JPS60147430A - 高白度，高重合度アジピン酸共重合ポリエステルの製造法 - Google Patents
高白度，高重合度アジピン酸共重合ポリエステルの製造法Info
- Publication number
- JPS60147430A JPS60147430A JP349684A JP349684A JPS60147430A JP S60147430 A JPS60147430 A JP S60147430A JP 349684 A JP349684 A JP 349684A JP 349684 A JP349684 A JP 349684A JP S60147430 A JPS60147430 A JP S60147430A
- Authority
- JP
- Japan
- Prior art keywords
- acid
- adipic acid
- derivative
- mol
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 title claims abstract description 48
- 239000001361 adipic acid Substances 0.000 title claims abstract description 25
- 235000011037 adipic acid Nutrition 0.000 title claims abstract description 24
- 229920000728 polyester Polymers 0.000 title claims abstract description 18
- 238000006116 polymerization reaction Methods 0.000 title claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims abstract description 32
- 238000006068 polycondensation reaction Methods 0.000 claims abstract description 29
- 150000003609 titanium compounds Chemical class 0.000 claims abstract description 20
- -1 phosphorus compound Chemical class 0.000 claims abstract description 19
- 238000005886 esterification reaction Methods 0.000 claims abstract description 17
- 230000032050 esterification Effects 0.000 claims abstract description 15
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 14
- 239000011574 phosphorus Substances 0.000 claims abstract description 14
- 239000002253 acid Substances 0.000 claims abstract description 12
- 238000005809 transesterification reaction Methods 0.000 claims description 12
- 239000007795 chemical reaction product Substances 0.000 claims description 5
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 abstract description 10
- 238000006243 chemical reaction Methods 0.000 abstract description 7
- 229910000147 aluminium phosphate Inorganic materials 0.000 abstract description 5
- YZYDPPZYDIRSJT-UHFFFAOYSA-K boron phosphate Chemical compound [B+3].[O-]P([O-])([O-])=O YZYDPPZYDIRSJT-UHFFFAOYSA-K 0.000 abstract description 4
- 229910000149 boron phosphate Inorganic materials 0.000 abstract description 4
- 239000000203 mixture Substances 0.000 abstract description 4
- 150000002148 esters Chemical class 0.000 abstract description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 abstract description 2
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 abstract description 2
- HKJYVRJHDIPMQB-UHFFFAOYSA-N propan-1-olate;titanium(4+) Chemical compound CCCO[Ti](OCCC)(OCCC)OCCC HKJYVRJHDIPMQB-UHFFFAOYSA-N 0.000 abstract 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 12
- 229920000642 polymer Polymers 0.000 description 11
- 239000003054 catalyst Substances 0.000 description 6
- VXUYXOFXAQZZMF-UHFFFAOYSA-N titanium(IV) isopropoxide Chemical compound CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 6
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 5
- 239000007858 starting material Substances 0.000 description 5
- 229920001634 Copolyester Polymers 0.000 description 4
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000000465 moulding Methods 0.000 description 4
- 239000011347 resin Substances 0.000 description 4
- 229920005989 resin Polymers 0.000 description 4
- 241000219112 Cucumis Species 0.000 description 3
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 210000003127 knee Anatomy 0.000 description 3
- 150000003018 phosphorus compounds Chemical class 0.000 description 3
- 229920000874 polytetramethylene terephthalate Polymers 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 3
- UDSFAEKRVUSQDD-UHFFFAOYSA-N Dimethyl adipate Chemical compound COC(=O)CCCCC(=O)OC UDSFAEKRVUSQDD-UHFFFAOYSA-N 0.000 description 2
- 108010009736 Protein Hydrolysates Proteins 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 125000005907 alkyl ester group Chemical group 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- MNNHAPBLZZVQHP-UHFFFAOYSA-N diammonium hydrogen phosphate Chemical compound [NH4+].[NH4+].OP([O-])([O-])=O MNNHAPBLZZVQHP-UHFFFAOYSA-N 0.000 description 2
