JPH09503541A - 水素化分解及び水素化脱ロウ方法 - Google Patents
水素化分解及び水素化脱ロウ方法Info
- Publication number
- JPH09503541A JPH09503541A JP7511261A JP51126195A JPH09503541A JP H09503541 A JPH09503541 A JP H09503541A JP 7511261 A JP7511261 A JP 7511261A JP 51126195 A JP51126195 A JP 51126195A JP H09503541 A JPH09503541 A JP H09503541A
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- hydrocracking
- zeolite
- zone
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
- C10G45/12—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G65/00—Treatment of hydrocarbon oils by two or more hydrotreatment processes only
- C10G65/02—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only
- C10G65/12—Treatment of hydrocarbon oils by two or more hydrotreatment processes only plural serial stages only including cracking steps and other hydrotreatment steps
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
- F02B3/00—Engines characterised by air compression and subsequent fuel addition
- F02B3/06—Engines characterised by air compression and subsequent fuel addition with compression ignition
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Crystallography & Structural Chemistry (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
- Steroid Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Superconductors And Manufacturing Methods Therefor (AREA)
Abstract
Description
Claims (1)
- 【特許請求の範囲】 1.343℃より上で沸騰する炭化水素性物質の実質的な部分を含む、ロウ含有 炭化水素供給原料を、供給原料のそれと比べて減少したロウ含量を有する中間留 分生成物へと転化する方法において、該方法が、 (a)供給原料を、水素の存在下で、担体、周期律表の第VIB族及び第VIII族か ら選ばれる少なくとも一つの水素化金属成分、及び0.7〜1.5nmの範囲の 孔直径を有する大きな孔のゼオライトを含む水素化触媒と、高められた温度及び 圧力の条件下で、水素化分解ゾーン中で接触させる工程、 (b)水素化分解ゾーンからの全流出物を、水素の存在下で、メタロシリケート 及びシリコアルミノホスフェートの群から選ばれた結晶性の、中間孔サイズのモ レキュラーシーブを含みかつ0.5〜0.7nmの範囲の孔直径を有する脱ロウ 触媒と、高められた温度及び圧力の条件下で、水素化脱ロウゾーン中で接触させ る工程、及び (c)ロウ含量が減少した中間留分生成物を回収する工程、 を含む方法。 2.水素化分解触媒中の大きな孔のゼオライトがY型ゼオライトである、請求の 範囲第1項に記載の方法。 3.脱ロウ触媒中のモレキュラーシーブが、ZSM−5フ ァミリーのゼオライトである請求の範囲第1項又は第2項に記載の方法。 4.脱ロウ触媒が、第VIB族及び第VIII族から選ばれる少なくとも一つの水素化 金属成分を含む請求の範囲第1項〜第3項のいずれか一つに記載の方法。 5.減少したロウ含量の中間留分生成物の回収に先だって、水素化脱ロウゾーン からの流出物の少なくとも一部を、高められた温度及び圧力の条件下で、水素化 処理ゾーン中にて、担体及び、第VIB及び第VIII族の金属から選ばれる少なくと も一つの金属成分を含有する水素化処理触媒と接触させる、請求の範囲第1項〜 第4項のいずれか一つに記載の方法。 6.高められた温度及び圧力の条件(これは、各段階で異なっても良い)が、2 60℃〜455℃の範囲の温度及び3〜21MPaの間の圧力である、請求の範 囲第1項〜第5項のいずれか一つに記載の方法。 7.請求の範囲第1項〜第6項のいずれか1つに記載の方法により得られた生成 物。
Applications Claiming Priority (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP93202853 | 1993-10-08 | ||
EP93202853.3 | 1993-10-08 | ||
SG1996003552A SG48893A1 (en) | 1993-10-08 | 1994-10-07 | Hydrocracking and hydrodewaxing process |
PCT/EP1994/003323 WO1995010578A1 (en) | 1993-10-08 | 1994-10-07 | Hydrocracking and hydrodewaxing process |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH09503541A true JPH09503541A (ja) | 1997-04-08 |
JP3665069B2 JP3665069B2 (ja) | 2005-06-29 |
Family
ID=26134029
