JPH0941070A - Wear resistant sintered alloy bearing low in mating attackability - Google Patents

Wear resistant sintered alloy bearing low in mating attackability

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Publication number
JPH0941070A
JPH0941070A JP21804295A JP21804295A JPH0941070A JP H0941070 A JPH0941070 A JP H0941070A JP 21804295 A JP21804295 A JP 21804295A JP 21804295 A JP21804295 A JP 21804295A JP H0941070 A JPH0941070 A JP H0941070A
Authority
JP
Japan
Prior art keywords
sintered alloy
distributed
porosity
low
ferrite phase
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP21804295A
Other languages
Japanese (ja)
Inventor
Sekihin You
楊  積彬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP21804295A priority Critical patent/JPH0941070A/en
Publication of JPH0941070A publication Critical patent/JPH0941070A/en
Withdrawn legal-status Critical Current

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  • Sliding-Contact Bearings (AREA)
  • Powder Metallurgy (AREA)

Abstract

PROBLEM TO BE SOLVED: To produce a wear resistant sintered alloy bearing low in mating attackability. SOLUTION: The sintered alloy bearing has a compsn. contg., by weight, 40 to 60% Fe, 0.1 to 5% Sn, 0.1 to 2% C, 0.05 to 1% S and 0.05 to 3% BN, furthermore contg., at need, 0.5 to 2% MoS2 , and the balance Cu with inevitable impurities. The bearing is composed of a low porosity Cu-Fe-Sn sintered alloy having a structure in which ferritic phases are dispersedly distributed into a matrix of a Cu-Sn alloy, furthermore, free graphite grown with S components as the neucleus is dispersedly distributed into the ferritic phases, and moreover, BN or BN and MoS2 are distributed over the boundary parts of the matrix and ferritic phases and having <=9% porosity.

Description

【発明の詳細な説明】Detailed Description of the Invention

【0001】[0001]

【発明の属する技術分野】この発明は、相手材である回
転軸に対するなじみ性にすぐれ、かつ自己潤滑性にもす
ぐれているので、苛酷な条件下での実用に際しても、き
わめて低い相手攻撃性で、すぐれた耐摩耗性を示す焼結
合金軸受に関するものである。
BACKGROUND OF THE INVENTION The present invention has excellent compatibility with a rotating shaft, which is a mating material, and excellent self-lubricating property. Therefore, even when it is put to practical use under severe conditions, it has a very low mating attack. The present invention relates to a sintered alloy bearing having excellent wear resistance.

【0002】[0002]

