JPS59193922A - 結晶性ポリアミド - Google Patents
結晶性ポリアミドInfo
- Publication number
- JPS59193922A JPS59193922A JP59026905A JP2690584A JPS59193922A JP S59193922 A JPS59193922 A JP S59193922A JP 59026905 A JP59026905 A JP 59026905A JP 2690584 A JP2690584 A JP 2690584A JP S59193922 A JPS59193922 A JP S59193922A
- Authority
- JP
- Japan
- Prior art keywords
- polyamide
- fibers
- copolymer
- mixtures
- polyamide copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 55
- 239000004952 Polyamide Substances 0.000 title claims abstract description 38
- 229920002647 polyamide Polymers 0.000 title claims abstract description 38
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 title abstract description 20
- ZETYUTMSJWMKNQ-UHFFFAOYSA-N n,n',n'-trimethylhexane-1,6-diamine Chemical compound CNCCCCCCN(C)C ZETYUTMSJWMKNQ-UHFFFAOYSA-N 0.000 title abstract description 4
- 229920001577 copolymer Polymers 0.000 claims abstract 7
- 239000000835 fiber Substances 0.000 claims description 23
- 239000003365 glass fiber Substances 0.000 claims description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 239000011521 glass Substances 0.000 claims description 12
- 239000010439 graphite Substances 0.000 claims description 11
- 229910002804 graphite Inorganic materials 0.000 claims description 11
- 239000011324 bead Substances 0.000 claims description 9
- 238000002347 injection Methods 0.000 claims description 9
- 239000007924 injection Substances 0.000 claims description 9
- 238000001746 injection moulding Methods 0.000 claims description 8
- -1 galanubide Substances 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 5
- 229920006039 crystalline polyamide Polymers 0.000 claims description 4
- 238000000465 moulding Methods 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 125000001183 hydrocarbyl group Chemical group 0.000 claims description 3
- 229930195734 saturated hydrocarbon Natural products 0.000 claims description 3
- 229930195733 hydrocarbon Natural products 0.000 claims 10
- 150000002430 hydrocarbons Chemical class 0.000 claims 9
- 239000002557 mineral fiber Substances 0.000 claims 7
- 239000004215 Carbon black (E152) Substances 0.000 claims 3
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 150000001721 carbon Chemical group 0.000 claims 2
- 238000006467 substitution reaction Methods 0.000 claims 2
- 229920000049 Carbon (fiber) Polymers 0.000 claims 1
- 239000004917 carbon fiber Substances 0.000 claims 1
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 claims 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 abstract description 44
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 abstract description 36
- 235000011037 adipic acid Nutrition 0.000 abstract description 22
- 239000001361 adipic acid Substances 0.000 abstract description 22
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 abstract description 4
- 239000012744 reinforcing agent Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 150000003839 salts Chemical class 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000000463 material Substances 0.000 description 6
- 238000006068 polycondensation reaction Methods 0.000 description 6
- 238000005452 bending Methods 0.000 description 5
- 239000003054 catalyst Substances 0.000 description 5
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 239000000178 monomer Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000000376 reactant Substances 0.000 description 3
- 239000012779 reinforcing material Substances 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000011049 filling Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- CVZIHNYAZLXRRS-HNNXBMFYSA-N (3s)-4-{[4-(but-2-ynyloxy)phenyl]sulfonyl}-n-hydroxy-2,2-dimethylthiomorpholine-3-carboxamide Chemical compound C1=CC(OCC#CC)=CC=C1S(=O)(=O)N1[C@@H](C(=O)NO)C(C)(C)SCC1 CVZIHNYAZLXRRS-HNNXBMFYSA-N 0.000 description 1
- UFFRSDWQMJYQNE-UHFFFAOYSA-N 6-azaniumylhexylazanium;hexanedioate Chemical compound [NH3+]CCCCCC[NH3+].[O-]C(=O)CCCCC([O-])=O UFFRSDWQMJYQNE-UHFFFAOYSA-N 0.000 description 1
