JPH0587510B2 - - Google Patents
Info
- Publication number
- JPH0587510B2 JPH0587510B2 JP58161168A JP16116883A JPH0587510B2 JP H0587510 B2 JPH0587510 B2 JP H0587510B2 JP 58161168 A JP58161168 A JP 58161168A JP 16116883 A JP16116883 A JP 16116883A JP H0587510 B2 JPH0587510 B2 JP H0587510B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- carbon atoms
- atom
- carbon
- hydrogen atom
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 150000001875 compounds Chemical class 0.000 claims abstract description 73
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims abstract description 39
- 230000012010 growth Effects 0.000 claims abstract description 29
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims abstract description 27
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 16
- 239000002585 base Substances 0.000 claims abstract description 13
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims abstract description 11
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims abstract description 10
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 10
- 150000001412 amines Chemical class 0.000 claims abstract description 8
- 230000002363 herbicidal effect Effects 0.000 claims abstract description 8
- 125000001453 quaternary ammonium group Chemical group 0.000 claims abstract description 6
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 claims abstract description 5
- 150000008044 alkali metal hydroxides Chemical class 0.000 claims abstract description 4
- 125000004432 carbon atom Chemical group C* 0.000 claims description 173
- 125000000217 alkyl group Chemical group 0.000 claims description 39
- 229910052799 carbon Inorganic materials 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 32
- 241000196324 Embryophyta Species 0.000 claims description 31
- -1 methoxy, difluoromethoxy, dimethylamino Chemical group 0.000 claims description 30
- 125000004438 haloalkoxy group Chemical group 0.000 claims description 29
- 125000003545 alkoxy group Chemical group 0.000 claims description 28
- 238000000034 method Methods 0.000 claims description 25
- 125000001188 haloalkyl group Chemical group 0.000 claims description 21
- 125000005843 halogen group Chemical group 0.000 claims description 19
- 125000005083 alkoxyalkoxy group Chemical group 0.000 claims description 18
- 125000004453 alkoxycarbonyl group Chemical group 0.000 claims description 12
- 125000004644 alkyl sulfinyl group Chemical group 0.000 claims description 10
- 125000004390 alkyl sulfonyl group Chemical group 0.000 claims description 10
- 125000004414 alkyl thio group Chemical group 0.000 claims description 10
- 239000004202 carbamide Substances 0.000 claims description 10
- 235000013339 cereals Nutrition 0.000 claims description 9
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 7
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 6
- 230000002401 inhibitory effect Effects 0.000 claims description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 6
- 230000008635 plant growth Effects 0.000 claims description 6
- 230000035784 germination Effects 0.000 claims description 5
- 125000004793 2,2,2-trifluoroethoxy group Chemical group FC(CO*)(F)F 0.000 claims description 4
- 244000068988 Glycine max Species 0.000 claims description 4
- IVRMZWNICZWHMI-UHFFFAOYSA-N azide group Chemical group [N-]=[N+]=[N-] IVRMZWNICZWHMI-UHFFFAOYSA-N 0.000 claims description 4
- 125000004786 difluoromethoxy group Chemical group [H]C(F)(F)O* 0.000 claims description 4
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 4
- 244000045561 useful plants Species 0.000 claims description 4
- IUABDXPHSUYOJL-UHFFFAOYSA-N 1-(2-azidophenyl)sulfonyl-3-(4-methoxy-6-methylpyrimidin-2-yl)urea Chemical group COC1=CC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)N=[N+]=[N-])=N1 IUABDXPHSUYOJL-UHFFFAOYSA-N 0.000 claims description 3
- 235000010469 Glycine max Nutrition 0.000 claims description 3
- 125000002147 dimethylamino group Chemical group [H]C([H])([H])N(*)C([H])([H])[H] 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 2
- 244000299507 Gossypium hirsutum Species 0.000 claims description 2
- 240000007594 Oryza sativa Species 0.000 claims description 2
- 235000007164 Oryza sativa Nutrition 0.000 claims description 2
- 240000000111 Saccharum officinarum Species 0.000 claims description 2
- 235000007201 Saccharum officinarum Nutrition 0.000 claims description 2
- 240000008042 Zea mays Species 0.000 claims description 2
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 claims description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 claims description 2
- 235000005822 corn Nutrition 0.000 claims description 2
- 235000009566 rice Nutrition 0.000 claims description 2
- OJXASOYYODXRPT-UHFFFAOYSA-N sulfamoylurea Chemical compound NC(=O)NS(N)(=O)=O OJXASOYYODXRPT-UHFFFAOYSA-N 0.000 claims description 2
- 150000001721 carbon Chemical group 0.000 claims 26
- 229940100389 Sulfonylurea Drugs 0.000 claims 4
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 claims 4
- ACCGNHVFKPYWNF-UHFFFAOYSA-N 1-azido-1-(benzenesulfonyl)-3-(triazin-4-yl)urea Chemical compound C=1C=CC=CC=1S(=O)(=O)N(N=[N+]=[N-])C(=O)NC1=CC=NN=N1 ACCGNHVFKPYWNF-UHFFFAOYSA-N 0.000 claims 2
- GNWGXASUBJBGGD-UHFFFAOYSA-N triazin-4-ylurea Chemical compound NC(=O)NC1=CC=NN=N1 GNWGXASUBJBGGD-UHFFFAOYSA-N 0.000 claims 2
- NKVJDERHPVKGPJ-UHFFFAOYSA-N 1-azido-1-(benzenesulfonyl)-3-pyrimidin-2-ylurea Chemical compound C=1C=CC=CC=1S(=O)(=O)N(N=[N+]=[N-])C(=O)NC1=NC=CC=N1 NKVJDERHPVKGPJ-UHFFFAOYSA-N 0.000 claims 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims 1
- 125000004429 atom Chemical group 0.000 claims 1
- 244000038559 crop plants Species 0.000 claims 1
- 239000002373 plant growth inhibitor Substances 0.000 claims 1
- 230000001105 regulatory effect Effects 0.000 abstract description 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 150000002431 hydrogen Chemical group 0.000 abstract 3
- 125000006677 (C1-C3) haloalkoxy group Chemical group 0.000 abstract 2
- 229910052736 halogen Inorganic materials 0.000 abstract 2
- 150000002367 halogens Chemical group 0.000 abstract 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 1
- 125000004768 (C1-C4) alkylsulfinyl group Chemical group 0.000 abstract 1
- 125000004769 (C1-C4) alkylsulfonyl group Chemical group 0.000 abstract 1
- 125000004767 (C1-C4) haloalkoxy group Chemical group 0.000 abstract 1
- 125000004765 (C1-C4) haloalkyl group Chemical group 0.000 abstract 1
- 125000000229 (C1-C4)alkoxy group Chemical group 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N nitrogen Substances N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 abstract 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 21
- 239000004480 active ingredient Substances 0.000 description 15
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 11
- 239000004094 surface-active agent Substances 0.000 description 10
- 239000011541 reaction mixture Substances 0.000 description 9
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 230000000694 effects Effects 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 6
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical class CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 6
- 239000000839 emulsion Substances 0.000 description 6
- 230000002265 prevention Effects 0.000 description 6