【従来の技術】従来、一般に各種駆動装置には、相手材
である回転軸の支持部材として焼結合金軸受が用いられ
ており、この焼結合金軸受が、重量%で(以下、組成に
関する%は重量%を示す)、Fe:40〜60%、S
n:0.1〜5%、C:0.1〜2%を含有し、残りが
Cuと不可避不純物からなる組成、並びに図3に組織拡
大模写図で示されるように、Cu−Sn系合金の素地に
パーライト相が分散分布した組織を有し、さらに9%以
下の気孔率を有する低気孔Cu−Fe−Sn系焼結合金
で構成されていることも良く知られるところである。
2. Description of the Related Art Conventionally, a sintered alloy bearing has been generally used as a supporting member of a rotating shaft which is a mating member in various drive devices. Indicates weight%), Fe: 40 to 60%, S
A composition containing n: 0.1 to 5%, C: 0.1 to 2%, and the balance of Cu and inevitable impurities, and a Cu-Sn alloy as shown in FIG. It is well known that it has a structure in which the pearlite phase is dispersedly distributed in the base material and is composed of a low porosity Cu—Fe—Sn system sintered alloy having a porosity of 9% or less.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の駆動装置
の高性能化および小型化、さらに高出力化はめざまし
く、これに伴ない、駆動装置の構造部材である回転軸の
回転は高速化し、かつこれへの負荷は高荷重となる傾向
にあるが、上記の従来焼結合金軸受においては、これを
構成する低気孔Cu−Fe−Sn系焼結合金が、図3に
示される通り素地中に存在するパーライト相が原因で、
相手材である回転軸に対するなじみ性が低く、さらに自
己潤滑性も十分でなく、したがって高速回転および高荷
重条件では相手攻撃性が強く現われ、かつ摩耗進行も加
速されるようになるのが避けられないのが現状である。
On the other hand, in recent years, the performance and size of the drive unit have been remarkably increased and the output thereof has been increased. As a result, the rotational speed of the rotary shaft, which is a structural member of the drive unit, has been increased. Moreover, the load on this tends to be high, but in the above-mentioned conventional sintered alloy bearing, the low-pore Cu—Fe—Sn-based sintered alloy that constitutes this bearing has a base material as shown in FIG. Due to the pearlite phase present in
It has low compatibility with the rotating shaft that is the mating material, and also has insufficient self-lubricating properties. Therefore, under high-speed rotation and high load conditions, it is possible to avoid strong mating aggression and accelerate the progress of wear. The current situation is that there are none.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者等は、
上述のような観点から、特になじみ性および自己潤滑性
のすぐれた焼結合金軸受を開発すべく、特に上記の従来
焼結合金軸受に着目し研究を行なった結果、上記の従来
焼結合金軸受を構成する低気孔Cu−Fe−Sn系焼結
合金に、合金成分としてSと窒化ほう素(以下、BNで
示す)、望ましくは六方晶窒化ほう素(以下、hBNで
示す)を含有させると、前記S成分が核となって遊離黒
鉛が析出し、この遊離黒鉛の成長をBN成分が促進する
ように作用することから、前記低気孔Cu−Fe−Sn
系焼結合金は、図1に組織拡大模写図で示される通り、
Cu−Sn系合金の素地に、硬質のパーライト相に代っ
て主体がFeのフェライト相が分散分布し、このフェラ
イト相内の粒界にそってS成分が核となって成長した微
細な遊離黒鉛が分散分布し、かつフェライト相と素地の
界面部にBN成分が分布した組織をもつようになり、こ
の結果の低気孔Cu−Fe−Sn系焼結合金は、軟質の
フェライト相と遊離黒鉛によってすぐれたなじみ性と自
己潤滑性をもち、さらに前記低気孔Cu−Fe−Sn系
焼結合金に硫化モリブデン(以下、MoS2 で示す)を
含有させると、同じく図2の組織拡大模写図で示される
通り、フェライト相と素地の界面部にBN成分と共に分
布して自己潤滑性が一段と向上したものになることか
ら、焼結合金軸受として高速回転および高荷重条件での
実用に際しても相手攻撃性が著しく低く、かつすぐれた
耐摩耗性を発揮するという研究結果を得たのである。
Means for Solving the Problems Accordingly, the present inventors have
From the above viewpoints, in order to develop a sintered alloy bearing excellent in conformability and self-lubricating property, particularly, the above-mentioned conventional sintered alloy bearing was studied by paying attention to the above-mentioned conventional sintered alloy bearing. When S and boron nitride (hereinafter, referred to as BN), preferably hexagonal boron nitride (hereinafter, referred to as hBN) are contained as alloy components in the low-pore Cu-Fe-Sn-based sintered alloy constituting Since the S component serves as a nucleus to precipitate free graphite and the BN component acts to promote the growth of the free graphite, the low-pore Cu—Fe—Sn
Sintered alloys, as shown in FIG.
In the base material of the Cu-Sn alloy, the ferrite phase mainly of Fe is dispersedly distributed in place of the hard pearlite phase, and the S component grows along the grain boundary in the ferrite phase as a nucleus The graphite has a disperse distribution and has a structure in which the BN component is distributed at the interface between the ferrite phase and the matrix. As a result, the low porosity Cu-Fe-Sn system sintered alloy has a soft ferrite phase and free graphite. When the low porosity Cu—Fe—Sn system sintered alloy further contains molybdenum sulfide (hereinafter, referred to as MoS 2 ), it has the excellent conformability and self-lubricating property. As shown, since it is distributed along with the BN component at the interface between the ferrite phase and the base material, and the self-lubricating property is further improved, it can be used as a sintered alloy bearing even when it is put to practical use under high-speed rotation and high-load conditions.撃性 is significantly lower, and than it was obtained the results of a study that exhibits excellent wear resistance.

