JP2001303217A - Fe BASED SINTERED ALLOY BEARING EXCELLENT IN SEIZURE RESISTANCE AND CRACKING RESISTANCE - Google Patents

Fe BASED SINTERED ALLOY BEARING EXCELLENT IN SEIZURE RESISTANCE AND CRACKING RESISTANCE

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Publication number
JP2001303217A
JP2001303217A JP2000129221A JP2000129221A JP2001303217A JP 2001303217 A JP2001303217 A JP 2001303217A JP 2000129221 A JP2000129221 A JP 2000129221A JP 2000129221 A JP2000129221 A JP 2000129221A JP 2001303217 A JP2001303217 A JP 2001303217A
Authority
JP
Japan
Prior art keywords
sintered alloy
resistance
based sintered
alloy bearing
bearing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
JP2000129221A
Other languages
Japanese (ja)
Inventor
Akitomo Komazaki
聰寛 駒崎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Materials Corp
Original Assignee
Mitsubishi Materials Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Materials Corp filed Critical Mitsubishi Materials Corp
Priority to JP2000129221A priority Critical patent/JP2001303217A/en
Publication of JP2001303217A publication Critical patent/JP2001303217A/en
Withdrawn legal-status Critical Current

Links

Abstract

PROBLEM TO BE SOLVED: To provide an Fe based sintered alloy bearing exhibiting excellent seizure resistance with a rotary shaft as a corresponding member under the high load-high speed driving condition and also improved in cracking resistance by its high toughness. SOLUTION: This Fe based sintered alloy bearing is composed of an Fe series sintered alloy having a composition containing, by mass, 18 to 25% Cu, 1 to 3% C and 0.1 to 5% CaF2, and the balance Fe with inevitable impurities and a structure in which Cu, CaF2 and free graphite are dispersedly distributed into a base essentially consisting of pearlite and bainite and also having a porosity of <=9%.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】この発明は、特に高荷重高速
運転条件下で、相手材である回転軸との間ですぐれた耐
焼付性を発揮し、かつ具備する高靭性によって耐割れ性
も向上したFe系焼結合金軸受に関するものである。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention exhibits excellent seizure resistance with a rotating shaft as a mating material, particularly under high load and high speed operation conditions, and also has improved crack resistance due to the high toughness provided. The present invention relates to an Fe-based sintered alloy bearing.

【0002】[0002]

【従来の技術】従来、一般に各種駆動装置には、相手材
である回転軸の支持部材として各種の焼結合金軸受が用
いられており、この焼結合金軸受の1種として、質量%
で(以下、組成に関する%は質量%を示す)、Cu:1
8〜25%、C:1〜3%、を含有し、残りがFeと不
可避不純物からなる組成、並びにパーライトおよびベー
ナイトを主体とした素地に、Cu、および遊離黒鉛が分
散分布した組織を有し、かつ9%以下の気孔率を有する
Fe系焼結合金軸受が知られている。
2. Description of the Related Art Conventionally, various driving devices generally use various sintered alloy bearings as a support member for a rotating shaft as a mating member. One type of the sintered alloy bearing is mass%.
(Hereinafter,% relating to the composition indicates mass%), Cu: 1
8 to 25%, C: 1 to 3%, the balance being composed of Fe and inevitable impurities, and a structure in which Cu and free graphite are dispersed and distributed in a base material mainly composed of pearlite and bainite. Fe-based sintered alloy bearings having a porosity of 9% or less are known.

【0003】[0003]

【発明が解決しようとする課題】一方、近年の駆動装置
の高性能化および高出力化はざましく、かつ小型化およ
び軽量化に対する要求も強く、これに伴ない、駆動装置
の構造部材である回転軸の回転は高速化し、かつ回転軸
への負荷は高荷重となる傾向にあるが、上記の従来Fe
系焼結合金軸受においては、高荷重高速運転条件下では
焼付きが発生し易く、また前記の小型化および軽量化の
目的で薄肉化すると靭性不足が原因で割れが発生し易く
なるのが現状である。
On the other hand, in recent years, high performance and high output of a driving device are remarkable, and there is a strong demand for reduction in size and weight. The rotation of the shaft tends to be faster and the load on the rotating shaft tends to be higher.
In the case of sintered sintered alloy bearings, seizure is likely to occur under high load and high speed operation conditions, and cracks are likely to occur due to lack of toughness if the thickness is reduced for the purpose of miniaturization and weight reduction. It is.