- ONIHPYYWNBVMID-UHFFFAOYSA-N diethyl benzene-1,4-dicarboxylate Chemical compound CCOC(=O)C1=CC=C(C(=O)OCC)C=C1 ONIHPYYWNBVMID-UHFFFAOYSA-N 0.000 description 2
- WOZVHXUHUFLZGK-UHFFFAOYSA-N dimethyl terephthalate Chemical compound COC(=O)C1=CC=C(C(=O)OC)C=C1 WOZVHXUHUFLZGK-UHFFFAOYSA-N 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- GNOIPBMMFNIUFM-UHFFFAOYSA-N hexamethylphosphoric triamide Chemical compound CN(C)P(=O)(N(C)C)N(C)C GNOIPBMMFNIUFM-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- WLJVNTCWHIRURA-UHFFFAOYSA-N pimelic acid Chemical compound OC(=O)CCCCCC(O)=O WLJVNTCWHIRURA-UHFFFAOYSA-N 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 description 2
- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 2
- PXGZQGDTEZPERC-UHFFFAOYSA-N 1,4-cyclohexanedicarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)CC1 PXGZQGDTEZPERC-UHFFFAOYSA-N 0.000 description 1
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 1
- 241000694851 Adipe Species 0.000 description 1
- 239000004254 Ammonium phosphate Substances 0.000 description 1
- 101100460146 Arabidopsis thaliana NEET gene Proteins 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- VIZORQUEIQEFRT-UHFFFAOYSA-N Diethyl adipate Chemical compound CCOC(=O)CCCCC(=O)OCC VIZORQUEIQEFRT-UHFFFAOYSA-N 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-N Metaphosphoric acid Chemical compound OP(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- WDIKJKHYXWFRHH-UHFFFAOYSA-N P(=O)(O)(O)O.C(C)C(CN=[N+]=[N-])CCCC Chemical compound P(=O)(O)(O)O.C(C)C(CN=[N+]=[N-])CCCC WDIKJKHYXWFRHH-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- QLZHNIAADXEJJP-UHFFFAOYSA-N Phenylphosphonic acid Chemical compound OP(O)(=O)C1=CC=CC=C1 QLZHNIAADXEJJP-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- OQPHEVHDBFEJRQ-UHFFFAOYSA-N [Li].P(O)(O)(O)=O Chemical compound [Li].P(O)(O)(O)=O OQPHEVHDBFEJRQ-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001278 adipic acid derivatives Chemical class 0.000 description 1
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 1
- 229910000148 ammonium phosphate Inorganic materials 0.000 description 1
- 235000019289 ammonium phosphates Nutrition 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- FJTUUPVRIANHEX-UHFFFAOYSA-N butan-1-ol;phosphoric acid Chemical compound CCCCO.OP(O)(O)=O FJTUUPVRIANHEX-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000006482 condensation reaction Methods 0.000 description 1
- 230000003111 delayed effect Effects 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- BEQVQKJCLJBTKZ-UHFFFAOYSA-N diphenylphosphinic acid Chemical compound C=1C=CC=CC=1P(=O)(O)C1=CC=CC=C1 BEQVQKJCLJBTKZ-UHFFFAOYSA-N 0.000 description 1
- XPPKVPWEQAFLFU-UHFFFAOYSA-N diphosphoric acid Chemical compound OP(O)(=O)OP(O)(O)=O XPPKVPWEQAFLFU-UHFFFAOYSA-N 0.000 description 1
- UHWHMHPXHWHWPX-UHFFFAOYSA-J dipotassium;oxalate;oxotitanium(2+) Chemical compound [K+].[K+].[Ti+2]=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O UHWHMHPXHWHWPX-UHFFFAOYSA-J 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- ITNVWQNWHXEMNS-UHFFFAOYSA-N methanolate;titanium(4+) Chemical compound [Ti+4].[O-]C.[O-]C.[O-]C.[O-]C ITNVWQNWHXEMNS-UHFFFAOYSA-N 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- BBJSDUUHGVDNKL-UHFFFAOYSA-J oxalate;titanium(4+) Chemical compound [Ti+4].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O BBJSDUUHGVDNKL-UHFFFAOYSA-J 0.000 description 1
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical compound [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- SQTLECAKIMBJGK-UHFFFAOYSA-I potassium;titanium(4+);pentafluoride Chemical compound [F-].[F-].[F-].[F-].[F-].[K+].[Ti+4] SQTLECAKIMBJGK-UHFFFAOYSA-I 0.000 description 1