【0005】この発明は、上記の研究結果にもとづいて
なされたものであって、Fe:40〜60%、 S
n:0.1〜5%、C:0.1〜2%、 S:
0.05〜1%、BN:0.05〜3%、を含有し、さ
らに必要に応じて、MoS2 :0.5〜2%、を含有
し、残りがCuと不可避不純物からなる組成、Cu−S
n系合金の素地に、フェライト相が分散分布し、かつ前
記フェライト相内にはS成分を核として成長した遊離黒
鉛が分散分布し、さらに前記素地とフェライト相の界面
部に、BN、またはBNとMoS2 が分布した組織、お
よび9%以下の気孔率、を有する低気孔Cu−Fe−S
n系焼結合金で構成してなる、相手攻撃性の低い耐摩耗
性焼結合金軸受に特徴を有するものである。
The present invention was made based on the above research results, and Fe: 40 to 60%, S
n: 0.1 to 5%, C: 0.1 to 2%, S:
0.05 to 1%, BN: 0.05 to 3%, and, if necessary, MoS 2 : 0.5 to 2%, and the balance of Cu and inevitable impurities. Cu-S
A ferrite phase is dispersed and distributed in the base of the n-based alloy, and free graphite that grows with the S component as a nucleus is dispersed and distributed in the ferrite phase. Further, BN or BN is formed at the interface between the base and the ferrite phase. Porosity Cu-Fe-S having a structure in which MoS 2 and MoS 2 are distributed, and a porosity of 9% or less.
It is characterized by a wear-resistant sintered alloy bearing made of an n-based sintered alloy and having low opponent attack.

【0006】つぎに、この発明の焼結合金軸受におい
て、これを構成する低気孔Cu−Fe−Sn系焼結合金
の成分組成および気孔率を上記の通りに限定した理由を
説明する。 (a) Fe Fe成分には、素地に分散分布するフェライト相を形成
してなじみ性を向上させる作用があるが、その割合が4
0%未満では相対的にフェライト相の割合が少なくなり
すぎて、所望の耐摩耗性を確保することができず、一方
その割合が60%を越えると、相対的に素地の割合が少
なくなりすぎて強度が低下するようになることから、そ
の割合を40〜60%、望ましくは45〜55%と定め
た。
Next, in the sintered alloy bearing of the present invention, the reason why the composition and porosity of the low-pore Cu-Fe-Sn sintered alloy constituting the bearing are limited as described above will be explained. (A) Fe The Fe component has a function of forming a ferrite phase dispersedly distributed in the matrix to improve the conformability, but the proportion thereof is 4
If it is less than 0%, the proportion of the ferrite phase becomes too small, and the desired wear resistance cannot be secured, while if it exceeds 60%, the proportion of the base material becomes too small. As a result, the strength is lowered, so the ratio is set to 40 to 60%, preferably 45 to 55%.

【0007】(b) Sn Sn成分には、Cuに固溶して素地のCu−Sn系合金
を形成し、強度を向上させる作用があるが、その割合が
0.1%未満では所望の強度を確保することができず、
一方その割合が5%を越えると素地に脆化傾向が現わ
れ、相手攻撃性が増すようになることから、その割合を
0.1〜5%、望ましくは1.5〜3.5%と定めた。
(B) Sn The Sn component has the function of forming a solid solution with Cu to form a Cu-Sn alloy of the base material and improving the strength, but if the proportion is less than 0.1%, the desired strength is obtained. Could not be secured,
On the other hand, if the ratio exceeds 5%, the base material tends to become brittle and the opponent aggression increases, so the ratio is set to 0.1 to 5%, preferably 1.5 to 3.5%. It was

【0008】(c) C C成分には、SとBN成分の作用でフェライト相内の粒
界に微細な遊離黒鉛として析出し、かつ成長して自己潤
滑性を向上させる作用があるが、その割合が0.1%未
満では遊離黒鉛の分布割合が少なすぎて所望の自己潤滑
性を確保することができず、一方その割合が2%を越え
ると完全な黒鉛化が困難になり、セメンタイトが析出す
るようになって相手攻撃性が高くなることから、その割
合を0.1〜2%、望ましくは0.5〜1.5%と定め
た。
(C) C C component has the function of precipitating and growing as fine free graphite at grain boundaries in the ferrite phase by the action of S and BN components, and improving self-lubricating property. If the ratio is less than 0.1%, the distribution ratio of free graphite is too small to secure the desired self-lubricating property. On the other hand, if the ratio exceeds 2%, complete graphitization becomes difficult and cementite becomes The ratio of attack is increased to 0.1 to 2%, preferably 0.5 to 1.5%, since the attacking property of the other party becomes high due to precipitation.

