JPS5946265B2 - 安定剤組成物 - Google Patents
安定剤組成物Info
- Publication number
- JPS5946265B2 JPS5946265B2 JP50123877A JP12387775A JPS5946265B2 JP S5946265 B2 JPS5946265 B2 JP S5946265B2 JP 50123877 A JP50123877 A JP 50123877A JP 12387775 A JP12387775 A JP 12387775A JP S5946265 B2 JPS5946265 B2 JP S5946265B2
- Authority
- JP
- Japan
- Prior art keywords
- copper
- polyolefins
- compounds
- methoxy
- naphthol
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims description 9
- 239000003381 stabilizer Substances 0.000 title claims description 3
- 229920000098 polyolefin Polymers 0.000 claims description 19
- 238000006731 degradation reaction Methods 0.000 claims description 12
- 230000015556 catabolic process Effects 0.000 claims description 11
- 239000003963 antioxidant agent Substances 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 4
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 230000003078 antioxidant effect Effects 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 2
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 24
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 12
- 229910052802 copper Inorganic materials 0.000 description 11
- 239000010949 copper Substances 0.000 description 11
- -1 polypropylenes Polymers 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000002530 phenolic antioxidant Substances 0.000 description 8
- 239000011541 reaction mixture Substances 0.000 description 8
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000243 solution Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 239000003112 inhibitor Substances 0.000 description 4
- 229920001155 polypropylene Polymers 0.000 description 4
- 230000006641 stabilisation Effects 0.000 description 4
- 238000011105 stabilization Methods 0.000 description 4
- FYSNRJHAOHDILO-UHFFFAOYSA-N thionyl chloride Chemical compound ClS(Cl)=O FYSNRJHAOHDILO-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 239000012265 solid product Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 3
- 229910052723 transition metal Inorganic materials 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- XOUQAVYLRNOXDO-UHFFFAOYSA-N 2-tert-butyl-5-methylphenol Chemical compound CC1=CC=C(C(C)(C)C)C(O)=C1 XOUQAVYLRNOXDO-UHFFFAOYSA-N 0.000 description 2
- ALKYHXVLJMQRLQ-UHFFFAOYSA-N 3-Hydroxy-2-naphthoate Chemical compound C1=CC=C2C=C(O)C(C(=O)O)=CC2=C1 ALKYHXVLJMQRLQ-UHFFFAOYSA-N 0.000 description 2
- SJTNTIRIRIPZDV-UHFFFAOYSA-N 3-methoxynaphthalen-2-ol Chemical compound C1=CC=C2C=C(O)C(OC)=CC2=C1 SJTNTIRIRIPZDV-UHFFFAOYSA-N 0.000 description 2
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical class [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 2
- 229910000881 Cu alloy Inorganic materials 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 239000007983 Tris buffer Substances 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 229950011260 betanaphthol Drugs 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 150000001879 copper Chemical class 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 2
- RARLPRMZJNIQGU-UHFFFAOYSA-N naphthalene-2-carbohydrazide Chemical compound C1=CC=CC2=CC(C(=O)NN)=CC=C21 RARLPRMZJNIQGU-UHFFFAOYSA-N 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- LENZDBCJOHFCAS-UHFFFAOYSA-N tris Chemical compound OCC(N)(CO)CO LENZDBCJOHFCAS-UHFFFAOYSA-N 0.000 description 2