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP51126195A Expired - Fee Related JP3665069B2 (ja) | 1993-10-08 | 1994-10-07 | 水素化分解及び水素化脱ロウ方法 |
Country Status (19)
Country | Link |
---|---|
US (1) | US5935414A (ja) |
EP (1) | EP0722478B1 (ja) |
JP (1) | JP3665069B2 (ja) |
KR (1) | KR100199849B1 (ja) |
CN (1) | CN1046755C (ja) |
AT (1) | ATE155519T1 (ja) |
AU (1) | AU683938B2 (ja) |
BR (1) | BR9407765A (ja) |
CA (1) | CA2173599C (ja) |
CZ (1) | CZ293108B6 (ja) |
DE (1) | DE69404320T2 (ja) |
ES (1) | ES2105762T3 (ja) |
FI (1) | FI961532A (ja) |
HU (1) | HU217791B (ja) |
NO (1) | NO961379L (ja) |
PL (1) | PL178305B1 (ja) |
RU (1) | RU2128681C1 (ja) |
SG (1) | SG48893A1 (ja) |
WO (1) | WO1995010578A1 (ja) |
Families Citing this family (39)
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HUP0004280A3 (en) * | 1996-07-15 | 2001-06-28 | Chevron U S A Inc San Francisc | Layered catalyst system for lube oil hydroconversion |
US6489167B1 (en) | 1996-09-25 | 2002-12-03 | The Government Of The United States As Represented By The Secretary Of The Department Of Human Services | Retroviral packaging cassettes amplified in the cytoplasm by autocatalytic Togavirus vectors |
US6093672A (en) * | 1997-03-20 | 2000-07-25 | Shell Oil Company | Noble metal hydrocracking catalysts |
FI102767B1 (fi) | 1997-05-29 | 1999-02-15 | Neste Oy | Menetelmä korkealuokkaisen dieselpolttoaineen valmistamiseksi |
FR2765206B1 (fr) * | 1997-06-25 | 1999-08-06 | Inst Francais Du Petrole | Zeolithe eu-1, catalyseur et procede pour l'amelioration du point d'ecoulement de charges contenant des paraffines |
FR2778343B1 (fr) | 1998-05-06 | 2000-06-16 | Inst Francais Du Petrole | Catalyseur a base de zeolithe y non globalement desaluminee, de bore et/ou de silicium et procede d'hydrocraquage |
FR2780311B1 (fr) * | 1998-06-25 | 2000-08-11 | Inst Francais Du Petrole | Catalyseur d'hydrocraquage comprenant une zeolithe y non globalement desaluminee, un element du groupe vb, et un element promoteur choisi dans le groupe forme par le bore, le phosphore et le silicium |
FR2797270B1 (fr) * | 1999-08-02 | 2003-03-07 | Inst Francais Du Petrole | Procede et flexible de production de bases huiles et eventuellement de distillats moyens de tres haute qualite |
FR2785617B1 (fr) * | 1998-11-06 | 2001-01-05 | Inst Francais Du Petrole | Procede flexible de production de bases huiles et eventuellement de distillats moyens de tres haute qualite |
KR100603225B1 (ko) * | 1998-11-06 | 2006-07-24 | 앵스띠뛰 프랑세 뒤 뻬뜨롤 | 의약용 오일 및 임의로 중간 증류물의 융통적인 제조 방법 |
FR2785616B1 (fr) * | 1998-11-06 | 2000-12-08 | Inst Francais Du Petrole | Procede flexible de production de bases huiles et eventuellement de distillats moyens de tres haute qualite |
CA2292314C (en) * | 1998-12-16 | 2007-02-06 | China Petrochemical Corporation | A process for producing diesel oils of superior quality and low solidifying point from fraction oils |
