JPS5767576A - Tetracyanoquinodimethane complex - Google Patents
Tetracyanoquinodimethane complexInfo
- Publication number
- JPS5767576A JPS5767576A JP14413580A JP14413580A JPS5767576A JP S5767576 A JPS5767576 A JP S5767576A JP 14413580 A JP14413580 A JP 14413580A JP 14413580 A JP14413580 A JP 14413580A JP S5767576 A JPS5767576 A JP S5767576A
- Authority
- JP
- Japan
- Prior art keywords
- tcnq
- compound
- formula
- organic solvent
- cyclic polyether
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Heterocyclic Compounds That Contain Two Or More Ring Oxygen Atoms (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
NEW MATERIAL:A compound of the formula (CR is cyclic polyether, e.g., 15- crown-5; M is Mg, Ca, Sr, Pb; TCNQ is tetracyanoquinodimethane; n is 1, 2, 3; p is 1, 2; q is 0, 1, 2).
USE: Reactive intermediate of other TCNQ complexes, organic electro-conductive material. The conductivity of the compound of the formula is 101W104 times as high as a simple salt of TCNQ.
PREPARATION: The reaction between a divalent metal salt of TCNQ, an excessive amount of cyclic polyether and, when necessary, TCNQ is conducted in an organic solvent at a temperature of 50°C to the boiling point of the solvent. The insoluble part is removed by hot filtration and the reaction mixture is cooled to precipitate the objective compound. The organic solvent is, e.g., alcohol, aromatic hydrocarbon, ketone, ether, halogenated hydrocarbon or DMF.
COPYRIGHT: (C)1982,JPO&Japio
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14413580A JPS5767576A (en) | 1980-10-15 | 1980-10-15 | Tetracyanoquinodimethane complex |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP14413580A JPS5767576A (en) | 1980-10-15 | 1980-10-15 | Tetracyanoquinodimethane complex |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5767576A true JPS5767576A (en) | 1982-04-24 |
JPH0131512B2 JPH0131512B2 (en) | 1989-06-26 |
Family
ID=15355026
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP14413580A Granted JPS5767576A (en) | 1980-10-15 | 1980-10-15 | Tetracyanoquinodimethane complex |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS5767576A (en) |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5545641A (en) * | 1978-09-27 | 1980-03-31 | Mitsubishi Chem Ind Ltd | Alkali metal-tetracyanoquinodimethane crown compound complex |
-
1980
- 1980-10-15 JP JP14413580A patent/JPS5767576A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5545641A (en) * | 1978-09-27 | 1980-03-31 | Mitsubishi Chem Ind Ltd | Alkali metal-tetracyanoquinodimethane crown compound complex |
Also Published As
Publication number | Publication date |
---|---|
JPH0131512B2 (en) | 1989-06-26 |
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