- MBIZXFATKUQOOA-UHFFFAOYSA-N 1,3,4-thiadiazole Chemical compound C1=NN=CS1 MBIZXFATKUQOOA-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- JTXMVXSTHSMVQF-UHFFFAOYSA-N 2-acetyloxyethyl acetate Chemical compound CC(=O)OCCOC(C)=O JTXMVXSTHSMVQF-UHFFFAOYSA-N 0.000 description 1
- UOBYKYZJUGYBDK-UHFFFAOYSA-N 2-naphthoic acid Chemical compound C1=CC=CC2=CC(C(=O)O)=CC=C21 UOBYKYZJUGYBDK-UHFFFAOYSA-N 0.000 description 1
- LZHCVNIARUXHAL-UHFFFAOYSA-N 2-tert-butyl-4-ethylphenol Chemical compound CCC1=CC=C(O)C(C(C)(C)C)=C1 LZHCVNIARUXHAL-UHFFFAOYSA-N 0.000 description 1
- IKEHOXWJQXIQAG-UHFFFAOYSA-N 2-tert-butyl-4-methylphenol Chemical compound CC1=CC=C(O)C(C(C)(C)C)=C1 IKEHOXWJQXIQAG-UHFFFAOYSA-N 0.000 description 1
- WPMYUUITDBHVQZ-UHFFFAOYSA-N 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoic acid Chemical compound CC(C)(C)C1=CC(CCC(O)=O)=CC(C(C)(C)C)=C1O WPMYUUITDBHVQZ-UHFFFAOYSA-N 0.000 description 1
- RTBQQRFTCVDODF-UHFFFAOYSA-N 3-methoxynaphthalene-2-carboxylic acid Chemical compound C1=CC=C2C=C(C(O)=O)C(OC)=CC2=C1 RTBQQRFTCVDODF-UHFFFAOYSA-N 0.000 description 1
- 125000004203 4-hydroxyphenyl group Chemical group [H]OC1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- GKWXYJOHDFZVBM-UHFFFAOYSA-N 6-tert-butyl-2,4-dimethyl-3-(sulfanylmethyl)phenol Chemical class CC1=CC(C(C)(C)C)=C(O)C(C)=C1CS GKWXYJOHDFZVBM-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 239000005751 Copper oxide Substances 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical group ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N alpha-naphthol Natural products C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- JWAZRIHNYRIHIV-UHFFFAOYSA-N beta-hydroxynaphthyl Natural products C1=CC=CC2=CC(O)=CC=C21 JWAZRIHNYRIHIV-UHFFFAOYSA-N 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 229910000431 copper oxide Inorganic materials 0.000 description 1
- VAYGXNSJCAHWJZ-UHFFFAOYSA-N dimethyl sulfate Chemical compound COS(=O)(=O)OC VAYGXNSJCAHWJZ-UHFFFAOYSA-N 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012259 ether extract Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- XCTLDQQOHIEUCJ-UHFFFAOYSA-N ethyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OCC)=CC=CC2=C1 XCTLDQQOHIEUCJ-UHFFFAOYSA-N 0.000 description 1
- HQKSINSCHCDMLS-UHFFFAOYSA-N ethyl naphthalene-2-carboxylate Chemical compound C1=CC=CC2=CC(C(=O)OCC)=CC=C21 HQKSINSCHCDMLS-UHFFFAOYSA-N 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 125000005843 halogen group Chemical group 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- MPLSAOVNAXJHHI-UHFFFAOYSA-N methyl 3-methoxynaphthalene-2-carboxylate Chemical compound C1=CC=C2C=C(OC)C(C(=O)OC)=CC2=C1 MPLSAOVNAXJHHI-UHFFFAOYSA-N 0.000 description 1
- HMRROBKAACRWBP-UHFFFAOYSA-N methyl naphthalene-1-carboxylate Chemical compound C1=CC=C2C(C(=O)OC)=CC=CC2=C1 HMRROBKAACRWBP-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N phthalic acid di-n-butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000012262 resinous product Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C243/00—Compounds containing chains of nitrogen atoms singly-bound to each other, e.g. hydrazines, triazanes
- C07C243/24—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids
- C07C243/38—Hydrazines having nitrogen atoms of hydrazine groups acylated by carboxylic acids with acylating carboxyl groups bound to carbon atoms of six-membered aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/22—Compounds containing nitrogen bound to another nitrogen atom
- C08K5/24—Derivatives of hydrazine
- C08K5/25—Carboxylic acid hydrazides
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Anti-Oxidant Or Stabilizer Compositions (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US515941 | 1974-10-18 | ||
| US05/515,941 US3931103A (en) | 1974-10-18 | 1974-10-18 | Copper inhibitors for polyolefins |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5164557A JPS5164557A (en, 2012) | 1976-06-04 |
| JPS5946265B2 true JPS5946265B2 (ja) | 1984-11-12 |
Family
ID=24053430
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP50123877A Expired JPS5946265B2 (ja) | 1974-10-18 | 1975-10-16 | 安定剤組成物 |
Country Status (15)
| Country | Link |
|---|---|
| US (1) | US3931103A (en, 2012) |
| JP (1) | JPS5946265B2 (en, 2012) |
| AR (1) | AR206725A1 (en, 2012) |
| AT (1) | AT340691B (en, 2012) |
| BE (1) | BE834609A (en, 2012) |
| BR (1) | BR7506781A (en, 2012) |
| CA (1) | CA1060473A (en, 2012) |
| CH (1) | CH618203A5 (en, 2012) |
| DE (1) | DE2545788A1 (en, 2012) |
| ES (1) | ES441872A1 (en, 2012) |
| FR (1) | FR2330672A1 (en, 2012) |
| GB (1) | GB1481388A (en, 2012) |
| IT (1) | IT1047506B (en, 2012) |
| NL (1) | NL7510872A (en, 2012) |
| ZA (1) | ZA755715B (en, 2012) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59107264U (ja) * | 1983-01-08 | 1984-07-19 | 株式会社サト− | 感熱記録表示紙 |
| JPH02165989A (ja) * | 1988-12-20 | 1990-06-26 | Ricoh Co Ltd | 感熱記録用ラベル |
| JPH06222717A (ja) * | 1992-11-30 | 1994-08-12 | Moore Business Forms Inc | ラベルシート及びその製造方法 |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5573769A (en) * | 1978-11-27 | 1980-06-03 | Hitachi Cable Ltd | Adhesive composition and laminate using the same |
| DE2933870A1 (de) * | 1979-08-21 | 1981-03-12 | Siemens AG, 1000 Berlin und 8000 München | N.n'-bis-salicyloyl-hydrazin als metalldesaktivator. |
| DE3210859A1 (de) * | 1982-03-24 | 1983-09-29 | Siemens AG, 1000 Berlin und 8000 München | Verfahren und vorrichtung zur herstellung von n.n'-bis-aroyl-hydrazinen |
| US4603161A (en) * | 1985-06-14 | 1986-07-29 | Olin Corporation | Selected oxyalkylated 2,6-dialkylphenol compounds and their use as stabilizers of organic materials against oxidative degradation |
| US4870157A (en) * | 1985-07-09 | 1989-09-26 | Olin Corporation | Selected 4-acyl-2,6-dialkylphenol adducts of saccharides and their use as stabilizers of organic materials against oxidative degradation |
| US5117057A (en) * | 1985-10-21 | 1992-05-26 | Rohm And Haas Company | Insecticidal N' substituted-N-N'-disubstituted-hydrazines |
| US4985461A (en) * | 1985-10-21 | 1991-01-15 | Rohm And Haas Company | Insecticidal N'-substituted-N,N'-diacylhydrazines |
| US5354762A (en) * | 1986-07-14 | 1994-10-11 | Rohm And Haas Company | Six-membered heterocyclic derivatives of N'-substituted N,N'-diacylhydrazines |
| DK483586A (da) * | 1985-10-21 | 1987-04-22 | Rohm & Haas | Insecticide n'-substituerede-n,n'-diacylhydraziner |
| US5225443A (en) * | 1986-05-01 | 1993-07-06 | Rohm And Haas Company | Insecticidal N'-substituted-N'-substituted N,N'-diacylhydrazines |