FR2808028B1 (fr) | 2000-04-21 | 2003-09-05 | Inst Francais Du Petrole | Procede flexible de production de bases huiles avec une zeolithe zsm-48 |
US6652735B2 (en) | 2001-04-26 | 2003-11-25 | Exxonmobil Research And Engineering Company | Process for isomerization dewaxing of hydrocarbon streams |
ATE368718T1 (de) * | 2001-11-16 | 2007-08-15 | Shell Int Research | Gegenstrom-hydroprocessing |
DE10256404B4 (de) * | 2002-05-31 | 2009-02-05 | Kataleuna Gmbh Catalysts | Katalysator zur Isomerisierung von festen Fischer-Tropsch-Paraffinen und Verfahren zu seiner Herstellung |
FR2841798B1 (fr) * | 2002-07-03 | 2005-03-04 | Inst Francais Du Petrole | Catalyseur d'hydrotraitement contenant un compose organique azote et son utilisation |
US20040256287A1 (en) * | 2003-06-19 | 2004-12-23 | Miller Stephen J. | Fuels and lubricants using layered bed catalysts in hydrotreating waxy feeds, including fischer-tropsch wax, plus solvent dewaxing |
US20040256286A1 (en) * | 2003-06-19 | 2004-12-23 | Miller Stephen J. | Fuels and lubricants using layered bed catalysts in hydrotreating waxy feeds, including Fischer-Tropsch wax |
US7115198B2 (en) * | 2003-10-22 | 2006-10-03 | Chevron U.S.A. Inc. | Hydrocarbon conversion using molecular sieve SSZ-51 |
US7749373B2 (en) * | 2004-12-17 | 2010-07-06 | Haldor Topsoe A/S | Hydrocracking process |
JP4769110B2 (ja) * | 2006-03-30 | 2011-09-07 | Jx日鉱日石エネルギー株式会社 | ワックスの水素化分解方法 |
AU2008206002B2 (en) * | 2007-01-15 | 2011-11-17 | Nippon Oil Corporation | Processes for production of liquid fuel |
JP5268177B2 (ja) * | 2007-05-01 | 2013-08-21 | Jx日鉱日石エネルギー株式会社 | 液体燃料の製造方法 |
US8431014B2 (en) * | 2009-10-06 | 2013-04-30 | Chevron U.S.A. Inc. | Process and catalyst system for improving dewaxing catalyst stability and lubricant oil yield |
CN102145291B (zh) * | 2010-02-10 | 2013-09-25 | 中国石油化工股份有限公司 | 一种加氢裂化催化剂及其制备方法及烃油裂化方法 |
KR101354235B1 (ko) | 2010-04-14 | 2014-02-13 | 에스케이이노베이션 주식회사 | 수소화 탈왁스 공정을 위한 촉매 및 이의 제조 방법 |
CN102485332B (zh) * | 2010-12-03 | 2013-10-16 | 中国石油天然气股份有限公司 | 一种含分子筛的馏分油加氢脱酸催化剂及其制备和应用 |
KR101885190B1 (ko) * | 2011-03-31 | 2018-08-06 | 셰브런 유.에스.에이.인크. | 탈랍 촉매 안정성 및 윤활유 수율을 개선하기 위한 신규 방법 및 촉매 시스템 |
US9200218B2 (en) | 2011-03-31 | 2015-12-01 | Exxonmobil Research And Engineering Company | Fuels hydrocracking with dewaxing of fuel products |
US20140058145A1 (en) * | 2012-08-21 | 2014-02-27 | Uop Llc | Production of olefins from a methane conversion process |
CN103059941B (zh) * | 2013-01-08 | 2015-09-30 | 中国海洋石油总公司 | 制备高辛烷值石脑油的加氢裂化方法 |
WO2014177429A1 (en) * | 2013-05-03 | 2014-11-06 | Haldor Topsøe A/S | Catalyst and process for dewaxing of hydrocarbons |
CN107345164B (zh) * | 2016-05-05 | 2018-10-12 | 中国石油化工股份有限公司 | 一种直馏柴油加氢裂化生产喷气燃料的方法 |
US10835866B2 (en) * | 2017-06-02 | 2020-11-17 | Paccar Inc | 4-way hybrid binary catalysts, methods and uses thereof |
US10906031B2 (en) | 2019-04-05 | 2021-02-02 | Paccar Inc | Intra-crystalline binary catalysts and uses thereof |
