GB963941A - Catalytic removal of nitrogen-containing compounds from hydrocarbons using hydrogen - Google Patents

Catalytic removal of nitrogen-containing compounds from hydrocarbons using hydrogen

Info

Publication number
GB963941A
GB963941A GB7510/61A GB751061A GB963941A GB 963941 A GB963941 A GB 963941A GB 7510/61 A GB7510/61 A GB 7510/61A GB 751061 A GB751061 A GB 751061A GB 963941 A GB963941 A GB 963941A
Authority
GB
United Kingdom
Prior art keywords
catalyst
nitrogen
containing compounds
sulphiding
oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB7510/61A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
California Research LLC
Original Assignee
California Research LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by California Research LLC filed Critical California Research LLC
Publication of GB963941A publication Critical patent/GB963941A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C10G45/06—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof
    • C10G45/08—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing nickel or cobalt metal, or compounds thereof in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/02—Sulfur, selenium or tellurium; Compounds thereof
    • B01J27/04—Sulfides
    • B01J27/047—Sulfides with chromium, molybdenum, tungsten or polonium
    • B01J27/051—Molybdenum
    • B01J27/0515—Molybdenum with iron group metals or platinum group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/20—Sulfiding

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

A process for the substantially complete removal of contaminating nitrogen-containing compounds from a distillable hydrocarbon oil comprises contacting the hydrocarbon oil together with from 500-10,000 S.C.F. of H2/bbl. at a temperature of 500-850 DEG F., a pressure of from 200-4000 p.s.i.g., and a liquid hourly space velocity of 0.2-10 with a sulphided Ni-Mo-Al2O3 catalyst containing 4-10% Ni and 15.5-30% Mo prepared by sulphiding the corresponding oxides (see Division B1). A typical hydrocarbon oil which is purified thus is a light cycle oil having a gravity of 25.4 API., an initial boiling point of 415 DEG F. an end point of 550 DEG F. and an initial intregen content of 900 p.p.m. Examples describe the treatment of cracked naphtha, coker distillate, Arabian gas oil, heavy cycle oil and cat-cracker feed.ALSO:A hydrodenitrification catalyst consists essentially of Ni and Mo sulphides on a predominantly alumina support and contains from 4-10% Ni and from 18,9-30% Mo in a weight ratio Ni to Mo of 0,2-0,5, which catalyst has been contacted in the oxide form with a sulphiding gas, e.g. H2S, to convert NiO and MoO3 predominantly to sulphides to obtain high selective activity for the hydrogenative removal of nitrogen-containing compounds from hydrocarbon streams. Other sulphiding agents mentioned are CS2, a mercaptan or a sulphide. Minor amounts of Co, Zn or Cu do not impair the catalyst's activity. Alumina supports used preferably have a pore volume above 0,4 cc./gm. and a surface area above 150 sq.m./gm. Comparative examples are given. U.S.A. Specification 2,758,957 is referred to.
GB7510/61A 1960-03-02 1961-03-01 Catalytic removal of nitrogen-containing compounds from hydrocarbons using hydrogen Expired GB963941A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US12319A US3114701A (en) 1960-03-02 1960-03-02 Catalytic hydrodenitrification process

Publications (1)

Publication Number Publication Date
GB963941A true GB963941A (en) 1964-07-15

Family

ID=21754398

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7510/61A Expired GB963941A (en) 1960-03-02 1961-03-01 Catalytic removal of nitrogen-containing compounds from hydrocarbons using hydrogen

Country Status (4)

Country Link
US (1) US3114701A (en)
DE (1) DE1470524A1 (en)
GB (1) GB963941A (en)
NL (2) NL261905A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4945079A (en) * 1984-11-13 1990-07-31 Aluminum Company Of America Catalyst of nickel and molybdenum supported on alumina
US6632414B2 (en) 2001-03-30 2003-10-14 Corning Incorporated Mini-structured catalyst beds for three-phase chemical processing
US6716339B2 (en) 2001-03-30 2004-04-06 Corning Incorporated Hydrotreating process with monolithic catalyst