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 6
- 239000002904 solvent Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 235000013877 carbamide Nutrition 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000002736 nonionic surfactant Substances 0.000 description 5
- 239000000843 powder Substances 0.000 description 5
- 229910052708 sodium Inorganic materials 0.000 description 5
- 239000011734 sodium Substances 0.000 description 5
- 244000025254 Cannabis sativa Species 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- CKXBURCPNPRDTM-UHFFFAOYSA-N n-azidobenzenesulfonamide Chemical compound [N-]=[N+]=NNS(=O)(=O)C1=CC=CC=C1 CKXBURCPNPRDTM-UHFFFAOYSA-N 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 4
- 239000002689 soil Substances 0.000 description 4
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 3
- LKASROVNGLIQDA-UHFFFAOYSA-N 1-(2-azidophenyl)sulfonyl-3-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)urea Chemical compound COC1=NC(C)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)N=[N+]=[N-])=N1 LKASROVNGLIQDA-UHFFFAOYSA-N 0.000 description 3
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 description 3
- 239000005995 Aluminium silicate Substances 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241000209510 Liliopsida Species 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 241000209504 Poaceae Species 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 3
- RWRDLPDLKQPQOW-UHFFFAOYSA-N Pyrrolidine Chemical class C1CCNC1 RWRDLPDLKQPQOW-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000002250 absorbent Substances 0.000 description 3
- 230000002745 absorbent Effects 0.000 description 3
- 229910052783 alkali metal Inorganic materials 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 235000012211 aluminium silicate Nutrition 0.000 description 3
- 239000000969 carrier Substances 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- UAOMVDZJSHZZME-UHFFFAOYSA-N diisopropylamine Chemical class CC(C)NC(C)C UAOMVDZJSHZZME-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000003337 fertilizer Substances 0.000 description 3
- 239000008187 granular material Substances 0.000 description 3
- 239000003630 growth substance Substances 0.000 description 3
- 239000004009 herbicide Substances 0.000 description 3
- 239000000543 intermediate Substances 0.000 description 3
- JJWLVOIRVHMVIS-UHFFFAOYSA-N isopropylamine Chemical compound CC(C)N JJWLVOIRVHMVIS-UHFFFAOYSA-N 0.000 description 3
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 3
- 229920001223 polyethylene glycol Polymers 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 238000006722 reduction reaction Methods 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 235000010288 sodium nitrite Nutrition 0.000 description 3
- 238000009331 sowing Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 239000000725 suspension Substances 0.000 description 3
- HMBXFOSKDPTNFM-UHFFFAOYSA-N 1-(2-azidophenyl)sulfonyl-3-(4,6-dimethoxypyrimidin-2-yl)urea Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)N=[N+]=[N-])=N1 HMBXFOSKDPTNFM-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 2
- 229910021532 Calcite Inorganic materials 0.000 description 2
- ROSDSFDQCJNGOL-UHFFFAOYSA-N Dimethylamine Chemical class CNC ROSDSFDQCJNGOL-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 2
- 240000005979 Hordeum vulgare Species 0.000 description 2
- 235000007340 Hordeum vulgare Nutrition 0.000 description 2
- BAVYZALUXZFZLV-UHFFFAOYSA-N Methylamine Chemical compound NC BAVYZALUXZFZLV-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical class C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical class C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- 229920001214 Polysorbate 60 Polymers 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical class C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical class N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 241000209056 Secale Species 0.000 description 2
- 244000061456 Solanum tuberosum Species 0.000 description 2
- 235000002595 Solanum tuberosum Nutrition 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000001931 aliphatic group Chemical group 0.000 description 2
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 2
- 150000003863 ammonium salts Chemical class 0.000 description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 2
- 239000012752 auxiliary agent Substances 0.000 description 2
- 125000003785 benzimidazolyl group Chemical class N1=C(NC2=C1C=CC=C2)* 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical class CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 125000004218 chloromethyl group Chemical group [H]C([H])(Cl)* 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 235000008504 concentrate Nutrition 0.000 description 2
- 230000001276 controlling effect Effects 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical class CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 2
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical class OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical class CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 2
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 2
- 125000001028 difluoromethyl group Chemical group [H]C(F)(F)* 0.000 description 2
- 238000010410 dusting Methods 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 125000006125 ethylsulfonyl group Chemical group 0.000 description 2
- 241001233957 eudicotyledons Species 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 230000008020 evaporation Effects 0.000 description 2
- 229910052731 fluorine Inorganic materials 0.000 description 2
- 239000011737 fluorine Substances 0.000 description 2
- 125000004216 fluoromethyl group Chemical group [H]C([H])(F)* 0.000 description 2
- 239000003966 growth inhibitor Substances 0.000 description 2
- AWJUIBRHMBBTKR-UHFFFAOYSA-N isoquinoline Chemical compound C1=NC=CC2=CC=CC=C21 AWJUIBRHMBBTKR-UHFFFAOYSA-N 0.000 description 2
- 125000006216 methylsulfinyl group Chemical group [H]C([H])([H])S(*)=O 0.000 description 2
- 125000004170 methylsulfonyl group Chemical group [H]C([H])([H])S(*)(=O)=O 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 239000012074 organic phase Substances 0.000 description 2
- 239000003415 peat Substances 0.000 description 2
- 229920000151 polyglycol Polymers 0.000 description 2
- 239000010695 polyglycol Substances 0.000 description 2
- 235000011118 potassium hydroxide Nutrition 0.000 description 2
- 235000012015 potatoes Nutrition 0.000 description 2
- 230000035484 reaction time Effects 0.000 description 2
- 238000001953 recrystallisation Methods 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 235000011121 sodium hydroxide Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical class CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 235000019354 vermiculite Nutrition 0.000 description 2
- CAHZKICHVXSVPO-UHFFFAOYSA-N (4-methoxy-6-methylpyrimidin-2-yl)urea Chemical compound COC1=CC(C)=NC(NC(N)=O)=N1 CAHZKICHVXSVPO-UHFFFAOYSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 description 1
- CCCYDOKQGBIRSK-UHFFFAOYSA-N 1-(2-aminophenyl)sulfonyl-3-(4,6-dimethoxypyrimidin-2-yl)urea Chemical compound COC1=CC(OC)=NC(NC(=O)NS(=O)(=O)C=2C(=CC=CC=2)N)=N1 CCCYDOKQGBIRSK-UHFFFAOYSA-N 0.000 description 1