【0009】(d) S S成分は、上記の通り遊離黒鉛の析出には不可欠の成分
であり、したがってその割合が0.05%未満では黒鉛
化が不十分となって所望の自己潤滑性が得られず、その
分セメンタイトが析出して相手攻撃性を増すようにな
り、一方その割合が1%を越えると急激に脆化し、強度
が低下するようになることから、その割合を0.05〜
1%、望ましくは0.1〜0.7%と定めた。
(D) The S S component is an essential component for the precipitation of free graphite as described above. Therefore, if the proportion thereof is less than 0.05%, graphitization becomes insufficient and the desired self-lubricating property is not obtained. When the ratio exceeds 0.05%, the cementite precipitates to increase the attacking property of the opponent, and when the ratio exceeds 1%, the strength is reduced. ~
It was set to 1%, preferably 0.1 to 0.7%.

【0010】(e) BN BN成分には、Cu−Sn系合金の素地とフェライト相
の界面部に分布して、フェライト相内の粒界にS成分を
核として析出した遊離黒鉛を成長させる、いいかえれば
パーライト相のセメンタイトを黒鉛化して前記パーライ
ト相をフェライト相と遊離黒鉛にする作用があるが、そ
の割合が0.05%未満では黒鉛化が不十分で、残留パ
ーライトによる相手攻撃性は避けられず、かつ所望の自
己潤滑性も得られず、一方その割合が3%を越えると焼
結性が低下し高強度を確保することができなくなること
から、その割合を0.05〜3%、望ましくは1〜3%
と定めた。
(E) BN The BN component is distributed at the interface between the base of the Cu-Sn alloy and the ferrite phase, and free graphite is deposited at the grain boundaries in the ferrite phase, with the S component as nuclei. In other words, it has the effect of graphitizing the cementite of the pearlite phase to convert the pearlite phase into the ferrite phase and free graphite. However, if the ratio is less than 0.05%, the graphitization is insufficient and the opponent attack by residual pearlite is avoided. In addition, the desired self-lubricating property cannot be obtained. On the other hand, if the ratio exceeds 3%, the sinterability is deteriorated and high strength cannot be secured, so the ratio is 0.05 to 3%. , Desirably 1-3%
I decided.

【0011】(f) MoS2 MoS2 成分には、上記の通りBNと共に素地とフェラ
イト相の界面部に分布して自己潤滑性を一段と向上させ
る作用があるので必要に応じて含有されるが、その割合
が0.5%未満では前記作用に所望の効果が得られず、
一方その割合が2%を越えると強度が急激に低下するよ
うになることから、その割合を0.5〜2%、望ましく
は1〜2%と定めた。
(F) MoS 2 The MoS 2 component is contained as necessary because it has a function of further improving the self-lubricating property by being distributed together with BN in the interface between the base and the ferrite phase as described above. If the ratio is less than 0.5%, the desired effect cannot be obtained in the above action,
On the other hand, when the ratio exceeds 2%, the strength rapidly decreases, so the ratio was set to 0.5 to 2%, preferably 1 to 2%.

【0012】(g) 気孔率 気孔率が9%を越えると、軸受の強度か低下し、特に高
強度が要求される場合に対応することができなくなるこ
とから、気孔率を9%以下、望ましくは7%以下と定め
た。
(G) Porosity If the porosity exceeds 9%, the strength of the bearing will decrease, and it will not be possible to deal with the case where particularly high strength is required. Therefore, the porosity is preferably 9% or less. Was set at 7% or less.

