JPS582997B2 - 重質炭化水素流の水添処理方法 - Google Patents
重質炭化水素流の水添処理方法Info
- Publication number
- JPS582997B2 JPS582997B2 JP53158114A JP15811478A JPS582997B2 JP S582997 B2 JPS582997 B2 JP S582997B2 JP 53158114 A JP53158114 A JP 53158114A JP 15811478 A JP15811478 A JP 15811478A JP S582997 B2 JPS582997 B2 JP S582997B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- pore volume
- pores
- weight
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000000034 method Methods 0.000 title claims description 79
- 150000002430 hydrocarbons Chemical class 0.000 title claims description 70
- 229930195733 hydrocarbon Natural products 0.000 title claims description 67
- 239000004215 Carbon black (E152) Substances 0.000 title claims description 59
- 238000005984 hydrogenation reaction Methods 0.000 title claims description 20
- 239000003054 catalyst Substances 0.000 claims description 201
- 239000011148 porous material Substances 0.000 claims description 142
- 229910052751 metal Inorganic materials 0.000 claims description 78
- 239000002184 metal Substances 0.000 claims description 78
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 63
- 150000002739 metals Chemical class 0.000 claims description 45
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 35
- 239000011651 chromium Substances 0.000 claims description 35
- 229910052750 molybdenum Inorganic materials 0.000 claims description 35
- 239000011733 molybdenum Substances 0.000 claims description 35
- 229910052804 chromium Inorganic materials 0.000 claims description 32
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims description 30
- 239000001257 hydrogen Substances 0.000 claims description 30
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 28
- 239000010941 cobalt Substances 0.000 claims description 27
- 229910017052 cobalt Inorganic materials 0.000 claims description 27
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 24
- -1 asphaltenes Chemical class 0.000 claims description 19
- 229910017464 nitrogen compound Inorganic materials 0.000 claims description 13
- 150000002830 nitrogen compounds Chemical class 0.000 claims description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- 229910052717 sulfur Inorganic materials 0.000 claims description 12
- 150000003464 sulfur compounds Chemical class 0.000 claims description 12
- 239000011593 sulfur Substances 0.000 claims description 11
- 150000001875 compounds Chemical class 0.000 claims description 10
- 150000003568 thioethers Chemical class 0.000 claims description 8
- 238000005470 impregnation Methods 0.000 claims description 7
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 5
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 48
- 239000000463 material Substances 0.000 description 34
- 239000003921 oil Substances 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 24
- 229910052759 nickel Inorganic materials 0.000 description 24
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 18
- 239000007789 gas Substances 0.000 description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 17
- 229910052720 vanadium Inorganic materials 0.000 description 15
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 14
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 description 13
- 238000006477 desulfuration reaction Methods 0.000 description 12
- 230000023556 desulfurization Effects 0.000 description 12
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 12
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 11
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 11
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 11
- 239000000243 solution Substances 0.000 description 11
- 238000012360 testing method Methods 0.000 description 11
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 9
- 239000000356 contaminant Substances 0.000 description 9
- 229910052742 iron Inorganic materials 0.000 description 9
- 238000012545 processing Methods 0.000 description 9
- 239000000377 silicon dioxide Substances 0.000 description 9