- 125000004206 2,2,2-trifluoroethyl group Chemical group [H]C([H])(*)C(F)(F)F 0.000 description 1
- IIBCXMVHDVUGFI-UHFFFAOYSA-N 2-(2-phenoxyethoxy)decan-2-ol Chemical compound CCCCCCCCC(C)(O)OCCOC1=CC=CC=C1 IIBCXMVHDVUGFI-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical group COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- RWHHYCRFXWLKCO-UHFFFAOYSA-N 2-azido-n-(oxomethylidene)benzenesulfonamide Chemical compound [N-]=[N+]=NC1=CC=CC=C1S(=O)(=O)N=C=O RWHHYCRFXWLKCO-UHFFFAOYSA-N 0.000 description 1
- 125000001340 2-chloroethyl group Chemical group [H]C([H])(Cl)C([H])([H])* 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- FOGYNLXERPKEGN-UHFFFAOYSA-N 3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfopropyl)phenoxy]propane-1-sulfonic acid Chemical class COC1=CC=CC(CC(CS(O)(=O)=O)OC=2C(=CC(CCCS(O)(=O)=O)=CC=2)OC)=C1O FOGYNLXERPKEGN-UHFFFAOYSA-N 0.000 description 1
- UZEFHQIOSJWWSB-UHFFFAOYSA-N 4-azidobenzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=C(N=[N+]=[N-])C=C1 UZEFHQIOSJWWSB-UHFFFAOYSA-N 0.000 description 1
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Chemical class CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 241001184547 Agrostis capillaris Species 0.000 description 1
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-M Carbamate Chemical compound NC([O-])=O KXDHJXZQYSOELW-UHFFFAOYSA-M 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000252254 Catostomidae Species 0.000 description 1
- 241001086557 Centrosema plumieri Species 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- 244000052363 Cynodon dactylon Species 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- KIWBPDUYBMNFTB-UHFFFAOYSA-N Ethyl hydrogen sulfate Chemical class CCOS(O)(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 241000410074 Festuca ovina Species 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- 241000209082 Lolium Species 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 244000061176 Nicotiana tabacum Species 0.000 description 1
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 241000209049 Poa pratensis Species 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical class [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- 239000004113 Sepiolite Substances 0.000 description 1
- 241001327284 Sorghastrum nutans Species 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 240000006694 Stellaria media Species 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 240000001260 Tropaeolum majus Species 0.000 description 1
- 235000004424 Tropaeolum majus Nutrition 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 125000002252 acyl group Chemical group 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910001854 alkali hydroxide Inorganic materials 0.000 description 1
- 229910052977 alkali metal sulfide Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 239000007900 aqueous suspension Substances 0.000 description 1
- 150000004982 aromatic amines Chemical class 0.000 description 1
- 238000000889 atomisation Methods 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 1
- BCOZLGOHQFNXBI-UHFFFAOYSA-M benzyl-bis(2-chloroethyl)-ethylazanium;bromide Chemical compound [Br-].ClCC[N+](CC)(CCCl)CC1=CC=CC=C1 BCOZLGOHQFNXBI-UHFFFAOYSA-M 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical class [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 235000011116 calcium hydroxide Nutrition 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000010531 catalytic reduction reaction Methods 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000007931 coated granule Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- 229940043279 diisopropylamine Drugs 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- WEHWNAOGRSTTBQ-UHFFFAOYSA-N dipropylamine Chemical class CCCNCCC WEHWNAOGRSTTBQ-UHFFFAOYSA-N 0.000 description 1
- 235000021186 dishes Nutrition 0.000 description 1
- MOTZDAYCYVMXPC-UHFFFAOYSA-N dodecyl hydrogen sulfate Chemical class CCCCCCCCCCCCOS(O)(=O)=O MOTZDAYCYVMXPC-UHFFFAOYSA-N 0.000 description 1
- 229940043264 dodecyl sulfate Drugs 0.000 description 1
- 239000010459 dolomite Substances 0.000 description 1
- 229910000514 dolomite Inorganic materials 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 1
- 125000004705 ethylthio group Chemical group C(C)S* 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 125000005313 fatty acid group Chemical group 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 230000009422 growth inhibiting effect Effects 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 235000021374 legumes Nutrition 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 235000012254 magnesium hydroxide Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical class COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 description 1
- 125000002816 methylsulfanyl group Chemical group [H]C([H])([H])S[*] 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 239000012764 mineral filler Substances 0.000 description 1
- 229910052901 montmorillonite Inorganic materials 0.000 description 1
- 125000006095 n-butyl sulfinyl group Chemical group 0.000 description 1
- 125000004708 n-butylthio group Chemical group C(CCC)S* 0.000 description 1
- DMFXUAWAYAOUIP-UHFFFAOYSA-N n-nitrobenzenesulfonamide Chemical compound [O-][N+](=O)NS(=O)(=O)C1=CC=CC=C1 DMFXUAWAYAOUIP-UHFFFAOYSA-N 0.000 description 1
- 125000006093 n-propyl sulfinyl group Chemical group 0.000 description 1
- 125000006124 n-propyl sulfonyl group Chemical group 0.000 description 1
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 1
- 150000002790 naphthalenes Chemical class 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000012044 organic layer Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 125000006340 pentafluoro ethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- BSCCSDNZEIHXOK-UHFFFAOYSA-N phenyl carbamate Chemical compound NC(=O)OC1=CC=CC=C1 BSCCSDNZEIHXOK-UHFFFAOYSA-N 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 125000005498 phthalate group Chemical class 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- 238000012794 pre-harvesting Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 239000008262 pumice Substances 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 125000000246 pyrimidin-2-yl group Chemical group [H]C1=NC(*)=NC([H])=C1[H] 0.000 description 1
- 150000003230 pyrimidines Chemical class 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical group 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 235000003441 saturated fatty acids Nutrition 0.000 description 1
- 150000004671 saturated fatty acids Chemical class 0.000 description 1
- 238000009738 saturating Methods 0.000 description 1
- 229910052624 sepiolite Inorganic materials 0.000 description 1
- 235000019355 sepiolite Nutrition 0.000 description 1
- 230000009528 severe injury Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 235000020354 squash Nutrition 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003460 sulfonic acids Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004546 suspension concentrate Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 150000003510 tertiary aliphatic amines Chemical class 0.000 description 1
