JPS6090089A - 水中のフツ素イオンの除去方法 - Google Patents
水中のフツ素イオンの除去方法Info
- Publication number
- JPS6090089A JPS6090089A JP19804183A JP19804183A JPS6090089A JP S6090089 A JPS6090089 A JP S6090089A JP 19804183 A JP19804183 A JP 19804183A JP 19804183 A JP19804183 A JP 19804183A JP S6090089 A JPS6090089 A JP S6090089A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- water
- fluorine
- ions
- ion
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 18
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 title abstract description 6
- -1 aminoalkylene phosphate Chemical compound 0.000 claims abstract description 33
- 239000003463 adsorbent Substances 0.000 claims abstract description 11
- 229910021645 metal ion Inorganic materials 0.000 claims abstract description 6
- 239000011737 fluorine Substances 0.000 claims description 17
- 229910052731 fluorine Inorganic materials 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 13
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 5
- 238000007788 roughening Methods 0.000 claims description 3
- 239000011347 resin Substances 0.000 abstract description 29
- 229920005989 resin Polymers 0.000 abstract description 29
- 239000013522 chelant Substances 0.000 abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 abstract description 7
- 229910019142 PO4 Inorganic materials 0.000 abstract description 5
- 239000010452 phosphate Substances 0.000 abstract description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 4
- 229910052742 iron Inorganic materials 0.000 abstract description 4
- 229920000178 Acrylic resin Polymers 0.000 abstract description 3
- 239000004925 Acrylic resin Substances 0.000 abstract description 3
- 239000003822 epoxy resin Substances 0.000 abstract description 3
- 125000000524 functional group Chemical group 0.000 abstract description 3
- 229920000647 polyepoxide Polymers 0.000 abstract description 3
- 239000005909 Kieselgur Substances 0.000 abstract description 2
- 229910021536 Zeolite Inorganic materials 0.000 abstract description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 abstract description 2
- 239000000741 silica gel Substances 0.000 abstract description 2
- 229910002027 silica gel Inorganic materials 0.000 abstract description 2
- 239000010457 zeolite Substances 0.000 abstract description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 abstract 1
- WESWKIRSMKBCAJ-UHFFFAOYSA-N [F].[Fe] Chemical compound [F].[Fe] WESWKIRSMKBCAJ-UHFFFAOYSA-N 0.000 abstract 1
- 239000007788 liquid Substances 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 4
- 239000011575 calcium Substances 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- JQSXBKFLDFIUPJ-UHFFFAOYSA-N 2-hydroxy-2-oxo-1,3,2lambda5-dioxaphosphetan-4-amine Chemical compound NC1OP(O)(=O)O1 JQSXBKFLDFIUPJ-UHFFFAOYSA-N 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- XBPMMPWZSQVGAJ-UHFFFAOYSA-N [La].[I] Chemical compound [La].[I] XBPMMPWZSQVGAJ-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 235000011116 calcium hydroxide Nutrition 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- 241001070941 Castanea Species 0.000 description 1
- 235000014036 Castanea Nutrition 0.000 description 1
- 239000007832 Na2SO4 Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 125000006294 amino alkylene group Chemical group 0.000 description 1
- 229910001570 bauxite Inorganic materials 0.000 description 1
- 210000000988 bone and bone Anatomy 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- 229910021644 lanthanide ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 230000008929 regeneration Effects 0.000 description 1
- 238000011069 regeneration method Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Landscapes
- Treatment Of Water By Ion Exchange (AREA)
- Water Treatment By Sorption (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19804183A JPS6090089A (ja) | 1983-10-22 | 1983-10-22 | 水中のフツ素イオンの除去方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP19804183A JPS6090089A (ja) | 1983-10-22 | 1983-10-22 | 水中のフツ素イオンの除去方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6090089A true JPS6090089A (ja) | 1985-05-21 |
| JPH0336592B2 JPH0336592B2 (en, 2012) | 1991-05-31 |
Family
ID=16384549
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP19804183A Granted JPS6090089A (ja) | 1983-10-22 | 1983-10-22 | 水中のフツ素イオンの除去方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6090089A (en, 2012) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006314957A (ja) * | 2005-05-13 | 2006-11-24 | Japan Organo Co Ltd | フッ素吸着剤を用いた水中のフッ素除去方法 |
| US9573660B2 (en) | 2012-02-06 | 2017-02-21 | Sbm Schiedam B.V. | Traction system for operating lines of a vessel |
| CN106430375A (zh) * | 2016-12-22 | 2017-02-22 | 郑州丽福爱生物技术有限公司 | 一种城乡污染河流治理用污水处理剂及其制备方法 |
| CN113073194A (zh) * | 2021-03-03 | 2021-07-06 | 安徽南都华铂新材料科技有限公司 | 一种废旧锂电池回收利用的除氟工艺 |
-
1983
- 1983-10-22 JP JP19804183A patent/JPS6090089A/ja active Granted
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006314957A (ja) * | 2005-05-13 | 2006-11-24 | Japan Organo Co Ltd | フッ素吸着剤を用いた水中のフッ素除去方法 |
| US9573660B2 (en) | 2012-02-06 | 2017-02-21 | Sbm Schiedam B.V. | Traction system for operating lines of a vessel |
| CN106430375A (zh) * | 2016-12-22 | 2017-02-22 | 郑州丽福爱生物技术有限公司 | 一种城乡污染河流治理用污水处理剂及其制备方法 |
| CN113073194A (zh) * | 2021-03-03 | 2021-07-06 | 安徽南都华铂新材料科技有限公司 | 一种废旧锂电池回收利用的除氟工艺 |
| CN113073194B (zh) * | 2021-03-03 | 2022-09-09 | 安徽南都华铂新材料科技有限公司 | 一种废旧锂电池回收利用的除氟工艺 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0336592B2 (en, 2012) | 1991-05-31 |
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