JPS59207922A - ラクトン―シロキサン共重合体組成物 - Google Patents
ラクトン―シロキサン共重合体組成物Info
- Publication number
- JPS59207922A JPS59207922A JP8225183A JP8225183A JPS59207922A JP S59207922 A JPS59207922 A JP S59207922A JP 8225183 A JP8225183 A JP 8225183A JP 8225183 A JP8225183 A JP 8225183A JP S59207922 A JPS59207922 A JP S59207922A
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- lactone
- group
- molecular weight
- block copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 32
- 229920001400 block copolymer Polymers 0.000 title claims description 26
- 238000004519 manufacturing process Methods 0.000 title claims description 14
- -1 lactone compound Chemical class 0.000 claims abstract description 77
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 28
- 239000003054 catalyst Substances 0.000 claims abstract description 15
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 9
- 125000003118 aryl group Chemical group 0.000 claims abstract description 6
- 238000003756 stirring Methods 0.000 claims abstract description 6
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 5
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 4
- 125000003545 alkoxy group Chemical group 0.000 claims abstract 2
- 150000001875 compounds Chemical class 0.000 claims description 22
- 238000005809 transesterification reaction Methods 0.000 claims description 6
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical class [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 150000007524 organic acids Chemical class 0.000 claims description 3
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 3
- 229910021626 Tin(II) chloride Inorganic materials 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229920000620 organic polymer Polymers 0.000 abstract description 18
- 229920000642 polymer Polymers 0.000 abstract description 17
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 14
- 230000000694 effects Effects 0.000 abstract description 7
- 239000000654 additive Substances 0.000 abstract description 5
- 150000002596 lactones Chemical class 0.000 abstract description 5
- 230000000996 additive effect Effects 0.000 abstract description 4
- 238000002156 mixing Methods 0.000 abstract description 3
- 229920002554 vinyl polymer Polymers 0.000 abstract description 3
- 125000005375 organosiloxane group Chemical group 0.000 abstract description 2
- 150000002148 esters Chemical group 0.000 abstract 1
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 47
- 229920001577 copolymer Polymers 0.000 description 47
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 25
- 239000004205 dimethyl polysiloxane Substances 0.000 description 24
- 238000000034 method Methods 0.000 description 18
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 14
- 239000007788 liquid Substances 0.000 description 14
- 239000007787 solid Substances 0.000 description 13
- 239000002904 solvent Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 12
- 238000000605 extraction Methods 0.000 description 11
- 229920000728 polyester Polymers 0.000 description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- OZJPLYNZGCXSJM-UHFFFAOYSA-N 5-valerolactone Chemical compound O=C1CCCCO1 OZJPLYNZGCXSJM-UHFFFAOYSA-N 0.000 description 8
- 239000004743 Polypropylene Substances 0.000 description 7
- 229920001155 polypropylene Polymers 0.000 description 7
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 5
- 238000006482 condensation reaction Methods 0.000 description 5
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 5
- 229920000098 polyolefin Polymers 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 4
- YHWCPXVTRSHPNY-UHFFFAOYSA-N butan-1-olate;titanium(4+) Chemical compound [Ti+4].CCCC[O-].CCCC[O-].CCCC[O-].CCCC[O-] YHWCPXVTRSHPNY-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000006116 polymerization reaction Methods 0.000 description 4
- 239000004800 polyvinyl chloride Substances 0.000 description 4
- 229920000915 polyvinyl chloride Polymers 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000007259 addition reaction Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 239000007795 chemical reaction product Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 230000018044 dehydration Effects 0.000 description 3
- 238000006297 dehydration reaction Methods 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 125000001424 substituent group Chemical group 0.000 description 3
- 238000009864 tensile test Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- 239000008096 xylene Substances 0.000 description 3
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 238000012661 block copolymerization Methods 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- BTLSLHNLDQCWKS-UHFFFAOYSA-N oxocan-2-one Chemical compound O=C1CCCCCCO1 BTLSLHNLDQCWKS-UHFFFAOYSA-N 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 2
- 238000007142 ring opening reaction Methods 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 2
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 1
- IYBOGQYZTIIPNI-UHFFFAOYSA-N 2-methylhexano-6-lactone Chemical compound CC1CCCCOC1=O IYBOGQYZTIIPNI-UHFFFAOYSA-N 0.000 description 1
- QUVMSYUGOKEMPX-UHFFFAOYSA-N 2-methylpropan-1-olate;titanium(4+) Chemical compound [Ti+4].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-].CC(C)C[O-] QUVMSYUGOKEMPX-UHFFFAOYSA-N 0.000 description 1
- IGOCBRYRWARFCY-UHFFFAOYSA-N 3-butyloxepan-2-one Chemical compound CCCCC1CCCCOC1=O IGOCBRYRWARFCY-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 229920008712 Copo Polymers 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- RSPISYXLHRIGJD-UHFFFAOYSA-N OOOO Chemical compound OOOO RSPISYXLHRIGJD-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- 238000000862 absorption spectrum Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 238000013019 agitation Methods 0.000 description 1
- 229920003232 aliphatic polyester Polymers 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000004703 alkoxides Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000033228 biological regulation Effects 0.000 description 1
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical group [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 description 1
- MXTOFRMIIQQSOE-UHFFFAOYSA-N butane;titanium(4+) Chemical compound [Ti+4].CCC[CH2-].CCC[CH2-].CCC[CH2-].CCC[CH2-] MXTOFRMIIQQSOE-UHFFFAOYSA-N 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000007810 chemical reaction solvent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- YBMRDBCBODYGJE-UHFFFAOYSA-N germanium oxide Inorganic materials O=[Ge]=O YBMRDBCBODYGJE-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- PVADDRMAFCOOPC-UHFFFAOYSA-N oxogermanium Chemical compound [Ge]=O PVADDRMAFCOOPC-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920001610 polycaprolactone Polymers 0.000 description 1
- 239000004632 polycaprolactone Substances 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- HKJYVRJHDIPMQB-UHFFFAOYSA-N propan-1-olate;titanium(4+) Chemical compound CCCO[Ti](OCCC)(OCCC)OCCC HKJYVRJHDIPMQB-UHFFFAOYSA-N 0.000 description 1
- RLJWTAURUFQFJP-UHFFFAOYSA-N propan-2-ol;titanium Chemical compound [Ti].CC(C)O.CC(C)O.CC(C)O.CC(C)O RLJWTAURUFQFJP-UHFFFAOYSA-N 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-L sebacate(2-) Chemical compound [O-]C(=O)CCCCCCCCC([O-])=O CXMXRPHRNRROMY-UHFFFAOYSA-L 0.000 description 1
- 238000004904 shortening Methods 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- VXUYXOFXAQZZMF-UHFFFAOYSA-N tetraisopropyl titanate Substances CC(C)O[Ti](OC(C)C)(OC(C)C)OC(C)C VXUYXOFXAQZZMF-UHFFFAOYSA-N 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 238000007039 two-step reaction Methods 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Silicon Polymers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyesters Or Polycarbonates (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8225183A JPS59207922A (ja) | 1983-05-11 | 1983-05-11 | ラクトン―シロキサン共重合体組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP8225183A JPS59207922A (ja) | 1983-05-11 | 1983-05-11 | ラクトン―シロキサン共重合体組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59207922A true JPS59207922A (ja) | 1984-11-26 |
| JPH0149297B2 JPH0149297B2 (https=) | 1989-10-24 |
Family
ID=13769215
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP8225183A Granted JPS59207922A (ja) | 1983-05-11 | 1983-05-11 | ラクトン―シロキサン共重合体組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59207922A (https=) |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6137843A (ja) * | 1984-07-24 | 1986-02-22 | ベーイプシロンカー‐ヘミー ゲゼルシヤフト ミツト ベシユレンクテル ハフツンク | ポリエステル基を含むシロキサンを製造する方法 |
| WO1986004072A1 (en) * | 1985-01-04 | 1986-07-17 | Thoratec Laboratories Corporation | Polysiloxane-polylactone block copolymers |
| JPS61157524A (ja) * | 1984-12-28 | 1986-07-17 | Toyobo Co Ltd | ポリエステルの製造方法 |
| US4636552A (en) * | 1984-05-30 | 1987-01-13 | Rhone-Poulenc Recherches | Novel silicone/polylactone graft copolymer |
| JPH01299819A (ja) * | 1988-05-27 | 1989-12-04 | Regurusu:Kk | ポリエステル樹脂及びその製造方法 |
| JPH0299558A (ja) * | 1988-10-06 | 1990-04-11 | Takemoto Oil & Fat Co Ltd | ポリエステル樹脂用耐衝撃性改良剤及び該改良剤を配合して成るポリエステル樹脂組成物 |
| JPH02196862A (ja) * | 1989-01-26 | 1990-08-03 | Shin Etsu Chem Co Ltd | ラクトン変性シリコーン組成物及びそれを含有してなる化粧料又は艶出し材料 |
| JPH02228323A (ja) * | 1989-03-02 | 1990-09-11 | Dainichiseika Color & Chem Mfg Co Ltd | シロキサン変性ポリエステル系樹脂及びその製造方法 |
| JPH02240822A (ja) * | 1989-03-15 | 1990-09-25 | Dainichiseika Color & Chem Mfg Co Ltd | 磁気記録媒体 |
| JPH02240823A (ja) * | 1989-03-15 | 1990-09-25 | Dainichiseika Color & Chem Mfg Co Ltd | 磁気記録媒体 |
| US4963595A (en) * | 1985-01-04 | 1990-10-16 | Thoratec Laboratories Corporation | Polysiloxane-polylactone block copolymers |
| JPH04100845A (ja) * | 1990-08-20 | 1992-04-02 | Dainichiseika Color & Chem Mfg Co Ltd | 樹脂組成物 |
| US5235003A (en) * | 1985-01-04 | 1993-08-10 | Thoratec Laboratories Corporation | Polysiloxane-polylactone block copolymers |
| US5962563A (en) * | 1995-11-15 | 1999-10-05 | Cobe Cardiovascular Operating Co., Inc. | Method for controlling surface concentration of a polymer additive |
| JP2001139689A (ja) * | 1999-11-17 | 2001-05-22 | Shin Etsu Chem Co Ltd | オルガノオキシ基末端オルガノポリシロキサンの製造方法 |
| WO2009139462A1 (ja) * | 2008-05-16 | 2009-11-19 | 日本電気株式会社 | 有機シリコン化合物およびシリカ系微粒子形成用材料 |
| WO2023120690A1 (ja) * | 2021-12-24 | 2023-06-29 | ダウ・東レ株式会社 | 反応性基含有ポリカプロラクトン化合物、それを用いる新規シリコーンエラストマー粒子および化粧料組成物その他の用途 |
-
1983
- 1983-05-11 JP JP8225183A patent/JPS59207922A/ja active Granted
Cited By (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4636552A (en) * | 1984-05-30 | 1987-01-13 | Rhone-Poulenc Recherches | Novel silicone/polylactone graft copolymer |
| JPS6137843A (ja) * | 1984-07-24 | 1986-02-22 | ベーイプシロンカー‐ヘミー ゲゼルシヤフト ミツト ベシユレンクテル ハフツンク | ポリエステル基を含むシロキサンを製造する方法 |
| JPS61157524A (ja) * | 1984-12-28 | 1986-07-17 | Toyobo Co Ltd | ポリエステルの製造方法 |
| EP0208734B1 (en) * | 1985-01-04 | 1990-12-27 | Th. Goldschmidt AG | Polysiloxane-polylactone block copolymers |