- CBXCPBUEXACCNR-UHFFFAOYSA-N tetraethylammonium Chemical compound CC[N+](CC)(CC)CC CBXCPBUEXACCNR-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- QEMXHQIAXOOASZ-UHFFFAOYSA-N tetramethylammonium Chemical compound C[N+](C)(C)C QEMXHQIAXOOASZ-UHFFFAOYSA-N 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- YFTHZRPMJXBUME-UHFFFAOYSA-N tripropylamine Chemical class CCCN(CCC)CCC YFTHZRPMJXBUME-UHFFFAOYSA-N 0.000 description 1
- 238000001665 trituration Methods 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 230000017260 vegetative to reproductive phase transition of meristem Effects 0.000 description 1
- 230000003442 weekly effect Effects 0.000 description 1
- 230000004580 weight loss Effects 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D521/00—Heterocyclic compounds containing unspecified hetero rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >NâCOâN< or >NâCSâN<
- A01N47/36—Ureas or thioureas containing the groups >NâCOâN< or >NâCSâN< containing the group >NâCOâN< directly attached to at least one heterocyclic ring; Thio analogues thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Plural Heterocyclic Compounds (AREA)
Description
æ¬çºæã¯é€èããã³çé·æå¶ç¹æ§ãæããæ°èŠ
ãªïŒ®âã¢ãžãããšãã«ã¹ã«ããã«âNâ²âããªã
ãžãã«âããã³âNâ²âããªã¢ãžãã«å°¿çŽ ããã®
補æ³ãããããå«ãçµæç©ãããã³éèãæçšæ€
ç©ã®æ œå¹äžã«ãããŠç¹ã«éžæçã«é²é€ãããã
ã®ããŸãã¯æ€ç©çé·ãæå¶ãŸãã¯é²æ¢ããããã®
ãããã®äœ¿çšæ¹æ³ã«é¢ãããã®ã§ããã æ¬çºæã®ïŒ®âã¢ãžãããšãã«ã¹ã«ããã«â
Nâ²âããªããžãã«âããã³âNâ²âããªã¢ãžãã«
å°¿çŽ äžŠã³ã«ãã®å¡©ã¯äžè¬åŒïŒ
ãªïŒ®âã¢ãžãããšãã«ã¹ã«ããã«âNâ²âããªã
ãžãã«âããã³âNâ²âããªã¢ãžãã«å°¿çŽ ããã®
補æ³ãããããå«ãçµæç©ãããã³éèãæçšæ€
ç©ã®æ œå¹äžã«ãããŠç¹ã«éžæçã«é²é€ãããã
ã®ããŸãã¯æ€ç©çé·ãæå¶ãŸãã¯é²æ¢ããããã®
ãããã®äœ¿çšæ¹æ³ã«é¢ãããã®ã§ããã æ¬çºæã®ïŒ®âã¢ãžãããšãã«ã¹ã«ããã«â
Nâ²âããªããžãã«âããã³âNâ²âããªã¢ãžãã«
å°¿çŽ äžŠã³ã«ãã®å¡©ã¯äžè¬åŒïŒ
ãåã
ãåŒäžã
ã¯çªçŽ ååãŸãã¯ã¡ãã³æ©ãè¡šããã
R1ã¯æ°ŽçŽ ååãããã²ã³ååããããåºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒâNR4R5ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šãããã
ã§è¡šããããã é€èå€ãšããŠæå¹ãªå°¿çŽ ãããªã¢ãžã³ããã³ã
ãªããžã³ã¯åŸæ¥æè¡ã«ãããŠäžè¬çã«ç¥ãããŠã
ããé€èããã³æ€ç©çé·æå¶äœçšãæããã¢ãªãŒ
ã«ã¹ã«ãã¢ã¢ã€ã«âè€çŽ ç°åŒã¢ããã«ã«ãã¢ã€ã«
ååç©ã¯æè¿äŸãã°ãšãŒãããç¹èš±é¡ç¬¬1515å·äž
ã«èšèŒãããŠããã äžèšã®å®çŸ©ã«ãããŠãã¢ã«ãã«åºã¯çŽéãŸãã¯
åå²éã¢ã«ãã«åºäŸãã°ã¡ãã«åºããšãã«åºãïœ
âãããã«åºãã€ãœãããã«åºããŸãã¯ããã«åº
ã®ïŒã€ã®ç°æ§äœãè¡šããã ã¢ã«ã³ãã·åºã¯ã¡ããã·åºããšããã·åºãïœâ
ããããã·åºãã€ãœããããã·åºããã³ãããã·
åºã®ïŒã€ã®ç°æ§äœãè¡šãããã¡ããã·åºããšãã
ã·åºãŸãã¯ã€ãœããããã·åºãšããã®ã奜ãŸã
ãã ã¢ã«ãã«ããªåºã¯äŸãã°ã¡ãã«ããªåºããšãã«
ããªåºãïœâãããã«ããªåºãã€ãœãããã«ããª
åºããã³ïœâããã«ããªåºãè¡šãããã¡ãã«ããª
åºããã³ãšãã«ããªåºãšããã®ã奜ãŸããã ã¢ã«ãã«ã¹ã«ãã€ãã«åºã¯äŸãã°ã¡ãã«ã¹ã«ã
ã€ãã«åºããšãã«ã¹ã«ãã€ãã«åºãïœâãããã«
ã¹ã«ãã€ãã«åºããã³ïœâããã«ã¹ã«ãã€ãã«åº
ãè¡šããã奜ãŸãããã®ãšããŠã¯ã¡ãã«ã¹ã«ãã€
ãã«åºããã³ãšãã«ã¹ã«ãã€ãã«åºãæããã
ãã ã¢ã«ãã«ã¹ã«ããã«åºã¯äŸãã°ã¡ãã«ã¹ã«ãã
ã«åºããšãã«ã¹ã«ããã«åºãŸãã¯ïœâãããã«ã¹
ã«ããã«åºãè¡šããã奜ãŸãããã®ãšããŠã¯ã¡ã
ã«ã¹ã«ããã«åºããã³ãšãã«ã¹ã«ããã«åºãæã
ãããã äžèšå®çŸ©ã«ãããããŸãåæ§ã«ããã¢ã«ãã«åº
ããã³ããã¢ã«ã³ãã·åºã®éšåãšããŠã®ããã²ã³
ååã¯åŒçŽ ååãå¡©çŽ ååããã³èçŽ ååãè¡šã
ããåŒçŽ ååããã³å¡©çŽ ååãšããã®ã奜ãŸã
ãã åŸã€ãŠãäžèšå®çŸ©ã«ããã眮æåºã®ããã¢ã«ã
ã«åºãŸãã¯ããã¢ã«ãã«éšåã¯ä»¥äžã®åºãããªã
ãšããŠç解ãããïŒã¯ããã¡ãã«åºããã«ãªãã¡
ãã«åºããžãã«ãªãã¡ãã«åºãããªãã«ãªãã¡ã
ã«åºãïŒâã¯ãããšãã«åºãïŒïŒïŒïŒïŒâããªã
ã«ãªããšãã«åºãïŒïŒïŒïŒïŒïŒïŒâããã©ãã«ãª
ããšãã«åºããã³ã¿ãã«ãªããšãã«åºãïŒïŒïŒïŒ
ïŒâããªãã«ãªãâïŒâã¯ãããšãã«åºãïŒïŒ
ïŒïŒïŒâããªãã«ãªãâïŒïŒïŒâãžã¯ãããšãã«
åºããã³ã¿ã¯ãããšãã«åºãïŒïŒïŒïŒïŒâããªã
ã«ãªããããã«åºãïŒïŒïŒâãžã¯ãããããã«
åºãïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâãããµãã«ãªãã
ããã«åºã奜ãŸãããã®ãšããŠã¯ãã«ãªãã¡ãã«
åºãã¯ããã¡ãã«åºããžãã«ãªãã¡ãã«åºããã³
ããªãã«ãªãã¡ãã«åºãæããããã æ¬çºæã¯ãŸããåŒã§è¡šããããååç©ãã¢ã
ã³ãã¢ã«ã«ãªéå±å¡©åºããã³ã¢ã«ã«ãªåé¡éå±å¡©
åºãŸãã¯ç¬¬ïŒã¢ã³ã¢ããŠã å¡©åºãšåœ¢æããããšã®
ã§ããå¡©ã«é¢ãããã®ã§ããã å¡©ã圢æãã奜ãŸããã¢ã«ã«ãªéå±æ°Žé žåç©ã
ãã³ã¢ã«ã«ãªåé¡éå±æ°Žé žåç©ã¯ãªããŠã ããã
ãªãŠã ãã«ãªãŠã ããã°ãã·ãŠã ãŸãã¯ã«ã«ã·ãŠ
ã ã®æ°Žé žåç©ãæã奜ãŸããã¯ãããªãŠã ãŸãã¯
ã«ãªãŠã ã®æ°Žé žåç©ã§ããã é©ããå¡©ã圢æããã¢ãã³ã®äŸãšããŠã¯ç¬¬äžã
第äºããã³ç¬¬äžèèªæããã³è³éŠæã¢ãã³äŸãã°
ã¡ãã«ã¢ãã³ããšãã«ã¢ãã³ããããã«ã¢ãã³ã
ã€ãœãããã«ã¢ãã³ãããã«ã¢ãã³ã®ïŒã€ã®ç°æ§
äœããžã¡ãã«ã¢ãã³ããžãšãã«ã¢ãã³ããžãšã¿ã
ãŒã«ã¢ãã³ããžãããã«ã¢ãã³ããžã€ãœãããã«
ã¢ãã³ããžâïœâããã«ã¢ãã³ããããªãžã³ãã
ããªãžã³ãã¢ã«ããªã³ãããªã¡ãã«ã¢ãã³ãããª
ãšãã«ã¢ãã³ãããªãããã«ã¢ãã³ãããã¯ãªãž
ã³ãããªãžã³ããããªã³ããã³ã€ãœãããªã³ãæ
ããããã奜ãŸããã¢ãã³ã¯ãšãã«ã¢ãã³ããã
ãã«ã¢ãã³ããžãšãã«ã¢ãã³ãŸãã¯ããªãšãã«ã¢
ãã³ã§ãããã€ãœãããã«ã¢ãã³ããã³ãžãšã¿ã
ãŒã«ã¢ãã³ãçšããã®ãæã奜ãŸããã 第åã¢ã³ã¢ããŠã å¡©åºã®äŸãšããŠã¯ãäžè¬ã«ã
ãã¢ã³ã¢ããŠã å¡©ã®éœã€ãªã³äŸãã°ããã©ã¡ãã«
ã¢ã³ã¢ããŠã éœã€ãªã³ãããªã¡ãã«ãã³ãžã«ã¢ã³
ã¢ããŠã éœã€ãªã³ãããªãšãã«ãã³ãžã³ã¢ã³ã¢ã
ãŠã éœã€ãªã³ãããã©ãšãã«ã¢ã³ã¢ããŠã éœã€ãª
ã³ãããªã¡ãã«ãšãã«ã¢ã³ã¢ããŠã éœã€ãªã³ãã
ããŠãŸãã¢ã³ã¢ããŠã éœã€ãªã³ãæããããã åŒã§è¡šããããååç©ã®å 奜ãŸãããã®ãšã
ãŠã¯ã ïœ ã¢ãžãåºãã¹ã«ããã«åºã«å¯ŸããŠïŒâäœã«ã
ããã ãŸãã¯ ïœ R1ãæ°ŽçŽ ååãè¡šãããã ãŸãã¯ ïœ R2ããã³R3ãå ±ã«ççŽ ååïŒåããå€ãã
å«ãŸãªããã ãŸãã¯ ïœ R2ããã³R3ãã¡ãã«åºãã¡ããã·åºããžã¡
ãã«ã¢ããåºããžãã«ãªãã¡ããã·åºããã³
ïŒïŒïŒïŒïŒâããªãã«ãªããšããã·åºãããªã
矀ããéžæããããã ãŸãã¯ ïœ R1ãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã«
ã«ããã«åºãè¡šãããã®ãæããããã åŒã§è¡šããããååç©ã®æŽã«å¥œãŸããå¯çŸ€
ã¯ãR1ãã¹ã«ããã«åºã«å¯ŸããŠïŒâäœã«ããç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã«ã«ããã«åºã
è¡šããããããŠR2ããã³R3ãã¡ãã«åºãã¡ãã
ã·åºããŸãã«ãªãã¡ããã·åºããžã¡ãã«ã¢ããåº
ããã³ïŒïŒïŒïŒïŒâããªãã«ãªããšããã·åºãã
ãªã矀ããéžæããããããŠå ±ã«ççŽ ååïŒåã
ãå€ããå«ãŸãªãååç©ãããªãã ãã®çŸ€ã«å±ãã奜ãŸããååç©ã¯åŒã«ãããŠ
R2ããã³R3ãã¡ãã«åºãã¡ããã·åºãŸãã¯ãžã
ã«ãªãã¡ããã·åºãè¡šããååç©ã§ããã 奜ãŸããåã ã®ååç©ã¯ïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«âïŒïŒïŒïŒïŒâããª
ã¢ãžã³âïŒâã€ã«ïŒå°¿çŽ ã âïŒïŒâã¡ããã·ã«ã«ããã«âïŒâã¢ãžãã
ãšãã«ã¹ã«ããã«âNâ²âïŒïŒâãžãã«ãªãã¡ãã
ã·âïŒâã¡ãã«ããªããžã³âïŒâã€ã«ïŒå°¿çŽ ã âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããžã³âïŒâã€
ã«ïŒå°¿çŽ ã§ããã åŒã§è¡šããããååç©ã®è£œé æ¹æ³ã¯éåžžäžæŽ»
æ§æº¶åªäžã§è¡ãã åŒã§è¡šããããååç©ã®ç¬¬äžã®è£œé æ¹æ³ã¯ã
次åŒïŒ
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒâNR4R5ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šãããã
ã§è¡šããããã é€èå€ãšããŠæå¹ãªå°¿çŽ ãããªã¢ãžã³ããã³ã
ãªããžã³ã¯åŸæ¥æè¡ã«ãããŠäžè¬çã«ç¥ãããŠã
ããé€èããã³æ€ç©çé·æå¶äœçšãæããã¢ãªãŒ
ã«ã¹ã«ãã¢ã¢ã€ã«âè€çŽ ç°åŒã¢ããã«ã«ãã¢ã€ã«
ååç©ã¯æè¿äŸãã°ãšãŒãããç¹èš±é¡ç¬¬1515å·äž
ã«èšèŒãããŠããã äžèšã®å®çŸ©ã«ãããŠãã¢ã«ãã«åºã¯çŽéãŸãã¯
åå²éã¢ã«ãã«åºäŸãã°ã¡ãã«åºããšãã«åºãïœ
âãããã«åºãã€ãœãããã«åºããŸãã¯ããã«åº
ã®ïŒã€ã®ç°æ§äœãè¡šããã ã¢ã«ã³ãã·åºã¯ã¡ããã·åºããšããã·åºãïœâ
ããããã·åºãã€ãœããããã·åºããã³ãããã·
åºã®ïŒã€ã®ç°æ§äœãè¡šãããã¡ããã·åºããšãã
ã·åºãŸãã¯ã€ãœããããã·åºãšããã®ã奜ãŸã
ãã ã¢ã«ãã«ããªåºã¯äŸãã°ã¡ãã«ããªåºããšãã«
ããªåºãïœâãããã«ããªåºãã€ãœãããã«ããª
åºããã³ïœâããã«ããªåºãè¡šãããã¡ãã«ããª
åºããã³ãšãã«ããªåºãšããã®ã奜ãŸããã ã¢ã«ãã«ã¹ã«ãã€ãã«åºã¯äŸãã°ã¡ãã«ã¹ã«ã
ã€ãã«åºããšãã«ã¹ã«ãã€ãã«åºãïœâãããã«
ã¹ã«ãã€ãã«åºããã³ïœâããã«ã¹ã«ãã€ãã«åº
ãè¡šããã奜ãŸãããã®ãšããŠã¯ã¡ãã«ã¹ã«ãã€
ãã«åºããã³ãšãã«ã¹ã«ãã€ãã«åºãæããã
ãã ã¢ã«ãã«ã¹ã«ããã«åºã¯äŸãã°ã¡ãã«ã¹ã«ãã
ã«åºããšãã«ã¹ã«ããã«åºãŸãã¯ïœâãããã«ã¹
ã«ããã«åºãè¡šããã奜ãŸãããã®ãšããŠã¯ã¡ã
ã«ã¹ã«ããã«åºããã³ãšãã«ã¹ã«ããã«åºãæã
ãããã äžèšå®çŸ©ã«ãããããŸãåæ§ã«ããã¢ã«ãã«åº
ããã³ããã¢ã«ã³ãã·åºã®éšåãšããŠã®ããã²ã³
ååã¯åŒçŽ ååãå¡©çŽ ååããã³èçŽ ååãè¡šã
ããåŒçŽ ååããã³å¡©çŽ ååãšããã®ã奜ãŸã
ãã åŸã€ãŠãäžèšå®çŸ©ã«ããã眮æåºã®ããã¢ã«ã
ã«åºãŸãã¯ããã¢ã«ãã«éšåã¯ä»¥äžã®åºãããªã
ãšããŠç解ãããïŒã¯ããã¡ãã«åºããã«ãªãã¡
ãã«åºããžãã«ãªãã¡ãã«åºãããªãã«ãªãã¡ã
ã«åºãïŒâã¯ãããšãã«åºãïŒïŒïŒïŒïŒâããªã
ã«ãªããšãã«åºãïŒïŒïŒïŒïŒïŒïŒâããã©ãã«ãª
ããšãã«åºããã³ã¿ãã«ãªããšãã«åºãïŒïŒïŒïŒ
ïŒâããªãã«ãªãâïŒâã¯ãããšãã«åºãïŒïŒ
ïŒïŒïŒâããªãã«ãªãâïŒïŒïŒâãžã¯ãããšãã«
åºããã³ã¿ã¯ãããšãã«åºãïŒïŒïŒïŒïŒâããªã
