JPS6096734A - 廃マンガン乾電池より有価物の完全回収法 - Google Patents
廃マンガン乾電池より有価物の完全回収法Info
- Publication number
- JPS6096734A JPS6096734A JP58205258A JP20525883A JPS6096734A JP S6096734 A JPS6096734 A JP S6096734A JP 58205258 A JP58205258 A JP 58205258A JP 20525883 A JP20525883 A JP 20525883A JP S6096734 A JPS6096734 A JP S6096734A
- Authority
- JP
- Japan
- Prior art keywords
- recovered
- manganese
- dry battery
- graphite
- heating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 27
- 239000011572 manganese Substances 0.000 title claims description 29
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims description 17
- 239000002699 waste material Substances 0.000 title claims description 11
- 238000011084 recovery Methods 0.000 title claims description 5
- 238000010438 heat treatment Methods 0.000 claims abstract description 29
- 229910052742 iron Inorganic materials 0.000 claims abstract description 21
- 229910052751 metal Inorganic materials 0.000 claims abstract description 20
- 239000002184 metal Substances 0.000 claims abstract description 20
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims abstract description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 14
- 239000010439 graphite Substances 0.000 claims abstract description 14
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000007787 solid Substances 0.000 claims abstract description 12
- 238000001816 cooling Methods 0.000 claims abstract description 3
- 238000001914 filtration Methods 0.000 claims abstract description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 35
- 239000011701 zinc Substances 0.000 claims description 22
- 229910052725 zinc Inorganic materials 0.000 claims description 16
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 14
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 238000007885 magnetic separation Methods 0.000 claims description 4
- 150000002736 metal compounds Chemical class 0.000 claims description 3
- 229910052793 cadmium Inorganic materials 0.000 abstract description 12
- 229910052753 mercury Inorganic materials 0.000 abstract description 8
- 230000002829 reductive effect Effects 0.000 abstract description 2
- 238000005188 flotation Methods 0.000 abstract 1
- 239000012071 phase Substances 0.000 description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 11
- 239000000243 solution Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 8
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 6
- 239000007789 gas Substances 0.000 description 5
- 229940099596 manganese sulfate Drugs 0.000 description 5
- 239000011702 manganese sulphate Substances 0.000 description 5
- 235000007079 manganese sulphate Nutrition 0.000 description 5
- 150000002739 metals Chemical class 0.000 description 5
- 239000007790 solid phase Substances 0.000 description 5
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 4
- 235000011114 ammonium hydroxide Nutrition 0.000 description 4
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 4
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011343 solid material Substances 0.000 description 3
- 239000011592 zinc chloride Substances 0.000 description 3
- 235000005074 zinc chloride Nutrition 0.000 description 3
- 150000003752 zinc compounds Chemical class 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052745 lead Inorganic materials 0.000 description 2
- 239000000155 melt Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 239000006148 magnetic separator Substances 0.000 description 1
- 229910000357 manganese(II) sulfate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
- Manufacture And Refinement Of Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58205258A JPS6096734A (ja) | 1983-11-01 | 1983-11-01 | 廃マンガン乾電池より有価物の完全回収法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58205258A JPS6096734A (ja) | 1983-11-01 | 1983-11-01 | 廃マンガン乾電池より有価物の完全回収法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6096734A true JPS6096734A (ja) | 1985-05-30 |
| JPH0361730B2 JPH0361730B2 (enrdf_load_stackoverflow) | 1991-09-20 |
Family
ID=16504004
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58205258A Granted JPS6096734A (ja) | 1983-11-01 | 1983-11-01 | 廃マンガン乾電池より有価物の完全回収法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6096734A (enrdf_load_stackoverflow) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003029148A2 (fr) | 2001-10-01 | 2003-04-10 | Erachem Comilog | Procede de preparation d'oxyde mixte de zinc et de manganese |
| JP2007012527A (ja) * | 2005-07-01 | 2007-01-18 | Jfe Kankyo Corp | 廃乾電池からの冶金原料の回収方法 |
| CN100431720C (zh) * | 2003-03-14 | 2008-11-12 | 于之涛 | 利用废旧锌锰干电池生产金属化合物的方法 |
| JP2011105581A (ja) * | 2009-11-20 | 2011-06-02 | Korea Inst Of Geoscience & Mineral Resources | マンガン及び亜鉛を含有する廃電池からの硫酸マンガン及び硫酸亜鉛の製造方法 |
| RU2486262C2 (ru) * | 2011-09-09 | 2013-06-27 | Закрытое акционерное общество "Экология" | Способ утилизации отработанных химических источников тока |
| JP2014201784A (ja) * | 2013-04-03 | 2014-10-27 | 東邦亜鉛株式会社 | 金属回収方法 |
| JP2019530795A (ja) * | 2016-10-31 | 2019-10-24 | 湖南金源新材料股▲ふん▼有限公司 | 電池廃棄物による硫酸ニッケル、硫酸マンガン、硫酸リチウム、硫酸コバルト及び四酸化三コバルトの製造方法 |
-
1983
- 1983-11-01 JP JP58205258A patent/JPS6096734A/ja active Granted
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003029148A2 (fr) | 2001-10-01 | 2003-04-10 | Erachem Comilog | Procede de preparation d'oxyde mixte de zinc et de manganese |
| CN100431720C (zh) * | 2003-03-14 | 2008-11-12 | 于之涛 | 利用废旧锌锰干电池生产金属化合物的方法 |
| JP2007012527A (ja) * | 2005-07-01 | 2007-01-18 | Jfe Kankyo Corp | 廃乾電池からの冶金原料の回収方法 |
| JP2011105581A (ja) * | 2009-11-20 | 2011-06-02 | Korea Inst Of Geoscience & Mineral Resources | マンガン及び亜鉛を含有する廃電池からの硫酸マンガン及び硫酸亜鉛の製造方法 |
| RU2486262C2 (ru) * | 2011-09-09 | 2013-06-27 | Закрытое акционерное общество "Экология" | Способ утилизации отработанных химических источников тока |
| JP2014201784A (ja) * | 2013-04-03 | 2014-10-27 | 東邦亜鉛株式会社 | 金属回収方法 |
| JP2019530795A (ja) * | 2016-10-31 | 2019-10-24 | 湖南金源新材料股▲ふん▼有限公司 | 電池廃棄物による硫酸ニッケル、硫酸マンガン、硫酸リチウム、硫酸コバルト及び四酸化三コバルトの製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0361730B2 (enrdf_load_stackoverflow) | 1991-09-20 |
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