US11007514B2 (en) | 2019-04-05 | 2021-05-18 | Paccar Inc | Ammonia facilitated cation loading of zeolite catalysts |
US10934918B1 (en) | 2019-10-14 | 2021-03-02 | Paccar Inc | Combined urea hydrolysis and selective catalytic reduction for emissions control |
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-
1994
- 1994-10-07 PL PL94313868A patent/PL178305B1/pl not_active IP Right Cessation
- 1994-10-07 CA CA002173599A patent/CA2173599C/en not_active Expired - Fee Related
- 1994-10-07 CZ CZ1996991A patent/CZ293108B6/cs not_active IP Right Cessation
- 1994-10-07 KR KR1019960701946A patent/KR100199849B1/ko not_active IP Right Cessation
- 1994-10-07 CN CN94193683A patent/CN1046755C/zh not_active Expired - Fee Related
- 1994-10-07 WO PCT/EP1994/003323 patent/WO1995010578A1/en active IP Right Grant
- 1994-10-07 BR BR9407765A patent/BR9407765A/pt not_active IP Right Cessation
- 1994-10-07 JP JP51126195A patent/JP3665069B2/ja not_active Expired - Fee Related
- 1994-10-07 AU AU78125/94A patent/AU683938B2/en not_active Ceased
- 1994-10-07 RU RU96108801/04A patent/RU2128681C1/ru not_active IP Right Cessation
- 1994-10-07 US US08/619,685 patent/US5935414A/en not_active Expired - Lifetime
- 1994-10-07 AT AT94928879T patent/ATE155519T1/de not_active IP Right Cessation
- 1994-10-07 HU HU9600895A patent/HU217791B/hu not_active IP Right Cessation
- 1994-10-07 EP EP94928879A patent/EP0722478B1/en not_active Revoked
- 1994-10-07 DE DE69404320T patent/DE69404320T2/de not_active Revoked
- 1994-10-07 SG SG1996003552A patent/SG48893A1/en unknown
- 1994-10-07 ES ES94928879T patent/ES2105762T3/es not_active Expired - Lifetime
-
1996
- 1996-04-03 NO NO19961379A patent/NO961379L/no not_active Application Discontinuation
- 1996-04-04 FI FI961532A patent/FI961532A/fi not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
CZ293108B6 (cs) | 2004-02-18 |
DE69404320D1 (de) | 1997-08-21 |
ES2105762T3 (es) | 1997-10-16 |
SG48893A1 (en) | 1998-05-18 |
AU7812594A (en) | 1995-05-04 |
PL313868A1 (en) | 1996-07-22 |
EP0722478B1 (en) | 1997-07-16 |
CN1046755C (zh) | 1999-11-24 |
HU9600895D0 (en) | 1996-06-28 |
FI961532A0 (fi) | 1996-04-04 |
PL178305B1 (pl) | 2000-04-28 |
NO961379D0 (no) | 1996-04-03 |
HU217791B (hu) | 2000-04-28 |
CA2173599A1 (en) | 1995-04-20 |
CZ99196A3 (en) | 1996-09-11 |
CN1132522A (zh) | 1996-10-02 |
EP0722478A1 (en) | 1996-07-24 |
CA2173599C (en) | 2004-07-20 |
HUT75022A (en) | 1997-03-28 |
ATE155519T1 (de) | 1997-08-15 |
AU683938B2 (en) | 1997-11-27 |
FI961532A (fi) | 1996-04-04 |
WO1995010578A1 (en) | 1995-04-20 |
NO961379L (no) | 1996-04-03 |
JP3665069B2 (ja) | 2005-06-29 |
RU2128681C1 (ru) | 1999-04-10 |
DE69404320T2 (de) | 1998-01-29 |
KR100199849B1 (ko) | 1999-06-15 |
US5935414A (en) | 1999-08-10 |
BR9407765A (pt) | 1997-03-18 |
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