【0013】[0013]

【発明の実施の形態】つぎに、この発明の焼結合金軸受
を実施例により具体的に説明する。原料粉末として、粒
度:−100メッシュのアトマイズFe−S合金(S:
0.3%含有)粉末、同−100メッシュのアトマイズ
Fe粉末、同−150メッシュの電解Cu粉末、同−1
00メッシュのSn粉末、同−100メッシュのCu−
Sn合金(Sn:9%含有)粉末、同−150メッシュ
のりん片状黒鉛粉末、同−100メッシュのhBN粉
末、および同−100メッシュのMoS2 粉末を用意
し、これら原料粉末を表1,2に示される配合組成に配
合し、これに潤滑剤として0.4%のステアリン酸亜鉛
を添加してV型ミキサーにて30分間混合した後、3.
5〜5ton/cm2 の範囲内の所定の圧力で圧粉体にプレス
成形し、この圧粉体を、アンモニア分解ガス雰囲気中、
850〜950℃の範囲内の所定温度に30分間保持の
条件で焼結して、同じく表1,2に示される気孔率およ
び配合組成と実質的に同一の成分組成をもった低気孔C
u−Fe−Sn系焼結合金で構成され、いずれも外径:
16mmφ×内径:8mmφ×長さ:8mmの寸法を有する本
発明焼結合金1〜15、および従来焼結合金軸受1〜7
をそれぞれ製造した。なお、本発明焼結合金軸受1〜1
5はいずれも図1または図2に示される組織を有し、ま
た従来焼結合金軸受1〜7はいずれも図3に示される組
織を有するものであった。
BEST MODE FOR CARRYING OUT THE INVENTION Next, the sintered alloy bearing of the present invention will be specifically described by way of Examples. As a raw material powder, atomized Fe-S alloy (S:
0.3% included) powder, atomized Fe powder of the same-100 mesh, electrolytic Cu powder of the same-150 mesh, same-1
00 mesh Sn powder, -100 mesh Cu-
Sn alloy (Sn: 9% content) powder, flaky graphite powder of -150 mesh, hBN powder of -100 mesh, and MoS 2 powder of -100 mesh were prepared. 2. After blending to the blending composition shown in 2, adding 0.4% zinc stearate as a lubricant to this and mixing with a V-type mixer for 30 minutes, 3.
The green compact is press-molded at a predetermined pressure within the range of 5 ton / cm 2 and the green compact is placed in an ammonia decomposing gas atmosphere.
Low porosity C that has been sintered at a predetermined temperature within the range of 850 to 950 ° C. for 30 minutes and has substantially the same composition as the porosity and the composition shown in Tables 1 and 2.
It is composed of u-Fe-Sn based sintered alloy, and each has an outer diameter:
16 mmφ × inner diameter: 8 mmφ × length: 8 mm of the present invention sintered alloys 1 to 15 and conventional sintered alloy bearings 1 to 7
Was manufactured respectively. The sintered alloy bearings 1 to 1 of the present invention
No. 5 had the structure shown in FIG. 1 or FIG. 2, and all the conventional sintered alloy bearings 1 to 7 had the structure shown in FIG.

【0014】ついで、この結果得られた各種の焼結合金
軸受のそれぞれを、合成油を真空浸油した状態で、図4
に概略正面図で示されるラジアル式摩擦試験機の支持治
具1に嵌め込み、これにS45C(炭素鋼)製回転軸3
を25μmのクリアランスで挿通し、前記回転軸3に焼
結合金軸受2、支持治具1、およびボールベアリング4
を介して20kgf/cm2 の高荷重Wをかけた状態で前記回
転軸を10,000rpm の回転数で高速回転させ、10
0時間運転の摩耗試験を行ない、試験後、焼結合金軸受
および回転軸の最大摩耗深さを測定した。この測定結果
を表1,2に示した。
Next, each of the various sintered alloy bearings obtained as a result was subjected to vacuum immersion of synthetic oil as shown in FIG.
It is fitted into a support jig 1 of a radial friction tester shown in a schematic front view in FIG.
With a clearance of 25 μm, and a sintered alloy bearing 2, a support jig 1, and a ball bearing 4 on the rotary shaft 3.
And a high load W of 20 kgf / cm 2 is applied thereto, the rotary shaft is rotated at a high speed of 10,000 rpm to obtain 10
A wear test was run for 0 hours, and after the test, the maximum wear depth of the sintered alloy bearing and the rotating shaft was measured. The measurement results are shown in Tables 1 and 2.

【0015】[0015]

【表1】 [Table 1]

【0016】[0016]

【表2】 [Table 2]

【0017】[0017]

【発明の効果】表1,2に示される結果から、本発明焼
結合金軸受1〜15は、いずれも高速回転および高荷重
運転の苛酷な条件にもかかわらず、基本的に素地中に分
散分布するフェライト相とこれに分散分布する微細な遊
離黒鉛によってすぐれたなじみ性と自己潤滑性を具備す
ることから、相手材である回転軸の摩耗少なく、すなわ
ち低い相手攻撃性で、すぐれた耐摩耗性を示すのに対し
て、従来焼結合金軸受1〜7においては、素地中に分散
分布する硬質のパーライト相が原因で、上記の苛酷な条
件下では著しく高い相手攻撃性を示すばかりでなく、な
じみ性にも劣るので偏摩耗が発生し易いことが明らかで
ある。上述のように、この発明の焼結合金軸受は、相手
材である回転軸に対するなじみ性にすぐれ、かつ自己潤
滑性にもすぐれているので、苛酷な条件下でも、きわめ
て低い相手攻撃性で、すぐれた耐摩耗性を長期に亘って
発揮するのである。
From the results shown in Tables 1 and 2, the sintered alloy bearings 1 to 15 of the present invention are basically dispersed in the matrix despite the severe conditions of high speed rotation and high load operation. The distributed ferrite phase and the fine free graphite dispersed and distributed in it provide excellent conformability and self-lubricating properties, so the rotating shaft, which is the mating material, has less wear, that is, low mating attack and excellent wear resistance. In contrast, the conventional sintered alloy bearings 1 to 7 show not only extremely high opponent aggressiveness under the above-mentioned severe conditions due to the hard pearlite phase dispersed and distributed in the matrix, It is clear that uneven wear is likely to occur because of poor conformability. As described above, the sintered alloy bearing of the present invention has excellent compatibility with the rotating shaft that is the mating material, and also has excellent self-lubricating property, so that even under harsh conditions, it has extremely low mating aggressiveness. It exhibits excellent wear resistance over a long period of time.

【図面の簡単な説明】[Brief description of drawings]

【図1】本発明焼結合金軸受を構成する低気孔Cu−F
e−Sn系焼結合金の組織拡大模写図である。
FIG. 1 is a low-pore Cu-F constituting the sintered alloy bearing of the present invention.
It is a structure expansion copy figure of an e-Sn system sintered alloy.

【図2】本発明焼結合金軸受を構成する低気孔Cu−F
e−Sn系焼結合金の組織拡大模写図である。
FIG. 2 Low porosity Cu-F constituting the sintered alloy bearing of the present invention
It is a structure expansion copy figure of an e-Sn system sintered alloy.

【図3】従来焼結合金軸受を構成する低気孔Cu−Fe
−Sn系焼結合金の組織拡大模写図である。
FIG. 3 Low porosity Cu—Fe forming a conventional sintered alloy bearing
It is a structure expansion copy figure of-Sn system sintered alloy.

【図4】ラジアル式摩擦試験機を示す概略正面図であ
る。
FIG. 4 is a schematic front view showing a radial friction tester.

【符号の説明】[Explanation of symbols]

1 支持治具 2 焼結合金軸受 3 回転軸 4 ボールベアリング 5 ロードセル 1 Support jig 2 Sintered alloy bearing 3 Rotating shaft 4 Ball bearing 5 Load cell

Claims (2)

