JPH0830193B2 - 軽質パラフィンからオレフィンを製造する方法 - Google Patents
軽質パラフィンからオレフィンを製造する方法Info
- Publication number
- JPH0830193B2 JPH0830193B2 JP4267995A JP26799592A JPH0830193B2 JP H0830193 B2 JPH0830193 B2 JP H0830193B2 JP 4267995 A JP4267995 A JP 4267995A JP 26799592 A JP26799592 A JP 26799592A JP H0830193 B2 JPH0830193 B2 JP H0830193B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- stream
- oxide
- solids
- reaction
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 150000001336 alkenes Chemical class 0.000 title claims description 19
- 239000012188 paraffin wax Substances 0.000 title claims description 10
- 238000004519 manufacturing process Methods 0.000 title claims description 9
- 239000003054 catalyst Substances 0.000 claims description 238
- 238000006243 chemical reaction Methods 0.000 claims description 101
- 238000000034 method Methods 0.000 claims description 76
- 238000006356 dehydrogenation reaction Methods 0.000 claims description 51
- 230000008569 process Effects 0.000 claims description 40
- 238000002156 mixing Methods 0.000 claims description 23
- 238000010791 quenching Methods 0.000 claims description 23
- 239000002245 particle Substances 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 15
- 238000000926 separation method Methods 0.000 claims description 14
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 11
- 230000000171 quenching effect Effects 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 7
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 150000001875 compounds Chemical class 0.000 claims description 6
- 150000003624 transition metals Chemical group 0.000 claims description 6
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical group [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052751 metal Inorganic materials 0.000 claims description 5
- 239000002184 metal Substances 0.000 claims description 5
- 229910052763 palladium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 4
- 238000003303 reheating Methods 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 3
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 3
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 3
- 235000012211 aluminium silicate Nutrition 0.000 claims description 3
- 229910052804 chromium Inorganic materials 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 3
- 229910000464 lead oxide Inorganic materials 0.000 claims description 3
- 229910044991 metal oxide Inorganic materials 0.000 claims description 3
- 150000004706 metal oxides Chemical class 0.000 claims description 3
- 150000002739 metals Chemical class 0.000 claims description 3
- 229910052759 nickel Inorganic materials 0.000 claims description 3
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 3
- 229910052697 platinum Inorganic materials 0.000 claims description 3
- 230000001172 regenerating effect Effects 0.000 claims description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 claims description 3
- 229910001887 tin oxide Inorganic materials 0.000 claims description 3
- 239000010457 zeolite Substances 0.000 claims description 3
- 229910021536 Zeolite Inorganic materials 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052720 vanadium Inorganic materials 0.000 claims description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims 2
- 239000003513 alkali Substances 0.000 claims 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims 2
- 230000014759 maintenance of location Effects 0.000 claims 2
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 claims 1
- XHCLAFWTIXFWPH-UHFFFAOYSA-N [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[V+5].[V+5] XHCLAFWTIXFWPH-UHFFFAOYSA-N 0.000 claims 1
- 229910000423 chromium oxide Inorganic materials 0.000 claims 1
- 229910000480 nickel oxide Inorganic materials 0.000 claims 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical group O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 claims 1
- HBEQXAKJSGXAIQ-UHFFFAOYSA-N oxopalladium Chemical compound [Pd]=O HBEQXAKJSGXAIQ-UHFFFAOYSA-N 0.000 claims 1
- MUMZUERVLWJKNR-UHFFFAOYSA-N oxoplatinum Chemical compound [Pt]=O MUMZUERVLWJKNR-UHFFFAOYSA-N 0.000 claims 1
- 229910003445 palladium oxide Inorganic materials 0.000 claims 1
- 229910003446 platinum oxide Inorganic materials 0.000 claims 1
- CHWRSCGUEQEHOH-UHFFFAOYSA-N potassium oxide Chemical compound [O-2].[K+].[K+] CHWRSCGUEQEHOH-UHFFFAOYSA-N 0.000 claims 1
- 229910001950 potassium oxide Inorganic materials 0.000 claims 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 claims 1
- 229910001935 vanadium oxide Inorganic materials 0.000 claims 1
- 239000007787 solid Substances 0.000 description 117
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 48
- 239000007789 gas Substances 0.000 description 45
- 230000000694 effects Effects 0.000 description 27
- 229930195733 hydrocarbon Natural products 0.000 description 26
- 150000002430 hydrocarbons Chemical class 0.000 description 26
- 230000003197 catalytic effect Effects 0.000 description 25
- 239000001294 propane Substances 0.000 description 24
- 239000004215 Carbon black (E152) Substances 0.000 description 14
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 14
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 14
- 239000003085 diluting agent Substances 0.000 description 13
- 238000006555 catalytic reaction Methods 0.000 description 12
- 230000008929 regeneration Effects 0.000 description 12
- 238000011069 regeneration method Methods 0.000 description 12
- 238000010790 dilution Methods 0.000 description 11
- 239000012895 dilution Substances 0.000 description 11
- 238000000197 pyrolysis Methods 0.000 description 10
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 9
- OFBQJSOFQDEBGM-UHFFFAOYSA-N n-pentane Natural products CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 9
- 230000001133 acceleration Effects 0.000 description 7
- 239000000446 fuel Substances 0.000 description 7
- 238000010438 heat treatment Methods 0.000 description 7
- 238000012546 transfer Methods 0.000 description 7
- 238000002485 combustion reaction Methods 0.000 description 6
- NNPPMTNAJDCUHE-UHFFFAOYSA-N isobutane Chemical compound CC(C)C NNPPMTNAJDCUHE-UHFFFAOYSA-N 0.000 description 6
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 6
- 239000012190 activator Substances 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 238000009826 distribution Methods 0.000 description 5
- 239000011148 porous material Substances 0.000 description 5
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 4
- 239000000571 coke Substances 0.000 description 4
- 239000000567 combustion gas Substances 0.000 description 4
- 238000009792 diffusion process Methods 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 239000001273 butane Substances 0.000 description 3
- 238000005336 cracking Methods 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000002349 favourable effect Effects 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- 239000001282 iso-butane Substances 0.000 description 3
- IJDNQMDRQITEOD-UHFFFAOYSA-N n-butane Chemical compound CCCC IJDNQMDRQITEOD-UHFFFAOYSA-N 0.000 description 3
- 238000004064 recycling Methods 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- 229910018404 Al2 O3 Inorganic materials 0.000 description 2
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 150000001720 carbohydrates Chemical class 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 239000002737 fuel gas Substances 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910000510 noble metal Inorganic materials 0.000 description 2
- 239000000376 reactant Substances 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 229910004865 K2 O Inorganic materials 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 230000001174 ascending effect Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 238000011021 bench scale process Methods 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000000969 carrier Substances 0.000 description 1
- 238000004523 catalytic cracking Methods 0.000 description 1
- 239000007806 chemical reaction intermediate Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000005094 computer simulation Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000002826 coolant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- FZFYOUJTOSBFPQ-UHFFFAOYSA-M dipotassium;hydroxide Chemical compound [OH-].[K+].[K+] FZFYOUJTOSBFPQ-UHFFFAOYSA-M 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000011143 downstream manufacturing Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000003701 inert diluent Substances 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000012821 model calculation Methods 0.000 description 1
- 238000003541 multi-stage reaction Methods 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 238000013404 process transfer Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000001141 propulsive effect Effects 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 238000002407 reforming Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000011949 solid catalyst Substances 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000004227 thermal cracking Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 230000007306 turnover Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3332—Catalytic processes with metal oxides or metal sulfides
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/0015—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
- B01J8/003—Feeding of the particles in the reactor; Evacuation of the particles out of the reactor in a downward flow
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
- B01J8/005—Separating solid material from the gas/liquid stream
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
- C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
- C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
- C07C5/333—Catalytic processes
- C07C5/3335—Catalytic processes with metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
- C07C2521/04—Alumina
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
- C07C2521/16—Clays or other mineral silicates
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
- C07C2523/04—Alkali metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/20—Vanadium, niobium or tantalum
- C07C2523/22—Vanadium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/24—Chromium, molybdenum or tungsten
- C07C2523/26—Chromium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C07C2523/32—Manganese, technetium or rhenium
- C07C2523/34—Manganese
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/42—Platinum
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
- C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
- C07C2523/44—Palladium
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/745—Iron
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
- C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
- C07C2523/74—Iron group metals
- C07C2523/755—Nickel
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2529/00—Catalysts comprising molecular sieves
- C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
- C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US07/757,177 US5254788A (en) | 1991-09-10 | 1991-09-10 | Process for the production of olefins from light paraffins |
| US07/757,177 | 1991-09-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH05194961A JPH05194961A (ja) | 1993-08-03 |
| JPH0830193B2 true JPH0830193B2 (ja) | 1996-03-27 |
Family
ID=25046716
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4267995A Expired - Fee Related JPH0830193B2 (ja) | 1991-09-10 | 1992-09-10 | 軽質パラフィンからオレフィンを製造する方法 |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US5254788A (enExample) |
| EP (1) | EP0532095A3 (enExample) |
| JP (1) | JPH0830193B2 (enExample) |
| KR (1) | KR930005947A (enExample) |
| CN (1) | CN1071410A (enExample) |
| AR (1) | AR247717A1 (enExample) |
| AU (1) | AU653056B2 (enExample) |
| BR (1) | BR9203498A (enExample) |
| CA (1) | CA2077505A1 (enExample) |
| FI (1) | FI924028A7 (enExample) |
| MX (1) | MX9205153A (enExample) |
| NO (1) | NO923340L (enExample) |
| TW (1) | TW212145B (enExample) |
Families Citing this family (52)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2697835B1 (fr) * | 1992-11-06 | 1995-01-27 | Inst Francais Du Petrole | Procédé et dispositif de déshydrogénation catalytique d'une charge paraffinique C2+ comprenant des moyens pour inhiber l'eau dans l'effluent. |
| RU2214383C1 (ru) * | 2002-04-29 | 2003-10-20 | Открытое акционерное общество "Уралоргсинтез" | Способ получения олефиновых углеводородов |
| US7402719B2 (en) * | 2002-06-13 | 2008-07-22 | Velocys | Catalytic oxidative dehydrogenation, and microchannel reactors for catalytic oxidative dehydrogenation |
| US7271307B2 (en) * | 2002-10-29 | 2007-09-18 | Sud-Chemie Inc. | Method for improving the performance of a dehydrogenation catalyst |
| US7405338B2 (en) * | 2003-04-07 | 2008-07-29 | Velocys | Dehydrogenation reactions in narrow reaction chambers and integrated reactors |
| MXPA06008965A (es) * | 2004-02-09 | 2007-02-20 | Down Chemical Company | Proceso para la preparacion de compuestos de hidrocarburos deshidrogenados. |
| US8378163B2 (en) | 2004-03-23 | 2013-02-19 | Velocys Corp. | Catalysts having catalytic material applied directly to thermally-grown alumina and catalytic methods using same, improved methods of oxidative dehydrogenation |
| US7999144B2 (en) | 2006-09-01 | 2011-08-16 | Velocys | Microchannel apparatus and methods of conducting catalyzed oxidative dehydrogenation |
| CN105859503A (zh) * | 2009-03-19 | 2016-08-17 | 陶氏环球技术有限责任公司 | 脱氢方法和催化剂 |
| EP2485997B1 (en) | 2009-10-09 | 2015-09-09 | Dow Global Technologies LLC | Process for the production of chlorinated and/or fluorinated propenes and higher alkenes |
| CN102596387B (zh) * | 2009-10-09 | 2015-11-25 | 陶氏环球技术有限责任公司 | 生产氯化和/或氟化丙烯和高级烯烃的等温多管反应器和方法 |
| EP2485833A2 (en) * | 2009-10-09 | 2012-08-15 | Dow Global Technologies LLC | Adiabatic plug flow reactors and process for producing a chlorinated and/or fluorinated propene and higher alkene |
| US8293670B2 (en) * | 2009-12-09 | 2012-10-23 | Uop Llc | Process for the production of propylene |
| US8624074B2 (en) | 2010-03-22 | 2014-01-07 | Uop Llc | Reactor flowscheme for dehydrogenation of propane to propylene |
| CN102211022A (zh) * | 2010-04-12 | 2011-10-12 | 南京大学扬州化学化工研究院 | 一种丙烷脱氢制丙烯的整体式催化剂制备方法 |
| US8598401B2 (en) | 2010-06-30 | 2013-12-03 | Uop Llc | Method for enhancing the performance of a catalyzed reaction |
| WO2012106453A2 (en) * | 2011-02-01 | 2012-08-09 | The Regents Of The University Of Colorado, A Body Corporate | Materials and methods for improving selectivity in heterogeneous catalysts and products thereof |
| EP2714631B1 (en) | 2011-05-31 | 2020-05-13 | Blue Cube IP LLC | Process for the production of chlorinated propenes |
| CN103562164B (zh) | 2011-05-31 | 2016-04-20 | 陶氏环球技术有限责任公司 | 生产氯化丙烯类的方法 |
| MX336250B (es) | 2011-06-08 | 2016-01-13 | Dow Agrosciences Llc | Proceso para la produccion de propenos clorados y/o fluorados. |
| US9475739B2 (en) | 2011-08-07 | 2016-10-25 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| US9233896B2 (en) | 2011-08-07 | 2016-01-12 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| JP6050372B2 (ja) | 2011-11-21 | 2016-12-21 | ブルー キューブ アイピー エルエルシー | クロロアルカンの製造方法 |
| CA2856717A1 (en) | 2011-12-02 | 2013-06-06 | Dow Global Technologies Llc | Process for the production of chlorinated alkanes |
| CN104024186B (zh) | 2011-12-02 | 2016-10-12 | 蓝立方知识产权有限责任公司 | 生产氯化烷烃的方法 |
| JP6170068B2 (ja) | 2011-12-13 | 2017-07-26 | ブルー キューブ アイピー エルエルシー | 塩素化プロパン及びプロペンの製造方法 |
| WO2013096311A1 (en) | 2011-12-22 | 2013-06-27 | Dow Global Technologies, Llc | Process for the production of tetrachloromethane |
| EP2794521B1 (en) | 2011-12-23 | 2016-09-21 | Dow Global Technologies LLC | Process for the production of alkenes and/or aromatic compounds |
| WO2014046970A1 (en) | 2012-09-20 | 2014-03-27 | Dow Global Technologies, Llc | Process for the production of chlorinated propenes |
| JP2015529247A (ja) | 2012-09-20 | 2015-10-05 | ダウ グローバル テクノロジーズ エルエルシー | 塩素化プロペンの生成のためのプロセス |
| US9795941B2 (en) | 2012-09-30 | 2017-10-24 | Blue Cube Ip Llc | Weir quench and processes incorporating the same |
| JP6363610B2 (ja) | 2012-10-26 | 2018-07-25 | ブルー キューブ アイピー エルエルシー | 混合器およびそれを組み込んだプロセス |
| US9150466B2 (en) * | 2012-11-20 | 2015-10-06 | Uop Llc | Counter-current fluidized bed reactor for the dehydrogenation of olefins |
| CN104870411B (zh) | 2012-12-18 | 2018-10-02 | 蓝立方知识产权有限责任公司 | 用于生产氯化丙烯的方法 |
| CA2894168C (en) | 2012-12-19 | 2018-04-24 | Dow Global Technologies Llc | Process for the production of chlorinated propenes |
