gmbh | Verfahren und Vorrichtung zur Entfernung von Sauerstoff aus wässrigen Monomerenlösungen |
| JP4679683B2 (ja) * | 1999-11-02 | 2011-04-27 | 株式会社日本触媒 | 吸水性重合体の製造方法、及び該重合体の製造装置 |
| DE102005042038A1 (de) * | 2005-09-02 | 2007-03-08 | Basf Ag | Verfahren zur Herstellung wasserabsorbierender Polymere |
| US8357766B2 (en) * | 2008-10-08 | 2013-01-22 | Evonik Stockhausen Gmbh | Continuous process for the production of a superabsorbent polymer |
| US8048942B2 (en) * | 2008-10-08 | 2011-11-01 | Evonik Stockhausen Gmbh | Process for the production of a superabsorbent polymer |
| US8063121B2 (en) * | 2008-10-08 | 2011-11-22 | Evonik Stockhausen Gmbh | Process for the production of a superabsorbent polymer |
| WO2010095427A1 (ja) | 2009-02-17 | 2010-08-26 | 株式会社日本触媒 | ポリアクリル酸系吸水性樹脂粉末およびその製造方法 |
| JP5794991B2 (ja) | 2009-10-09 | 2015-10-14 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 吸水性ポリマー粒子を製造するための加熱蒸気凝縮物の使用 |
| JP5647625B2 (ja) | 2009-12-24 | 2015-01-07 | 株式会社日本触媒 | ポリアクリル酸系吸水性樹脂粉末及びその製造方法 |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5437910A (en) * | 1977-08-31 | 1979-03-20 | Ishikawajima Kenzai Kogyo Kk | Method of installing internal bag for underground water reservior |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3737500A (en) * | 1968-05-06 | 1973-06-05 | Union Oil Co | Method for extruding gelatinous material |
| US3644305A (en) * | 1969-10-29 | 1972-02-22 | Nalco Chemical Co | Spray polymerization |
| JPS51103990A (ja) * | 1975-03-12 | 1976-09-14 | Toa Gosei Chem Ind | Hiryudoseigansuihorimaanoseizoho |
| US4020256A (en) * | 1975-07-03 | 1977-04-26 | The Dow Chemical Company | Method for preparing polymers from water soluble vinyl monomers |
| US4395340A (en) * | 1981-07-14 | 1983-07-26 | Halliburton Company | Enhanced oil recovery methods and systems |
-
1984
- 1984-11-21 JP JP59244545A patent/JPS61126103A/ja active Granted
-
1985
- 1985-11-18 US US06/799,025 patent/US4656232A/en not_active Expired - Lifetime
- 1985-11-19 DE DE3540994A patent/DE3540994C2/de not_active Expired - Lifetime
- 1985-11-21 GB GB08528677A patent/GB2173203B/en not_active Expired
- 1985-11-21 KR KR1019850008724A patent/KR910002464B1/ko not_active Expired
- 1985-11-21 FR FR858517256A patent/FR2573431B1/fr not_active Expired
- 1985-11-21 CN CN85109197.0A patent/CN1003590B/zh not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5437910A (en) * | 1977-08-31 | 1979-03-20 | Ishikawajima Kenzai Kogyo Kk | Method of installing internal bag for underground water reservior |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH08171234A (ja) * | 1995-06-26 | 1996-07-02 | Canon Inc | 画像形成方法 |
| WO2002081608A3 (en) * | 2001-04-02 | 2003-03-06 | Nippon Catalytic Chem Ind | Method for producing chemical reactive substance and polycarboxylic acid produced thereby |
| US6825289B2 (en) | 2001-04-02 | 2004-11-30 | Nippon Shokubai Co., Ltd. | Method for producing chemical reactive substance and polycarboxylic acid produced thereby |
| JP2009507119A (ja) * | 2005-09-07 | 2009-02-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 重合法 |
| JP2009507117A (ja) * | 2005-09-07 | 2009-02-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 重合法 |
| JP2009507118A (ja) * | 2005-09-07 | 2009-02-19 | ビーエーエスエフ ソシエタス・ヨーロピア | 重合法 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2173203B (en) | 1988-08-03 |
| DE3540994C2 (de) | 1994-11-03 |
| DE3540994A1 (de) | 1986-05-22 |
| KR860004087A (ko) | 1986-06-18 |
| US4656232A (en) | 1987-04-07 |
| KR910002464B1 (ko) | 1991-04-23 |
| FR2573431A1 (fr) | 1986-05-23 |
| CN85109197A (zh) | 1986-05-10 |
| FR2573431B1 (fr) | 1989-12-01 |
| GB8528677D0 (en) | 1985-12-24 |
| CN1003590B (zh) | 1989-03-15 |
| JPH0214362B2 (enExample) | 1990-04-06 |
| GB2173203A (en) | 1986-10-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS61126103A (ja) | 重合体の製造法 | |
| US4625001A (en) | Method for continuous production of cross-linked polymer | |
| JP2749495B2 (ja) | 高濃度オゾン水製造方法及び高濃度オゾン水製造装置 | |
| DE3760674D1 (en) | Process for discontinually preparing fine particles of cured polymers | |
| JPS6029320B2 (ja) | 集塵方法 | |
| KR101863464B1 (ko) | 역상 중합 방법 | |
| CN105612186A (zh) | 反相聚合方法 | |
| KR100449195B1 (ko) | 잔류단량체제거장치및방법 | |
| US4528337A (en) | Process and apparatus for manufacturing vinyl chloride polymers | |
| US4743664A (en) | Process for producing α,β-unsaturated carboxylic acid polymer | |
| SU580844A3 (ru) | Способ получени полимера или сополимера акролонитрила | |
| CN112705061A (zh) | 一种盘式超微气泡发生器 | |
| US2847405A (en) | Continuous process for the polymerization of acrylonitrile | |
| US20180022837A1 (en) | Reverse-phase polymerisation process incorporating a microfluidic device | |
| JPH02138306A (ja) | 吸水性樹脂の製造法 | |
| CN209481258U (zh) | 一种净水剂的添加系统 | |
| RU2006131296A (ru) | Способ непрерывного получения водорастворимого полимера и водорастворимый полимер | |
| JP4312316B2 (ja) | エチレン性不飽和単量体の投入方法 | |
| JPS63141632A (ja) | 気体を液体に接触させる方法 | |
| CN217148840U (zh) | 一种水处理用消毒装置 | |
| US6716273B1 (en) | Method and device for eliminating oxygen contained in aqueous monomer solutions | |
| CN210103606U (zh) | 污水池聚合物沉降浓度调节装置 | |
| JPS6132043B2 (enExample) | ||
| JPH05310815A (ja) | ビニル系単量体の回収法 | |
| JPH05146236A (ja) | 水生生物育成装置 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |