JPS5974151A - 耐熱分解性に優れる熱可塑性樹脂組成物 - Google Patents
耐熱分解性に優れる熱可塑性樹脂組成物Info
- Publication number
- JPS5974151A JPS5974151A JP18567782A JP18567782A JPS5974151A JP S5974151 A JPS5974151 A JP S5974151A JP 18567782 A JP18567782 A JP 18567782A JP 18567782 A JP18567782 A JP 18567782A JP S5974151 A JPS5974151 A JP S5974151A
- Authority
- JP
- Japan
- Prior art keywords
- acrylonitrile
- thermoplastic resin
- resin composition
- polymer
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011342 resin composition Substances 0.000 title claims description 13
- 229920005992 thermoplastic resin Polymers 0.000 title claims description 13
- 238000005979 thermal decomposition reaction Methods 0.000 title abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 20
- 229920000642 polymer Polymers 0.000 claims abstract description 17
- -1 acrylate ester Chemical class 0.000 claims abstract description 12
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims abstract description 11
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 238000006116 polymerization reaction Methods 0.000 claims description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 5
- 238000000354 decomposition reaction Methods 0.000 claims description 5
- 125000005396 acrylic acid ester group Chemical group 0.000 claims description 2
- 125000005907 alkyl ester group Chemical group 0.000 claims description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract description 6
- 125000000217 alkyl group Chemical group 0.000 abstract description 5
- 229920003244 diene elastomer Polymers 0.000 abstract description 5
- 239000005062 Polybutadiene Substances 0.000 abstract description 3
- 229920002857 polybutadiene Polymers 0.000 abstract description 3
- 239000002245 particle Substances 0.000 abstract description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 8
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 5
- 238000000465 moulding Methods 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 239000003999 initiator Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 238000005469 granulation Methods 0.000 description 3
- 230000003179 granulation Effects 0.000 description 3
- 229910052709 silver Inorganic materials 0.000 description 3
- 239000004332 silver Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 230000004580 weight loss Effects 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 239000004816 latex Substances 0.000 description 2
- 229920000126 latex Polymers 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000010558 suspension polymerization method Methods 0.000 description 2
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
- GNSFRPWPOGYVLO-UHFFFAOYSA-N 3-hydroxypropyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCCO GNSFRPWPOGYVLO-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 150000008360 acrylonitriles Chemical class 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000008267 milk Substances 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- KUKFKAPJCRZILJ-UHFFFAOYSA-N prop-2-enenitrile;prop-2-enoic acid Chemical compound C=CC#N.OC(=O)C=C KUKFKAPJCRZILJ-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18567782A JPS5974151A (ja) | 1982-10-20 | 1982-10-20 | 耐熱分解性に優れる熱可塑性樹脂組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP18567782A JPS5974151A (ja) | 1982-10-20 | 1982-10-20 | 耐熱分解性に優れる熱可塑性樹脂組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5974151A true JPS5974151A (ja) | 1984-04-26 |
| JPS6328461B2 JPS6328461B2 (en, 2012) | 1988-06-08 |
Family
ID=16174931
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP18567782A Granted JPS5974151A (ja) | 1982-10-20 | 1982-10-20 | 耐熱分解性に優れる熱可塑性樹脂組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5974151A (en, 2012) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60231751A (ja) * | 1984-05-02 | 1985-11-18 | Japan Synthetic Rubber Co Ltd | 熱可塑性樹脂組成物 |
| JPS60238347A (ja) * | 1984-05-14 | 1985-11-27 | Mitsui Toatsu Chem Inc | 熱分解性樹脂組成物 |
| JPS61500797A (ja) * | 1984-06-07 | 1986-04-24 | ザ ダウ ケミカル カンパニ− | 芳香族／イソプロペニル芳香族コポリマ−とグラフトゴムコンセントレ−トとのポリブレンド |
| KR100848176B1 (ko) | 2007-10-25 | 2008-07-23 | 제일모직주식회사 | 내열도가 우수한 투명 열가소성 수지 조성물 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4999552A (en, 2012) * | 1973-01-24 | 1974-09-20 | ||
| JPS5193948A (ja) * | 1975-02-14 | 1976-08-18 | Taishogekiseinokairyosaretanitorirukeijugotaisoseibutsu |
-
1982
- 1982-10-20 JP JP18567782A patent/JPS5974151A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4999552A (en, 2012) * | 1973-01-24 | 1974-09-20 | ||
| JPS5193948A (ja) * | 1975-02-14 | 1976-08-18 | Taishogekiseinokairyosaretanitorirukeijugotaisoseibutsu |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60231751A (ja) * | 1984-05-02 | 1985-11-18 | Japan Synthetic Rubber Co Ltd | 熱可塑性樹脂組成物 |
| JPS60238347A (ja) * | 1984-05-14 | 1985-11-27 | Mitsui Toatsu Chem Inc | 熱分解性樹脂組成物 |
| JPS61500797A (ja) * | 1984-06-07 | 1986-04-24 | ザ ダウ ケミカル カンパニ− | 芳香族／イソプロペニル芳香族コポリマ−とグラフトゴムコンセントレ−トとのポリブレンド |
| KR100848176B1 (ko) | 2007-10-25 | 2008-07-23 | 제일모직주식회사 | 내열도가 우수한 투명 열가소성 수지 조성물 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6328461B2 (en, 2012) | 1988-06-08 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR102068650B1 (ko) | 그라프트 공중합체, 이의 제조방법, 이를 포함하는 열가소성 수지 조성물 및 성형품 | |
| EP0208382B1 (en) | Rubber-reinforced styrenic polymer resins having improved flow and gloss characteristics | |
| JPS5974151A (ja) | 耐熱分解性に優れる熱可塑性樹脂組成物 | |
| GB2044276A (en) | High nitrile impact resistant resins | |
| JP2524367B2 (ja) | 残存ブタジエン含量を低滅させたａｂｓ成形用組成物 | |
| JP3286971B2 (ja) | スチレン系共重合体、該共重合体を含有する熱可塑性樹脂組成物及びそれらの製造法 | |
| JPH0415821B2 (en, 2012) | ||
| DE19502200A1 (de) | Thermoplaste mit hoher Wärmeformbeständigkeit und verbesserter Thermostabilität | |
| JPS63304042A (ja) | 耐熱性熱可塑性樹脂組成物 | |
| JPS5861108A (ja) | 熱可塑性樹脂の製造方法 | |
| JPH04264116A (ja) | 耐衝撃性スチレン系樹脂の製造方法 | |
| JPH0428749A (ja) | 高外観耐熱性熱可塑性樹脂組成物及び成形品 | |
| JP2006526682A (ja) | スチレン系熱可塑性樹脂組成物 | |
| JPS61223006A (ja) | 熱可塑性樹脂の製造方法 | |
| JPS6336632B2 (en, 2012) | ||
| JP2546936B2 (ja) | スチレン系樹脂組成物 | |
| JPH069734A (ja) | ローブ型グラフト共重合体を含有する改善された耐衝撃性をもつ樹脂組成物及びそれらの製造法 | |
| JPH0129218B2 (en, 2012) | ||
| US3830879A (en) | Polyblend comprising graft copolymer and resinous terpolymer | |
| JPH0440383B2 (en, 2012) | ||
| JPS635412B2 (en, 2012) | ||
| JPH01141940A (ja) | 熱可塑性樹脂組成物 | |
| JPS5980455A (ja) | 耐熱性耐衝撃性樹脂組成物 | |
| JPH01234466A (ja) | 耐熱性熱可塑性樹脂組成物 | |
| JPS62129333A (ja) | 耐熱性樹脂組成物 |