- 229940005657 pyrophosphoric acid Drugs 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 229910000348 titanium sulfate Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- OIDNQHTUUMEJMX-UHFFFAOYSA-H zinc titanium(4+) hexafluoride Chemical compound [F-].[F-].[F-].[F-].[F-].[F-].[Ti+4].[Zn++] OIDNQHTUUMEJMX-UHFFFAOYSA-H 0.000 description 1
Landscapes
- Polyesters Or Polycarbonates (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP349684A JPS60147430A (ja) | 1984-01-13 | 1984-01-13 | 高白度，高重合度アジピン酸共重合ポリエステルの製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP349684A JPS60147430A (ja) | 1984-01-13 | 1984-01-13 | 高白度，高重合度アジピン酸共重合ポリエステルの製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS60147430A true JPS60147430A (ja) | 1985-08-03 |
| JPH0480932B2 JPH0480932B2 (enExample) | 1992-12-21 |
Family
ID=11558947
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP349684A Granted JPS60147430A (ja) | 1984-01-13 | 1984-01-13 | 高白度，高重合度アジピン酸共重合ポリエステルの製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS60147430A (enExample) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5446079A (en) * | 1990-11-30 | 1995-08-29 | Eastman Chemical Company | Aliphatic-aromatic copolyesters and cellulose ester/polymer blends |
| US6303738B1 (en) | 2000-08-04 | 2001-10-16 | E. I. Du Pont De Nemours And Company | Esterification process |
| US6353084B1 (en) | 1995-01-13 | 2002-03-05 | Basf Aktiengesellschaft | Biodegradable polyestreramide and a process of preparing |
| WO2013012706A1 (en) * | 2011-07-15 | 2013-01-24 | Saudi Basic Industries Corporation | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| WO2013033285A1 (en) | 2011-08-30 | 2013-03-07 | Saudi Basic Industries Corporation | Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst |
| JP2014520933A (ja) * | 2011-07-15 | 2014-08-25 | サウディ ベーシック インダストリーズ コーポレイション | 色が安定な生分解性脂肪族／芳香族共重合ポリエステル、製造方法、及びその物品 |
| WO2015013573A1 (en) | 2012-07-30 | 2015-01-29 | Sabic Innovative Plastics Ip B.V. | Process for the preparation of poly(alkylene terephthalate) employing an in-situ titanium-containing catalyst and compositions derived therefrom |
| WO2015116510A1 (en) | 2014-01-28 | 2015-08-06 | Sabic Global Technologies B.V. | Modified endcapped poly(alkylene terephthalate) prepared by employing an in-situ titanium-containing catalyst and compositions derived therefrom |
| US9487622B2 (en) | 2013-07-25 | 2016-11-08 | Sabic Global Technologies B.V. | Process for the preparation of modified poly(alkylene terephthalate) employing an in-situ titanium-containing catalyst |
| WO2016202607A1 (en) | 2015-06-18 | 2016-12-22 | Sabic Global Technologies B.V. | Polybutylene terephthalate composition with improved hydrolytic stability |
| US9771474B2 (en) | 2012-07-30 | 2017-09-26 | Sabic Global Technologies B.V. | Hydrostability of polybutylene terephthalate composition |
| WO2023243609A1 (ja) * | 2022-06-17 | 2023-12-21 | 東洋紡株式会社 | 共重合ポリエステル樹脂及びその成形体、並びに共重合ポリエステル樹脂の製造方法 |
-
1984
- 1984-01-13 JP JP349684A patent/JPS60147430A/ja active Granted
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5446079A (en) * | 1990-11-30 | 1995-08-29 | Eastman Chemical Company | Aliphatic-aromatic copolyesters and cellulose ester/polymer blends |
| US5580911A (en) * | 1990-11-30 | 1996-12-03 | Eastman Chemical Company | Aliphatic-aromatic copolyesters and cellulose ester/polymer blends |
| US6342304B1 (en) | 1990-11-30 | 2002-01-29 | Eastman Chemical Company | Aliphatic aromatic copolyesters |
| US6353084B1 (en) | 1995-01-13 | 2002-03-05 | Basf Aktiengesellschaft | Biodegradable polyestreramide and a process of preparing |
| US6303738B1 (en) | 2000-08-04 | 2001-10-16 | E. I. Du Pont De Nemours And Company | Esterification process |
| AU2012284305B2 (en) * | 2011-07-15 | 2015-05-07 | Saudi Basic Industries Corporation | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| WO2013012706A1 (en) * | 2011-07-15 | 2013-01-24 | Saudi Basic Industries Corporation | Color-stabilized biodegradable aliphatic-aromatic copolyesters, methods of manufacture, and articles thereof |