【0004】[0004]

【課題を解決するための手段】そこで、本発明者は、特
に上記の従来Fe系焼結合金軸受に着目し、これの耐焼
付性および耐割れ性改善を図るべく研究を行った結果、
上記の従来Fe系焼結合金軸受を構成するFe系焼結合
金に、弗化カルシウム(以下、CaF2で示す)を0.
1〜5%の割合で含有させると、このCaF2が素地に
分散分布して耐焼付性を著しく向上させると共に、素地
に分散分布するCuを微細化するほか、Cuの素地への
固溶を抑制して、できるだけ多くのCuが素地中に分散
分布するように作用することから、靭性が向上し、薄肉
化しても割れ発生が防止されるようになるという研究結
果を得たのである。
Therefore, the present inventor has paid particular attention to the above-mentioned conventional Fe-based sintered alloy bearing, and has conducted research to improve seizure resistance and crack resistance thereof.
Calcium fluoride (hereinafter, referred to as CaF 2 ) is added to the Fe-based sintered alloy constituting the above-mentioned conventional Fe-based sintered alloy bearing in an amount of 0.1%.
When contained at a ratio of 1 to 5%, this CaF 2 is dispersed and distributed in the base material to significantly improve the seizure resistance, and also finely disperses and distributes Cu in the base material. Research has been carried out to suppress as much as possible so that as much Cu as possible is dispersed and distributed in the substrate, thereby improving toughness and preventing cracking even when the thickness is reduced.

【0005】この発明は、上記の研究結果に基づいてな
されたものであって、Cu:18〜25%、C:1〜3
%、CaF2:0.1〜5%、を含有し、残りがFeと
不可避不純物からなる組成、並びにパーライトおよびベ
ーナイトを主体とした素地に、Cu、CaF2、および
遊離黒鉛が分散分布した組織を有し、かつ9%以下の気
孔率を有するFe系焼結合金で構成してなる、耐焼付性
および耐割れ性にすぐれたFe系焼結合金軸受に特徴を
有するものである。
The present invention has been made on the basis of the above-mentioned research results, and it has been found that Cu: 18 to 25% and C: 1 to 3
%, CaF 2 : 0.1 to 5%, and the balance is composed of Fe and unavoidable impurities, and a structure in which Cu, CaF 2 and free graphite are dispersed and distributed in a base material mainly composed of pearlite and bainite. And a Fe-based sintered alloy bearing having excellent seizure resistance and cracking resistance, comprising an Fe-based sintered alloy having a porosity of 9% or less.

【0006】つぎに、この発明のFe系焼結合金軸受を
構成するFe系焼結合金の組成および気孔率を上記の通
りに限定した理由を説明する。 (a)Cu含有量 Cu成分は、液相焼結を可能ならしめ、もって所定の強
度を確保するのに不可欠の成分であるが、上記の通りC
aF2の作用で素地への固溶が抑制され、かつ微細化し
た状態で素地中に分散分布して靭性、すなわち耐割れ性
を向上させる作用をもつが、その含有量が18%未満で
は前記作用に所望の効果が得られず、一方その含有量が
25%を越えると摩耗が急激に進行するようになること
から、その含有量を18〜25%、望ましくは19〜2
1%と定めた。
Next, the reason why the composition and porosity of the Fe-based sintered alloy constituting the Fe-based sintered alloy bearing of the present invention are limited as described above will be described. (A) Cu content The Cu component is an indispensable component for enabling liquid phase sintering and thereby ensuring a predetermined strength.
The action of aF 2 suppresses solid solution in the base material and disperses and distributes in the base material in a finely divided state to improve toughness, that is, an effect of improving crack resistance. If the desired effect is not obtained, the wear will rapidly progress if the content exceeds 25%, so that the content is 18 to 25%, preferably 19 to 2%.
It was determined to be 1%.

【0007】(b)C含有量 C成分は、素地のパーライトおよびベーナイト、さらに
セメンタイトを形成して耐摩耗性を向上させるほか、素
地に遊離黒鉛として分散分布して潤滑性の向上にも寄与
する作用をもつが、その含有量が1%未満では前記作用
に所望の効果が得られず、一方その含有量が3%を越え
ると相手攻撃性が増大するようになることから、その含
有量を1〜3%、望ましくは1.5〜2.5%と定め
た。
(B) C content The C component forms pearlite and bainite of the base material, and further improves the wear resistance by forming cementite, and also contributes to the improvement of lubricity by dispersing and distributing as free graphite in the base material. If the content is less than 1%, the desired effect cannot be obtained in the above-mentioned effect, while if the content exceeds 3%, the aggressiveness of the opponent increases, so that the content is reduced. 1-3%, preferably 1.5-2.5%.