| US4812896A (en) * | 1986-11-13 | 1989-03-14 | Olin Corporation | Metal electronic package sealed with thermoplastic having a grafted metal deactivator and antioxidant |
| US20040043170A1 (en) * | 2002-06-24 | 2004-03-04 | The Procter & Gamble Company | Food package |
| JP2010523796A (ja) * | 2007-04-11 | 2010-07-15 | ダウ グローバル テクノロジーズ インコーポレイティド | オレフィンポリマーにおける使用のための重金属不活性化剤／阻害剤 |
| ES2603185T3 (es) * | 2007-07-31 | 2017-02-24 | Dow Global Technologies Llc | Composiciones poliméricas que tienen un índice de blancura mejorado, procedimiento para producirlas y artículos hechos con las mismas |
| US10316171B2 (en) | 2013-09-23 | 2019-06-11 | Agienic, Inc. | Thermal stabilization of polymers using functionalized particles of transition metal compounds |
| CN110982806B (zh) * | 2019-08-30 | 2022-09-02 | 浙江工业大学 | 一种蛋白质芳基衍生物及其制备方法 |
| CN114292464B (zh) * | 2021-11-24 | 2023-06-02 | 富海(东营)新材料科技有限公司 | 用反应挤出设备生产高流动聚丙烯的方法 |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH529803A (de) * | 1970-05-19 | 1972-10-31 | Ciba Geigy Ag | Verwendung von Diacyldihydraziden als Stabilisatoren für Polyolefine |
| US3849942A (en) * | 1972-04-05 | 1974-11-26 | Gen Tire & Rubber Co | Harmonic composite grind |
-
1974
- 1974-10-18 US US05/515,941 patent/US3931103A/en not_active Expired - Lifetime
-
1975
- 1975-01-01 AR AR260514A patent/AR206725A1/es active
- 1975-09-05 CA CA234,852A patent/CA1060473A/en not_active Expired
- 1975-09-08 ZA ZA00755715A patent/ZA755715B/xx unknown
- 1975-09-16 NL NL7510872A patent/NL7510872A/xx not_active Application Discontinuation
- 1975-09-17 GB GB38284/75A patent/GB1481388A/en not_active Expired
- 1975-09-18 IT IT51398/75A patent/IT1047506B/it active
- 1975-10-13 DE DE19752545788 patent/DE2545788A1/de not_active Withdrawn
- 1975-10-16 CH CH1346975A patent/CH618203A5/de not_active IP Right Cessation
- 1975-10-16 JP JP50123877A patent/JPS5946265B2/ja not_active Expired
- 1975-10-16 BR BR7506781*A patent/BR7506781A/pt unknown
- 1975-10-16 FR FR7531706A patent/FR2330672A1/fr active Granted
- 1975-10-17 ES ES441872A patent/ES441872A1/es not_active Expired
- 1975-10-17 BE BE161021A patent/BE834609A/xx not_active IP Right Cessation
- 1975-10-17 AT AT792575A patent/AT340691B/de not_active IP Right Cessation
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59107264U (ja) * | 1983-01-08 | 1984-07-19 | 株式会社サト− | 感熱記録表示紙 |
| JPH02165989A (ja) * | 1988-12-20 | 1990-06-26 | Ricoh Co Ltd | 感熱記録用ラベル |
| JPH06222717A (ja) * | 1992-11-30 | 1994-08-12 | Moore Business Forms Inc | ラベルシート及びその製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1481388A (en) | 1977-07-27 |
| AR206725A1 (es) | 1976-08-13 |
| NL7510872A (nl) | 1976-04-21 |
| ATA792575A (de) | 1977-04-15 |
| BR7506781A (pt) | 1976-08-17 |
| CH618203A5 (en, 2012) | 1980-07-15 |
| FR2330672A1 (fr) | 1977-06-03 |
| CA1060473A (en) | 1979-08-14 |
| BE834609A (fr) | 1976-04-20 |
| FR2330672B1 (en, 2012) | 1981-05-22 |
| ES441872A1 (es) | 1978-01-16 |
| AU8472675A (en) | 1977-03-17 |
| US3931103A (en) | 1976-01-06 |
| IT1047506B (it) | 1980-10-20 |
| DE2545788A1 (de) | 1976-04-29 |
| AT340691B (de) | 1977-12-27 |
| ZA755715B (en) | 1976-08-25 |
| JPS5164557A (en, 2012) | 1976-06-04 |
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