【特許請求の範囲】[Claims] 【請求項1】 重量%で、 Fe:40〜60%、 Sn:0.1〜5%、 C:0.1〜2%、 S:0.05〜1%、 窒化ほう素:0.05〜3%、を含有し、残りがCuと
不可避不純物からなる組成、 Cu−Sn系合金の素地に、フェライト相が分散分布
し、かつ前記フェライト相内にはS成分を核として成長
した遊離黒鉛が分散分布し、さらに前記素地とフェライ
ト相の界面部に窒化ほう素が分布した組織、 および9%以下の気孔率、を有する低気孔Cu−Fe−
Sn系焼結合金で構成したことを特徴とする相手攻撃性
の低い耐摩耗性焼結合金軸受。
1. By weight%, Fe: 40 to 60%, Sn: 0.1 to 5%, C: 0.1 to 2%, S: 0.05 to 1%, boron nitride: 0.05 A free graphite in which a ferrite phase is dispersedly distributed in a base material of a Cu—Sn alloy, and the rest is grown with the S component as a nucleus in the ferrite phase. Of low-porosity Cu-Fe- having a structure in which is dispersed and further, boron nitride is distributed at the interface between the matrix and the ferrite phase, and a porosity of 9% or less.
A wear-resistant sintered alloy bearing having a low opponent attack characteristic, which is composed of a Sn-based sintered alloy.
【請求項2】 重量%で、 Fe:40〜60%、 Sn:0.1〜5%、 C:0.1〜2%、 S:0.05〜1%、 窒化ほう素:0.05〜3%、 硫化モリブデン:0.5〜2%、を含有し、残りがCu
と不可避不純物からなる組成、 Cu−Sn系合金の素地に、フェライト相が分散分布
し、かつ前記フェライト相内にはS成分を核として成長
した遊離黒鉛が分散分布し、さらに前記素地とフェライ
ト相の界面部に窒化ほう素と硫化モリブデンが分布した
組織、 および9%以下の気孔率、を有する低気孔Cu−Fe−
Sn系焼結合金で構成したことを特徴とする相手攻撃性
の低い耐摩耗性焼結合金軸受。
2. By weight%, Fe: 40 to 60%, Sn: 0.1 to 5%, C: 0.1 to 2%, S: 0.05 to 1%, boron nitride: 0.05 ~ 3%, molybdenum sulfide: 0.5-2%, the rest Cu
And a composition consisting of unavoidable impurities, a ferrite phase is dispersed and distributed in the base material of the Cu—Sn alloy, and free graphite that grows with the S component as a nucleus is distributed and distributed in the ferrite phase. Low-porosity Cu-Fe- having a structure in which boron nitride and molybdenum sulfide are distributed at the interface of, and a porosity of 9% or less.
A wear-resistant sintered alloy bearing having a low opponent attack characteristic, which is composed of a Sn-based sintered alloy.
JP21804295A 1995-08-03 1995-08-03 Wear resistant sintered alloy bearing low in mating attackability Withdrawn JPH0941070A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP21804295A JPH0941070A (en) 1995-08-03 1995-08-03 Wear resistant sintered alloy bearing low in mating attackability

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP21804295A JPH0941070A (en) 1995-08-03 1995-08-03 Wear resistant sintered alloy bearing low in mating attackability

Publications (1)

Publication Number Publication Date
JPH0941070A true JPH0941070A (en) 1997-02-10

Family

ID=16713743

Family Applications (1)

Application Number Title Priority Date Filing Date
JP21804295A Withdrawn JPH0941070A (en) 1995-08-03 1995-08-03 Wear resistant sintered alloy bearing low in mating attackability

Country Status (1)

Country Link
JP (1) JPH0941070A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000036169A1 (en) * 1998-12-16 2000-06-22 Victorian Rail Track Low resistivity materials with improved wear performance for electrical current transfer and methods for preparing same
JP2000230556A (en) * 1999-02-09 2000-08-22 Nippon Kagaku Yakin Co Ltd Bearing
WO2014041976A1 (en) * 2012-09-12 2014-03-20 Ntn株式会社 Machine component made of ferrous sintered metal
CN106756213A (en) * 2016-11-11 2017-05-31 中南大学 A kind of copper-base material with high abrasive resistance and preparation method thereof

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000036169A1 (en) * 1998-12-16 2000-06-22 Victorian Rail Track Low resistivity materials with improved wear performance for electrical current transfer and methods for preparing same
JP2000230556A (en) * 1999-02-09 2000-08-22 Nippon Kagaku Yakin Co Ltd Bearing
WO2014041976A1 (en) * 2012-09-12 2014-03-20 Ntn株式会社 Machine component made of ferrous sintered metal
CN104583443A (en) * 2012-09-12 2015-04-29 Ntn株式会社 Machine component made of ferrous sintered metal
US9970086B2 (en) 2012-09-12 2018-05-15 Ntn Corporation Machine component made of ferrous sintered metal
US11035027B2 (en) 2012-09-12 2021-06-15 Ntn Corporation Machine component made of ferrous sintered metal
CN106756213A (en) * 2016-11-11 2017-05-31 中南大学 A kind of copper-base material with high abrasive resistance and preparation method thereof

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