ã«ãªããããã«åºãïŒïŒïŒâãžã¯ãããããã«
åºãïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒïŒâãããµãã«ãªãã
ããã«åºã奜ãŸãããã®ãšããŠã¯ãã«ãªãã¡ãã«
åºãã¯ããã¡ãã«åºããžãã«ãªãã¡ãã«åºããã³
ããªãã«ãªãã¡ãã«åºãæããããã æ¬çºæã¯ãŸããåŒã§è¡šããããååç©ãã¢ã
ã³ãã¢ã«ã«ãªéå±å¡©åºããã³ã¢ã«ã«ãªåé¡éå±å¡©
åºãŸãã¯ç¬¬ïŒã¢ã³ã¢ããŠã å¡©åºãšåœ¢æããããšã®
ã§ããå¡©ã«é¢ãããã®ã§ããã å¡©ã圢æãã奜ãŸããã¢ã«ã«ãªéå±æ°Žé žåç©ã
ãã³ã¢ã«ã«ãªåé¡éå±æ°Žé žåç©ã¯ãªããŠã ããã
ãªãŠã ãã«ãªãŠã ããã°ãã·ãŠã ãŸãã¯ã«ã«ã·ãŠ
ã ã®æ°Žé žåç©ãæã奜ãŸããã¯ãããªãŠã ãŸãã¯
ã«ãªãŠã ã®æ°Žé žåç©ã§ããã é©ããå¡©ã圢æããã¢ãã³ã®äŸãšããŠã¯ç¬¬äžã
第äºããã³ç¬¬äžèèªæããã³è³éŠæã¢ãã³äŸãã°
ã¡ãã«ã¢ãã³ããšãã«ã¢ãã³ããããã«ã¢ãã³ã
ã€ãœãããã«ã¢ãã³ãããã«ã¢ãã³ã®ïŒã€ã®ç°æ§
äœããžã¡ãã«ã¢ãã³ããžãšãã«ã¢ãã³ããžãšã¿ã
ãŒã«ã¢ãã³ããžãããã«ã¢ãã³ããžã€ãœãããã«
ã¢ãã³ããžâïœâããã«ã¢ãã³ããããªãžã³ãã
ããªãžã³ãã¢ã«ããªã³ãããªã¡ãã«ã¢ãã³ãããª
ãšãã«ã¢ãã³ãããªãããã«ã¢ãã³ãããã¯ãªãž
ã³ãããªãžã³ããããªã³ããã³ã€ãœãããªã³ãæ
ããããã奜ãŸããã¢ãã³ã¯ãšãã«ã¢ãã³ããã
ãã«ã¢ãã³ããžãšãã«ã¢ãã³ãŸãã¯ããªãšãã«ã¢
ãã³ã§ãããã€ãœãããã«ã¢ãã³ããã³ãžãšã¿ã
ãŒã«ã¢ãã³ãçšããã®ãæã奜ãŸããã 第åã¢ã³ã¢ããŠã å¡©åºã®äŸãšããŠã¯ãäžè¬ã«ã
ãã¢ã³ã¢ããŠã å¡©ã®éœã€ãªã³äŸãã°ããã©ã¡ãã«
ã¢ã³ã¢ããŠã éœã€ãªã³ãããªã¡ãã«ãã³ãžã«ã¢ã³
ã¢ããŠã éœã€ãªã³ãããªãšãã«ãã³ãžã³ã¢ã³ã¢ã
ãŠã éœã€ãªã³ãããã©ãšãã«ã¢ã³ã¢ããŠã éœã€ãª
ã³ãããªã¡ãã«ãšãã«ã¢ã³ã¢ããŠã éœã€ãªã³ãã
ããŠãŸãã¢ã³ã¢ããŠã éœã€ãªã³ãæããããã åŒã§è¡šããããååç©ã®å 奜ãŸãããã®ãšã
ãŠã¯ã ïœ ã¢ãžãåºãã¹ã«ããã«åºã«å¯ŸããŠïŒâäœã«ã
ããã ãŸãã¯ ïœ R1ãæ°ŽçŽ ååãè¡šãããã ãŸãã¯ ïœ R2ããã³R3ãå ±ã«ççŽ ååïŒåããå€ãã
å«ãŸãªããã ãŸãã¯ ïœ R2ããã³R3ãã¡ãã«åºãã¡ããã·åºããžã¡
ãã«ã¢ããåºããžãã«ãªãã¡ããã·åºããã³
ïŒïŒïŒïŒïŒâããªãã«ãªããšããã·åºãããªã
矀ããéžæããããã ãŸãã¯ ïœ R1ãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã«
ã«ããã«åºãè¡šãããã®ãæããããã åŒã§è¡šããããååç©ã®æŽã«å¥œãŸããå¯çŸ€
ã¯ãR1ãã¹ã«ããã«åºã«å¯ŸããŠïŒâäœã«ããç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã«ã«ããã«åºã
è¡šããããããŠR2ããã³R3ãã¡ãã«åºãã¡ãã
ã·åºããŸãã«ãªãã¡ããã·åºããžã¡ãã«ã¢ããåº
ããã³ïŒïŒïŒïŒïŒâããªãã«ãªããšããã·åºãã
ãªã矀ããéžæããããããŠå ±ã«ççŽ ååïŒåã
ãå€ããå«ãŸãªãååç©ãããªãã ãã®çŸ€ã«å±ãã奜ãŸããååç©ã¯åŒã«ãããŠ
R2ããã³R3ãã¡ãã«åºãã¡ããã·åºãŸãã¯ãžã
ã«ãªãã¡ããã·åºãè¡šããååç©ã§ããã 奜ãŸããåã ã®ååç©ã¯ïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«âïŒïŒïŒïŒïŒâããª
ã¢ãžã³âïŒâã€ã«ïŒå°¿çŽ ã âïŒïŒâã¡ããã·ã«ã«ããã«âïŒâã¢ãžãã
ãšãã«ã¹ã«ããã«âNâ²âïŒïŒâãžãã«ãªãã¡ãã
ã·âïŒâã¡ãã«ããªããžã³âïŒâã€ã«ïŒå°¿çŽ ã âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããžã³âïŒâã€
ã«ïŒå°¿çŽ ã§ããã åŒã§è¡šããããååç©ã®è£œé æ¹æ³ã¯éåžžäžæŽ»
æ§æº¶åªäžã§è¡ãã åŒã§è¡šããããååç©ã®ç¬¬äžã®è£œé æ¹æ³ã¯ã
次åŒïŒ
ãåã
ãåŒäžãR1ã¯åŒã«ãããŠå®çŸ©ããããã®ãš
åãæå³ãè¡šããããã§è¡šããããã¢ãžãããšã
ã«ã¹ã«ãã³ã¢ãããšæ¬¡åŒïŒ
åãæå³ãè¡šããããã§è¡šããããã¢ãžãããšã
ã«ã¹ã«ãã³ã¢ãããšæ¬¡åŒïŒ
ãåŒã
ãåŒäžãïŒR2ããã³R3ã¯åŒã«ãããŠå®çŸ©ã
ãããã®ãšåãæå³ãè¡šããããããŠïŒ²ã¯ããšã
ã«åºãã¢ã«ãã«åºãŸãã¯çœ®æãããšãã«åºãè¡šã
ãããã§è¡šããããâããªããžãã«âãŸãã¯ïŒ®
âããªã¢ãžãã«ã«ã«ãã¡ãŒããå¡©åºã®ååšäžã§å
å¿ãããããšãããªãã åŒã§è¡šããããååç©ãåŸã第äºã®æ¹æ³ã¯æ¬¡
åŒïŒ
ãããã®ãšåãæå³ãè¡šããããããŠïŒ²ã¯ããšã
ã«åºãã¢ã«ãã«åºãŸãã¯çœ®æãããšãã«åºãè¡šã
ãããã§è¡šããããâããªããžãã«âãŸãã¯ïŒ®
âããªã¢ãžãã«ã«ã«ãã¡ãŒããå¡©åºã®ååšäžã§å
å¿ãããããšãããªãã åŒã§è¡šããããååç©ãåŸã第äºã®æ¹æ³ã¯æ¬¡
åŒïŒ
ãåã
ãåŒäžãR1ã¯åŒã«ãããŠå®çŸ©ããããã®ãš
åãæå³ãè¡šããããã§è¡šããããã¢ãžãããšã
ã«ã¹ã«ããã«ã€ãœã·ã¢ããŒãã次åŒïŒ
åãæå³ãè¡šããããã§è¡šããããã¢ãžãããšã
ã«ã¹ã«ããã«ã€ãœã·ã¢ããŒãã次åŒïŒ
ãåŒã
ãåŒäžãR2ããã³R3ã¯åŒã«ãããŠå®çŸ©ãã
ããã®ãšåãæå³ãè¡šããããã§è¡šããããã¢ã
ã³ãšãææã§ããã°å¡©åºã®ååšäžã§åå¿ãããã
ãšãããªãã åŒã§è¡šããããååç©ã¯æ¬¡åŒïŒ
ããã®ãšåãæå³ãè¡šããããã§è¡šããããã¢ã
ã³ãšãææã§ããã°å¡©åºã®ååšäžã§åå¿ãããã
ãšãããªãã åŒã§è¡šããããååç©ã¯æ¬¡åŒïŒ
ãåã
ãåŒäžãR1ã¯åŒã«ãããŠå®çŸ©ããããã®ãš
åãæå³ãè¡šãããã¯ããšãã«åºãã¢ã«ãã«åº
ãŸãã¯çœ®æããšãã«åºãè¡šããããã§è¡šãããã
âã¢ãžãããšãã«ã¹ã«ããã«ã«ã«ãã¡ãŒããäž
èšã®åŒã§è¡šããããã¢ãã³ãšåå¿ãããããšã«
ãã€ãŠããŸãåŸãããšãã§ããã æåŸã«ãåŒã§è¡šããããååç©ã¯æ¬¡åŒïŒ
åãæå³ãè¡šãããã¯ããšãã«åºãã¢ã«ãã«åº
ãŸãã¯çœ®æããšãã«åºãè¡šããããã§è¡šãããã
âã¢ãžãããšãã«ã¹ã«ããã«ã«ã«ãã¡ãŒããäž
èšã®åŒã§è¡šããããã¢ãã³ãšåå¿ãããããšã«
ãã€ãŠããŸãåŸãããšãã§ããã æåŸã«ãåŒã§è¡šããããååç©ã¯æ¬¡åŒïŒ
ãåã
ãåŒäžãïŒR1ïŒR2ããã³R3ã¯åŒã«ãããŠå®
矩ããããã®ãšåãæå³ãè¡šããããã§è¡šããã
ãã¢ããã¹ã«ããã«å°¿çŽ ããžã¢ãŸåããŠå ¬ç¥æ¹æ³
ã«ããã¢ãžãåºãå°å ¥ããããšã«ãã€ãŠããŸãåŸ
ãããã ææã§ããã°ãåŒã§è¡šããããå°¿çŽ ãã¢ã
ã³ãã¢ã«ã«ãªéå±æ°Žé žåç©ãŸãã¯ã¢ã«ã«ãªåé¡é
å±æ°Žé žåç©ãŸãã¯ç¬¬åã¢ã³ã¢ããŠã å¡©åºã«ããä»
å å¡©ã«å€ããããšãã§ããããã®å€æã¯äŸãã°åŒ
ã§è¡šããããååç©ãåœã¢ã«éã®å¡©åºãšåå¿ã
ãã次ãã§èžçºã«ãã溶åªãé€ãããšã«ããè¡ã
ããã åŒïŒããã³ã§è¡šããããåºçºååç©ã¯å ¬
ç¥ããŸãã¯å ¬ç¥æ¹æ³ã«ãã補é ããããšãã§ã
ãã åŒã§è¡šããããæ°èŠãªãã«ãªãã¢ã«ã³ãã·ã¢
ããããªããžã³ããã³ãã«ãªãã¢ã«ã³ãã·ã¢ãã
ããªã¢ãžã³ããã³è©²ååç©ã®è£œé æ¹æ³ããã³åŒ
ã§è¡šããããååç©ã®è£œé æ¹æ³ã¯ãšãŒãããç¹èš±
é¡ç¬¬70804å·ã«èšèŒãããŠããã åŒããã³åŒã§è¡šããããæ°èŠãªååç©ã¯åŒ
ã§è¡šããããã¢ãžãããšãã«ã¹ã«ãã³ã¢ããã
ãå ¬ç¥æ¹æ³ã«ãã€ãŠè£œé ãããããã®ååç©ã¯åŒ
ã§è¡šããããååç©ã®åæã®ããã«ç¹ã«éçºã
ãããã®ã§ãããããæ æ¬çºæã®ç®çããªããŠã
ãã åŒã§è¡šããããã¢ãžãããšãã«ã¹ã«ãã³ã¢ã
ãã®ããã€ãã¯å ¬ç¥ã§ãããããã«ã€ããŠã¯ã
Monatshefte der ChemieïŒ81ïŒ970ã980ïŒ1950ïŒ
ãåç §ãã åŒã§è¡šããããæ°èŠãªã¢ãžãããšãã«ã¹ã«ã
ã³ã¢ãã䞊ã³ã«åŒããã³åŒã§è¡šããããäžé
äœã¯åŒã§è¡šããããååç©ã®åæã®ããã«ç¹ã«
éçºããããã®ã§ããããããŠãŸãæ¬çºæã®ä»ã®
ç®çããªããŠãããæ°èŠãªã¢ãžãããšãã«ã¹ã«ã
ã³ã¢ããã¯äžè¬åŒïœïŒ
矩ããããã®ãšåãæå³ãè¡šããããã§è¡šããã
ãã¢ããã¹ã«ããã«å°¿çŽ ããžã¢ãŸåããŠå ¬ç¥æ¹æ³
ã«ããã¢ãžãåºãå°å ¥ããããšã«ãã€ãŠããŸãåŸ
ãããã ææã§ããã°ãåŒã§è¡šããããå°¿çŽ ãã¢ã
ã³ãã¢ã«ã«ãªéå±æ°Žé žåç©ãŸãã¯ã¢ã«ã«ãªåé¡é
å±æ°Žé žåç©ãŸãã¯ç¬¬åã¢ã³ã¢ããŠã å¡©åºã«ããä»
å å¡©ã«å€ããããšãã§ããããã®å€æã¯äŸãã°åŒ
ã§è¡šããããååç©ãåœã¢ã«éã®å¡©åºãšåå¿ã
ãã次ãã§èžçºã«ãã溶åªãé€ãããšã«ããè¡ã
ããã åŒïŒããã³ã§è¡šããããåºçºååç©ã¯å ¬
ç¥ããŸãã¯å ¬ç¥æ¹æ³ã«ãã補é ããããšãã§ã
ãã åŒã§è¡šããããæ°èŠãªãã«ãªãã¢ã«ã³ãã·ã¢
ããããªããžã³ããã³ãã«ãªãã¢ã«ã³ãã·ã¢ãã
ããªã¢ãžã³ããã³è©²ååç©ã®è£œé æ¹æ³ããã³åŒ
ã§è¡šããããååç©ã®è£œé æ¹æ³ã¯ãšãŒãããç¹èš±
é¡ç¬¬70804å·ã«èšèŒãããŠããã åŒããã³åŒã§è¡šããããæ°èŠãªååç©ã¯åŒ
ã§è¡šããããã¢ãžãããšãã«ã¹ã«ãã³ã¢ããã
ãå ¬ç¥æ¹æ³ã«ãã€ãŠè£œé ãããããã®ååç©ã¯åŒ
ã§è¡šããããååç©ã®åæã®ããã«ç¹ã«éçºã
ãããã®ã§ãããããæ æ¬çºæã®ç®çããªããŠã
ãã åŒã§è¡šããããã¢ãžãããšãã«ã¹ã«ãã³ã¢ã
ãã®ããã€ãã¯å ¬ç¥ã§ãããããã«ã€ããŠã¯ã
Monatshefte der ChemieïŒ81ïŒ970ã980ïŒ1950ïŒ
ãåç §ãã åŒã§è¡šããããæ°èŠãªã¢ãžãããšãã«ã¹ã«ã
ã³ã¢ãã䞊ã³ã«åŒããã³åŒã§è¡šããããäžé
äœã¯åŒã§è¡šããããååç©ã®åæã®ããã«ç¹ã«
éçºããããã®ã§ããããããŠãŸãæ¬çºæã®ä»ã®
ç®çããªããŠãããæ°èŠãªã¢ãžãããšãã«ã¹ã«ã
ã³ã¢ããã¯äžè¬åŒïœïŒ
ãåã
ãåŒäžãR1ã¯åŒã«ãããŠå®çŸ©ããããã®ãš
åãæå³ãè¡šããããã§è¡šããããã åŒïœã§è¡šããããååç©ã¯éåžžå ¬ç¥æ¹æ³äŸã
ã°éå±ãšé žã®çµåãã«ãã觊åªçéå ãã¢ãã«ã¬
ã ãšã¢ã«ã³ãŒã«æ°Žæº¶æ¶²ã«ããéå ãŸãã¯ã¢ã«ã«ãª
éå±ã¹ã«ãã€ãã«ããéå ã«ãã€ãŠå¯Ÿå¿ãããã
ãããšãã«ã¹ã«ãã³ã¢ãããã¢ããååç©ã«éå
ãã次ãã§å ¬ç¥æ¹æ³ã«ããã¢ããååç©ããžã¢ãŸ
åãããããŠåŸããããžã¢ãŸããŠã å¡©ãåŒïœã§
è¡šããããã¢ãžãååç©ãå€ããããšã«ããåŸã
ããã åæ§ãªæ¹æ³ã¯äŸãã°Monatshefte der
ChemieïŒ81ïŒ970ã980ïŒ1950ïŒãŸãã¯Houbenâ
WeylãMethoden der organischenïŒChemieïŒ
4th editionïŒVol.10ïŒ3.781ã836 äžã«èšèŒãã
ãŠããã åŒã§è¡šããããäžéäœã¯éå ã«ãã察å¿ãã
ãããããšãã«ã¹ã«ããã«å°¿çŽ ããåæ§ãªæ¹æ³ã«
ãã€ãŠåŸãããšãã§ããããã®ãããªãããããš
ãã«ã¹ã«ããã«å°¿çŽ ã¯å ¬ç¥ã§ããããŸãã¯å ¬ç¥æ¹
æ³ã«ããåŸãããã åŒã§è¡šããããååç©ãåŸãããã«ã¯äŸãã°
å¡©åã¡ãã¬ã³ãããã©ããããã©ã³ãã¢ã»ããã
ãªã«ããžãªããµã³ãŸãã¯ãã«ãšã³ã®ãããªäžæ§ã
äžæŽ»æ§ææ©æº¶åªäžã§ãããã®åå¿ãè¡ãã®ã䟿å©
ã§ããã åå¿æž©åºŠã¯â20°ãªããïŒ120âã®ç¯å²ã奜ãŸã
ããåå¿ã¯éåžžãããã«çºç±çã§ããããããŠå®€
æž©ã§è¡ãããšãã§ãããåå¿æéãççž®ãããã
ãã¯ãŸãåå¿ãéå§ããããã«ã¯åå¿æ··åç©ãç
æé沞ç¹ãŸã§å ç±ããã®ã奜éœåã§ããã觊åªãš
ããŠå¡©åºãŸãã¯ã€ãœã·ã¢ããŒããïŒïŒïŒæ»Žå ãã
ãšåå¿æéãççž®ããããšãã§ããã æçµçæç©ã¯ãåå¿æ··åç©ãæ¿çž®ãããããŠïŒ
ãŸãã¯èžçºã«ãã溶åªãé€å»ãããããŠåçµæ¶ãŸ
ãã¯æº¶è§£æ§ã®ä¹ãã溶åªäŸãã°ãšãŒãã«ãè³éŠæ
çåæ°ŽçŽ ãŸãã¯å¡©çŽ åçåæ°ŽçŽ äžã§åºäœæ®éšãã
ãã€ã¶ãããšã«ããåé¢ããããšãã§ããã åŒã§è¡šããããååç©ã¯å®å®ãªååç©ã§ã
ãããããŠãã®åæ±ãã«ãããŠã¯å šãé²è·æ段ã
å¿ èŠãšããªãã äœãæœçšæ¯çã§çšããå Žåã«ã¯ãåŒã§è¡šãã
ããååç©ã¯è¯å¥œãªéžæççé·æå¶ããã³éžæç
é€èç¹æ§ãæãããã®ããæçšæ€ç©ç¹ã«ããšãã
ã³ãç©é¡ãæ£ã倧è±ããšãããããããã³çš²ã®å
ç©«ã®ããã«ãããã䜿çšããã®ã奜ãŸããããã
ã€ãã®å Žåã«ãããŠã¯çŸåšç·åé€èå€ã«ãã€ãŠã®
ã¿é²é€ãããéèã«å¯ŸããŠããŸãæå·ãäžããã
ãšãã§ããã ãããã®ååç©ã®ããã€ãã®äœçšåœ¢æ ã¯éåžžã®
å Žåãšã¯ç°ãªããå€ãã¯è»¢æµå¯èœã§ãããããªã
ã¡ãããã¯æ€ç©ã«ãã€ãŠåžåããã次ãã§ããã
ãäœçšããä»ã®éšæã«ç§»åãããããæ äŸãã°è¡š
é¢åŠçã«ããå€å¹Žçéèã®æ ¹ã«æå·ãäžããããš
ãå¯èœã§ãããä»ã®é€èå€ããã³çé·æå¶å€ã«æ¯
ã¹ãŠãåŒã§è¡šããããæ°èŠãªååç©ã¯éåžžã«äœ
ãæœçšæ¯çã§çšããããå Žåã§ãå¹æãããã åŒã§è¡šããããååç©ã¯æ œå¹æ€ç©ãŸãã¯åç©«
äœç©ã®åç©«éãå¢å ãããããšãã§ããçé·èª¿ç¯
ç¹æ§ã瀺ããæŽã«ãåŒã§è¡šããããååç©ã®å€
ãã¯æ¿åºŠã«å¿ããŠçé·é²æ¢äœçšã瀺ããååèæ€
ç©ããã³ååèæ€ç©åæ¹ã®çé·ã劚ãããããã
ãæ äŸãã°åŒã§è¡šããããååç©ã¯ç±åž¯å°åã§
éäœãšããŠãã°ãã°æ œå¹ãããè±ç§æ€ç©ã®çé·ã
éžæçã«é²æ¢ããã®ã§ããã®çµæãæ œå¹æ€ç©ã®é
ã®åå£ã®æµžé£ãé²ãããéäœã¯æ œå¹æ€ç©ãšç«¶åã
ãããšãã§ããªãã å€ãã®æ œå¹æ€ç©ã®èäžçé·ãé²æ¢ãããããæ œ
å¹é¢ç©åœãããå€ãã®æ€ç©ãæçš®ããããšãã§
ãããã®çµæåäœé¢ç©åœãããå€ãã®åç©«éãåŸ
ãããšãã§ãããçé·èª¿ç¯å€ã䜿çšããå Žåã®å
ç©«éå¢å€§ã®ãã詳现ãªæ©æ§ãšããŠã¯ãèäžçé·ã
é²æ¢ãããããè±ãå²ãå®ããªãã®ãä¿é²ããã
ãã®æ é€åãå¢å ããããšãã§ããããã§ããã ååèæ€ç©äŸãã°ç§èãŸãã¯æ œå¹æ€ç©äŸãã°ç©
ç©ã®èäžçé·ã®é²æ¢ã¯ãã°ãã°ææã§ããããŠå¥œ
éœåã§ããããã®ãããªçé·ã®é²æ¢ã¯ãç¹ã«ç§è
ã«ãããŠã¯ãè±æ®µãå ¬åã競æå ŽãŸãã¯è·¯è©ã«ã
ããå蟌ã®é »åºŠãããã«ããæžå°ãããããšãã§
ããã®ã§çµæžçãªèå³ãããã è·¯è©ã®äžããã³å€æŽç·ã®è¿ããŸãã¯æŽã«äžè¬ç
ã«ã¯åŒ·ãçé·ãæãŸãããªãåºåã®äžã§ã®èãã
ã³æšã®çé·ã®é²æ¢ããŸãéèŠã§ããã ç©ç©ã®äžã®çé·ãé²æ¢ããããã®çé·èª¿ç¯å€ã®
䜿çšããŸããèãæžå°ãããŠçå°åãåç©«åã®å
害ã®å±éºãå®å šã«é€ãããã«éèŠã§ãããæŽã«ã
çé·èª¿ç¯å€ã¯ãç©ç©ã®èã匷åãããããŠå害ã
é²æ¢ããããšãã§ããã æŽã«åŒã§è¡šããããååç©ã¯è²¯èµããããã
ã®çºèœãé²ãã®ã«é©ããŠãããå¬æã®è²¯èµã®éã
ãããããã¯ãã°ãã°çºèœãããã®çµæçž®å°ãé
éæ倱ããã³è æãèµ·ãã é«æ¯çã§æœçšããå Žåã«ã¯ãç·ãŠã®è©Šéšæ€ç©ã
ãã®çé·ã«å€§ããªæå·ãåããŠæ¯ããã æ¬çºæã¯ãŸãåŒã§è¡šããããæ°èŠååç©ãå«
ãé€èããã³çé·æå¶å€çµæç©ã䞊ã³ã«çºèœåã
ãã³çºèœåŸã®éèã®é²é€ãããã³ååèæ€ç©ãã
ã³ååèæ€ç©ç¹ã«ç§èãç±åž¯éäœããã³ç èæ€ç©
ã®åžæã®çé·é²æ¢ã®æ¹æ³ã«ããŸãé¢ãããã®ã§ã
ãã åŒã®ååç©ã¯ãã®ãŸãŸã®åœ¢æ ã§ãæãã¯å¥œãŸ
ããã¯è£œå€æ¥çã§æ £çšã®è£å©å€ãšå ±ã«äœ¿çšããã
å ¬ç¥ã®æ¹æ³ã«ããä¹³å€å液ã被èŠæ§ããŒã¹ã
ïŒcoatable pasteïŒãçŽæ¥åŽé§å¯èœãªãŸãã¯åžéå¯
èœãªæº¶æ¶²ãåžéä¹³å€ãæ°Žåå€ã氎溶å€ãç²å€ãç²
å€ãããã³äŸãã°ããªããŒç©è³ªã«ããã«ãã»ã«å
å€ã«è£œå€åããããçµæç©ã®æ§è³ªãšåæ§ãåŽé§ã
é§åãæ£ç²ãæ£æ°ŽãŸãã¯æ³šæ°Žã®ãããªé©çšæ³ã¯ã
ç®çãšãã察象ããã³äœ¿çšç°å¢ã«äŸåããŠéžã°ã
ãã 補æãå³ã¡åŒã®ååç©ïŒæå¹æåïŒããã³é©
åœãªå Žåã«ã¯åºäœãŸãã¯æ¶²äœã®è£å©å€ãå«ãçµæ
ç©ãŸãã¯è£œå€ã¯ãå ¬ç¥ã®æ¹æ³ã«ãããäŸãã°æå¹
æåã溶åªãåºäœæ äœããã³é©åœãªå Žåã«ã¯è¡šé¢
掻æ§ååç©ïŒçé¢æŽ»æ§å€ïŒã®ãããªå¢éå€ãšåäž
ã«æ··åããã³ïŒãŸãã¯æ©ç ããããšã«ããã補é
ãããã é©åœãªæº¶åªã¯æ¬¡ã®ãã®ã§ããïŒè³éŠæçåæ°Ž
çŽ ã奜ãŸããã¯ççŽ ååæ°ïŒãªãã12ã®éšåãäŸ
ãã°ãã·ã¬ã³æ··åç©ãŸãã¯çœ®æããã¿ã¬ã³ïŒãžã
ãã«ãã¿ã¬ãŒããŸãã¯ãžãªã¯ãã«ãã¿ã¬ãŒãã®ã
ããªãã¿ã¬ãŒãïŒã·ã¯ããããµã³ãŸãã¯ãã©ãã€
ã³ã®ãããªèèªæçåæ°ŽçŽ ïŒãšã¿ããŒã«ããšãã¬
ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãŸãã¯ã¢ããšãã«ãšãŒã
ã«ã®ãããªã¢ã«ã³ãŒã«ããã³ã°ãªã³ãŒã«äžŠã³ã«ã
ããã®ãšãŒãã«ããã³ãšã¹ãã«ïŒã·ã¯ããããµã
ã³ã®ãããªã±ãã³ïŒïŒ®âã¡ãã«âïŒâãããªã
ã³ããžã¡ãã«ã¹ã«ããã·ããŸãã¯ãžã¡ãã«ãã«ã
ã¢ããã®ãããªåŒ·æ¥µæ§æº¶åªïŒäžŠã³ã«ãšããã·åã³
ã³ãããæ²¹ãŸãã¯å€§è±æ²¹ã®ãããªãšããã·åæ€ç©
æ²¹ïŒãŸãã¯æ°Žã äŸãã°ç²å€ããã³åæ£æ§ç²æ«ã«äœ¿çšã§ããåºäœ
æ äœã¯éåžžãæ¹è§£ç³ãã¿ã«ã¯ãã«ãªãªã³ãã¢ã³ã¢
ãªããã€ããŸãã¯ã¢ã¿ãã«ãžã€ã€ãã®ãããªå€©ç¶
é±ç©å å¡«å€ã§ãããç©æ§ãæ¹è¯ããããã«ãé«å
æ£ã±ã€é žãŸãã¯é«åæ£åžåæ§ããªããŒãå ããã
ãšãå¯èœã§ãããé©åœãªç²ç¶ååžåæ§æ äœã¯å€å
æ§åã®ãã®ã§ãäŸãã°è»œç³ãç Žç ã¬ã³ã¬ãã»ããª
ã©ã€ããŸãã¯ãã³ããã€ãã§ããïŒãããŠé©åœãª
éåžåæ§æ äœã¯æ¹è§£ç³ãŸãã¯ç ã®ãããªç©è³ªã§ã
ããæŽã«éåžžã«å€ãã®äºåç²ç¶åããç¡æ©è³ªãã
ã³ææ©è³ªã®ç©è³ªãç¹ã«ãããã€ããŸãã¯ç²ç¶åæ€
ç©æ®éªžãã䜿çšãåŸãã 補å€åãã¹ãåŒã®ååç©ã®æ§è³ªã«ããããé©
åœãªè¡šé¢æŽ»æ§ååç©ã¯è¯å¥œãªä¹³åæ§ãåæ£æ§ãã
ã³æ¹¿æœ€æ§ãæããéã€ãªã³æ§ãã«ãªãã³æ§ãã
ã³ïŒãŸãã¯ã¢ããªã³æ§çé¢æŽ»æ§å€ã§ãããâçé¢
掻æ§å€âã®çšèªã¯çé¢æŽ»æ§å€ã®æ··åç©ããå«ãã
ã®ãšç解ããããã é©åœãªã¢ããªã³æ§éæŒæŽ»æ§å€ã¯ã氎溶æ§ç³é¹žã
ãã³æ°Žæº¶æ§åæè¡šé¢æŽ»æ§ååç©ã®äž¡è ã§ããåŸ
ãã é©åœãªç³é¹žã¯é«çŽèèªé žïŒC10ãC22ïŒã¢ã«ã«ãª
éå±å¡©ãã¢ã«ã«ãªåé¡éå±å¡©ããŸãã¯é眮æãŸã
ã¯çœ®æã®ã¢ã³ã¢ããŠã å¡©ãäŸãã°ãªã¬ã€ã³é žãŸã
ã¯ã¹ãã¢ãªã³é žãæãã¯äŸãã°ã³ã³ãããæ²¹ãŸã
ã¯ç£èããåŸããã倩ç¶èèªé žæ··åç©ã®ãããªãŠ
ã ãŸãã¯ã«ãªãŠã å¡©ã§ãããèèªé žã¡ãã«ã¿ãŠãª
ã³å¡©ããŸãçšãåŸãã ããããªãããããããåæçé¢æŽ»æ§å€ãç¹ã«
èèªæã¹ã«ãããŒããèèªæãµã«ããšãŒããã¹ã«
ãã³åãã³ãºã€ãããŸãŒã«èªå°äœãŸãã¯ã¢ã«ãã«
ã¢ãªãŒã«ã¹ã«ãããŒãããæŽã«é »ç¹ã«äœ¿çšãã
ãã èèªæã¹ã«ãããŒããŸãã¯ãµã«ããšãŒãã¯éåžž
ã¢ã«ã«ãªéå±å¡©ãã¢ã«ã«ãªåé¡éå±å¡©æãã¯é眮
æãŸãã¯çœ®æã®ã¢ã³ã¢ããŠã å¡©ã®åœ¢æ ã«ãããã
ããŠã¢ã·ã«åºã®ã¢ã«ãã«éšåããå«ãççŽ ååæ°
ïŒãªãã22ã®ã¢ã«ãã«åºãå«ã¿ãäŸãã°ãªã°ãã¹
ã«ãã³é žãããã·ã«ãµã«ããšãŒããŸãã¯å€©ç¶èèª
é žããåŸãããèèªæã¢ã«ã³ãŒã«ãµã«ããšãŒãã®
æ··åç©ã®ãããªãŠã ãŸãã¯ã«ã«ã·ãŠã å¡©ã§ããã
ãããã®ååç©ã«ã¯ç¡«é žãšã¹ãã«ã®å¡©ããã³èèª
æã¢ã«ã³ãŒã«ïŒãšãã¬ã³ãªãã·ãä»å ç©ã®ã¹ã«ã
ã³é žã®å¡©ãå«ãŸãããã¹ã«ãã³åãã³ãºã€ãããŸ
ãŒã«èªå°äœã¯ã奜ãŸããã¯äºã€ã®ã¹ã«ãã³é žåºãš
ïŒãªãã22åã®ççŽ ååãå«ãäžã€ã®èèªé žåºãš
ãå«ããã¢ã«ãã«ã¢ãªãŒã«ã¹ã«ãããŒãã®äŸã¯ã
ããã¿ã¬ã³ã¹ã«ãã³é žïŒãã«ã ã¢ã«ãããçž®åç
æç©ã®ãããªãŠã ãã«ãã·ãŠã ãŸãã¯ããªãšã¿ã
ãŒã«ã¢ãã³å¡©ã§ããã察å¿ãããã¹ããšãŒããäŸ
ãã°ïŒãªãã14ã¢ã«ã®ãšãã¬ã³ ãªãã·ã ãå«
ãïœâããã«ããšããŒã«ä»å ç©ã®ãªã³é žãšã¹ãã«
ã®å¡©ãããŸãé©åœã§ããã éã€ãªã³æ§çé¢æŽ»æ§å€ã¯ã奜ãŸããã¯èèªæãŸ
ãã¯èç°åŒã¢ã«ã³ãŒã«ããŸãã¯é£œåãŸãã¯äžé£œå
èèªé žããã³ã¢ã«ãã«ããšããŒã«ã®ããªã°ãªã³ãŒ
ã« ãšãŒãã«èªå°äœã§ããã該èªå°äœã¯ïŒãªãã
30åã®ã°ãªã³ãŒã« ãšãŒãã«åºã ïŒèèªæïŒç
åæ°ŽçŽ éšåã«ïŒãªãã20åã®ççŽ ååããããŠã¢
ã«ãã«ããšããŒã«ã®ã¢ã«ãã«éšåã«ïŒãªãã18å
ã®ççŽ ååãå«ãã ä»ã®é©åœãªéã€ãªã³æ§çé¢æŽ»æ§å€ã¯ãããªãšã
ã¬ã³ ãªãã·ããšããªãããã¬ã³ ã°ãªã³ãŒã«ã
ãšãã¬ã³ãžã¢ãã³ããªãããã¬ã³ ã°ãªã³ãŒã«ã
ãã³ã¢ã«ãã«éäžã«ïŒãªãã10åã®ççŽ ååãå«
ãã¢ã«ãã«ããªãããã¬ã³ ã°ãªã³ãŒã«ãšã®æ°Žæº¶
æ§ä»å ç©ã§ããããã®ä»å ç©ã¯20ãªãã250åã®
ãšãã¬ã³ ã°ãªã³ãŒã« ãšãŒãã«åºããã³10ãªã
ã100åã®ãããã¬ã³ ã°ãªã³ãŒã« ãšãŒãã«åº
ãå«ãããããã®ååç©ã¯éåžžãããã¬ã³ ã°ãª
ã³ãŒã«åäœåœãïŒãªããïŒåã®ãšãã¬ã³ã°ãªã³ãŒ
ã«åäœãå«ãã éã€ãªã³æ§çé¢æŽ»æ§å€ã®ä»£è¡šçäŸã¯ãããã«ã
ãšããŒã«âããªãšããã·ãšã¿ããŒã«ãããã·æ²¹ã
ãªã°ãªã³ãŒã« ãšãŒãã«ãããªãããã¬ã³ïŒããª
ãšãã¬ã³ ãªãã·ãä»å ç©ãããªããã«ããšãã
ã·ããªãšããã·ãšã¿ããŒã«ãããªãšãã¬ã³ ã°ãª
ã³ãŒã«ããã³ãªã¯ãã«ããšããã·ãšããã·ãšã¿ã
ãŒã«ã§ãããããªãªãã·ãšãã¬ã³ãœã«ãã¿ã³ãã
ã³ããªãªãã·ãšãã¬ã³ ãœã«ãã¿ã³ ããªãªã¬ãŒ
ãã®èèªé žãšã¹ãã«ããŸãé©åœãªéã€ãªã³æ§çé¢
掻æ§å€ã§ããã ã«ãªãã³æ§çé¢æŽ»æ§å€ã¯ã奜ãŸããã¯ïŒ®â眮æ
åºãšããŠå°ãªããšãäžã€ã®ççŽ ååæ°ïŒãªãã22
ã®ã¢ã«ãã«åºãšãä»ã®çœ®æåºãšããŠäœçŽé眮æãŸ
ãã¯ããã²ã³åã¢ã«ãã«åºããã³ãžã«åºãŸãã¯äœ
çŽããããã·ã¢ã«ãã«åºãšãå«ã第åã¢ã³ã¢ããŠ
ã å¡©ã§ããã該塩ã¯å¥œãŸããã¯ããã²ã³åç©ãã¡
ãã«ç¡«é žå¡©ãŸãã¯ãšãã«ç¡«é žå¡©ã®åœ¢æ ã«ãããäŸ
ãã°ã¹ãã¢ãªã«ããªã¡ãã«ã¢ã³ã¢ããŠã ã¯ããª
ããŸãã¯ãã³ãžã« ãžâïŒïŒâã¯ãããšãã«ïŒãš
ãã«ã¢ã³ã¢ããŠã ããããã§ããã 補å€æ¥çã§æ £çšã®çé¢æŽ»æ§å€ã¯äŸãã°H.Staâ
cheïŒâTensidâTaschenbuchâïŒ2nd.editionïŒC.
Hanser VerlagïŒMunichããã³ViennaïŒ1981ïŒ
ããã³ïŒïŒJ.AshïŒâEncyclopedia of
SurfactantsâïŒVol.ãïŒChemical
Publishing Co.New YorkïŒ1980ã81äžã«èšèŒ
ãããŠããã 蟲è¬è£œå€ã¯éåžžãåŒã®ååç©0.1ãªãã95ïŒ ã
奜ãŸããã¯0.1ãªãã80ïŒ ãåºäœãŸãã¯æ¶²äœè£å©
å€ïŒãªãã99.9ïŒ ãããã³çé¢æŽ»æ§å€ïŒãªãã25
ïŒ ïŒå¥œãŸããã¯0.1ãªãã25ïŒ ãå«ãã 奜ãŸãã補å€ãšããŠã¯ç¹ã«äžèšã®æåãããªã
ãã®ãæããããïŒïŒ ã¯ééçŸåçã瀺ããïŒïŒä¹³
å€å液 匊å¹æåïŒ ïŒãªãã20ïŒ ã奜ãŸããã¯ïŒãªãã
10ïŒ çé¢æŽ»æ§å€ïŒ ïŒãªãã30ïŒ ã奜ãŸããã¯10ãªã
ã20ïŒ æ¶²äœæ äœïŒ 50ãªãã94ïŒ ã奜ãŸããã¯70ãªãã
85ïŒ ç² å€ æå¹æåïŒ 0.1ãªãã10ïŒ ã奜ãŸããã¯0.1ãªã
ãïŒïŒ åºäœæ äœïŒ 99.9ãªãã90ïŒ ã奜ãŸããã¯99.9ãª
ãã99ïŒ æžæ¿å液 æå¹æåïŒ ïŒãªãã75ïŒ ã奜ãŸããã¯10ãªãã
50ïŒ æ°Ž ïŒ 94ãªãã25ïŒ ã奜ãŸããã¯90ãªãã
30ïŒ çé¢æŽ»æ§å€ïŒ ïŒãªãã40ïŒ ã奜ãŸããã¯ïŒãªã
ã30ïŒ æ°Ž å å€ æå¹æåïŒ 0.5ãªãã90ïŒ ã奜ãŸããã¯10ãªã
ã80ïŒ çé¢æŽ»æ§å€ïŒ 0.5ãªãã20ïŒ ã奜ãŸããã¯ïŒãª
ãã15ïŒ åºäœæ äœïŒ ïŒãªãã90ïŒ ã奜ãŸããã¯15ãªãã
90ïŒ ç² å€ æå¹æåïŒ 0.5ãªãã30ïŒ ã奜ãŸããã¯ïŒãªã
ã15ïŒ åºäœæ äœïŒ 99.5ãªãã70ïŒ ã奜ãŸããã¯97ãªã
ã85ïŒ åžè²©åã¯å¥œãŸããã¯æ¿åç©ãšããŠè£œå€åããã
ããæ¶è²»è ã¯éåžžåžé補å€ã䜿çšããã補æã¯
0.001ïŒ ã®ãããªäœæ¿åºŠã«åžéããããšãã§ããã
æœçšæ¯çã¯éåžž0.01ãªãã10Kgæå¹æåïŒa.
i.ïŒïŒhaã奜ãŸããã¯0.025ãªããïŒKga.i.ïŒhaã§
ããã ãã®çµæç©ã¯ãŸãä»ã®æåäŸãã°å®å®å€ãæ¶æ³¡
å€ãç²åºŠèª¿ç¯å€ãçµåå€ãç²çä»äžå€äžŠã³ã«è¥æ
ãŸãã¯ãç¹å¥ãªå¹æã®ããã«ä»ã®æå¹æåãå«æ
ããŠãããã æ¬çºæãäžèšå®æœäŸã«ãã詳现ã«èª¬æããã å®æœäŸïŒïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«âïŒïŒïŒïŒïŒâã
ãªã¢ãžã³âïŒâã€ã«ïŒå°¿çŽ æ°ŽïŒmläžã®äºç¡é žãããªãŠã ïŒïœã®æº¶æ¶²ã0°ãª
ããïŒâã§ãâïŒïŒâã¢ããããšãã«ã¹ã«ãã
ã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«âïŒïŒïŒïŒ
ïŒâããªã¢ãžã³âïŒâã€ã«ïŒå°¿çŽ 3.4ïœãæ°·10ïœ
ããã³36ïŒ å¡©é žïŒmlã®æ··åç©ã«ãã€ããå ããã
åå¿æ··åç©ãïŒâã§ïŒæéæªæããåŸãæ°ŽïŒmläž
ã®ããã«ãŠã ã¢ãžãïŒïœã®æº¶æ¶²ã滎å ãã次ãã§
枩床ã20âã«äžæãããŸã§æŸçœ®ãããåå¿æ··åç©
ãå¡©åã³ã¡ãã¬ã³å20mlã§ïŒåæœåºãããæ··åã
ãææ©çžã也ç¥ãã次ãã§æ¿çž®ãããæ®éšã®åçµ
æ¶ã«ãã175âã§å解ãããâïŒïŒâã¢ãžãããš
ãã«ã¹ã«ããã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡
ãã«âïŒïŒïŒïŒïŒâããªã¢ãžã³âïŒâã€ã«ïŒå°¿çŽ
1.0ïœãåŸãã å®æœäŸïŒïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒïŒïŒâãžã¡ããã·ããªããžã³âïŒâã€ã«ïŒ
å°¿çŽ æ°ŽïŒmläžã®äºç¡é žãããªãŠã 1.0ïœã®æº¶æ¶²ãïŒ
âãªããïŒâã§ãâïŒïŒâã¢ããããšãã«ã¹ã«
ããã«ïŒâNâ²âïŒãžã¡ããã·ããªããžã³âïŒâã€
ã«ïŒå°¿çŽ 3.5ïœãæ°·10ïœããã³36ïŒ å¡©é žïŒmlã®æ··
åç©ã«ãã€ããå ãããåå¿æ··åç©ãïŒâã§ïŒæ
éæªæããåŸãæ°ŽïŒmläžã®ãããªãŠã ã¢ãžãïŒïœ
ã®æº¶æ¶²ã滎å ãã次ãã§æž©åºŠã20床ã«äžæãããŸ
ã§æŸçœ®ãããåå¿æ··åç©ãå¡©åã¡ãã¬ã³å20mlã§
ïŒåæœåºãããæ··åããææ©å±€ã也ç¥ãã次ãã§
æ¿çž®ãããæ®éšã®åçµæ¶ã«ãã190âã§å解ãã
âïŒã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²âïŒïŒïŒïŒ
âãžã¡ããã·ããªããžã³âïŒâã€ã«ïŒå°¿çŽ 0.52ïœ
ãåŸãã å®æœäŸïŒïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããžã³âïŒâ
ã€ã«ïŒå°¿çŽ æ°ŽïŒmläžã®äºç¡é žãããªãŠã ïŒïœã®æº¶æ¶²ã0°ãª
ããïŒâã§ãâïŒïŒâã¢ããããšãã«ã¹ã«ãã
ã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããž
ã³âïŒâã€ã«ïŒå°¿çŽ 3.4ïœãæ°·10ïœããã³36ïŒ å¡©
é žïŒmlã®æ··åç©ã«ãã€ããå ãããåå¿æ··åç©ã
ïŒâã§ïŒæéæªæããåŸãæ°ŽïŒmläžã®ããã«ãŠã
ã¢ãžãïŒïœã®æº¶æ¶²ã滎å ãã次ãã§æž©åºŠã20âã«
äžæãããŸã§æŸçœ®ãããåå¿æ··åç©ãå¡©åã¡ãã¬
ã³å20mlã§ïŒåæœåºãããæ··åããææ©çžã也ç¥
ãã次ãã§æ¿çž®ãããæ®éšã®åçµæ¶ã«ãã178°ãª
ãã179âã§å解ããâïŒïŒâã¢ãžãããšãã«ã¹
ã«ããã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«ã
ãªããžã³âïŒâã€ã«ïŒå°¿çŽ 0.85ïœãåŸãã å®æœäŸïŒïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããžã³âïŒâ
ã€ã«ïŒå°¿çŽ ãžãªããµã³10mläžã®ïŒ®âïŒïŒâã¡ããã·âïŒâ
ã¡ãã«ããªããžã³âïŒâã€ã«ïŒããšãã«ã«ã«ãã¡
ãŒã2.9ïœã®æº¶æ¶²ã20°ãªãã25âã§ããžãªããµã³
20mläžã®ïŒâã¢ãžãããšãã«ã¹ã«ãã³ã¢ããïŒïœ
ããã³ïŒïŒïŒâãžã¢ã¶ãã·ã¯ã ïŒïŒïŒïŒïŒïŒïŒ
ãŠã³ãã»ã³âïŒ 1.6mlã®æº¶æ¶²ã«æ»Žå ããã次ã
ã§åå¿æ··åç©ãæ°Ž200mläžã«æå ¥ãã次ãã§æ°Žæ§
æ··åç©ãå¡©é žã«ãã€ãŠé žæ§åãpH2ãšãããæ²æ®¿
ããçæç©ãåé¢ããé ¢é žãšãã«ã§æž æµãã次ã
ã§ä¹Ÿç¥ããŠãèç¹192âã®ç·å³ããã³ãçµæ¶ã®åœ¢
æ ã§ïŒ®âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâ
Nâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããžã³âïŒ
âã€ã«ïŒå°¿çŽ ãåç67ïŒ ã§åŸãã äžèšè¡šäžã«èšèŒãããäžéäœããã³æçµçæç©
ã¯åæ§ã®æ¹æ³ã«ãã€ãŠåŸãããã
åãæå³ãè¡šããããã§è¡šããããã åŒïœã§è¡šããããååç©ã¯éåžžå ¬ç¥æ¹æ³äŸã
ã°éå±ãšé žã®çµåãã«ãã觊åªçéå ãã¢ãã«ã¬
ã ãšã¢ã«ã³ãŒã«æ°Žæº¶æ¶²ã«ããéå ãŸãã¯ã¢ã«ã«ãª
éå±ã¹ã«ãã€ãã«ããéå ã«ãã€ãŠå¯Ÿå¿ãããã
ãããšãã«ã¹ã«ãã³ã¢ãããã¢ããååç©ã«éå
ãã次ãã§å ¬ç¥æ¹æ³ã«ããã¢ããååç©ããžã¢ãŸ
åãããããŠåŸããããžã¢ãŸããŠã å¡©ãåŒïœã§
è¡šããããã¢ãžãååç©ãå€ããããšã«ããåŸã
ããã åæ§ãªæ¹æ³ã¯äŸãã°Monatshefte der
ChemieïŒ81ïŒ970ã980ïŒ1950ïŒãŸãã¯Houbenâ
WeylãMethoden der organischenïŒChemieïŒ
4th editionïŒVol.10ïŒ3.781ã836 äžã«èšèŒãã
ãŠããã åŒã§è¡šããããäžéäœã¯éå ã«ãã察å¿ãã
ãããããšãã«ã¹ã«ããã«å°¿çŽ ããåæ§ãªæ¹æ³ã«
ãã€ãŠåŸãããšãã§ããããã®ãããªãããããš
ãã«ã¹ã«ããã«å°¿çŽ ã¯å ¬ç¥ã§ããããŸãã¯å ¬ç¥æ¹
æ³ã«ããåŸãããã åŒã§è¡šããããååç©ãåŸãããã«ã¯äŸãã°
å¡©åã¡ãã¬ã³ãããã©ããããã©ã³ãã¢ã»ããã
ãªã«ããžãªããµã³ãŸãã¯ãã«ãšã³ã®ãããªäžæ§ã
äžæŽ»æ§ææ©æº¶åªäžã§ãããã®åå¿ãè¡ãã®ã䟿å©
ã§ããã åå¿æž©åºŠã¯â20°ãªããïŒ120âã®ç¯å²ã奜ãŸã
ããåå¿ã¯éåžžãããã«çºç±çã§ããããããŠå®€
æž©ã§è¡ãããšãã§ãããåå¿æéãççž®ãããã
ãã¯ãŸãåå¿ãéå§ããããã«ã¯åå¿æ··åç©ãç
æé沞ç¹ãŸã§å ç±ããã®ã奜éœåã§ããã觊åªãš
ããŠå¡©åºãŸãã¯ã€ãœã·ã¢ããŒããïŒïŒïŒæ»Žå ãã
ãšåå¿æéãççž®ããããšãã§ããã æçµçæç©ã¯ãåå¿æ··åç©ãæ¿çž®ãããããŠïŒ
ãŸãã¯èžçºã«ãã溶åªãé€å»ãããããŠåçµæ¶ãŸ
ãã¯æº¶è§£æ§ã®ä¹ãã溶åªäŸãã°ãšãŒãã«ãè³éŠæ
çåæ°ŽçŽ ãŸãã¯å¡©çŽ åçåæ°ŽçŽ äžã§åºäœæ®éšãã
ãã€ã¶ãããšã«ããåé¢ããããšãã§ããã åŒã§è¡šããããååç©ã¯å®å®ãªååç©ã§ã
ãããããŠãã®åæ±ãã«ãããŠã¯å šãé²è·æ段ã
å¿ èŠãšããªãã äœãæœçšæ¯çã§çšããå Žåã«ã¯ãåŒã§è¡šãã
ããååç©ã¯è¯å¥œãªéžæççé·æå¶ããã³éžæç
é€èç¹æ§ãæãããã®ããæçšæ€ç©ç¹ã«ããšãã
ã³ãç©é¡ãæ£ã倧è±ããšãããããããã³çš²ã®å
ç©«ã®ããã«ãããã䜿çšããã®ã奜ãŸããããã
ã€ãã®å Žåã«ãããŠã¯çŸåšç·åé€èå€ã«ãã€ãŠã®
ã¿é²é€ãããéèã«å¯ŸããŠããŸãæå·ãäžããã
ãšãã§ããã ãããã®ååç©ã®ããã€ãã®äœçšåœ¢æ ã¯éåžžã®
å Žåãšã¯ç°ãªããå€ãã¯è»¢æµå¯èœã§ãããããªã
ã¡ãããã¯æ€ç©ã«ãã€ãŠåžåããã次ãã§ããã
ãäœçšããä»ã®éšæã«ç§»åãããããæ äŸãã°è¡š
é¢åŠçã«ããå€å¹Žçéèã®æ ¹ã«æå·ãäžããããš
ãå¯èœã§ãããä»ã®é€èå€ããã³çé·æå¶å€ã«æ¯
ã¹ãŠãåŒã§è¡šããããæ°èŠãªååç©ã¯éåžžã«äœ
ãæœçšæ¯çã§çšããããå Žåã§ãå¹æãããã åŒã§è¡šããããååç©ã¯æ œå¹æ€ç©ãŸãã¯åç©«
äœç©ã®åç©«éãå¢å ãããããšãã§ããçé·èª¿ç¯
ç¹æ§ã瀺ããæŽã«ãåŒã§è¡šããããååç©ã®å€
ãã¯æ¿åºŠã«å¿ããŠçé·é²æ¢äœçšã瀺ããååèæ€
ç©ããã³ååèæ€ç©åæ¹ã®çé·ã劚ãããããã
ãæ äŸãã°åŒã§è¡šããããååç©ã¯ç±åž¯å°åã§
éäœãšããŠãã°ãã°æ œå¹ãããè±ç§æ€ç©ã®çé·ã
éžæçã«é²æ¢ããã®ã§ããã®çµæãæ œå¹æ€ç©ã®é
ã®åå£ã®æµžé£ãé²ãããéäœã¯æ œå¹æ€ç©ãšç«¶åã
ãããšãã§ããªãã å€ãã®æ œå¹æ€ç©ã®èäžçé·ãé²æ¢ãããããæ œ