【0008】(c)CaF2含有量 CaF2成分は、上記の通り素地に分散分布して、特に
高荷重高速運転条件下での耐焼付性を著しく向上させる
と共に、Cuの素地への固溶を抑制して素地への分散分
布を促進し、かつこれの微細化に寄与する作用をもつ
が、その含有量が0.1%未満では前記作用に所望の効
果が得られず、一方その含有量が5%を越えると急激に
靭性が低下し、所望のすぐれた耐割れ性を確保すること
ができなくなることから、その含有量を0.1〜5%、
望ましくは2〜4%と定めた。
(C) CaF 2 content The CaF 2 component is dispersed and distributed in the matrix as described above, and remarkably improves the seizure resistance particularly under high-load and high-speed operation conditions. Has an effect of promoting the distribution of dispersion on the substrate and contributing to the miniaturization of the material. However, if the content is less than 0.1%, the desired effect cannot be obtained in the above-mentioned effect. If the amount exceeds 5%, the toughness rapidly decreases, and it becomes impossible to secure the desired excellent crack resistance, so that the content is 0.1 to 5%.
Preferably, it is set to 2 to 4%.

【0009】(d)気孔率 気孔率が9%を越えると、強度および靭性が急激に低下
し、高荷重の高面圧下では割れが発生し易くなることか
ら、気孔率を9%以下、望ましくは7%以下と定めた。
(D) Porosity When the porosity exceeds 9%, the strength and toughness rapidly decrease, and cracks easily occur under high load and high surface pressure. Therefore, the porosity is preferably 9% or less. Has been determined to be 7% or less.

【0010】[0010]

【発明の実施の態様】つぎに、この発明のFe系焼結合
金軸受を実施例により具体的に説明する。原料粉末とし
て、40〜200μmの範囲内の所定の平均粒径を有す
るアトマイズ鉄粉、電解銅粉、CaF2粉末、および炭
素粉末を用意し、これら原料粉末を表1に示される配合
組成に配合し、これに潤滑材として0.4%のステアリ
ン酸亜鉛を添加してV型ミキサーにて30分間混合した
後、196〜588MPaの範囲内の所定の圧力で圧粉
体にプレス成形し、これらの圧粉体を、アンモニア分解
ガス雰囲気中、1090〜1150℃の範囲内の所定の
温度に30分間保持の条件で燒結して、同じく表1に示
される気孔率および表1の配合組成と実質的に同じ組成
をもったFe系焼結合金で構成され、いずれも外形:1
8mm×内径:8mm×幅:8mmの寸法をもった本発
明焼結合金軸受1〜8および従来焼結合金軸受1〜6を
それぞれ製造した。
Next, the present invention will be described in more detail with reference to examples. Atomized iron powder, electrolytic copper powder, CaF 2 powder, and carbon powder having a predetermined average particle size in the range of 40 to 200 μm were prepared as raw material powders, and these raw material powders were blended in the composition shown in Table 1. Then, 0.4% of zinc stearate was added as a lubricant to the mixture, and the mixture was mixed by a V-type mixer for 30 minutes. Then, the mixture was pressed into a green compact at a predetermined pressure in the range of 196 to 588 MPa. Is sintered at a predetermined temperature in the range of 1,090 to 1,150 ° C. for 30 minutes in an ammonia decomposition gas atmosphere, and the porosity shown in Table 1 and the composition shown in Table 1 are substantially the same. Are composed of Fe-based sintered alloys having the same composition.
The sintered alloy bearings 1 to 8 of the present invention and the conventional sintered alloy bearings 1 to 6 having the dimensions of 8 mm × inner diameter: 8 mm × width: 8 mm were manufactured, respectively.

【0011】この結果得られた各種の焼結合金軸受につ
いて、これを構成するFe系焼結合金の組織を光学顕微
鏡(200倍および400倍)にて観察したところ、本
発明焼結合金軸受1〜8は、いずれもパーライト相およ
びベーナイト相を主体とし、かつセメンタイト相が存在
する素地に、Cu相、CaF2相、および遊離黒鉛相が
分散分布した組織を示し、一方従来焼結合金軸受1〜6
は、いずれもパーライト相およびベーナイト相を主体と
し、かつセメンタイト相が存在する素地に、Cu相およ
び遊離黒鉛相が分散分布した組織を示したが、Cu相の
割合が相対的に少なく、かつ相対的に粗大化した状態が
観察された。
With respect to the various sintered alloy bearings obtained as a result, the structure of the Fe-based sintered alloy constituting the sintered alloy bearing was observed with an optical microscope (200 × and 400 ×). No. 8 to No. 8 each show a structure in which a Cu phase, a CaF 2 phase and a free graphite phase are dispersed and distributed in a base material in which a pearlite phase and a bainite phase are mainly contained and a cementite phase is present. ~ 6
Shows a structure in which a Cu phase and a free graphite phase are dispersed and distributed in a matrix mainly composed of a pearlite phase and a bainite phase, and a cementite phase is present. A coarse state was observed.

【0012】つぎに、上記の各種焼結合金軸受につい
て、耐焼付性を評価する目的で、 ブロック寸法:長さ:40mm×幅:10mm×厚さ:
10mm、 ブロック材:SCM420の焼入れ焼戻し熱処理材、 軸受回転数:600r.p.m.、 軸受の外周面に接して上側に水平配置した上記ブロック
を介して前記軸受に付加される荷重の付加態様:2分経
過毎に19.6Nづつ増加、の条件でブロックオンリン
グ試験を行い、軸受に焼付きが発生した時点の荷重(焼
付荷重という)を測定した。また、上記の各種焼結合金
軸受について、耐割れ性(靭性)を評価する目的で、衝
撃値および圧壊強度を測定した。さらに、これらの各種
焼結合金軸受について、高荷重高速運転条件下での耐摩
耗性を評価する目的で、図1に概略正面図で示されるラ
ジアル式摩耗試験機を用い、これの支持治具1に軸受2
を嵌め込んだ状態で、 回転軸3の材質:JIS・S45C、 軸受2と回転軸3のクリアランス:25μm、 回転軸3に軸受2、支持治具1、およびボールベアリン
グ4を介して付加される荷重(W):98N、 回転軸3の回転数:1200r.p.m.、 運転時間:1時間、 の条件で摩耗試験を行い、試験後の軸受内周面における
最大摩耗深さを測定すると共に、その摩耗状況を観察し
た。
Next, with respect to the above various sintered alloy bearings, in order to evaluate the seizure resistance, a block size: length: 40 mm × width: 10 mm × thickness:
10 mm, Block material: SCM420 quenched and tempered heat-treated material, Bearing rotation speed: 600 r. p. m. A block-on-ring test was performed under the condition that the load applied to the bearing via the block horizontally arranged on the upper side in contact with the outer peripheral surface of the bearing was increased by 19.6 N every 2 minutes. The load (seizing load) at the time when seizure occurred on the bearing was measured. The impact value and crushing strength of the various sintered alloy bearings were measured for the purpose of evaluating the crack resistance (toughness). Further, for the purpose of evaluating the wear resistance of these various sintered alloy bearings under high load and high speed operation conditions, a radial type abrasion tester shown in a schematic front view in FIG. Bearing 1 for 2
The material of the rotating shaft 3 is JIS S45C, the clearance between the bearing 2 and the rotating shaft 3 is 25 μm, and is added to the rotating shaft 3 via the bearing 2, the support jig 1, and the ball bearing 4. Load (W): 98 N, number of rotations of the rotating shaft 3: 1200 r. p. m. , Operation time: 1 hour, a wear test was performed, the maximum wear depth on the bearing inner peripheral surface after the test was measured, and the wear state was observed.

