JPS59184723A - 結晶性メタロシリケ−トの製造法 - Google Patents
結晶性メタロシリケ−トの製造法Info
- Publication number
- JPS59184723A JPS59184723A JP5916083A JP5916083A JPS59184723A JP S59184723 A JPS59184723 A JP S59184723A JP 5916083 A JP5916083 A JP 5916083A JP 5916083 A JP5916083 A JP 5916083A JP S59184723 A JPS59184723 A JP S59184723A
- Authority
- JP
- Japan
- Prior art keywords
- source
- methanol
- water
- silica
- crystalline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004519 manufacturing process Methods 0.000 title claims description 10
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 58
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 51
- 239000000203 mixture Substances 0.000 claims abstract description 28
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 27
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052783 alkali metal Inorganic materials 0.000 claims abstract description 5
- 150000001340 alkali metals Chemical group 0.000 claims abstract description 5
- 229910052751 metal Inorganic materials 0.000 claims abstract description 5
- 239000002184 metal Substances 0.000 claims abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 4
- 238000010438 heat treatment Methods 0.000 claims abstract description 4
- 229910052710 silicon Inorganic materials 0.000 claims abstract 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 4
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 4
- 230000000737 periodic effect Effects 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims 1
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 11
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 10
- 229910052681 coesite Inorganic materials 0.000 abstract description 6
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 6
- 229910052682 stishovite Inorganic materials 0.000 abstract description 6
- 229910052905 tridymite Inorganic materials 0.000 abstract description 6
- 239000003054 catalyst Substances 0.000 abstract description 5
- 239000003463 adsorbent Substances 0.000 abstract description 3
- 150000002739 metals Chemical class 0.000 abstract description 2
- 230000003197 catalytic effect Effects 0.000 abstract 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 14
- 238000000034 method Methods 0.000 description 12
- 238000002441 X-ray diffraction Methods 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000010304 firing Methods 0.000 description 7
- 239000013078 crystal Substances 0.000 description 6
- JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 6
- 229910052810 boron oxide Inorganic materials 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 4
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 description 3
- 235000019353 potassium silicate Nutrition 0.000 description 3
- 230000035484 reaction time Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 241000511343 Chondrostoma nasus Species 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- PHFQLYPOURZARY-UHFFFAOYSA-N chromium trinitrate Chemical compound [Cr+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PHFQLYPOURZARY-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 2
- -1 hydroxyl ions Chemical class 0.000 description 2
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical compound [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 description 2
- 239000011541 reaction mixture Substances 0.000 description 2
- 238000007873 sieving Methods 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 229910001388 sodium aluminate Inorganic materials 0.000 description 2
- 239000011973 solid acid Substances 0.000 description 2
- BNGXYYYYKUGPPF-UHFFFAOYSA-M (3-methylphenyl)methyl-triphenylphosphanium;chloride Chemical compound [Cl-].CC1=CC=CC(C[P+](C=2C=CC=CC=2)(C=2C=CC=CC=2)C=2C=CC=CC=2)=C1 BNGXYYYYKUGPPF-UHFFFAOYSA-M 0.000 description 1
- MFGOFGRYDNHJTA-UHFFFAOYSA-N 2-amino-1-(2-fluorophenyl)ethanol Chemical compound NCC(O)C1=CC=CC=C1F MFGOFGRYDNHJTA-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000004111 Potassium silicate Substances 0.000 description 1
- 239000004115 Sodium Silicate Substances 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 229910000272 alkali metal oxide Inorganic materials 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 229910001593 boehmite Inorganic materials 0.000 description 1
- HUCVOHYBFXVBRW-UHFFFAOYSA-M caesium hydroxide Inorganic materials [OH-].[Cs+] HUCVOHYBFXVBRW-UHFFFAOYSA-M 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 150000003841 chloride salts Chemical class 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 239000005350 fused silica glass Substances 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 235000011007 phosphoric acid Nutrition 0.000 description 1