| US9382176B2 (en) | 2013-02-27 | 2016-07-05 | Blue Cube Ip Llc | Process for the production of chlorinated propenes |
| EP2964597B1 (en) | 2013-03-09 | 2017-10-04 | Blue Cube IP LLC | Process for the production of chlorinated alkanes |
| ES2716382T3 (es) * | 2013-07-02 | 2019-06-12 | Saudi Basic Ind Corp | Proceso e instalación para la conversión de petróleo crudo en petroquímicos que tiene una eficacia mejorada del carbono |
| CN111875468A (zh) * | 2013-11-12 | 2020-11-03 | 陶氏环球技术有限责任公司 | 催化脱氢方法 |
| CN105728021A (zh) * | 2015-04-01 | 2016-07-06 | 长春工业大学 | 一种异丁烷脱氢制异丁烯用复合载体催化剂及制备方法 |
| CN104941640A (zh) * | 2015-05-29 | 2015-09-30 | 南开大学 | 一种用于丙烷催化脱氢制丙烯的催化剂及其制备方法 |
| US9815040B2 (en) * | 2015-06-26 | 2017-11-14 | Dow Global Technologies Llc | Fluid solids contacting device |
| KR101758226B1 (ko) * | 2015-07-10 | 2017-07-17 | 한국화학연구원 | 탄화수소의 탈수소화를 통해 올레핀을 제조하기 위한 촉매 및 그 제조방법 |
| WO2018002771A1 (en) * | 2016-06-28 | 2018-01-04 | Sabic Global Technologies B.V. | Methods for producing olefins from light hydrocarbons |
| CN106563452A (zh) * | 2016-10-09 | 2017-04-19 | 华南理工大学 | 用于异丁烷催化脱氢制异丁烯的铁催化剂及其制备方法与应用 |
| CN106732528A (zh) * | 2016-11-14 | 2017-05-31 | 中海油天津化工研究设计院有限公司 | 一种晶粒分布不同的低碳烷烃脱氢催化剂及其制备方法 |
| AR111992A1 (es) | 2017-06-19 | 2019-09-11 | Dow Global Technologies Llc | Sistemas de reactor que comprenden el reciclado de fluidos |
| CN113227022A (zh) * | 2018-12-28 | 2021-08-06 | Sk燃气 株式会社 | 利用循环流化床工艺的烯烃制造方法 |
| CN113710633A (zh) * | 2019-03-21 | 2021-11-26 | 凯洛格·布朗及鲁特有限公司 | 用于催化链烷烃脱氢和催化剂回收的方法 |
| WO2020205487A1 (en) * | 2019-03-29 | 2020-10-08 | Purdue Research Foundation | Methane ethane crackers |
| WO2022208416A1 (en) * | 2021-04-01 | 2022-10-06 | Chevron U.S.A. Inc. | Metallocene catalyzed propylene oligomerisation without separation of alkane and olefin |
| CN114804023A (zh) * | 2022-04-11 | 2022-07-29 | 西南石油大学 | 用于天然气制氢和炭黑的金属-熔盐制备方法和用途 |
Family Cites Families (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2335488A (en) * | 1937-07-03 | 1943-11-30 | Conrad Richard | Process for carrying out catalytic reactions in the gas phase |
| US2906695A (en) * | 1956-08-07 | 1959-09-29 | Exxon Research Engineering Co | High temperature short time hydrocarbon conversion process |
| GB817127A (en) * | 1957-01-18 | 1959-07-22 | Bataafsche Petroleum | A process for the catalytic conversion of hydrocarbons or hydrocarbon mixtures |
| JPS4914721B1 (enExample) * | 1970-08-11 | 1974-04-10 | ||
| US3674887A (en) * | 1970-12-24 | 1972-07-04 | Phillips Petroleum Co | Oxidative dehydrogenation process |
| US4108913A (en) * | 1974-09-23 | 1978-08-22 | The Goodyear Tire & Rubber Company | Dehydrogenation process |
| DE2909763C2 (de) * | 1979-03-13 | 1982-09-09 | Deggendorfer Werft Und Eisenbau Gmbh, 8360 Deggendorf | Verfahren zur katalytischen einstufigen, isothermen Dehydrierung von Äthylbenzol zu Styrol |
| US4433984A (en) * | 1979-07-06 | 1984-02-28 | Stone & Webster Engineering Corp. | Low residence time solid-gas separation device and system |
| US4376225A (en) * | 1981-08-05 | 1983-03-08 | Uop Inc. | Dehydrogenation process utilizing indirect heat exchange and direct combustion heating |
| USRE33728E (en) * | 1981-11-24 | 1991-10-29 | Total Engineering And Research Company | Method for catalytically converting residual oils |
| US4459071A (en) * | 1982-01-25 | 1984-07-10 | Stone & Webster Engineering Corp. | Solids flow regulator |
| US4453865A (en) * | 1982-07-21 | 1984-06-12 | Stone & Webster Engineering Corp. | Automatic pressure sensitive regulation assembly |
| US4615792A (en) * | 1985-04-25 | 1986-10-07 | Uop Inc. | Hydrogen circulation for moving bed catalyst transfer systems |
| JPS6239692A (ja) * | 1985-08-13 | 1987-02-20 | コンパニ−・フランセ−ズ・ド・ラフイナ−ジユ | 反応温度の調整による炭化水素装入物の接触クラッキング方法および装置 |
| US4762961A (en) * | 1986-12-15 | 1988-08-09 | Standard Oil Company | Preparation of vanadium III oxidic compounds and dehydrogenation of paraffins |
| US4814067A (en) * | 1987-08-11 | 1989-03-21 | Stone & Webster Engineering Corporation | Particulate solids cracking apparatus and process |
| US4919898A (en) * | 1987-08-11 | 1990-04-24 | Stone & Webster Engineering Corp. | Particulate solids cracking apparatus |
