JPS6048451B2 - ガリウム回収法 - Google Patents
ガリウム回収法Info
- Publication number
- JPS6048451B2 JPS6048451B2 JP52114480A JP11448077A JPS6048451B2 JP S6048451 B2 JPS6048451 B2 JP S6048451B2 JP 52114480 A JP52114480 A JP 52114480A JP 11448077 A JP11448077 A JP 11448077A JP S6048451 B2 JPS6048451 B2 JP S6048451B2
- Authority
- JP
- Japan
- Prior art keywords
- organic phase
- gallium
- aqueous
- acid
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229910052733 gallium Inorganic materials 0.000 title claims description 63
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 title claims description 62
- 238000000034 method Methods 0.000 title claims description 43
- 238000011084 recovery Methods 0.000 title description 12
- 239000012074 organic phase Substances 0.000 claims description 64
- 239000000243 solution Substances 0.000 claims description 36
- 239000008346 aqueous phase Substances 0.000 claims description 27
- 239000002253 acid Substances 0.000 claims description 25
- 229910052782 aluminium Inorganic materials 0.000 claims description 21
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 21
- 239000007864 aqueous solution Substances 0.000 claims description 21
- 239000011734 sodium Substances 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 20
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 20
- 229910052708 sodium Inorganic materials 0.000 claims description 20
- MCJGNVYPOGVAJF-UHFFFAOYSA-N quinolin-8-ol Chemical group C1=CN=C2C(O)=CC=CC2=C1 MCJGNVYPOGVAJF-UHFFFAOYSA-N 0.000 claims description 17
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 claims description 11
- 229910001388 sodium aluminate Inorganic materials 0.000 claims description 11
- 239000005725 8-Hydroxyquinoline Substances 0.000 claims description 10
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 10
- 229960003540 oxyquinoline Drugs 0.000 claims description 10
- 150000004325 8-hydroxyquinolines Chemical class 0.000 claims description 9
- 239000012071 phase Substances 0.000 claims description 9
- 239000003960 organic solvent Substances 0.000 claims description 8
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 239000011260 aqueous acid Substances 0.000 claims description 6
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims description 5
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 5
- 150000004645 aluminates Chemical class 0.000 claims description 5
- 229910017604 nitric acid Inorganic materials 0.000 claims description 5
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 claims description 4
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 4
- 238000000622 liquid--liquid extraction Methods 0.000 claims description 4
- 238000000638 solvent extraction Methods 0.000 claims description 4
- 238000004131 Bayer process Methods 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 125000000129 anionic group Chemical group 0.000 claims description 2
- 238000004519 manufacturing process Methods 0.000 claims 3
- 125000001931 aliphatic group Chemical group 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 239000003925 fat Substances 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 claims 1
- 239000001257 hydrogen Substances 0.000 claims 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 1
- 238000000605 extraction Methods 0.000 description 16
- 239000000203 mixture Substances 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000012670 alkaline solution Substances 0.000 description 5
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 4
- -1 alkenyl 8-hydroxyquinoline Chemical compound 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000001172 regenerating effect Effects 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 2
- 230000001476 alcoholic effect Effects 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 239000003637 basic solution Substances 0.000 description 2
- 239000002738 chelating agent Substances 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052593 corundum Inorganic materials 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- FNXKBSAUKFCXIK-UHFFFAOYSA-M sodium;hydrogen carbonate;8-hydroxy-7-iodoquinoline-5-sulfonic acid Chemical class [Na+].OC([O-])=O.C1=CN=C2C(O)=C(I)C=C(S(O)(=O)=O)C2=C1 FNXKBSAUKFCXIK-UHFFFAOYSA-M 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229910001845 yogo sapphire Inorganic materials 0.000 description 2
- PLLBRTOLHQQAQQ-UHFFFAOYSA-N 8-methylnonan-1-ol Chemical compound CC(C)CCCCCCCO PLLBRTOLHQQAQQ-UHFFFAOYSA-N 0.000 description 1
- 241000132007 Bahia Species 0.000 description 1
- 229930194845 Bahia Natural products 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 235000017858 Laurus nobilis Nutrition 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 239000006286 aqueous extract Substances 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000008139 complexing agent Substances 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G15/00—Compounds of gallium, indium or thallium
- C01G15/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/02—Aluminium oxide; Aluminium hydroxide; Aluminates
- C01F7/46—Purification of aluminium oxide, aluminium hydroxide or aluminates
- C01F7/47—Purification of aluminium oxide, aluminium hydroxide or aluminates of aluminates, e.g. removal of compounds of Si, Fe, Ga or of organic compounds from Bayer process liquors
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/36—Heterocyclic compounds
- C22B3/362—Heterocyclic compounds of a single type
- C22B3/364—Quinoline
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Geochemistry & Mineralogy (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Extraction Or Liquid Replacement (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR7629009A FR2365641A2 (fr) | 1976-09-27 | 1976-09-27 | Procede de recuperation du gallium de solutions tres basiques par extraction liquide/liquide |
| FR7629009 | 1976-09-27 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5352289A JPS5352289A (en) | 1978-05-12 |
| JPS6048451B2 true JPS6048451B2 (ja) | 1985-10-28 |
Family
ID=9178124
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52114480A Expired JPS6048451B2 (ja) | 1976-09-27 | 1977-09-22 | ガリウム回収法 |
Country Status (11)
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2411894A1 (fr) * | 1977-12-15 | 1979-07-13 | Rhone Poulenc Ind | Procede d'extraction du gallium |
| AU560201B2 (en) * | 1981-09-17 | 1987-04-02 | Sumitomo Chemical Company, Limited | Gallium recovery |
| FR2532296B1 (fr) * | 1982-08-26 | 1985-06-07 | Rhone Poulenc Spec Chim | Procede d'extraction du gallium a l'aide d'hydroxyquinoleines substituees et de composes organophosphores |
| FR2532295A1 (fr) * | 1982-08-26 | 1984-03-02 | Rhone Poulenc Spec Chim | Procede d'extraction du gallium a l'aide d'hydroxyquinoleines substituees et de sulfates ou sulfonates substitues |
| JPS6042234A (ja) * | 1983-08-11 | 1985-03-06 | Mitsubishi Chem Ind Ltd | ガリウムの回収法 |
| CH656643A5 (de) * | 1983-11-29 | 1986-07-15 | Sulzer Ag | Verfahren zur fluessig-fluessig-extraktion von gallium aus basischen, waessrigen loesungen mit hilfe eines organischen extraktionsmittels. |
| CN1012812B (zh) * | 1986-01-31 | 1991-06-12 | 三菱化成株式会社 | 镓的回收方法 |
| CA1306612C (en) * | 1986-09-08 | 1992-08-25 | Vaikuntam I. Lakshmanan | Process for treatment of flyash |
| FR2614887B1 (fr) * | 1987-05-06 | 1990-11-30 | Rhone Poulenc Chimie | Procede de recuperation de gallium par extraction liquide-liquide |
| FR2616157A1 (fr) * | 1987-06-02 | 1988-12-09 | Pechiney Aluminium | Procede d'extraction et de purification du gallium des liqueurs bayer |
| DE3719437A1 (de) * | 1987-06-11 | 1988-12-22 | Hoechst Ag | Verfahren zur gewinnung von gallium aus basisch waessrigen natriumaluminatloesungen durch fluessig-fluessigextraktion |
| FR2620695B1 (fr) * | 1987-09-21 | 1990-01-05 | Rhone Poulenc Chimie | Procede de recuperation de gallium par extraction liquide-liquide |
| LU87108A1 (fr) * | 1988-01-18 | 1989-08-30 | Metallurgie Hoboken | Procede d'extraction de metal |
| GB8915959D0 (en) * | 1989-07-12 | 1989-08-31 | Ici Plc | Heterocyclic thione |
| FR2654439B1 (fr) * | 1989-11-15 | 1992-02-07 | Rhone Poulenc Chimie | Procede de recuperation de gallium a partir de solutions basiques les contenant. |
| DE4014015A1 (de) * | 1990-04-27 | 1991-11-14 | Schering Ag | Verfahren zur herstellung von chelatisierenden ionenaustaucherharzen und deren verwendung zur extraktion von metallen |
| US5221525A (en) * | 1991-04-26 | 1993-06-22 | N. A. Degerstrom, Inc. | Solvent extraction of gallium from acidic solutions containing phosphorus |
| US5484470A (en) * | 1994-07-28 | 1996-01-16 | E. I. Du Pont De Nemours And Company | Enhancement of gold lixiviation using nitrogen and sulfur heterocyclic aromatic compounds |
| BRPI0709451A2 (pt) * | 2006-03-31 | 2011-07-12 | Alcoa Australia | método para o controle da precipitação de alumina de soluções do processo bayer e solvente orgánico |
| DE102013013876A1 (de) | 2013-08-20 | 2015-03-12 | Merck Patent Gmbh | Metallkomplexe |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3637711A (en) * | 1968-03-25 | 1972-01-25 | Ashland Oil Inc | Beta-alkenyl substituted 8-hydroxyquinolines |
| US3971843A (en) * | 1974-07-12 | 1976-07-27 | Rhone-Poulenc Industries | Process for liquid/liquid extraction of gallium |
| FR2532296B1 (fr) * | 1982-08-26 | 1985-06-07 | Rhone Poulenc Spec Chim | Procede d'extraction du gallium a l'aide d'hydroxyquinoleines substituees et de composes organophosphores |
| CH655710A5 (de) * | 1983-11-17 | 1986-05-15 | Sulzer Ag | Verfahren zur fluessig-fluessig-extraktion von gallium aus natriumaluminatloesung mit hilfe eines organischen extraktionsmittels. |
-
1976
- 1976-09-27 FR FR7629009A patent/FR2365641A2/fr active Granted
-
1977
- 1977-09-22 JP JP52114480A patent/JPS6048451B2/ja not_active Expired
- 1977-09-23 CA CA287,402A patent/CA1099522A/en not_active Expired
- 1977-09-26 GB GB40017/77A patent/GB1593289A/en not_active Expired
- 1977-09-26 AU AU29097/77A patent/AU513388B2/en not_active Expired
- 1977-09-26 CH CH1174277A patent/CH610931A5/xx not_active IP Right Cessation
- 1977-09-26 YU YU2276/77A patent/YU39821B/xx unknown
- 1977-09-27 DE DE19772743475 patent/DE2743475A1/de not_active Withdrawn
- 1977-09-27 IT IT51155/77A patent/IT1116115B/it active
- 1977-09-27 ES ES462677A patent/ES462677A1/es not_active Expired
-
1986
- 1986-12-03 US US06/937,239 patent/US4724129A/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5352289A (en) | 1978-05-12 |
| AU2909777A (en) | 1979-04-05 |
| FR2365641A2 (fr) | 1978-04-21 |
| CH610931A5 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1979-05-15 |
| FR2365641B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1981-11-13 |
| US4724129A (en) | 1988-02-09 |
| DE2743475A1 (de) | 1978-03-30 |
| IT1116115B (it) | 1986-02-10 |
| ES462677A1 (es) | 1978-06-16 |
| AU513388B2 (en) | 1980-11-27 |
| YU39821B (en) | 1985-04-30 |
| GB1593289A (en) | 1981-07-15 |
| YU227677A (en) | 1982-08-31 |
| CA1099522A (en) | 1981-04-21 |
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