JPS58152010A - 接着性並びに引張強さに優れた接着用変性ゴムの製造法 - Google Patents
接着性並びに引張強さに優れた接着用変性ゴムの製造法Info
- Publication number
- JPS58152010A JPS58152010A JP3306382A JP3306382A JPS58152010A JP S58152010 A JPS58152010 A JP S58152010A JP 3306382 A JP3306382 A JP 3306382A JP 3306382 A JP3306382 A JP 3306382A JP S58152010 A JPS58152010 A JP S58152010A
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- acrylic acid
- derivative
- graft polymerization
- modified
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 63
- 239000005060 rubber Substances 0.000 title claims abstract description 60
- 238000004519 manufacturing process Methods 0.000 title claims description 4
- 238000010559 graft polymerization reaction Methods 0.000 claims abstract description 16
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 150000001451 organic peroxides Chemical class 0.000 claims abstract description 12
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000001301 oxygen Substances 0.000 claims abstract description 10
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 10
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 7
- 229920001577 copolymer Polymers 0.000 claims abstract description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims abstract description 5
- 229920003052 natural elastomer Polymers 0.000 claims abstract description 5
- 229920001194 natural rubber Polymers 0.000 claims abstract description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 claims abstract description 5
- 229920001195 polyisoprene Polymers 0.000 claims abstract description 4
- 239000004711 α-olefin Substances 0.000 claims abstract description 4
- 239000003505 polymerization initiator Substances 0.000 claims description 10
- 238000004898 kneading Methods 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 239000000853 adhesive Substances 0.000 abstract description 6
- 230000001070 adhesive effect Effects 0.000 abstract description 6
- 239000003999 initiator Substances 0.000 abstract description 3
- 239000007790 solid phase Substances 0.000 abstract description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract 2
- 238000010438 heat treatment Methods 0.000 description 8
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 6
- 229920005549 butyl rubber Polymers 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 5
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 3
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 3
- SPTHWAJJMLCAQF-UHFFFAOYSA-M ctk4f8481 Chemical compound [O-]O.CC(C)C1=CC=CC=C1C(C)C SPTHWAJJMLCAQF-UHFFFAOYSA-M 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- YKTNISGZEGZHIS-UHFFFAOYSA-N 2-$l^{1}-oxidanyloxy-2-methylpropane Chemical group CC(C)(C)O[O] YKTNISGZEGZHIS-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 125000005395 methacrylic acid group Chemical group 0.000 description 2
- 239000012778 molding material Substances 0.000 description 2
- 230000000379 polymerizing effect Effects 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- XSZYESUNPWGWFQ-UHFFFAOYSA-N 1-(2-hydroperoxypropan-2-yl)-4-methylcyclohexane Chemical compound CC1CCC(C(C)(C)OO)CC1 XSZYESUNPWGWFQ-UHFFFAOYSA-N 0.000 description 1
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- KYARBIJYVGJZLB-UHFFFAOYSA-N 7-amino-4-hydroxy-2-naphthalenesulfonic acid Chemical compound OC1=CC(S(O)(=O)=O)=CC2=CC(N)=CC=C21 KYARBIJYVGJZLB-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- 235000010893 Bischofia javanica Nutrition 0.000 description 1
- 240000005220 Bischofia javanica Species 0.000 description 1
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 1
- 230000027311 M phase Effects 0.000 description 1
- 239000004820 Pressure-sensitive adhesive Substances 0.000 description 1
- 125000003236 benzoyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C(*)=O 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 238000005520 cutting process Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 1
- HSOOVEKLGOIEFF-UHFFFAOYSA-N ethenyl nitrate Chemical compound [O-][N+](=O)OC=C HSOOVEKLGOIEFF-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 239000012770 industrial material Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 238000010303 mechanochemical reaction Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- -1 t-butylperoxy Chemical group 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Polymerization Catalysts (AREA)
- Graft Or Block Polymers (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3306382A JPS58152010A (ja) | 1982-03-04 | 1982-03-04 | 接着性並びに引張強さに優れた接着用変性ゴムの製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP3306382A JPS58152010A (ja) | 1982-03-04 | 1982-03-04 | 接着性並びに引張強さに優れた接着用変性ゴムの製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58152010A true JPS58152010A (ja) | 1983-09-09 |
| JPS6234326B2 JPS6234326B2 (enrdf_load_stackoverflow) | 1987-07-27 |
Family
ID=12376270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP3306382A Granted JPS58152010A (ja) | 1982-03-04 | 1982-03-04 | 接着性並びに引張強さに優れた接着用変性ゴムの製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58152010A (enrdf_load_stackoverflow) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61118479A (ja) * | 1984-11-15 | 1986-06-05 | Toyo Soda Mfg Co Ltd | 粘着剤組成物 |
| US20130296493A1 (en) * | 2012-05-01 | 2013-11-07 | Bridgestone Corporation | Modified natural rubber and method of manufacturing the same, rubber composition and tire |
| JP2014218538A (ja) * | 2013-05-01 | 2014-11-20 | 株式会社ブリヂストン | 変性天然ゴム及びその製造方法、並びにゴム組成物及びタイヤ |
-
1982
- 1982-03-04 JP JP3306382A patent/JPS58152010A/ja active Granted
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61118479A (ja) * | 1984-11-15 | 1986-06-05 | Toyo Soda Mfg Co Ltd | 粘着剤組成物 |
| US20130296493A1 (en) * | 2012-05-01 | 2013-11-07 | Bridgestone Corporation | Modified natural rubber and method of manufacturing the same, rubber composition and tire |
| US9181378B2 (en) * | 2012-05-01 | 2015-11-10 | Bridgestone Corporation | Modified natural rubber and method of manufacturing the same, rubber composition and tire |
| JP2014218538A (ja) * | 2013-05-01 | 2014-11-20 | 株式会社ブリヂストン | 変性天然ゴム及びその製造方法、並びにゴム組成物及びタイヤ |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS6234326B2 (enrdf_load_stackoverflow) | 1987-07-27 |
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