| US4985136A (en) * | 1987-11-05 | 1991-01-15 | Bartholic David B | Ultra-short contact time fluidized catalytic cracking process |
| EP0381870B1 (en) * | 1989-02-08 | 1993-05-12 | Stone & Webster Engineering Corporation | Process for the production of olefins |
| US4956510A (en) * | 1989-03-14 | 1990-09-11 | Mobil Oil Corp. | Hydrocarbon upgrading process and reaction section design with regenerated catalyst quench |
-
1991
- 1991-09-10 US US07/757,177 patent/US5254788A/en not_active Expired - Lifetime
-
1992
- 1992-08-26 NO NO92923340A patent/NO923340L/no unknown
- 1992-09-03 CA CA002077505A patent/CA2077505A1/en not_active Abandoned
- 1992-09-03 AR AR92323110A patent/AR247717A1/es active
- 1992-09-04 EP EP19920202681 patent/EP0532095A3/en not_active Withdrawn
- 1992-09-07 KR KR1019920016265A patent/KR930005947A/ko not_active Abandoned
- 1992-09-09 AU AU22876/92A patent/AU653056B2/en not_active Ceased
- 1992-09-09 MX MX9205153A patent/MX9205153A/es unknown
- 1992-09-09 BR BR929203498A patent/BR9203498A/pt not_active Application Discontinuation
- 1992-09-09 FI FI924028A patent/FI924028A7/fi not_active Application Discontinuation
- 1992-09-10 CN CN92111388A patent/CN1071410A/zh active Pending
- 1992-09-10 JP JP4267995A patent/JPH0830193B2/ja not_active Expired - Fee Related
- 1992-11-03 TW TW081108742A patent/TW212145B/zh active
Also Published As
| Publication number | Publication date |
|---|---|
| AU2287692A (en) | 1993-03-11 |
| US5254788A (en) | 1993-10-19 |
| EP0532095A2 (en) | 1993-03-17 |
| TW212145B (enExample) | 1993-09-01 |
| FI924028A7 (fi) | 1993-03-11 |
| KR930005947A (ko) | 1993-04-20 |
| EP0532095A3 (en) | 1993-05-12 |
| BR9203498A (pt) | 1993-04-13 |
| AU653056B2 (en) | 1994-09-15 |
| CN1071410A (zh) | 1993-04-28 |
| FI924028A0 (fi) | 1992-09-09 |
| JPH05194961A (ja) | 1993-08-03 |
| NO923340D0 (no) | 1992-08-26 |
| AR247717A1 (es) | 1995-03-31 |
| MX9205153A (es) | 1993-03-01 |
| NO923340L (no) | 1993-03-11 |
| CA2077505A1 (en) | 1993-03-11 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPH0830193B2 (ja) | 軽質パラフィンからオレフィンを製造する方法 | |
| RU2731380C2 (ru) | Интегрированный способ дегидрирования c3-c4-углеводородов | |
| EP0753037B1 (en) | Process and apparatus for producing light olefins | |
| US5167795A (en) | Process for the production of olefins and aromatics | |
| EP0381870B1 (en) | Process for the production of olefins | |
| JPH11514700A (ja) | 流動床反応器を利用した炭化水素の変換方法および装置 | |
| US5220093A (en) | Process for production of olefins from mixtures of light paraffins | |
| KR101489768B1 (ko) | 알칸 스트림을 탈수소화하는 촉매 탈수소화 방법 및 장치 | |
| US3767566A (en) | Catalytic petroleum conversion process | |
| JPH03504394A (ja) | 乱流流動触媒床反応器中でのプロペン・エテン混合物の改質方法 | |
| US11286217B2 (en) | Process and apparatus for reacting feed with fluidized catalyst and confined quench | |
| US11491453B2 (en) | Process and apparatus for reacting feed with a fluidized catalyst over a temperature profile | |
| JP3955332B2 (ja) | 改良された接触区域を使用する炭化水素装入物の流動床触媒クラッキング方法および装置 | |
| CN116981509A (zh) | 用于多区流化床反应器中的催化剂再生的集成循环系统及其使用方法 | |
| US2967878A (en) | Vapor phase catalytic conversion processes | |
| US10550336B2 (en) | Methods for catalytic cracking | |
| CN119156363A (zh) | 用于使用包括铁的催化剂通过脱氢制备轻烯烃的方法 | |
| CN103788992A (zh) | 一种催化裂化方法 | |
| EP0639216B1 (en) | Catalytic cracking process and apparatus therefor | |
| EP0419609B1 (en) | Turbulent fluid bed paraffin conversion process | |
| US11794159B2 (en) | Process and apparatus for contacting feed and catalyst with improved catalyst mixing | |
| US20230191354A1 (en) | Process and apparatus for contacting feed and catalyst with improved fluid dynamics | |
| CN111073695B (zh) | 一种费托合成石脑油改质方法 | |
| CN119173490A (zh) | 用于使用包含铬的催化剂通过脱氢制备轻烯烃的方法 | |
| JP2025538470A (ja) | 複数の触媒入口を利用して炭化水素を脱水素する方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20080327 Year of fee payment: 12 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090327 Year of fee payment: 13 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20090327 Year of fee payment: 13 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20100327 Year of fee payment: 14 |
|
| LAPS | Cancellation because of no payment of annual fees |