- UBDHSURDYAETAL-UHFFFAOYSA-N 8-aminonaphthalene-1,3,6-trisulfonic acid Chemical compound OS(=O)(=O)C1=CC(S(O)(=O)=O)=C2C(N)=CC(S(O)(=O)=O)=CC2=C1 UBDHSURDYAETAL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 241001655798 Taku Species 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical group [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 230000008014 freezing Effects 0.000 description 1
- 238000007710 freezing Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000002074 melt spinning Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000010802 sludge Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000002912 waste gas Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
- C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
- C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
- C08G69/265—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids from at least two different diamines or at least two different dicarboxylic acids
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyamides (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Artificial Filaments (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US466898 | 1983-02-16 | ||
| US06/466,898 US4476280A (en) | 1983-02-16 | 1983-02-16 | Polyamide compositions from mixtures of trimethylhexamethylene diamine, hexamethylene diamine and diacids |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59193922A true JPS59193922A (ja) | 1984-11-02 |
| JPH0356577B2 JPH0356577B2 (enExample) | 1991-08-28 |
Family
ID=23853505
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59026905A Granted JPS59193922A (ja) | 1983-02-16 | 1984-02-15 | 結晶性ポリアミド |
Country Status (6)
| Country | Link |
|---|---|
| US (1) | US4476280A (enExample) |
| EP (1) | EP0121983B2 (enExample) |
| JP (1) | JPS59193922A (enExample) |
| AT (1) | ATE44285T1 (enExample) |
| CA (1) | CA1226994A (enExample) |
| DE (1) | DE3478813D1 (enExample) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62282014A (ja) * | 1986-05-30 | 1987-12-07 | Seiken:Kk | 繊維の製造方法 |
| JPH01118636A (ja) * | 1987-10-27 | 1989-05-11 | Shunji Yoshida | 合成糸状体 |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4591473A (en) * | 1982-11-12 | 1986-05-27 | Allied Corporation | Method of spinning a nylon yarn having improved retention of a soil repellent finish on the nylon yarn |
| US4603166A (en) * | 1983-02-16 | 1986-07-29 | Amoco Corporation | Crystalline polyamide composition from dicarboxylic acid mixture and diamine |
| USRE34447E (en) * | 1983-02-16 | 1993-11-16 | Amoco Corporation | Crystalline polyamide composition from dicarboxylic acid mixture and diamine |
| JPS60158220A (ja) * | 1984-01-27 | 1985-08-19 | Mitsui Petrochem Ind Ltd | 摺動材用成形材料 |
| DE3506656A1 (de) * | 1985-02-26 | 1986-08-28 | Bayer Ag, 5090 Leverkusen | Verfahren zur herstellung von copolyamiden aus aromatischen dicarbonsaeuren, adipinsaeure und hexamethylendiamin |
| DE3934926A1 (de) * | 1989-10-20 | 1991-04-25 | Huels Chemische Werke Ag | Gegenueber alkoholen und kochendem wasser bestaendige formmassen |
| US5194578A (en) * | 1990-06-21 | 1993-03-16 | E.I. Du Pont De Nemours And Company | Fiber-forming copolyamide from 2-methyl-pentamethylene diamine |
| US5321120A (en) * | 1993-01-26 | 1994-06-14 | Bostik, Inc. | Copolyamide adhesive compositions containing asymmetric aliphatic residues |
| US5987688A (en) * | 1995-11-09 | 1999-11-23 | Gillette Canada Inc. | Gum-massaging oral brush |
| US5760167A (en) * | 1995-11-15 | 1998-06-02 | Industrial Technology Research Institute | Copolyamide composition with a high glass transition temperature and a low melting point |
| US6886207B1 (en) | 1999-06-14 | 2005-05-03 | The Procter & Gamble Company | Toothbrush |
| US6553604B1 (en) | 2000-03-16 | 2003-04-29 | Gillette Canada Company | Toothbrush |
| US7934284B2 (en) | 2003-02-11 | 2011-05-03 | Braun Gmbh | Toothbrushes |
| US20060272112A9 (en) | 2003-03-14 | 2006-12-07 | The Gillette Company | Toothbrush |
| US20040177462A1 (en) | 2003-03-14 | 2004-09-16 | The Gillette Company | Toothbrush head |
| ES2650712T3 (es) | 2003-04-23 | 2018-01-22 | The Procter & Gamble Company | Cepillos dentales eléctricos |
| US7941886B2 (en) | 2003-09-19 | 2011-05-17 | Braun Gmbh | Toothbrushes |