- 238000002474 experimental method Methods 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 239000010779 crude oil Substances 0.000 description 7
- 230000000694 effects Effects 0.000 description 7
- 239000003209 petroleum derivative Substances 0.000 description 7
- 239000007788 liquid Substances 0.000 description 6
- 239000000395 magnesium oxide Substances 0.000 description 6
- APUPEJJSWDHEBO-UHFFFAOYSA-P ammonium molybdate Chemical compound [NH4+].[NH4+].[O-][Mo]([O-])(=O)=O APUPEJJSWDHEBO-UHFFFAOYSA-P 0.000 description 5
- 239000011609 ammonium molybdate Substances 0.000 description 5
- 229940010552 ammonium molybdate Drugs 0.000 description 5
- 235000018660 ammonium molybdate Nutrition 0.000 description 5
- 238000009835 boiling Methods 0.000 description 5
- 238000004517 catalytic hydrocracking Methods 0.000 description 5
- 239000000295 fuel oil Substances 0.000 description 5
- 230000000737 periodic effect Effects 0.000 description 5
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 5
- 229910052721 tungsten Inorganic materials 0.000 description 5
- 239000010937 tungsten Substances 0.000 description 5
- JOSWYUNQBRPBDN-UHFFFAOYSA-P ammonium dichromate Chemical compound [NH4+].[NH4+].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O JOSWYUNQBRPBDN-UHFFFAOYSA-P 0.000 description 4
- 238000005336 cracking Methods 0.000 description 4
- 239000000446 fuel Substances 0.000 description 4
- 229910052809 inorganic oxide Inorganic materials 0.000 description 4
- 150000002902 organometallic compounds Chemical class 0.000 description 4
- 230000000704 physical effect Effects 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000005292 vacuum distillation Methods 0.000 description 4
- XZMCDFZZKTWFGF-UHFFFAOYSA-N Cyanamide Chemical compound NC#N XZMCDFZZKTWFGF-UHFFFAOYSA-N 0.000 description 3
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 3
- 238000004523 catalytic cracking Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 3
- 238000006317 isomerization reaction Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 229910000476 molybdenum oxide Inorganic materials 0.000 description 3
- PQQKPALAQIIWST-UHFFFAOYSA-N oxomolybdenum Chemical class [Mo]=O PQQKPALAQIIWST-UHFFFAOYSA-N 0.000 description 3
- 239000003208 petroleum Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 241000238557 Decapoda Species 0.000 description 2
- 241000588731 Hafnia Species 0.000 description 2
- 230000002411 adverse Effects 0.000 description 2
- 239000010426 asphalt Substances 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 238000006356 dehydrogenation reaction Methods 0.000 description 2
- 230000002939 deleterious effect Effects 0.000 description 2
- 230000001627 detrimental effect Effects 0.000 description 2
- CJNBYAVZURUTKZ-UHFFFAOYSA-N hafnium(IV) oxide Inorganic materials O=[Hf]=O CJNBYAVZURUTKZ-UHFFFAOYSA-N 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 229910052976 metal sulfide Inorganic materials 0.000 description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 238000002203 pretreatment Methods 0.000 description 2
- 238000000746 purification Methods 0.000 description 2
- 238000002407 reforming Methods 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 241000143060 Americamysis bahia Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- 208000033830 Hot Flashes Diseases 0.000 description 1
- 206010060800 Hot flush Diseases 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 229910052770 Uranium Inorganic materials 0.000 description 1
- RNGSTWPRDROEIW-UHFFFAOYSA-N [Ni].N1C(C=C2N=C(C=C3NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 Chemical class [Ni].N1C(C=C2N=C(C=C3NC(=C4)C=C3)C=C2)=CC=C1C=C1C=CC4=N1 RNGSTWPRDROEIW-UHFFFAOYSA-N 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 230000029936 alkylation Effects 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- AZDRQVAHHNSJOQ-UHFFFAOYSA-N alumane Chemical class [AlH3] AZDRQVAHHNSJOQ-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- VXAUWWUXCIMFIM-UHFFFAOYSA-M aluminum;oxygen(2-);hydroxide Chemical compound [OH-].[O-2].[Al+3] VXAUWWUXCIMFIM-UHFFFAOYSA-M 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000011021 bench scale process Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- CETPSERCERDGAM-UHFFFAOYSA-N ceric oxide Chemical compound O=[Ce]=O CETPSERCERDGAM-UHFFFAOYSA-N 0.000 description 1
