GB2011463A - Process for the Hydrotreating of Heavy Hydrocarbon Streams - Google Patents

Process for the Hydrotreating of Heavy Hydrocarbon Streams

Info

Publication number
GB2011463A
GB2011463A GB7848853A GB7848853A GB2011463A GB 2011463 A GB2011463 A GB 2011463A GB 7848853 A GB7848853 A GB 7848853A GB 7848853 A GB7848853 A GB 7848853A GB 2011463 A GB2011463 A GB 2011463A
Authority
GB
United Kingdom
Prior art keywords
range
calculated
amount
present
heavy hydrocarbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7848853A
Other versions
GB2011463B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Standard Oil Co
Original Assignee
Standard Oil Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US05/967,413 external-priority patent/US4181602A/en
Priority claimed from US05/967,432 external-priority patent/US4188284A/en
Application filed by Standard Oil Co filed Critical Standard Oil Co
Publication of GB2011463A publication Critical patent/GB2011463A/en
Application granted granted Critical
Publication of GB2011463B publication Critical patent/GB2011463B/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8878—Chromium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/28—Molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/64—Pore diameter
    • B01J35/647—2-50 nm
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/66—Pore distribution
    • B01J35/67—Pore distribution monomodal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

The process comprises contacting a heavy hydrocarbon stream containing metals and asphaltenes under suitable conditions and in the presence of hydrogen with a catalyst comprising a hydrogenating component comprising molybdenum and chromium, their oxides, their sulfides, or mixtures thereof on a large-pore, catalytically active alumina. The catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.8 cc/gm, a surface area within the range of about 150 m<2>/gm to about 300 m<2>/gm, and an average pore diameter within the range of about 100 ANGSTROM (10nm) to about 200 ANGSTROM (20 nm). The hydrogenating component can include cobalt and/or its oxide and/or its sulfide. The molybdenum is present in an amount within the range of about 5 wt.% to about 15 wt.%, calculated as MoO3 and based upon total catalyst weight, the chromium is present in an amount within the range of about 5 wt.% to about 20 wt.%, calculated as Cr2O3 and based upon the total catalyst weight, and the cobalt, when present, is there in an amount within the range of about 0.1 wt.% to about 5 wt.%, calculated as CoO and based upon the total catalyst weight. The flow diagram depicts a preferred embodiment of the process. <IMAGE>
GB7848853A 1977-12-21 1978-12-18 Process for the hydrotreating of heafy hydrocarbon streams Expired GB2011463B (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US86284777A 1977-12-21 1977-12-21
US86284877A 1977-12-21 1977-12-21
US05/967,413 US4181602A (en) 1977-12-21 1978-12-07 Process for the hydrotreating of heavy hydrocarbon streams
US05/967,432 US4188284A (en) 1977-12-21 1978-12-07 Process for the hydrotreating of heavy hydrocarbon streams

Publications (2)

Publication Number Publication Date
GB2011463A true GB2011463A (en) 1979-07-11
GB2011463B GB2011463B (en) 1982-05-19

Family

ID=27505940

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7848853A Expired GB2011463B (en) 1977-12-21 1978-12-18 Process for the hydrotreating of heafy hydrocarbon streams

Country Status (6)

Country Link
JP (1) JPS582997B2 (en)
CA (1) CA1102729A (en)
DD (1) DD140894A5 (en)
DE (1) DE2855398A1 (en)
FR (1) FR2412603A1 (en)
GB (1) GB2011463B (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0016599A1 (en) * 1979-03-19 1980-10-01 Standard Oil Company Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur and catalyst used in such hydrotreatment
EP0050911A1 (en) * 1980-10-24 1982-05-05 Standard Oil Company Catalyst and process for the hydrodenitrogenation and hydrocracking of high-nitrogen feeds
EP0050912A1 (en) * 1980-10-24 1982-05-05 Standard Oil Company Catalyst and process for the hydrotreating of nitrogen-containing feeds
FR2550544A1 (en) * 1983-08-10 1985-02-15 Hydrocarbon Research Inc Catalyst for hydro-demetallisation and hydroconversion
EP0280342A2 (en) * 1987-01-27 1988-08-31 Shell Internationale Researchmaatschappij B.V. Process for the catalytic conversion of hydrocarbon oils
US11406965B2 (en) 2016-09-07 2022-08-09 Mexichem Fluor S.A. De C.V. Catalyst and process using the catalyst for manufacturing fluorinated hydrocarbons
US11452990B2 (en) 2016-09-07 2022-09-27 Mexichem Fluor S.A. De C.V. Catalyst and process using the catalyst for manufacturing fluorinated hydrocarbons