| US20080081368A1 (en) * | 2006-10-03 | 2008-04-03 | Anne Marie Bailey | Method and apparatus that increases efficiency and reproducibility in immunohistochemistry and immunocytochemistry |
| US8309640B2 (en) | 2008-05-23 | 2012-11-13 | Sabic Innovative Plastics Ip B.V. | High dielectric constant laser direct structuring materials |
| DE102009027611A1 (de) | 2009-07-10 | 2011-01-13 | Evonik Degussa Gmbh | Formmasse auf Basis eines Terephthalsäure- sowie Trimethylhexamethylendiamin-Einheit enthaltenden Copolyamids |
| JP2013544296A (ja) | 2010-10-25 | 2013-12-12 | サビック・イノベーティブ・プラスチックス・アイピー・ベスローテン・フェンノートシャップ | レーザダイレクトストラクチャリング材料の改善された無電解メッキ性能 |
| JP2013545832A (ja) | 2010-10-26 | 2013-12-26 | サビック・イノベーティブ・プラスチックス・アイピー・ベスローテン・フェンノートシャップ | すべての色特性を有するレーザダイレクトストラクチャリング材料 |
| RU2485357C1 (ru) * | 2012-02-27 | 2013-06-20 | Закрытое акционерное общество "Научно-производственная фирма "Невинтермаш" | Лопатка обратно-направляющего аппарата центробежной ступени |
| US9185800B2 (en) | 2012-09-17 | 2015-11-10 | Sabic Global Technologies B.V. | Laser direct structuring materials with improved plating performance and acceptable mechanical properties |
| EP4590763A1 (en) | 2022-09-19 | 2025-07-30 | Solvay Specialty Polymers USA, LLC | Bio based polyamides and corresponding polymer compositions |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5278298A (en) * | 1975-11-12 | 1977-07-01 | Monsanto Co | Fiber formable random copolyamide |
| JPS6026140B2 (ja) * | 1976-11-18 | 1985-06-21 | バイエル・アクチエンゲゼルシヤフト | 透明なコポリアミド |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3145193A (en) * | 1959-10-29 | 1964-08-18 | Grace W R & Co | Polyamides from a mixture of isophthalic acid, terephthalic acid and branched chain aliphatic diamine |
| NL264981A (enExample) * | 1961-05-08 | |||
| NL296609A (enExample) * | 1962-08-14 | |||
| DE1495393B2 (de) * | 1964-11-12 | 1979-10-18 | Dynamit Nobel Ag, 5210 Troisdorf | Verfahren zur Herstellung von Polyamiden aus Methylestern der Tere- und/oder Isophthalsäure und alipatischen primären Diaminen |
| DE1595495A1 (de) * | 1966-04-01 | 1970-03-26 | Witten Gmbh Chem Werke | Verfahren zur Herstellung von Mischpolyamiden der Tere- und Isophthalsaeure mit alipatischen Dicarbonsaeuren in feinkoerniger Form |
| DE1770406A1 (de) * | 1968-05-14 | 1972-02-10 | Wolff Walsrode Ag | Schrumpffaehige filmbildende Copolyamide,ihre Herstellung und ihre Verwendung |
| US3932362A (en) * | 1968-10-28 | 1976-01-13 | Dynamit Nobel Aktiengesellschaft | Amorphous polyamide of C-alkyl substituted diamine and terephthalic acid dialkyl ester having improved electrical creep resistance |
| US3842046A (en) * | 1969-06-26 | 1974-10-15 | Veba Chemie Ag | Polyamides of trimethylhexamethylenediamine cycloaliphatic dicarboxylic acid and carbocyclic aromatic dicarboxylic acid |
| BE756343A (fr) * | 1969-09-18 | 1971-03-01 | Dynamit Nobel Ag | Polyamides particulierement appropries pour les matieres a mouler |
| NL7108318A (enExample) * | 1970-07-04 | 1972-01-06 |
-
1983
- 1983-02-16 US US06/466,898 patent/US4476280A/en not_active Expired - Lifetime
-
1984
- 1984-02-03 CA CA000446714A patent/CA1226994A/en not_active Expired
- 1984-02-07 DE DE8484300743T patent/DE3478813D1/de not_active Expired
- 1984-02-07 AT AT84300743T patent/ATE44285T1/de active
- 1984-02-07 EP EP84300743A patent/EP0121983B2/en not_active Expired - Lifetime
- 1984-02-15 JP JP59026905A patent/JPS59193922A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5278298A (en) * | 1975-11-12 | 1977-07-01 | Monsanto Co | Fiber formable random copolyamide |
| JPS6026140B2 (ja) * | 1976-11-18 | 1985-06-21 | バイエル・アクチエンゲゼルシヤフト | 透明なコポリアミド |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62282014A (ja) * | 1986-05-30 | 1987-12-07 | Seiken:Kk | 繊維の製造方法 |
| JPH01118636A (ja) * | 1987-10-27 | 1989-05-11 | Shunji Yoshida | 合成糸状体 |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0356577B2 (enExample) | 1991-08-28 |
| CA1226994A (en) | 1987-09-15 |
| DE3478813D1 (en) | 1989-08-03 |
| US4476280A (en) | 1984-10-09 |
| ATE44285T1 (de) | 1989-07-15 |
| EP0121983A2 (en) | 1984-10-17 |
| EP0121983A3 (en) | 1985-05-08 |
| EP0121983B2 (en) | 1996-01-03 |
| EP0121983B1 (en) | 1989-06-28 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |