JPH0747248A - 層状構造プラズマ重合体複合膜 - Google Patents
層状構造プラズマ重合体複合膜Info
- Publication number
- JPH0747248A JPH0747248A JP6132060A JP13206094A JPH0747248A JP H0747248 A JPH0747248 A JP H0747248A JP 6132060 A JP6132060 A JP 6132060A JP 13206094 A JP13206094 A JP 13206094A JP H0747248 A JPH0747248 A JP H0747248A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- membrane
- layers
- selective
- permeable
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012528 membrane Substances 0.000 title claims abstract description 135
- 229920000642 polymer Polymers 0.000 title description 37
- 239000002131 composite material Substances 0.000 title description 16
- 230000035699 permeability Effects 0.000 claims abstract description 29
- UQEAIHBTYFGYIE-UHFFFAOYSA-N hexamethyldisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)C UQEAIHBTYFGYIE-UHFFFAOYSA-N 0.000 claims description 34
- GCSJLQSCSDMKTP-UHFFFAOYSA-N ethenyl(trimethyl)silane Chemical compound C[Si](C)(C)C=C GCSJLQSCSDMKTP-UHFFFAOYSA-N 0.000 claims description 33
- 238000006116 polymerization reaction Methods 0.000 claims description 10
- 239000011148 porous material Substances 0.000 claims description 6
- 230000001186 cumulative effect Effects 0.000 claims description 4
- 229920005597 polymer membrane Polymers 0.000 abstract description 16
- 238000005452 bending Methods 0.000 abstract description 11
- 238000010030 laminating Methods 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 221
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 46
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 39
- 239000001301 oxygen Substances 0.000 description 39
- 229910052760 oxygen Inorganic materials 0.000 description 39
- 229910052757 nitrogen Inorganic materials 0.000 description 29
- 230000000052 comparative effect Effects 0.000 description 22
- 238000000926 separation method Methods 0.000 description 22
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 21
- 229920006254 polymer film Polymers 0.000 description 16
- 239000000178 monomer Substances 0.000 description 13
- 230000007547 defect Effects 0.000 description 12
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 241000894007 species Species 0.000 description 9
- 230000004888 barrier function Effects 0.000 description 8
- 238000012360 testing method Methods 0.000 description 6
- 238000000576 coating method Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000012466 permeate Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000013459 approach Methods 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- 238000000151 deposition Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 229920002492 poly(sulfone) Polymers 0.000 description 3
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 239000003012 bilayer membrane Substances 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 230000032798 delamination Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000014509 gene expression Effects 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- -1 polyvinylene carbonate Polymers 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 229920002379 silicone rubber Polymers 0.000 description 2
- 239000004945 silicone rubber Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000005388 borosilicate glass Substances 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920006380 polyphenylene oxide Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
- B01D69/12—Composite membranes; Ultra-thin membranes
- B01D69/125—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction
- B01D69/127—In situ manufacturing by polymerisation, polycondensation, cross-linking or chemical reaction using electrical discharge or plasma-polymerisation
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Separation Using Semi-Permeable Membranes (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US08/076,386 US5354469A (en) | 1993-06-14 | 1993-06-14 | Layered plasma polymer composite membranes |
| US08/076386 | 1993-06-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0747248A true JPH0747248A (ja) | 1995-02-21 |
Family
ID=22131679
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP6132060A Pending JPH0747248A (ja) | 1993-06-14 | 1994-06-14 | 層状構造プラズマ重合体複合膜 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US5354469A (enExample) |
| EP (1) | EP0630682B1 (enExample) |
| JP (1) | JPH0747248A (enExample) |
| AU (1) | AU6458894A (enExample) |
| CA (1) | CA2125063A1 (enExample) |
| DE (1) | DE69402761T2 (enExample) |
| NO (1) | NO942203L (enExample) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017038284A1 (ja) * | 2015-08-31 | 2017-03-09 | 富士フイルム株式会社 | ガス分離複合膜、ガス分離モジュール、ガス分離装置、ガス分離方法、及びガス分離複合膜の製造方法 |
Families Citing this family (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5478383A (en) * | 1993-10-14 | 1995-12-26 | Canon Kabushiki Kaisha | Ink, and ink-jet recording method and instrument using the same |
| US6165253A (en) * | 1994-05-23 | 2000-12-26 | New Jersey Institute Of Technology | Apparatus for removal of volatile organic compounds from gaseous mixtures |
| US5753009A (en) * | 1996-05-14 | 1998-05-19 | New Jersey Institute Of Technology | Method and apparatus for selectively removing a component from a multicomponent gas/vapor mixture |
| US5993515A (en) * | 1996-05-14 | 1999-11-30 | New Jersey Institute Of Technology | Apparatus and process for selectively removing a component from a multicomponent aqueous solution by pervaporation |
| US20060113189A1 (en) * | 2002-09-05 | 2006-06-01 | Atsunori Hiratsuka | Method for separating substances |
| US20110304412A1 (en) * | 2010-06-10 | 2011-12-15 | Hao Zhang | Acoustic Wave Resonators and Methods of Manufacturing Same |
| US20120247327A1 (en) * | 2010-09-27 | 2012-10-04 | Conocophillips Company | Hollow-fiber membrane contactors |
| US20150135957A1 (en) * | 2013-11-19 | 2015-05-21 | Applied Membrane Technology, Inc. | Organosiloxane Films for Gas Separations |
| US9339770B2 (en) | 2013-11-19 | 2016-05-17 | Applied Membrane Technologies, Inc. | Organosiloxane films for gas separations |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA1139680A (en) * | 1979-06-25 | 1983-01-18 | Minoru Yamamoto | Gas separating members and a method of making the same |
| US4347139A (en) * | 1980-03-24 | 1982-08-31 | Juichiro Ozawa | Membrane for reverse osmosis and method of making the same |
| JPS58180205A (ja) * | 1982-04-16 | 1983-10-21 | Sumitomo Electric Ind Ltd | 東京都港区虎ノ門二丁目５番２１号 |
| US4533369A (en) * | 1982-05-28 | 1985-08-06 | Sumitomo Electric Industries, Ltd. | Gas-permselective composite membranes and process for the production thereof |
| JPS60137417A (ja) * | 1983-12-23 | 1985-07-22 | Toyota Central Res & Dev Lab Inc | 気体分離部材およびその製造方法 |
| AU7134787A (en) * | 1986-04-11 | 1987-10-15 | Applied Membrane Technology Inc. | Gas permselective membrane prepared by plasma polymerisation coating techniques |
| US5207909A (en) * | 1992-03-25 | 1993-05-04 | Exxon Research And Engineering Company | Plasma polymer membrane (C-2564) |
-
1993
- 1993-06-14 US US08/076,386 patent/US5354469A/en not_active Expired - Fee Related
-
1994
- 1994-06-03 CA CA002125063A patent/CA2125063A1/en not_active Abandoned
- 1994-06-08 AU AU64588/94A patent/AU6458894A/en not_active Abandoned
- 1994-06-09 EP EP94304155A patent/EP0630682B1/en not_active Expired - Lifetime
- 1994-06-09 DE DE69402761T patent/DE69402761T2/de not_active Expired - Fee Related
- 1994-06-13 NO NO942203A patent/NO942203L/no unknown
- 1994-06-14 JP JP6132060A patent/JPH0747248A/ja active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017038284A1 (ja) * | 2015-08-31 | 2017-03-09 | 富士フイルム株式会社 | ガス分離複合膜、ガス分離モジュール、ガス分離装置、ガス分離方法、及びガス分離複合膜の製造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0630682A2 (en) | 1994-12-28 |
| DE69402761D1 (de) | 1997-05-28 |
| NO942203L (no) | 1994-12-15 |
| CA2125063A1 (en) | 1994-12-15 |
| US5354469A (en) | 1994-10-11 |
| DE69402761T2 (de) | 1997-07-31 |
| EP0630682A3 (enExample) | 1995-01-25 |
| EP0630682B1 (en) | 1997-04-23 |
| AU6458894A (en) | 1994-12-15 |
| NO942203D0 (no) | 1994-06-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| KR101813170B1 (ko) | 그래핀 함유 분리막 | |
| JP4139456B2 (ja) | 脱気膜 | |
| Kawakami et al. | Modification of gas permeabilities of polymer membranes by plasma coating | |
| JPH0747248A (ja) | 層状構造プラズマ重合体複合膜 | |
| JPS60161703A (ja) | 気体選択透過膜複合体 | |
| JPS58180205A (ja) | 東京都港区虎ノ門二丁目５番２１号 | |
| US5013338A (en) | Plasma-assisted polymerization of monomers onto polymers and gas separation membranes produced thereby | |
| JPH0457372B2 (enExample) | ||
| KR20240033236A (ko) | 층들 간의 접착력이 향상된 박막 복합 멤브레인 및 이의 용도 | |
| JPS6312316A (ja) | プラズマ重合被覆技法によつて製造されたガス選択透過性複合膜 | |
| JP3020120B2 (ja) | テトラハロビスフェノールから誘導したポリカーボネートを主体とする半透膜を用いてガス混合物から水素を分離する方法 | |
| JPS5966308A (ja) | 気体透過複合膜 | |
| EP0336999B1 (en) | Reactive posttreatment for gas separation membranes | |
| Babcock | Layered plasma polymer composite membranes | |
| JPH038808B2 (enExample) | ||
| JPS61149226A (ja) | ガス選択透過性複合膜およびその製造方法 | |
| JPS59115738A (ja) | ガス選択透過性膜およびその製造方法 | |
| JPS642407B2 (enExample) | ||
| US20250121333A1 (en) | Advanced carbon molecular sieve membranes derived from composite polyimide hollow fiber precursors | |
| JPS61153105A (ja) | ガス選択透過性複合膜の製造方法 | |
| Oh et al. | The permeation resistance of interface and the directional dependence of permeation in plasma-grafted composite membranes | |
| JPH03169330A (ja) | 複合膜 | |
| JPS61149210A (ja) | ガス選択透過性複合膜の製造方法 | |
| JP4723749B2 (ja) | 選択透過複合膜の製造方法 | |
| JPS6260933B2 (enExample) |