Families Citing this family (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3172864A (en) * 1961-09-21 1965-03-09 Activation of deactivatex hydro- benitkimcation catalysts
US3189540A (en) * 1962-01-02 1965-06-15 California Research Corp Production of lubricating oils by catalytic hydrogenation
US3242101A (en) * 1962-07-24 1966-03-22 Sinclair Research Inc Nickel-molybdenum-alumina hydrocarbon conversion catalyst
US3231520A (en) * 1962-12-26 1966-01-25 Texaco Inc Catalyst and method of making same
US3227646A (en) * 1963-02-28 1966-01-04 Chevron Res Hydrodenitrification process and catalysts
US3227661A (en) * 1963-02-28 1966-01-04 Chevron Res Method of preparing a catalyst composition by coprecipitation at a constant ph
US3205165A (en) * 1963-08-23 1965-09-07 Universal Oil Prod Co Hydrorefining process
US3265615A (en) * 1963-12-05 1966-08-09 Chevron Res Chromium-containing hydrofining catalysts
US3285860A (en) * 1963-12-09 1966-11-15 Union Oil Co Method of preparing nickel-molyb-denum-alumina catalysts
US3320181A (en) * 1964-01-30 1967-05-16 Chevron Res Hydrocarbon conversion catalysts com prising molybdenum sulfide and nickel sulfide dispersed within alumina
US3291751A (en) * 1964-01-30 1966-12-13 Chevron Res Preparation of a catalyst containing a molybdenum compound dispersed within alumina
US3268438A (en) * 1965-04-29 1966-08-23 Chevron Res Hydrodenitrification of oil with countercurrent hydrogen
US3477963A (en) * 1966-12-20 1969-11-11 Sun Oil Co Carbon disulfide sulfiding of catalysts
US3528910A (en) * 1967-06-26 1970-09-15 Sinclair Research Inc Hydrotreating process utilizing alkyl disulfide for in situ catalyst activation
US3528909A (en) * 1967-09-25 1970-09-15 Chevron Res Conversion of metals-containing hydrocarbon oils
DE1645829B1 (en) * 1968-01-13 1972-05-31 Universal Oil Prod Co Multi-stage process for the catalytic conversion of a hydrocarbon oil containing nitrogen compounds with an initial boiling point of 288 to 371 deg. C.
GB1379202A (en) * 1970-11-30 1975-01-02 Shell Int Research Two-stage hydrocracking process employing a supported nickel- molybdenum catalyst
US3897365A (en) * 1973-09-20 1975-07-29 American Cyanamid Co Hydrotreating catalyst and process therefor
US4181602A (en) * 1977-12-21 1980-01-01 Standard Oil Company (Indiana) Process for the hydrotreating of heavy hydrocarbon streams
US4191635A (en) * 1977-12-21 1980-03-04 Standard Oil Company (Indiana) Process for the cracking of heavy hydrocarbon streams
US4188284A (en) * 1977-12-21 1980-02-12 Standard Oil Company (Indiana) Process for the hydrotreating of heavy hydrocarbon streams
US4224144A (en) * 1979-03-19 1980-09-23 Standard Oil Company (Indiana) Hydrotreating a hydrocarbon stream to remove nitrogen and sulfur
CA1159039A (en) * 1980-11-21 1983-12-20 Harvey D. Schindler Hydrotreating catalyst and use thereof
JPS6115739A (en) * 1984-04-25 1986-01-23 Toa Nenryo Kogyo Kk Hydrogenating-treatment catalyst
US4990243A (en) * 1989-05-10 1991-02-05 Chevron Research And Technology Company Process for hydrodenitrogenating hydrocarbon oils
US5071805A (en) * 1989-05-10 1991-12-10 Chevron Research And Technology Company Catalyst system for hydrotreating hydrocarbons
EP3150710B1 (en) * 2014-03-20 2022-05-11 Cj Cheiljedang Corporation Method for preparing homoserine lactone and organic acid from microorganism-derived o-acyl homoserine
KR20230060033A (en) * 2021-10-27 2023-05-04 에스케이이노베이션 주식회사 Method for Improving Selective Hydrogenation of Unsaturated Hydrocarbons in Aromatics via Catalyst Pretreatment

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2905636A (en) * 1957-06-27 1959-09-22 Universal Oil Prod Co Manufacture and use of supported molybdenum-containing catalysts
US2983676A (en) * 1958-01-13 1961-05-09 Union Oil Co Hydrorefining of heavy mineral oils
US2988501A (en) * 1958-08-18 1961-06-13 Union Oil Co Hydrorefining of crude oils
NL256776A (en) * 1959-10-29

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4945079A (en) * 1984-11-13 1990-07-31 Aluminum Company Of America Catalyst of nickel and molybdenum supported on alumina
US6632414B2 (en) 2001-03-30 2003-10-14 Corning Incorporated Mini-structured catalyst beds for three-phase chemical processing
US6716339B2 (en) 2001-03-30 2004-04-06 Corning Incorporated Hydrotreating process with monolithic catalyst

Also Published As

Publication number Publication date
DE1470524A1 (en) 1968-12-12
NL123195C (en)
US3114701A (en) 1963-12-17
NL261905A (en)
DE1470520A1 (en) 1969-02-06

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