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6065092A (en) * 1983-09-21 1985-04-13 Res Assoc Petroleum Alternat Dev<Rapad> Removal of metal from oil sand oil and residual oil
JPS60225397A (en) * 1984-04-20 1985-11-09 株式会社東芝 High frequency heater
JPS6166397A (en) * 1984-09-07 1986-04-05 株式会社東芝 High frequency heater
US8123932B2 (en) * 2002-12-20 2012-02-28 Eni S.P.A. Process for the conversion of heavy feedstocks such as heavy crude oils and distillation residues

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB353507A (en) * 1930-04-25 1931-07-27 Bataafsche Petroleum Process of refining liquid carbonaceous materials such as petroleum products and residues, asphalt and the like
US2577823A (en) * 1948-02-06 1951-12-11 Standard Oil Co Hydrodesulfurization of sulfurcontaining hydrocarbon fractions
DE1037627B (en) * 1953-06-15 1958-08-28 Socony Mobil Oil Co Inc Catalyst for the treatment of hydrocarbons or hydrocarbon mixtures, in particular for reforming processes and processes for their production
US3245919A (en) * 1961-05-22 1966-04-12 Sinclair Refining Co Boehmite base precursor
US3265615A (en) * 1963-12-05 1966-08-09 Chevron Res Chromium-containing hydrofining catalysts
US3752776A (en) * 1970-11-16 1973-08-14 Mobil Oil Corp Multimetalite catalysts

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0016599A1 (en) * 1979-03-19 1980-10-01 Standard Oil Company Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur and catalyst used in such hydrotreatment
EP0050911A1 (en) * 1980-10-24 1982-05-05 Standard Oil Company Catalyst and process for the hydrodenitrogenation and hydrocracking of high-nitrogen feeds
EP0050912A1 (en) * 1980-10-24 1982-05-05 Standard Oil Company Catalyst and process for the hydrotreating of nitrogen-containing feeds
FR2550544A1 (en) * 1983-08-10 1985-02-15 Hydrocarbon Research Inc Catalyst for hydro-demetallisation and hydroconversion
EP0280342A2 (en) * 1987-01-27 1988-08-31 Shell Internationale Researchmaatschappij B.V. Process for the catalytic conversion of hydrocarbon oils
EP0280342A3 (en) * 1987-01-27 1989-10-11 Shell Internationale Research Maatschappij B.V. Process for the catalytic conversion of hydrocarbon oils
US11406965B2 (en) 2016-09-07 2022-08-09 Mexichem Fluor S.A. De C.V. Catalyst and process using the catalyst for manufacturing fluorinated hydrocarbons
US11452990B2 (en) 2016-09-07 2022-09-27 Mexichem Fluor S.A. De C.V. Catalyst and process using the catalyst for manufacturing fluorinated hydrocarbons

Also Published As

Publication number Publication date
JPS54116004A (en) 1979-09-10
CA1102729A (en) 1981-06-09
FR2412603B1 (en) 1984-02-24
GB2011463B (en) 1982-05-19
JPS582997B2 (en) 1983-01-19
DD140894A5 (en) 1980-04-02
FR2412603A1 (en) 1979-07-20
DE2855398A1 (en) 1979-07-05

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee