JPS6011517A - モノビニル芳香族系樹脂組成物 - Google Patents
モノビニル芳香族系樹脂組成物Info
- Publication number
- JPS6011517A JPS6011517A JP11809983A JP11809983A JPS6011517A JP S6011517 A JPS6011517 A JP S6011517A JP 11809983 A JP11809983 A JP 11809983A JP 11809983 A JP11809983 A JP 11809983A JP S6011517 A JPS6011517 A JP S6011517A
- Authority
- JP
- Japan
- Prior art keywords
- resin composition
- monovinyl aromatic
- degree
- polymerization
- component particles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims abstract description 31
- 125000003118 aryl group Chemical group 0.000 title claims abstract description 17
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 32
- 239000002245 particle Substances 0.000 claims abstract description 26
- 229920002857 polybutadiene Polymers 0.000 claims abstract description 17
- 239000005063 High cis polybutadiene Substances 0.000 claims abstract description 14
- 238000004132 cross linking Methods 0.000 claims abstract description 13
- 239000000178 monomer Substances 0.000 claims abstract description 11
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 8
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 5
- 238000006116 polymerization reaction Methods 0.000 abstract description 22
- 239000000203 mixture Substances 0.000 abstract description 10
- 229920001971 elastomer Polymers 0.000 abstract 1
- 230000002794 monomerizing effect Effects 0.000 abstract 1
- 239000005060 rubber Substances 0.000 abstract 1
- 230000007423 decrease Effects 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 239000003054 catalyst Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000012662 bulk polymerization Methods 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 3
- UIHCLUNTQKBZGK-UHFFFAOYSA-N 3-methyl-2-pentanone Chemical compound CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- OXGOEZHUKDEEKS-UHFFFAOYSA-N 3-tert-butylperoxy-1,1,5-trimethylcyclohexane Chemical compound CC1CC(OOC(C)(C)C)CC(C)(C)C1 OXGOEZHUKDEEKS-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- 239000005064 Low cis polybutadiene Substances 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000002174 Styrene-butadiene Substances 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- -1 alkyl mercaptan Chemical compound 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000012933 diacyl peroxide Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000010559 graft polymerization reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000012778 molding material Substances 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000012071 phase Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
Landscapes
- Graft Or Block Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11809983A JPS6011517A (ja) | 1983-07-01 | 1983-07-01 | モノビニル芳香族系樹脂組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11809983A JPS6011517A (ja) | 1983-07-01 | 1983-07-01 | モノビニル芳香族系樹脂組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6011517A true JPS6011517A (ja) | 1985-01-21 |
| JPH0318647B2 JPH0318647B2 (enrdf_load_stackoverflow) | 1991-03-13 |
Family
ID=14727975
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP11809983A Granted JPS6011517A (ja) | 1983-07-01 | 1983-07-01 | モノビニル芳香族系樹脂組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6011517A (enrdf_load_stackoverflow) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6178856A (ja) * | 1984-09-27 | 1986-04-22 | Idemitsu Petrochem Co Ltd | 耐フロン性シート材料 |
| JPS6274944A (ja) * | 1985-09-30 | 1987-04-06 | Idemitsu Petrochem Co Ltd | モノビニル芳香族系樹脂組成物の製造方法 |
| JPS6274945A (ja) * | 1985-09-30 | 1987-04-06 | Idemitsu Petrochem Co Ltd | モノビニル芳香族系樹脂組成物 |
| JPS6366215A (ja) * | 1986-09-05 | 1988-03-24 | Ube Ind Ltd | 耐衝撃性ポリスチレン系樹脂組成物 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54141838A (en) * | 1978-04-25 | 1979-11-05 | Mitsui Toatsu Chem Inc | Styrene resin composition |
| JPS57143313A (en) * | 1981-03-02 | 1982-09-04 | Ube Ind Ltd | Preparation of impact-resistant polystyrene resin |
-
1983
- 1983-07-01 JP JP11809983A patent/JPS6011517A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS54141838A (en) * | 1978-04-25 | 1979-11-05 | Mitsui Toatsu Chem Inc | Styrene resin composition |
| JPS57143313A (en) * | 1981-03-02 | 1982-09-04 | Ube Ind Ltd | Preparation of impact-resistant polystyrene resin |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6178856A (ja) * | 1984-09-27 | 1986-04-22 | Idemitsu Petrochem Co Ltd | 耐フロン性シート材料 |
| JPS6274944A (ja) * | 1985-09-30 | 1987-04-06 | Idemitsu Petrochem Co Ltd | モノビニル芳香族系樹脂組成物の製造方法 |
| JPS6274945A (ja) * | 1985-09-30 | 1987-04-06 | Idemitsu Petrochem Co Ltd | モノビニル芳香族系樹脂組成物 |
| JPS6366215A (ja) * | 1986-09-05 | 1988-03-24 | Ube Ind Ltd | 耐衝撃性ポリスチレン系樹脂組成物 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0318647B2 (enrdf_load_stackoverflow) | 1991-03-13 |
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