| WO1986004072A1 (en) * | 1985-01-04 | 1986-07-17 | Thoratec Laboratories Corporation | Polysiloxane-polylactone block copolymers |
| US4663413A (en) * | 1985-01-04 | 1987-05-05 | Thoratec Laboratories Corp. | Polysiloxane-polylactone block copolymers |
| US5235003A (en) * | 1985-01-04 | 1993-08-10 | Thoratec Laboratories Corporation | Polysiloxane-polylactone block copolymers |
| US4963595A (en) * | 1985-01-04 | 1990-10-16 | Thoratec Laboratories Corporation | Polysiloxane-polylactone block copolymers |
| JPH01299819A (ja) * | 1988-05-27 | 1989-12-04 | Regurusu:Kk | ポリエステル樹脂及びその製造方法 |
| JPH0299558A (ja) * | 1988-10-06 | 1990-04-11 | Takemoto Oil & Fat Co Ltd | ポリエステル樹脂用耐衝撃性改良剤及び該改良剤を配合して成るポリエステル樹脂組成物 |
| JPH02196862A (ja) * | 1989-01-26 | 1990-08-03 | Shin Etsu Chem Co Ltd | ラクトン変性シリコーン組成物及びそれを含有してなる化粧料又は艶出し材料 |
| JPH02228323A (ja) * | 1989-03-02 | 1990-09-11 | Dainichiseika Color & Chem Mfg Co Ltd | シロキサン変性ポリエステル系樹脂及びその製造方法 |
| JPH02240823A (ja) * | 1989-03-15 | 1990-09-25 | Dainichiseika Color & Chem Mfg Co Ltd | 磁気記録媒体 |
| JPH02240822A (ja) * | 1989-03-15 | 1990-09-25 | Dainichiseika Color & Chem Mfg Co Ltd | 磁気記録媒体 |
| JPH04100845A (ja) * | 1990-08-20 | 1992-04-02 | Dainichiseika Color & Chem Mfg Co Ltd | 樹脂組成物 |
| US5962563A (en) * | 1995-11-15 | 1999-10-05 | Cobe Cardiovascular Operating Co., Inc. | Method for controlling surface concentration of a polymer additive |
| JP2001139689A (ja) * | 1999-11-17 | 2001-05-22 | Shin Etsu Chem Co Ltd | オルガノオキシ基末端オルガノポリシロキサンの製造方法 |
| WO2009139462A1 (ja) * | 2008-05-16 | 2009-11-19 | 日本電気株式会社 | 有機シリコン化合物およびシリカ系微粒子形成用材料 |
| US8329849B2 (en) | 2008-05-16 | 2012-12-11 | Nec Corporation | Organic silicon compound and material for forming silica-based fine particle |
| WO2023120690A1 (ja) * | 2021-12-24 | 2023-06-29 | ダウ・東レ株式会社 | 反応性基含有ポリカプロラクトン化合物、それを用いる新規シリコーンエラストマー粒子および化粧料組成物その他の用途 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0149297B2 (https=) | 1989-10-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS59207922A (ja) | ラクトン―シロキサン共重合体組成物 | |
| Teramoto et al. | Cellulose diacetate-graft-poly (lactic acid) s: synthesis of wide-ranging compositions and their thermal and mechanical properties | |
| CN103772878B (zh) | 完全生物降解材料及其制备方法以及化妆品包装盒 | |
| US3121070A (en) | Thermally modified polymers of polypropylene and other polymers and process for preparing the same | |
| US4472556A (en) | Method for enhancing one or more mechanical properties of partially crystalline thermoplastics | |
| TWI633150B (zh) | 含聚酯基底共聚物的熱收縮膜 | |
| JP2004161802A (ja) | 生分解性ポリエステル系樹脂組成物およびその製造方法 | |
| CA2712709A1 (en) | Process for the plasticization of lactic acid polymers | |
| US3299181A (en) | Thermally modified polyethylene and other polymers and process for preparing the same | |
| JPH07196803A (ja) | フッ素化ポリジオルガノシロキサン基剤及びストックの製造方法 | |
| WO2013119450A1 (en) | Bioderived compatibilizer for biopolymers | |
| CN106574103B (zh) | 包括基于聚丙交酯的聚合物的组合物 | |
| JP2022506554A (ja) | 耐高温性、耐老化性ポリグリコライドコポリマーおよびその組成 | |
| FR2656619A1 (fr) | Procede de reticulation de (co)polymeres, compositions reticulables, applications et objets conformes. | |
| JP5483833B2 (ja) | 耐熱性向上剤、熱可塑性樹脂組成物及び成形品 | |
| JP2010142985A (ja) | 樹脂組成物の成形方法及び成形品 | |
| JPH02110111A (ja) | ペンタブロモベンジルエステルモノアクリレートの重合法 | |
| JP2009001950A (ja) | 合成皮革 | |
| JP2591932B2 (ja) | 生物分解性重合体フィルム及びその調製方法 | |
| CN118541404A (zh) | 具有加工助剂的生物降解性聚合物组合物 | |
| JPS6020905A (ja) | 新規熱可塑性重合体 | |
| El Fray et al. | Synthesis and characterization of multiblock copolyesters containing poly (dimethylsiloxane) in the soft segments | |
| JP2575896B2 (ja) | グラフトブロックコポリマーの製造方法及び使用 | |
| JPH02191606A (ja) | 反応性ポリ塩化ビニルおよびこれから製造したポリマー製品 | |
| CN114456608B (zh) | 硬质pvc挤出加工用润滑剂及其制备方法 |