JPS582313A - 耐熱・耐衝撃性樹脂の製造方法 - Google Patents
耐熱・耐衝撃性樹脂の製造方法Info
- Publication number
- JPS582313A JPS582313A JP10204681A JP10204681A JPS582313A JP S582313 A JPS582313 A JP S582313A JP 10204681 A JP10204681 A JP 10204681A JP 10204681 A JP10204681 A JP 10204681A JP S582313 A JPS582313 A JP S582313A
- Authority
- JP
- Japan
- Prior art keywords
- polymerization
- monomer
- weight
- unsaturated dicarboxylic
- vinyl
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011347 resin Substances 0.000 title claims abstract description 11
- 229920005989 resin Polymers 0.000 title claims abstract description 11
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 239000000178 monomer Substances 0.000 claims abstract description 71
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 54
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 42
- 238000012662 bulk polymerization Methods 0.000 claims abstract description 32
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 31
- 238000010557 suspension polymerization reaction Methods 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 9
- 229920003244 diene elastomer Polymers 0.000 claims abstract description 6
- 238000010559 graft polymerization reaction Methods 0.000 claims abstract description 3
- 238000000034 method Methods 0.000 claims description 10
- 125000005397 methacrylic acid ester group Chemical group 0.000 claims description 3
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 claims 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 abstract description 28
- 150000008064 anhydrides Chemical class 0.000 abstract description 19
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 abstract description 16
- 229920001971 elastomer Polymers 0.000 abstract description 15
- 229920000642 polymer Polymers 0.000 abstract description 15
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 abstract description 10
- 239000005060 rubber Substances 0.000 abstract description 8
- 229920003048 styrene butadiene rubber Polymers 0.000 abstract description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 abstract description 3
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 abstract description 3
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000003960 organic solvent Substances 0.000 abstract description 2
- 229920001577 copolymer Polymers 0.000 description 17
- 238000006243 chemical reaction Methods 0.000 description 13
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 11
- 150000001991 dicarboxylic acids Chemical class 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- 238000003756 stirring Methods 0.000 description 9
- 238000007334 copolymerization reaction Methods 0.000 description 6
- 239000000725 suspension Substances 0.000 description 6
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000003381 stabilizer Substances 0.000 description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 3
- 229920005603 alternating copolymer Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- 239000011259 mixed solution Substances 0.000 description 3
- 229920002857 polybutadiene Polymers 0.000 description 3
- 239000003505 polymerization initiator Substances 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 description 2
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000004372 Polyvinyl alcohol Substances 0.000 description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 2
- 229910001873 dinitrogen Inorganic materials 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 238000009751 slip forming Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000010558 suspension polymerization method Methods 0.000 description 2
- OYUNTGBISCIYPW-UHFFFAOYSA-N 2-chloroprop-2-enenitrile Chemical compound ClC(=C)C#N OYUNTGBISCIYPW-UHFFFAOYSA-N 0.000 description 1
- KGIGUEBEKRSTEW-UHFFFAOYSA-N 2-vinylpyridine Chemical compound C=CC1=CC=CC=N1 KGIGUEBEKRSTEW-UHFFFAOYSA-N 0.000 description 1
- PFASSPYFJVNBQQ-UHFFFAOYSA-N 3-ethoxyfuran-2,5-dione Chemical compound CCOC1=CC(=O)OC1=O PFASSPYFJVNBQQ-UHFFFAOYSA-N 0.000 description 1