| JP2014520933A (ja) * | 2011-07-15 | 2014-08-25 | サウディ ベーシック インダストリーズ コーポレイション | 色が安定な生分解性脂肪族／芳香族共重合ポリエステル、製造方法、及びその物品 |
| JP2014525505A (ja) * | 2011-08-30 | 2014-09-29 | サウディ ベーシック インダストリーズ コーポレイション | 脂肪族−芳香族コポリエステル、組成物、及びコポリエステルの製造法 |
| WO2013033285A1 (en) | 2011-08-30 | 2013-03-07 | Saudi Basic Industries Corporation | Method for the preparation of (polybutylene-co-adipate terephthalate) through the in situ phosphorus containing titanium based catalyst |
| US9670313B2 (en) | 2012-07-30 | 2017-06-06 | Sabic Global Technologies B.V. | Hydrostability of polyester composition |
| WO2015013573A1 (en) | 2012-07-30 | 2015-01-29 | Sabic Innovative Plastics Ip B.V. | Process for the preparation of poly(alkylene terephthalate) employing an in-situ titanium-containing catalyst and compositions derived therefrom |
| US9771474B2 (en) | 2012-07-30 | 2017-09-26 | Sabic Global Technologies B.V. | Hydrostability of polybutylene terephthalate composition |
| US10087323B2 (en) | 2012-07-30 | 2018-10-02 | Sabic Global Technologies B.V. | Hydrostability of polycarbonate polybutylene terephthalate composition |
| US9487622B2 (en) | 2013-07-25 | 2016-11-08 | Sabic Global Technologies B.V. | Process for the preparation of modified poly(alkylene terephthalate) employing an in-situ titanium-containing catalyst |
| WO2015116510A1 (en) | 2014-01-28 | 2015-08-06 | Sabic Global Technologies B.V. | Modified endcapped poly(alkylene terephthalate) prepared by employing an in-situ titanium-containing catalyst and compositions derived therefrom |
| CN105940034A (zh) * | 2014-01-28 | 2016-09-14 | Sabic环球技术有限责任公司 | 通过使用原位含钛催化剂制备的改性的封端的聚(对苯二甲酸亚烷基酯)和来源于此的组合物 |
| US9944773B2 (en) | 2014-01-28 | 2018-04-17 | Sabic Global Technologies B.V. | Modified endcapped poly(alkylene terephthalate) prepared by employing an in situ titanium-containing catalyst and compositions derived therefrom |
| WO2016202607A1 (en) | 2015-06-18 | 2016-12-22 | Sabic Global Technologies B.V. | Polybutylene terephthalate composition with improved hydrolytic stability |
| WO2023243609A1 (ja) * | 2022-06-17 | 2023-12-21 | 東洋紡株式会社 | 共重合ポリエステル樹脂及びその成形体、並びに共重合ポリエステル樹脂の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0480932B2 (enExample) | 1992-12-21 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR940010346B1 (ko) | 폴리부틸렌테레프탈레이트계 중합체의 제조방법 | |
| JP6408982B2 (ja) | ポリエステル樹脂およびその製造方法 | |
| EP1384740A1 (en) | Process for preparing copolyesters of terephthalic acid, ethylene glycol, and 1,4-cyclohexanedimethanol exhibiting a neutral hue, high clarity and increased brightness | |
| JP2012514065A (ja) | イソソルビドが共重合されたポリエステル樹脂の製造方法 | |
| JPS60147430A (ja) | 高白度，高重合度アジピン酸共重合ポリエステルの製造法 | |
| US4264751A (en) | Copolyester resin having minimal carboxyl terminated ends and method for producing the same | |
| JPH04279633A (ja) | ジカルボン酸の低級ジアルキルエステル及びグリコールからポリエチレンテレフタレートベースのポリマーを製造する方法 | |
| US3346541A (en) | Process for manufacturing linear fiber and film forming polyesters by polycondensation in the presence of a titanium alkoxide catalyst and a germanium compound | |
| JP4639478B2 (ja) | 改質ポリエステルの製造方法 | |
| JP3108047B2 (ja) | ポリエステル樹脂の製造方法 | |
| JPH11236442A (ja) | ポリエステルの製造方法 | |
| JP7579527B1 (ja) | 共重合ポリエステル樹脂の製造方法 | |
| JP7548469B2 (ja) | 共重合ポリエステル樹脂 | |
| JPS5838722A (ja) | ポリエステルの製造方法 | |
| JPH05117379A (ja) | 耐光性に優れたポリエステルの製造方法 | |
| JPS591416B2 (ja) | ポリエステルの製造方法 | |
| KR0122004B1 (ko) | 폴리에스테르의 제조방법 | |
| JPH04234428A (ja) | ポリエステルの製造方法 | |
| KR0122003B1 (ko) | 폴리에스테르의 제조방법 | |
| KR101726511B1 (ko) | 폴리에스테르 중합용 촉매 조성물 및 이를 이용한 폴리에스테르 수지의 제조방법 | |
| JPS5834493B2 (ja) | ポリエステルの製造方法 | |
| KR20040029760A (ko) | 중축합 반응속도가 우수한 1,4-사이클로헥산디메탄올이공중합된 폴리에스테르 수지의 제조방법 | |
| WO2024070038A1 (ja) | 共重合ポリエステル樹脂 | |
| WO2024070037A1 (ja) | 共重合ポリエステル樹脂 | |
| JPS5932488B2 (ja) | 高重合度ポリテトラメチレンテレフタレ−トの製造法 |