JPS6045274B2 - 金属析出物の化学的剥離用組成物および方法 - Google Patents
金属析出物の化学的剥離用組成物および方法Info
- Publication number
- JPS6045274B2 JPS6045274B2 JP55158043A JP15804380A JPS6045274B2 JP S6045274 B2 JPS6045274 B2 JP S6045274B2 JP 55158043 A JP55158043 A JP 55158043A JP 15804380 A JP15804380 A JP 15804380A JP S6045274 B2 JPS6045274 B2 JP S6045274B2
- Authority
- JP
- Japan
- Prior art keywords
- ions
- nickel
- composition according
- stripping
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims description 43
- 229910052751 metal Inorganic materials 0.000 title claims description 27
- 239000002184 metal Substances 0.000 title claims description 27
- 238000000034 method Methods 0.000 title claims description 22
- 239000000126 substance Substances 0.000 title claims description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 63
- 239000000243 solution Substances 0.000 claims description 33
- 229910052759 nickel Inorganic materials 0.000 claims description 28
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 21
- 229910017604 nitric acid Inorganic materials 0.000 claims description 21
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 16
- 239000010949 copper Substances 0.000 claims description 16
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 15
- 229910052802 copper Inorganic materials 0.000 claims description 15
- 150000002500 ions Chemical class 0.000 claims description 13
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 11
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 claims description 11
- 229910001448 ferrous ion Inorganic materials 0.000 claims description 9
- 229910001096 P alloy Inorganic materials 0.000 claims description 8
- 229910001453 nickel ion Inorganic materials 0.000 claims description 8
- OFNHPGDEEMZPFG-UHFFFAOYSA-N phosphanylidynenickel Chemical compound [P].[Ni] OFNHPGDEEMZPFG-UHFFFAOYSA-N 0.000 claims description 8
- VEQPNABPJHWNSG-UHFFFAOYSA-N Nickel(2+) Chemical compound [Ni+2] VEQPNABPJHWNSG-UHFFFAOYSA-N 0.000 claims description 7
- 239000002244 precipitate Substances 0.000 claims description 6
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 5
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052793 cadmium Inorganic materials 0.000 claims description 5
- BDOSMKKIYDKNTQ-UHFFFAOYSA-N cadmium atom Chemical compound [Cd] BDOSMKKIYDKNTQ-UHFFFAOYSA-N 0.000 claims description 5
- 229910021645 metal ion Inorganic materials 0.000 claims description 5
- 239000011135 tin Substances 0.000 claims description 5
- 229910052718 tin Inorganic materials 0.000 claims description 5
- 229910052725 zinc Inorganic materials 0.000 claims description 5
- 239000011701 zinc Substances 0.000 claims description 5
- 229910001369 Brass Inorganic materials 0.000 claims description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 4
- 239000010951 brass Substances 0.000 claims description 4
- 239000011651 chromium Substances 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052703 rhodium Inorganic materials 0.000 claims description 4
- 239000010948 rhodium Substances 0.000 claims description 4
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 4
- JPVYNHNXODAKFH-UHFFFAOYSA-N Cu2+ Chemical compound [Cu+2] JPVYNHNXODAKFH-UHFFFAOYSA-N 0.000 claims description 3
- WAEMQWOKJMHJLA-UHFFFAOYSA-N Manganese(2+) Chemical compound [Mn+2] WAEMQWOKJMHJLA-UHFFFAOYSA-N 0.000 claims description 3
- 239000003929 acidic solution Substances 0.000 claims description 3
- 230000000977 initiatory effect Effects 0.000 claims description 3
- 229910001437 manganese ion Inorganic materials 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 2
- 238000004299 exfoliation Methods 0.000 claims 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 8
- -1 alkali metal salts Chemical class 0.000 description 8
- 238000007747 plating Methods 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 6
- 230000008901 benefit Effects 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 239000011780 sodium chloride Substances 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- 229910000640 Fe alloy Inorganic materials 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 238000009713 electroplating Methods 0.000 description 3