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- 108010088249 Monogen Proteins 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 125000005396 acrylic acid ester group Chemical group 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 238000012648 alternating copolymerization Methods 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001273 butane Substances 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000012295 chemical reaction liquid Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- OSIMQZHJCXQJDX-UHFFFAOYSA-N furan-2,5-dione;prop-2-enenitrile Chemical compound C=CC#N.O=C1OC(=O)C=C1 OSIMQZHJCXQJDX-UHFFFAOYSA-N 0.000 description 1
- AYBSOYWZTRUFMW-UHFFFAOYSA-N furan-2,5-dione;prop-2-enenitrile;styrene Chemical compound C=CC#N.O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 AYBSOYWZTRUFMW-UHFFFAOYSA-N 0.000 description 1
- WOLATMHLPFJRGC-UHFFFAOYSA-N furan-2,5-dione;styrene Chemical compound O=C1OC(=O)C=C1.C=CC1=CC=CC=C1 WOLATMHLPFJRGC-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 1
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- -1 unsaturated dicarboxylic acid hydride Chemical class 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
Landscapes
- Polymerisation Methods In General (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10204681A JPS582313A (ja) | 1981-06-30 | 1981-06-30 | 耐熱・耐衝撃性樹脂の製造方法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10204681A JPS582313A (ja) | 1981-06-30 | 1981-06-30 | 耐熱・耐衝撃性樹脂の製造方法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS582313A true JPS582313A (ja) | 1983-01-07 |
| JPH0138125B2 JPH0138125B2 (enrdf_load_stackoverflow) | 1989-08-11 |
Family
ID=14316821
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10204681A Granted JPS582313A (ja) | 1981-06-30 | 1981-06-30 | 耐熱・耐衝撃性樹脂の製造方法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS582313A (enrdf_load_stackoverflow) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6044517A (ja) * | 1983-08-19 | 1985-03-09 | Japan Synthetic Rubber Co Ltd | 艶消し熱可塑性樹脂組成物 |
| JPS6426618A (en) * | 1988-06-30 | 1989-01-27 | Japan Synthetic Rubber Co Ltd | Matte thermoplastic polymer |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5380490A (en) * | 1976-12-23 | 1978-07-15 | Gen Electric | Copolymerization process of alkenyl aromatic monomer and unsaturated acid anhydride |
| JPS5518479A (en) * | 1978-07-24 | 1980-02-08 | Monsanto Co | Rubber denatured terpolymer |
-
1981
- 1981-06-30 JP JP10204681A patent/JPS582313A/ja active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5380490A (en) * | 1976-12-23 | 1978-07-15 | Gen Electric | Copolymerization process of alkenyl aromatic monomer and unsaturated acid anhydride |
| JPS5518479A (en) * | 1978-07-24 | 1980-02-08 | Monsanto Co | Rubber denatured terpolymer |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS6044517A (ja) * | 1983-08-19 | 1985-03-09 | Japan Synthetic Rubber Co Ltd | 艶消し熱可塑性樹脂組成物 |
| JPS6426618A (en) * | 1988-06-30 | 1989-01-27 | Japan Synthetic Rubber Co Ltd | Matte thermoplastic polymer |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0138125B2 (enrdf_load_stackoverflow) | 1989-08-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3469264B2 (ja) | 耐熱性共重合体の製造法 | |
| US2886553A (en) | Process for the suspension polymerization of vinylidene aromatic hydrocarbons having rubbery conjugated 1, 3-diene polymers dissolved therein | |
| JP3151481B2 (ja) | ゴム変性共重合樹脂の製法およびゴム変性共重合樹脂組成物 | |
| JP3137752B2 (ja) | トナー用樹脂の製造方法 | |
| JPS6331488B2 (enrdf_load_stackoverflow) | ||
| US4055713A (en) | Iodine molecular weight regulators in suspension polymerization systems | |
| JPS582313A (ja) | 耐熱・耐衝撃性樹脂の製造方法 | |
| US3983187A (en) | Iodine molecular weight regulators in suspension polymerization systems | |
| JP3353844B2 (ja) | ゴム変性共重合樹脂の製法およびゴム変性共重合樹脂組成物 | |
| JPH02265908A (ja) | 共役ジエン系共重合体の製造方法 | |
| US5747593A (en) | Process for producing rubber-modified styrene resin | |
| US3265677A (en) | Process for regulating molecular weight in polymerization of vinylidene monomers using 1-methylcyclohexene-1 as regulator | |
| CA2007333A1 (en) | Preparation of large beads of styrene/methacrylic acid copolymer | |
| US4598124A (en) | Mass polymerization process for ABS polyblends | |
| JP3390529B2 (ja) | ゴム変性スチレン系樹脂の連続的製造方法 | |
| JP2565378B2 (ja) | 共重合体の製造法 | |
| JPH0146522B2 (enrdf_load_stackoverflow) | ||
| JPS5851961B2 (ja) | 共重合体の製造方法 | |
| JP3193422B2 (ja) | エポキシ基末端を有する重合体の製造法 | |
| JPH0667986B2 (ja) | 芳香族ビニル系共重合体の製造方法 | |
| JPH0543606A (ja) | マレイミド含有芳香族ビニル系樹脂の製造方法 | |
| JPS581125B2 (ja) | タイシヨウゲキセイジユシノセイゾウホウ | |
| JPS6023692B2 (ja) | 耐衝撃性ポリスチレン組成物を製造する方法 | |
| JPS6252761B2 (enrdf_load_stackoverflow) | ||
| JP2002121232A (ja) | クロロプレン共重合体の製造方法 |