- NNHHDJVEYQHLHG-UHFFFAOYSA-N potassium silicate Chemical compound [K+].[K+].[O-][Si]([O-])=O NNHHDJVEYQHLHG-UHFFFAOYSA-N 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 229910052911 sodium silicate Inorganic materials 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229910001631 strontium chloride Inorganic materials 0.000 description 1
- AHBGXTDRMVNFER-UHFFFAOYSA-L strontium dichloride Chemical compound [Cl-].[Cl-].[Sr+2] AHBGXTDRMVNFER-UHFFFAOYSA-L 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000002747 voluntary effect Effects 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C01B35/08—Compounds containing boron and nitrogen, phosphorus, oxygen, sulfur, selenium or tellurium
- C01B35/10—Compounds containing boron and oxygen
- C01B35/1009—Compounds containing boron and oxygen having molecular-sieve properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5916083A JPS59184723A (ja) | 1983-04-06 | 1983-04-06 | 結晶性メタロシリケ−トの製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP5916083A JPS59184723A (ja) | 1983-04-06 | 1983-04-06 | 結晶性メタロシリケ−トの製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59184723A true JPS59184723A (ja) | 1984-10-20 |
| JPH0551531B2 JPH0551531B2 (enrdf_load_stackoverflow) | 1993-08-02 |
Family
ID=13105334
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP5916083A Granted JPS59184723A (ja) | 1983-04-06 | 1983-04-06 | 結晶性メタロシリケ−トの製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59184723A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62105917A (ja) * | 1985-11-01 | 1987-05-16 | Agency Of Ind Science & Technol | アルカリ土類金属含有アルミノボロシリケ−ト，その製造方法およびそれを触媒とする低級オレフインの製造方法 |
| JPS62162616A (ja) * | 1986-01-10 | 1987-07-18 | Chiyoda Chem Eng & Constr Co Ltd | 結晶性メタロシリケ−ト |
| JP2016505498A (ja) * | 2012-12-21 | 2016-02-25 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 小さな結晶ｚｓｍ−５、その合成および使用 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5243800A (en) * | 1975-09-29 | 1977-04-06 | Ici Ltd | Process for preparing zeolite |
| JPS54151600A (en) * | 1978-04-06 | 1979-11-28 | Shell Int Research | Manufacture of zeolite |
-
1983
- 1983-04-06 JP JP5916083A patent/JPS59184723A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5243800A (en) * | 1975-09-29 | 1977-04-06 | Ici Ltd | Process for preparing zeolite |
| JPS54151600A (en) * | 1978-04-06 | 1979-11-28 | Shell Int Research | Manufacture of zeolite |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62105917A (ja) * | 1985-11-01 | 1987-05-16 | Agency Of Ind Science & Technol | アルカリ土類金属含有アルミノボロシリケ−ト，その製造方法およびそれを触媒とする低級オレフインの製造方法 |
| JPS62162616A (ja) * | 1986-01-10 | 1987-07-18 | Chiyoda Chem Eng & Constr Co Ltd | 結晶性メタロシリケ−ト |
| JP2016505498A (ja) * | 2012-12-21 | 2016-02-25 | エクソンモービル ケミカル パテンツ インコーポレイテッド | 小さな結晶ｚｓｍ−５、その合成および使用 |
| US10081552B2 (en) | 2012-12-21 | 2018-09-25 | Exxonmobil Research And Engineering Company | Small crystal ZSM-5, its synthesis and use |
| US10662068B2 (en) | 2012-12-21 | 2020-05-26 | Exxonmobil Research & Engineering Company | Small crystal ZSM-5, its synthesis and use |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0551531B2 (enrdf_load_stackoverflow) | 1993-08-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5926924A (ja) | 結晶性シリケートの製造方法 | |
| JPH06507877A (ja) | 硼珪酸塩ゼオライトの製造 | |
| JPS5860613A (ja) | ガリウム−および／またはインジウム含有ゼオライトおよびそれらの製造方法ならびにそれらの用途 | |
| JPS59184723A (ja) | 結晶性メタロシリケ−トの製造法 | |
| JPS6011222A (ja) | 分子篩ゼオライトおよびその製法 | |
| JPH0228523B2 (enrdf_load_stackoverflow) | ||
| JPS62138320A (ja) | 合成フオ−ジヤサイト成形体の製造法 | |
| JPS59184722A (ja) | 結晶性メタロシリケ−トの製造方法 | |
| JPH11221470A (ja) | 窒素酸化物還元用触媒及び窒素酸化物の還元方法 | |
| US7097772B2 (en) | Method of purifying a waste stream using a microporous composition | |
| JPH0672009B2 (ja) | 大結晶モルデナイト及びその製造方法 | |
| JPS5992913A (ja) | 結晶性鉄シリケ−ト焼成体およびその製造方法 | |
| JPS6117417A (ja) | 結晶性アルミノシリケ−トゼオライトおよびその製造方法 | |
| JPS6065714A (ja) | 鉄―チタン―金属含有結晶性シリケートの製造方法 | |
| JPH03229620A (ja) | 窒素酸化物含有排ガスの浄化方法 | |
| JP2002507184A (ja) | アクチニド含有モレキュラーシーブ | |
| JPS5983927A (ja) | 新規結晶性アルミノシリケ−トゼオライトおよびその製造方法 | |
| US1896627A (en) | Catalytic oxidation of ammonia | |
| JPS5916833A (ja) | 低級オレフインの製造方法 | |
| JPS60147494A (ja) | 炭化水素の製造方法 | |
| JPS63277509A (ja) | 改良されたｚｓｍ型ゼオライトの製造方法 | |
| JPS59176219A (ja) | 有機原料の転化方法 | |
| JPH0672010B2 (ja) | 結晶性アルミノシリケ−ト及びその製造方法 | |
| JPS623014A (ja) | 結晶性アルミノ珪酸塩およびその製造法 | |
| JPS6049131B2 (ja) | 改良された結晶質アルミノシリケ−トの製造方法 |