- UGKDIUIOSMUOAW-UHFFFAOYSA-N iron nickel Chemical compound [Fe].[Ni] UGKDIUIOSMUOAW-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- FAYIWMIPOUXCOX-UHFFFAOYSA-L B(O)(O)O.[Ni](Cl)Cl Chemical compound B(O)(O)O.[Ni](Cl)Cl FAYIWMIPOUXCOX-UHFFFAOYSA-L 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 229910021380 Manganese Chloride Inorganic materials 0.000 description 2
- GLFNIEUTAYBVOC-UHFFFAOYSA-L Manganese chloride Chemical compound Cl[Mn]Cl GLFNIEUTAYBVOC-UHFFFAOYSA-L 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 229910001431 copper ion Inorganic materials 0.000 description 2
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 description 2
- 229960002089 ferrous chloride Drugs 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 description 2
- XBDUTCVQJHJTQZ-UHFFFAOYSA-L iron(2+) sulfate monohydrate Chemical compound O.[Fe+2].[O-]S([O-])(=O)=O XBDUTCVQJHJTQZ-UHFFFAOYSA-L 0.000 description 2
- 235000002867 manganese chloride Nutrition 0.000 description 2
- 239000011565 manganese chloride Substances 0.000 description 2
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical compound [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 2
- VASIZKWUTCETSD-UHFFFAOYSA-N manganese(II) oxide Inorganic materials [Mn]=O VASIZKWUTCETSD-UHFFFAOYSA-N 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- WYOHYGGHYATVOZ-UHFFFAOYSA-L nickel(2+);sulfate;pentahydrate Chemical compound O.O.O.O.O.[Ni+2].[O-]S([O-])(=O)=O WYOHYGGHYATVOZ-UHFFFAOYSA-L 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- 229920001944 Plastisol Polymers 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 235000011130 ammonium sulphate Nutrition 0.000 description 1
- 239000011260 aqueous acid Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 1
- 229910000366 copper(II) sulfate Inorganic materials 0.000 description 1
- JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
- 229960003280 cupric chloride Drugs 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 229940099596 manganese sulfate Drugs 0.000 description 1
- 235000007079 manganese sulphate Nutrition 0.000 description 1
- 239000011702 manganese sulphate Substances 0.000 description 1
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 1
- ISPYRSDWRDQNSW-UHFFFAOYSA-L manganese(II) sulfate monohydrate Chemical compound O.[Mn+2].[O-]S([O-])(=O)=O ISPYRSDWRDQNSW-UHFFFAOYSA-L 0.000 description 1
- BZDIAFGKSAYYFC-UHFFFAOYSA-N manganese;hydrate Chemical compound O.[Mn] BZDIAFGKSAYYFC-UHFFFAOYSA-N 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical compound Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 description 1
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 description 1
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 description 1
- 239000004999 plastisol Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
- C23F1/00—Etching metallic material by chemical means
- C23F1/44—Compositions for etching metallic material from a metallic material substrate of different composition
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- ing And Chemical Polishing (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US06/094,617 US4244833A (en) | 1979-11-15 | 1979-11-15 | Composition and process for chemically stripping metallic deposits |
| US94617 | 1987-09-09 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5684477A JPS5684477A (en) | 1981-07-09 |
| JPS6045274B2 true JPS6045274B2 (ja) | 1985-10-08 |
Family
ID=22246187
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP55158043A Expired JPS6045274B2 (ja) | 1979-11-15 | 1980-11-10 | 金属析出物の化学的剥離用組成物および方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US4244833A (show.php) |
| JP (1) | JPS6045274B2 (show.php) |
| AR (1) | AR223719A1 (show.php) |
| AU (1) | AU531247B2 (show.php) |
| BR (1) | BR8005840A (show.php) |
| CA (1) | CA1137396A (show.php) |
| DE (1) | DE3030919A1 (show.php) |
| ES (1) | ES494329A0 (show.php) |
| FR (1) | FR2469443A1 (show.php) |
| GB (1) | GB2063923B (show.php) |
| IT (1) | IT1142184B (show.php) |
| MX (1) | MX154502A (show.php) |
| NL (1) | NL8004320A (show.php) |
Families Citing this family (18)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4289576A (en) * | 1980-05-27 | 1981-09-15 | Halliburton Company | Method for removing cobalt-containing deposits from surfaces |
| US4402800A (en) * | 1981-10-02 | 1983-09-06 | Ash James J | Apparatus and method of treating tabs of printed circuit boards and the like |
