JPS6030750B2 - 銅含有電解液からセレンを除去する方法 - Google Patents
銅含有電解液からセレンを除去する方法Info
- Publication number
- JPS6030750B2 JPS6030750B2 JP52044161A JP4416177A JPS6030750B2 JP S6030750 B2 JPS6030750 B2 JP S6030750B2 JP 52044161 A JP52044161 A JP 52044161A JP 4416177 A JP4416177 A JP 4416177A JP S6030750 B2 JPS6030750 B2 JP S6030750B2
- Authority
- JP
- Japan
- Prior art keywords
- copper
- selenium
- containing electrolyte
- electrolyte
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000011669 selenium Substances 0.000 title claims description 49
- 239000010949 copper Substances 0.000 title claims description 44
- BUGBHKTXTAQXES-UHFFFAOYSA-N Selenium Chemical compound [Se] BUGBHKTXTAQXES-UHFFFAOYSA-N 0.000 title claims description 42
- 229910052802 copper Inorganic materials 0.000 title claims description 42
- 229910052711 selenium Inorganic materials 0.000 title claims description 42
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims description 41
- 239000003792 electrolyte Substances 0.000 title claims description 23
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 20
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 13
- 229910052759 nickel Inorganic materials 0.000 claims description 8
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 150000002739 metals Chemical class 0.000 claims description 5
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 2
- 150000001340 alkali metals Chemical class 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims 1
- 239000002244 precipitate Substances 0.000 claims 1
- 239000000243 solution Substances 0.000 description 16
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 8
- 229910000831 Steel Inorganic materials 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- 239000012535 impurity Substances 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 3
- 239000003929 acidic solution Substances 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 239000008151 electrolyte solution Substances 0.000 description 1
- 238000009854 hydrometallurgy Methods 0.000 description 1
- FLTRNWIFKITPIO-UHFFFAOYSA-N iron;trihydrate Chemical compound O.O.O.[Fe] FLTRNWIFKITPIO-UHFFFAOYSA-N 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- YFLLTMUVNFGTIW-UHFFFAOYSA-N nickel;sulfanylidenecopper Chemical compound [Ni].[Cu]=S YFLLTMUVNFGTIW-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012465 retentate Substances 0.000 description 1
- -1 selenium Chemical compound 0.000 description 1
- CBXWGGFGZDVPNV-UHFFFAOYSA-N so4-so4 Chemical compound OS(O)(=O)=O.OS(O)(=O)=O CBXWGGFGZDVPNV-UHFFFAOYSA-N 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
- C22B15/0091—Treating solutions by chemical methods by cementation
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0084—Treating solutions
- C22B15/0089—Treating solutions by chemical methods
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C1/00—Electrolytic production, recovery or refining of metals by electrolysis of solutions
- C25C1/12—Electrolytic production, recovery or refining of metals by electrolysis of solutions of copper
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Electrochemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Electrolytic Production Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US05/678,047 US4026797A (en) | 1976-04-19 | 1976-04-19 | Precipitation of selenium from copper electrowinning solutions |
| US678047 | 1976-04-19 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS52129615A JPS52129615A (en) | 1977-10-31 |
| JPS6030750B2 true JPS6030750B2 (ja) | 1985-07-18 |
Family
ID=24721165
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP52044161A Expired JPS6030750B2 (ja) | 1976-04-19 | 1977-04-19 | 銅含有電解液からセレンを除去する方法 |
Country Status (3)
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1089188A (en) * | 1977-08-19 | 1980-11-11 | Donald R. Weir | Purification of copper sulfate solution |
| US4214900A (en) * | 1979-08-08 | 1980-07-29 | Amax Inc. | Production of nonferrous metals with low selenium contents |
| CA1139258A (en) * | 1980-08-19 | 1983-01-11 | Donald R. Weir | Removal of selenium from acidic copper sulphate solutions |