【0013】[0013]

【表1】 [Table 1]

【0014】[0014]

【発明の効果】表1に示される通り、本発明焼結合金軸
受1〜8は、いずれも従来焼結合金軸受1〜6に比して
一段と高い焼付荷重、衝撃値、および圧壊強度を示し、
これらの結果は、上記の高荷重高速運転条件での摩耗試
験に明確に現われており、本発明焼結合金軸受1〜8
は、従来焼結合金軸受1〜6に比してすぐれた耐焼付性
および耐割れ性(靭性)を発揮し、すぐれた耐摩耗性を
示すのに対して、従来焼結合金軸受1〜6には焼付きお
よび割れ現象が現われており、これが原因で摩耗が一段
と促進されるようになることが明らかである。上述の通
り、この発明のFe系焼結合金軸受は、すぐれた耐焼付
性および耐割れ性(靭性)を有し、高荷重高速運転条件
ですぐれた耐摩耗性を発揮するものであり、したがって
駆動装置の高性能化および高出力化、さらに小型化およ
び軽量化に十分満足に対応できるものである。
As shown in Table 1, all of the sintered alloy bearings 1 to 8 of the present invention show much higher seizure load, impact value and crushing strength than the conventional sintered alloy bearings 1 to 6. ,
These results are clearly shown in the wear test under the high-load and high-speed operation conditions described above, and the sintered alloy bearings 1 to 8 of the present invention.
Exhibits superior seizure resistance and cracking resistance (toughness) as compared to conventional sintered alloy bearings 1 to 6 and exhibits excellent wear resistance, whereas conventional sintered alloy bearings 1 to 6 In this case, seizure and cracking phenomena appear, and it is clear that this causes the wear to be further accelerated. As described above, the Fe-based sintered alloy bearing of the present invention has excellent seizure resistance and crack resistance (toughness) and exhibits excellent wear resistance under high load and high speed operation conditions. The present invention can satisfactorily cope with high performance and high output of the drive device, and further downsizing and weight reduction.

【図面の簡単な説明】[Brief description of the drawings]

【図1】ラジアル式摩耗試験機を示す概略正面図であ
る。
FIG. 1 is a schematic front view showing a radial type wear tester.

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) C22C 38/16 C22C 38/16 F16C 33/12 F16C 33/12 B // F16C 33/14 33/14 A ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI Theme coat ゛ (Reference) C22C 38/16 C22C 38/16 F16C 33/12 F16C 33/12 B // F16C 33/14 33/14 A

Claims (1)

【特許請求の範囲】[Claims] 【請求項1】 質量%で、 Cu:18〜25%、 C:1〜3%、 弗化カルシウム:0.1〜5%、を含有し、残りがFe
と不可避不純物からなる組成、並びにパーライトおよび
ベーナイトを主体とした素地に、Cu、弗化カルシウ
ム、および遊離黒鉛が分散分布した組織を有し、かつ9
%以下の気孔率を有するFe系焼結合金で構成したこと
を特徴とする耐焼付性および耐割れ性にすぐれたFe系
焼結合金軸受。
1. A mass% of Cu: 18 to 25%, C: 1 to 3%, and calcium fluoride: 0.1 to 5%, with the balance being Fe
Having a structure in which Cu, calcium fluoride, and free graphite are dispersed and distributed in a base material mainly composed of pearlite and bainite, and
An Fe-based sintered alloy bearing having excellent seizure resistance and cracking resistance, comprising an Fe-based sintered alloy having a porosity of not more than 0.1%.
JP2000129221A 2000-04-28 2000-04-28 Fe BASED SINTERED ALLOY BEARING EXCELLENT IN SEIZURE RESISTANCE AND CRACKING RESISTANCE Withdrawn JP2001303217A (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006299346A (en) * 2005-04-20 2006-11-02 Mitsubishi Materials Pmg Corp Sliding component and method for producing the same
WO2006114912A1 (en) 2005-04-20 2006-11-02 Mitsubishi Materials Pmg Corporation Sliding component and method for manufacturing the same
US8167971B2 (en) 2005-04-20 2012-05-01 Diamet Corporation Sliding part and method of manufacturing the same
KR101303516B1 (en) * 2005-04-20 2013-09-03 가부시키가이샤 다이야멧트 Sliding component and method for manufacturing the same
US9017599B2 (en) 2005-04-20 2015-04-28 Diamet Corporation Sliding part and method of manufacturing the same
JP2008007794A (en) * 2006-06-27 2008-01-17 Mitsubishi Materials Pmg Corp BEARING MADE OF Cu-Ni-Sn SERIES COPPER BASED SINTERED ALLOY FOR ELECTRONIC CONTROL TYPE THROTTLE
JP2011127742A (en) * 2009-12-21 2011-06-30 Diamet:Kk Oil-impregnated sintered bearing and method for manufacturing the same
JP2012067393A (en) * 2011-11-02 2012-04-05 Diamet:Kk Sliding component

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