| US4402799A (en) * | 1981-10-02 | 1983-09-06 | Chemcut Corporation | Apparatus and method of treating tabs of printed circuit boards and the like |
| US4385967A (en) * | 1981-10-07 | 1983-05-31 | Chemcut Corporation | Electroplating apparatus and method |
| US4746369A (en) * | 1982-01-11 | 1988-05-24 | Enthone, Incorporated | Peroxide selective stripping compositions and method |
| US4608091A (en) * | 1982-01-11 | 1986-08-26 | Enthone, Incorporated | Peroxide selective stripping compositions and method |
| US4404074A (en) * | 1982-05-27 | 1983-09-13 | Occidental Chemical Corporation | Electrolytic stripping bath and process |
| US4554049A (en) * | 1984-06-07 | 1985-11-19 | Enthone, Incorporated | Selective nickel stripping compositions and method of stripping |
| US4666625A (en) * | 1984-11-27 | 1987-05-19 | The Drackett Company | Method of cleaning clogged drains |
| CH674851A5 (show.php) * | 1987-12-01 | 1990-07-31 | Bbc Brown Boveri & Cie | |
| US5227016A (en) * | 1992-02-25 | 1993-07-13 | Henkel Corporation | Process and composition for desmutting surfaces of aluminum and its alloys |
| JPH1072682A (ja) * | 1996-08-30 | 1998-03-17 | Mec Kk | 錫および錫合金の剥離液 |
| GB2334969B (en) * | 1998-03-05 | 2003-03-12 | British Steel Plc | Coated metal products |
| US7285229B2 (en) * | 2003-11-07 | 2007-10-23 | Mec Company, Ltd. | Etchant and replenishment solution therefor, and etching method and method for producing wiring board using the same |
| JP4827252B2 (ja) * | 2006-09-25 | 2011-11-30 | ダイハツ工業株式会社 | 車両の車体構造 |
| CA2808981A1 (en) * | 2013-03-05 | 2014-09-05 | Sherritt International Corporation | Method of recovering metals while mitigating corrosion |
| CN106715763B (zh) * | 2015-03-13 | 2019-06-07 | 奥野制药工业株式会社 | 夹具用电解剥离剂 |
| CN117364091A (zh) * | 2023-09-26 | 2024-01-09 | 江门市瑞期精细化学工程有限公司 | 一种电镀层剥离液及其制备方法和应用 |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2200486A (en) * | 1939-05-10 | 1940-05-14 | Western Electric Co | Material and method for removing coatings of nickel or the like from a metal base |
| US3015630A (en) * | 1959-08-24 | 1962-01-02 | Gen Electric | Aqueous solution for stripping nickel |
| US3367874A (en) * | 1966-09-23 | 1968-02-06 | Haviland Products Co | Process and composition for acid dissolution of metals |
| GB1353960A (en) * | 1971-09-21 | 1974-05-22 | Rolls Royce | Method of etching a partially masked surface |
| US3856694A (en) * | 1973-06-18 | 1974-12-24 | Oxy Metal Finishing Corp | Process for stripping nickel from articles and composition utilized therein |
| GB1518038A (en) * | 1975-12-19 | 1978-07-19 | Sterling Drug Inc | Process for removing calcium oxalate scale |
-
1979
- 1979-11-15 US US06/094,617 patent/US4244833A/en not_active Expired - Lifetime
-
1980
- 1980-07-15 CA CA000356214A patent/CA1137396A/en not_active Expired
- 1980-07-24 AU AU60758/80A patent/AU531247B2/en not_active Expired - Fee Related
- 1980-07-28 NL NL8004320A patent/NL8004320A/nl not_active Application Discontinuation
- 1980-07-30 AR AR281983A patent/AR223719A1/es active
- 1980-08-16 DE DE19803030919 patent/DE3030919A1/de not_active Ceased
- 1980-08-18 ES ES494329A patent/ES494329A0/es active Granted
- 1980-09-12 BR BR8005840A patent/BR8005840A/pt unknown
- 1980-09-25 FR FR8020643A patent/FR2469443A1/fr active Granted
- 1980-10-28 GB GB8034590A patent/GB2063923B/en not_active Expired
- 1980-11-10 JP JP55158043A patent/JPS6045274B2/ja not_active Expired
- 1980-11-13 IT IT50149/80A patent/IT1142184B/it active
- 1980-11-14 MX MX184773A patent/MX154502A/es unknown
Also Published As
| Publication number | Publication date |
|---|---|
| ES8105791A1 (es) | 1981-06-16 |
| BR8005840A (pt) | 1981-06-09 |
| DE3030919A1 (de) | 1981-05-21 |
| MX154502A (es) | 1987-09-24 |
| US4244833A (en) | 1981-01-13 |
| FR2469443A1 (fr) | 1981-05-22 |
| FR2469443B1 (show.php) | 1984-01-27 |
| ES494329A0 (es) | 1981-06-16 |
| GB2063923B (en) | 1983-09-21 |
| IT8050149A0 (it) | 1980-11-13 |
| AU6075880A (en) | 1981-05-21 |
| AR223719A1 (es) | 1981-09-15 |
| JPS5684477A (en) | 1981-07-09 |
| GB2063923A (en) | 1981-06-10 |
| IT1142184B (it) | 1986-10-08 |
| AU531247B2 (en) | 1983-08-18 |
| CA1137396A (en) | 1982-12-14 |
| NL8004320A (nl) | 1981-06-16 |
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