| US4405464A (en) * | 1981-08-31 | 1983-09-20 | Kerr-Mcgee Nuclear Corporation | Process for the removal of selenium from aqueous systems |
| CA1146723A (en) * | 1981-10-30 | 1983-05-24 | Donald R. Weir | Removal of selenium from acidic copper/nickel solutions |
| US4377556A (en) * | 1982-04-09 | 1983-03-22 | Sherritt Gordon Mines Limited | Process for removing dissolved selenium values from an acidic aqueous copper sulphate solution |
| US5314623A (en) * | 1984-04-30 | 1994-05-24 | Kdf Fluid Treatment, Inc. | Method for treating fluids |
| US5135654A (en) * | 1984-04-30 | 1992-08-04 | Kdf Fluid Treatment, Inc. | Method for treating fluids |
| US4544541A (en) * | 1984-06-14 | 1985-10-01 | Amax Inc. | Removal of hexavalent selenium from nickel, cobalt or copper sulfate solution |
| US4790945A (en) * | 1987-05-08 | 1988-12-13 | Shell Oil Company | Removal of hydrogen selenide |
| US4792405A (en) * | 1987-05-08 | 1988-12-20 | Shell Oil Company | Removal of hydrogen selenide liquids |
| US4806264A (en) * | 1987-09-01 | 1989-02-21 | The United Sates Of America As Represented By The Secretary Of The Interior | Method of selectively removing selenium ions from an aqueous solution |
| JPH07109515B2 (ja) * | 1988-09-26 | 1995-11-22 | 富士ゼロックス株式会社 | 電子写真感光体からセレン層を除去する方法 |
| US4940549A (en) * | 1989-01-31 | 1990-07-10 | Santina Water Company | Method for removing toxic metals from agricultural drain water |
| US5089141A (en) * | 1990-11-09 | 1992-02-18 | The United States Of America As Represented By The Secretary Of The Interior | Chemical process for removing selenium from water |
| US5200082A (en) * | 1991-07-02 | 1993-04-06 | Santina Water Company | Method for removing toxic substances from industrial and agricultural waste water |
| US5431825A (en) * | 1992-10-29 | 1995-07-11 | Chemical Waste Management, Inc. | Method for the reduction and stabilization of metals |
| US6238570B1 (en) * | 1999-02-25 | 2001-05-29 | General Electric Company | Method for treating aqueous composition contaminants |
| US6751814B2 (en) * | 2001-11-02 | 2004-06-22 | Roy Mattson | Whirlpool bath filter and suction device |
| US6760931B1 (en) * | 2002-08-02 | 2004-07-13 | Roy W. Mattson, Jr. | Non-electric sanitation water vessel system |
| US20090106888A1 (en) * | 2002-08-02 | 2009-04-30 | Roy W. Mattson, Jr. | Safety device |
| US7146659B2 (en) | 2002-08-02 | 2006-12-12 | Mattson Jr Roy W | Hydromassage antimicrobial whirlpool bathtub |
| US7144362B2 (en) * | 2004-10-29 | 2006-12-05 | Heritage Environmental Servicers, Llc | Method for chemically stabilizing waste materials containing multivalent oxyanions |
| US20180319674A1 (en) * | 2017-05-04 | 2018-11-08 | Uop Llc | Removal of selenocyanate from industrial water systems with sulfided metal adsorbents |
| CN110565120B (zh) * | 2019-10-18 | 2021-09-07 | 东北大学 | 一种在含铜铁液中脱除并回收铜的方法 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2889206A (en) * | 1953-09-30 | 1959-06-02 | Kawecki Chemical Company | Recovery of selenium |
| GB808637A (en) * | 1955-08-09 | 1959-02-11 | Diamond Alkali Co | Improvements in or relating to the recovery of selenium |
| US2930678A (en) * | 1956-10-16 | 1960-03-29 | Norddeutsche Affinerie | Process for the production of selenium of at least 99.99% purity |
| SU149765A1 (ru) * | 1961-09-29 | 1961-11-30 | В.Н. Нестеров | Способ извлечени селена из шламов |
| US3914375A (en) * | 1974-04-08 | 1975-10-21 | Amax Inc | Method of removing selenium from copper solution |
| US3959097A (en) * | 1975-05-30 | 1976-05-25 | Amax Inc. | Selenium rejection during acid leaching of matte |
| US3933635A (en) * | 1975-07-15 | 1976-01-20 | The United States Of America As Represented By The Secretary Of The Interior | Method for removing soluble selenium from acidic waste water |
-
1976
- 1976-04-19 US US05/678,047 patent/US4026797A/en not_active Expired - Lifetime
-
1977
- 1977-04-15 FR FR7711379A patent/FR2348980A1/fr active Granted
- 1977-04-19 JP JP52044161A patent/JPS6030750B2/ja not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US4026797A (en) | 1977-05-31 |
| JPS52129615A (en) | 1977-10-31 |
| FR2348980B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1983-10-21 |
| FR2348980A1 (fr) | 1977-11-18 |
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