- 229910000422 cerium(IV) oxide Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910000423 chromium oxide Inorganic materials 0.000 description 1
- GRWVQDDAKZFPFI-UHFFFAOYSA-H chromium(III) sulfate Chemical compound [Cr+3].[Cr+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O GRWVQDDAKZFPFI-UHFFFAOYSA-H 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- UFMZWBIQTDUYBN-UHFFFAOYSA-N cobalt dinitrate Chemical compound [Co+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O UFMZWBIQTDUYBN-UHFFFAOYSA-N 0.000 description 1
- 229910001981 cobalt nitrate Inorganic materials 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000007580 dry-mixing Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 229910052732 germanium Inorganic materials 0.000 description 1
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000010763 heavy fuel oil Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011344 liquid material Substances 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 125000005609 naphthenate group Chemical group 0.000 description 1
- 150000002816 nickel compounds Chemical class 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical class [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- ZCUFMDLYAMJYST-UHFFFAOYSA-N thorium dioxide Chemical compound O=[Th]=O ZCUFMDLYAMJYST-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/24—Chromium, molybdenum or tungsten
- B01J23/28—Molybdenum
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/66—Pore distribution
- B01J35/67—Pore distribution monomodal
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US86284777A | 1977-12-21 | 1977-12-21 | |
| US86284877A | 1977-12-21 | 1977-12-21 | |
| US05/967,413 US4181602A (en) | 1977-12-21 | 1978-12-07 | Process for the hydrotreating of heavy hydrocarbon streams |
| US05/967,432 US4188284A (en) | 1977-12-21 | 1978-12-07 | Process for the hydrotreating of heavy hydrocarbon streams |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS54116004A JPS54116004A (en) | 1979-09-10 |
| JPS582997B2 true JPS582997B2 (ja) | 1983-01-19 |
Family
ID=27505940
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP53158114A Expired JPS582997B2 (ja) | 1977-12-21 | 1978-12-21 | 重質炭化水素流の水添処理方法 |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPS582997B2 (de) |
| CA (1) | CA1102729A (de) |
| DD (1) | DD140894A5 (de) |
| DE (1) | DE2855398A1 (de) |
| FR (1) | FR2412603A1 (de) |
| GB (1) | GB2011463B (de) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60225397A (ja) * | 1984-04-20 | 1985-11-09 | 株式会社東芝 | 高周波加熱装置 |
| JPH0546079B2 (de) * | 1984-09-07 | 1993-07-12 | Tokyo Shibaura Electric Co |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4224144A (en) * | 1979-03-19 | 1980-09-23 | Standard Oil Company (Indiana) | Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur |
| ATE10068T1 (de) * | 1980-10-24 | 1984-11-15 | Standard Oil Company | Katalysator und verfahren zur hydrodenitrifizierung und hydrokrackung stickstoffreicher beschickungen. |
| ZA814030B (en) * | 1980-10-24 | 1982-06-30 | Standard Oil Co | Catalyst and process for the hydrotreating of nitrogen-containing feeds |
| CA1217756A (en) * | 1983-08-10 | 1987-02-10 | Hri, Inc. | Demetallization catalyst and process for metals- containing hydrocarbon feedstocks |
| JPS6065092A (ja) * | 1983-09-21 | 1985-04-13 | Res Assoc Petroleum Alternat Dev<Rapad> | オイルサンド油および残渣油の脱金属法 |
| GB8701740D0 (en) * | 1987-01-27 | 1987-03-04 | Shell Int Research | Catalytic conversion of hydrocarbon oils |
| US8123932B2 (en) * | 2002-12-20 | 2012-02-28 | Eni S.P.A. | Process for the conversion of heavy feedstocks such as heavy crude oils and distillation residues |
| GB201615197D0 (en) * | 2016-09-07 | 2016-10-19 | Mexichem Fluor Sa De Cv | Catalyst and process using the catalyst |
| GB201615209D0 (en) * | 2016-09-07 | 2016-10-19 | Mexichem Fluor Sa De Cv | Catalyst and process using the catalyst |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB353507A (en) * | 1930-04-25 | 1931-07-27 | Bataafsche Petroleum | Process of refining liquid carbonaceous materials such as petroleum products and residues, asphalt and the like |
| US2577823A (en) * | 1948-02-06 | 1951-12-11 | Standard Oil Co | Hydrodesulfurization of sulfurcontaining hydrocarbon fractions |
| DE1037627B (de) * | 1953-06-15 | 1958-08-28 | Socony Mobil Oil Co Inc | Katalysator zur Behandlung von Kohlenwasserstoffen oder Kohlenwasserstoffgemischen, insbesondere fuer Reformierverfahren und Verfahren zu seiner Herstellung |
| US3245919A (en) * | 1961-05-22 | 1966-04-12 | Sinclair Refining Co | Boehmite base precursor |
| US3265615A (en) * | 1963-12-05 | 1966-08-09 | Chevron Res | Chromium-containing hydrofining catalysts |
| US3752776A (en) * | 1970-11-16 | 1973-08-14 | Mobil Oil Corp | Multimetalite catalysts |
-
1978
- 1978-12-18 GB GB7848853A patent/GB2011463B/en not_active Expired
- 1978-12-20 CA CA318,313A patent/CA1102729A/en not_active Expired
- 1978-12-21 FR FR7836039A patent/FR2412603A1/fr active Granted
- 1978-12-21 DE DE19782855398 patent/DE2855398A1/de not_active Withdrawn
- 1978-12-21 DD DD78210059A patent/DD140894A5/de unknown
- 1978-12-21 JP JP53158114A patent/JPS582997B2/ja not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60225397A (ja) * | 1984-04-20 | 1985-11-09 | 株式会社東芝 | 高周波加熱装置 |
| JPH0546079B2 (de) * | 1984-09-07 | 1993-07-12 | Tokyo Shibaura Electric Co |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS54116004A (en) | 1979-09-10 |
| CA1102729A (en) | 1981-06-09 |
| FR2412603B1 (de) | 1984-02-24 |
| GB2011463B (en) | 1982-05-19 |
| DD140894A5 (de) | 1980-04-02 |
| FR2412603A1 (fr) | 1979-07-20 |
| GB2011463A (en) | 1979-07-11 |
| DE2855398A1 (de) | 1979-07-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4181602A (en) | Process for the hydrotreating of heavy hydrocarbon streams | |
| US4191635A (en) | Process for the cracking of heavy hydrocarbon streams | |
| US4431525A (en) | Three-catalyst process for the hydrotreating of heavy hydrocarbon streams | |
| US4212729A (en) | Process for demetallation and desulfurization of heavy hydrocarbons | |
| US4225421A (en) | Process for hydrotreating heavy hydrocarbons | |
| US4297242A (en) | Process for demetallation and desulfurization of heavy hydrocarbons | |
| US4188284A (en) | Process for the hydrotreating of heavy hydrocarbon streams | |
| KR102542845B1 (ko) | 고 수소화탈질소 선택도 수소처리 촉매 | |
| US4657663A (en) | Hydrotreating process employing a three-stage catalyst system wherein a titanium compound is employed in the second stage | |
| CA2403999C (en) | Staged hydrotreating method for naphtha desulfurization | |
| US4306965A (en) | Hydrotreating process | |
| JPS6361357B2 (de) | ||
| US4224144A (en) | Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur | |
| AU2001249836A1 (en) | Staged hydrotreating method for naphtha desulfurization | |
| JP2004230383A (ja) | 硫黄化合物及びオレフィンを含む留分の水素処理に使用可能な部分的にコーキングされた触媒 | |
| US4278566A (en) | Hydrotreating process | |
| JP4452911B2 (ja) | 第８族および第６ｂ族の元素を含む担持触媒の存在下に、硫黄含有化合物およびオレフィンを含む留分を水素化脱硫するための方法 | |
| JPS582997B2 (ja) | 重質炭化水素流の水添処理方法 | |
| WO2004078886A1 (ja) | 軽油留分の水素化処理方法 | |
| EP0034908B1 (de) | Verfahren zur hydrierenden Entmetallisierung von Kohlenwasserstoffströmen | |
| JPH1088152A (ja) | 炭化水素油の水素化精製方法 | |
| US4210525A (en) | Hydrodenitrogenation of demetallized residual oil | |
| CN118434832A (zh) | 包括稀释步骤的含有硫化合物的汽油的处理方法 | |
| CS235073B2 (cs) | Způsob hydrogenacnihn zpracování frakce těžkých uhlovodíků obsahující kovy, asfalteny, sloučeniny síry a sloučeniny dusíku | |
| PL118183B1 (en) | Method of catalytic hydrogenation of heavy hydrocarbons glevodorodov |