å¹é¢ç©åœãããå€ãã®æ€ç©ãæçš®ããããšãã§
ãããã®çµæåäœé¢ç©åœãããå€ãã®åç©«éãåŸ
ãããšãã§ãããçé·èª¿ç¯å€ã䜿çšããå Žåã®å
ç©«éå¢å€§ã®ãã詳现ãªæ©æ§ãšããŠã¯ãèäžçé·ã
é²æ¢ãããããè±ãå²ãå®ããªãã®ãä¿é²ããã
ãã®æ é€åãå¢å ããããšãã§ããããã§ããã ååèæ€ç©äŸãã°ç§èãŸãã¯æ œå¹æ€ç©äŸãã°ç©
ç©ã®èäžçé·ã®é²æ¢ã¯ãã°ãã°ææã§ããããŠå¥œ
éœåã§ããããã®ãããªçé·ã®é²æ¢ã¯ãç¹ã«ç§è
ã«ãããŠã¯ãè±æ®µãå ¬åã競æå ŽãŸãã¯è·¯è©ã«ã
ããå蟌ã®é »åºŠãããã«ããæžå°ãããããšãã§
ããã®ã§çµæžçãªèå³ãããã è·¯è©ã®äžããã³å€æŽç·ã®è¿ããŸãã¯æŽã«äžè¬ç
ã«ã¯åŒ·ãçé·ãæãŸãããªãåºåã®äžã§ã®èãã
ã³æšã®çé·ã®é²æ¢ããŸãéèŠã§ããã ç©ç©ã®äžã®çé·ãé²æ¢ããããã®çé·èª¿ç¯å€ã®
䜿çšããŸããèãæžå°ãããŠçå°åãåç©«åã®å
害ã®å±éºãå®å šã«é€ãããã«éèŠã§ãããæŽã«ã
çé·èª¿ç¯å€ã¯ãç©ç©ã®èã匷åãããããŠå害ã
é²æ¢ããããšãã§ããã æŽã«åŒã§è¡šããããååç©ã¯è²¯èµããããã
ã®çºèœãé²ãã®ã«é©ããŠãããå¬æã®è²¯èµã®éã
ãããããã¯ãã°ãã°çºèœãããã®çµæçž®å°ãé
éæ倱ããã³è æãèµ·ãã é«æ¯çã§æœçšããå Žåã«ã¯ãç·ãŠã®è©Šéšæ€ç©ã
ãã®çé·ã«å€§ããªæå·ãåããŠæ¯ããã æ¬çºæã¯ãŸãåŒã§è¡šããããæ°èŠååç©ãå«
ãé€èããã³çé·æå¶å€çµæç©ã䞊ã³ã«çºèœåã
ãã³çºèœåŸã®éèã®é²é€ãããã³ååèæ€ç©ãã
ã³ååèæ€ç©ç¹ã«ç§èãç±åž¯éäœããã³ç èæ€ç©
ã®åžæã®çé·é²æ¢ã®æ¹æ³ã«ããŸãé¢ãããã®ã§ã
ãã åŒã®ååç©ã¯ãã®ãŸãŸã®åœ¢æ ã§ãæãã¯å¥œãŸ
ããã¯è£œå€æ¥çã§æ £çšã®è£å©å€ãšå ±ã«äœ¿çšããã
å ¬ç¥ã®æ¹æ³ã«ããä¹³å€å液ã被èŠæ§ããŒã¹ã
ïŒcoatable pasteïŒãçŽæ¥åŽé§å¯èœãªãŸãã¯åžéå¯
èœãªæº¶æ¶²ãåžéä¹³å€ãæ°Žåå€ã氎溶å€ãç²å€ãç²
å€ãããã³äŸãã°ããªããŒç©è³ªã«ããã«ãã»ã«å
å€ã«è£œå€åããããçµæç©ã®æ§è³ªãšåæ§ãåŽé§ã
é§åãæ£ç²ãæ£æ°ŽãŸãã¯æ³šæ°Žã®ãããªé©çšæ³ã¯ã
ç®çãšãã察象ããã³äœ¿çšç°å¢ã«äŸåããŠéžã°ã
ãã 補æãå³ã¡åŒã®ååç©ïŒæå¹æåïŒããã³é©
åœãªå Žåã«ã¯åºäœãŸãã¯æ¶²äœã®è£å©å€ãå«ãçµæ
ç©ãŸãã¯è£œå€ã¯ãå ¬ç¥ã®æ¹æ³ã«ãããäŸãã°æå¹
æåã溶åªãåºäœæ äœããã³é©åœãªå Žåã«ã¯è¡šé¢
掻æ§ååç©ïŒçé¢æŽ»æ§å€ïŒã®ãããªå¢éå€ãšåäž
ã«æ··åããã³ïŒãŸãã¯æ©ç ããããšã«ããã補é
ãããã é©åœãªæº¶åªã¯æ¬¡ã®ãã®ã§ããïŒè³éŠæçåæ°Ž
çŽ ã奜ãŸããã¯ççŽ ååæ°ïŒãªãã12ã®éšåãäŸ
ãã°ãã·ã¬ã³æ··åç©ãŸãã¯çœ®æããã¿ã¬ã³ïŒãžã
ãã«ãã¿ã¬ãŒããŸãã¯ãžãªã¯ãã«ãã¿ã¬ãŒãã®ã
ããªãã¿ã¬ãŒãïŒã·ã¯ããããµã³ãŸãã¯ãã©ãã€
ã³ã®ãããªèèªæçåæ°ŽçŽ ïŒãšã¿ããŒã«ããšãã¬
ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãŸãã¯ã¢ããšãã«ãšãŒã
ã«ã®ãããªã¢ã«ã³ãŒã«ããã³ã°ãªã³ãŒã«äžŠã³ã«ã
ããã®ãšãŒãã«ããã³ãšã¹ãã«ïŒã·ã¯ããããµã
ã³ã®ãããªã±ãã³ïŒïŒ®âã¡ãã«âïŒâãããªã
ã³ããžã¡ãã«ã¹ã«ããã·ããŸãã¯ãžã¡ãã«ãã«ã
ã¢ããã®ãããªåŒ·æ¥µæ§æº¶åªïŒäžŠã³ã«ãšããã·åã³
ã³ãããæ²¹ãŸãã¯å€§è±æ²¹ã®ãããªãšããã·åæ€ç©
æ²¹ïŒãŸãã¯æ°Žã äŸãã°ç²å€ããã³åæ£æ§ç²æ«ã«äœ¿çšã§ããåºäœ
æ äœã¯éåžžãæ¹è§£ç³ãã¿ã«ã¯ãã«ãªãªã³ãã¢ã³ã¢
ãªããã€ããŸãã¯ã¢ã¿ãã«ãžã€ã€ãã®ãããªå€©ç¶
é±ç©å å¡«å€ã§ãããç©æ§ãæ¹è¯ããããã«ãé«å
æ£ã±ã€é žãŸãã¯é«åæ£åžåæ§ããªããŒãå ããã
ãšãå¯èœã§ãããé©åœãªç²ç¶ååžåæ§æ äœã¯å€å
æ§åã®ãã®ã§ãäŸãã°è»œç³ãç Žç ã¬ã³ã¬ãã»ããª
ã©ã€ããŸãã¯ãã³ããã€ãã§ããïŒãããŠé©åœãª
éåžåæ§æ äœã¯æ¹è§£ç³ãŸãã¯ç ã®ãããªç©è³ªã§ã
ããæŽã«éåžžã«å€ãã®äºåç²ç¶åããç¡æ©è³ªãã
ã³ææ©è³ªã®ç©è³ªãç¹ã«ãããã€ããŸãã¯ç²ç¶åæ€
ç©æ®éªžãã䜿çšãåŸãã 補å€åãã¹ãåŒã®ååç©ã®æ§è³ªã«ããããé©
åœãªè¡šé¢æŽ»æ§ååç©ã¯è¯å¥œãªä¹³åæ§ãåæ£æ§ãã
ã³æ¹¿æœ€æ§ãæããéã€ãªã³æ§ãã«ãªãã³æ§ãã
ã³ïŒãŸãã¯ã¢ããªã³æ§çé¢æŽ»æ§å€ã§ãããâçé¢
掻æ§å€âã®çšèªã¯çé¢æŽ»æ§å€ã®æ··åç©ããå«ãã
ã®ãšç解ããããã é©åœãªã¢ããªã³æ§éæŒæŽ»æ§å€ã¯ã氎溶æ§ç³é¹žã
ãã³æ°Žæº¶æ§åæè¡šé¢æŽ»æ§ååç©ã®äž¡è ã§ããåŸ
ãã é©åœãªç³é¹žã¯é«çŽèèªé žïŒC10ãC22ïŒã¢ã«ã«ãª
éå±å¡©ãã¢ã«ã«ãªåé¡éå±å¡©ããŸãã¯é眮æãŸã
ã¯çœ®æã®ã¢ã³ã¢ããŠã å¡©ãäŸãã°ãªã¬ã€ã³é žãŸã
ã¯ã¹ãã¢ãªã³é žãæãã¯äŸãã°ã³ã³ãããæ²¹ãŸã
ã¯ç£èããåŸããã倩ç¶èèªé žæ··åç©ã®ãããªãŠ
ã ãŸãã¯ã«ãªãŠã å¡©ã§ãããèèªé žã¡ãã«ã¿ãŠãª
ã³å¡©ããŸãçšãåŸãã ããããªãããããããåæçé¢æŽ»æ§å€ãç¹ã«
èèªæã¹ã«ãããŒããèèªæãµã«ããšãŒããã¹ã«
ãã³åãã³ãºã€ãããŸãŒã«èªå°äœãŸãã¯ã¢ã«ãã«
ã¢ãªãŒã«ã¹ã«ãããŒãããæŽã«é »ç¹ã«äœ¿çšãã
ãã èèªæã¹ã«ãããŒããŸãã¯ãµã«ããšãŒãã¯éåžž
ã¢ã«ã«ãªéå±å¡©ãã¢ã«ã«ãªåé¡éå±å¡©æãã¯é眮
æãŸãã¯çœ®æã®ã¢ã³ã¢ããŠã å¡©ã®åœ¢æ ã«ãããã
ããŠã¢ã·ã«åºã®ã¢ã«ãã«éšåããå«ãççŽ ååæ°
ïŒãªãã22ã®ã¢ã«ãã«åºãå«ã¿ãäŸãã°ãªã°ãã¹
ã«ãã³é žãããã·ã«ãµã«ããšãŒããŸãã¯å€©ç¶èèª
é žããåŸãããèèªæã¢ã«ã³ãŒã«ãµã«ããšãŒãã®
æ··åç©ã®ãããªãŠã ãŸãã¯ã«ã«ã·ãŠã å¡©ã§ããã
ãããã®ååç©ã«ã¯ç¡«é žãšã¹ãã«ã®å¡©ããã³èèª
æã¢ã«ã³ãŒã«ïŒãšãã¬ã³ãªãã·ãä»å ç©ã®ã¹ã«ã
ã³é žã®å¡©ãå«ãŸãããã¹ã«ãã³åãã³ãºã€ãããŸ
ãŒã«èªå°äœã¯ã奜ãŸããã¯äºã€ã®ã¹ã«ãã³é žåºãš
ïŒãªãã22åã®ççŽ ååãå«ãäžã€ã®èèªé žåºãš
ãå«ããã¢ã«ãã«ã¢ãªãŒã«ã¹ã«ãããŒãã®äŸã¯ã
ããã¿ã¬ã³ã¹ã«ãã³é žïŒãã«ã ã¢ã«ãããçž®åç
æç©ã®ãããªãŠã ãã«ãã·ãŠã ãŸãã¯ããªãšã¿ã
ãŒã«ã¢ãã³å¡©ã§ããã察å¿ãããã¹ããšãŒããäŸ
ãã°ïŒãªãã14ã¢ã«ã®ãšãã¬ã³ ãªãã·ã ãå«
ãïœâããã«ããšããŒã«ä»å ç©ã®ãªã³é žãšã¹ãã«
ã®å¡©ãããŸãé©åœã§ããã éã€ãªã³æ§çé¢æŽ»æ§å€ã¯ã奜ãŸããã¯èèªæãŸ
ãã¯èç°åŒã¢ã«ã³ãŒã«ããŸãã¯é£œåãŸãã¯äžé£œå
èèªé žããã³ã¢ã«ãã«ããšããŒã«ã®ããªã°ãªã³ãŒ
ã« ãšãŒãã«èªå°äœã§ããã該èªå°äœã¯ïŒãªãã
30åã®ã°ãªã³ãŒã« ãšãŒãã«åºã ïŒèèªæïŒç
åæ°ŽçŽ éšåã«ïŒãªãã20åã®ççŽ ååããããŠã¢
ã«ãã«ããšããŒã«ã®ã¢ã«ãã«éšåã«ïŒãªãã18å
ã®ççŽ ååãå«ãã ä»ã®é©åœãªéã€ãªã³æ§çé¢æŽ»æ§å€ã¯ãããªãšã
ã¬ã³ ãªãã·ããšããªãããã¬ã³ ã°ãªã³ãŒã«ã
ãšãã¬ã³ãžã¢ãã³ããªãããã¬ã³ ã°ãªã³ãŒã«ã
ãã³ã¢ã«ãã«éäžã«ïŒãªãã10åã®ççŽ ååãå«
ãã¢ã«ãã«ããªãããã¬ã³ ã°ãªã³ãŒã«ãšã®æ°Žæº¶
æ§ä»å ç©ã§ããããã®ä»å ç©ã¯20ãªãã250åã®
ãšãã¬ã³ ã°ãªã³ãŒã« ãšãŒãã«åºããã³10ãªã
ã100åã®ãããã¬ã³ ã°ãªã³ãŒã« ãšãŒãã«åº
ãå«ãããããã®ååç©ã¯éåžžãããã¬ã³ ã°ãª
ã³ãŒã«åäœåœãïŒãªããïŒåã®ãšãã¬ã³ã°ãªã³ãŒ
ã«åäœãå«ãã éã€ãªã³æ§çé¢æŽ»æ§å€ã®ä»£è¡šçäŸã¯ãããã«ã
ãšããŒã«âããªãšããã·ãšã¿ããŒã«ãããã·æ²¹ã
ãªã°ãªã³ãŒã« ãšãŒãã«ãããªãããã¬ã³ïŒããª
ãšãã¬ã³ ãªãã·ãä»å ç©ãããªããã«ããšãã
ã·ããªãšããã·ãšã¿ããŒã«ãããªãšãã¬ã³ ã°ãª
ã³ãŒã«ããã³ãªã¯ãã«ããšããã·ãšããã·ãšã¿ã
ãŒã«ã§ãããããªãªãã·ãšãã¬ã³ãœã«ãã¿ã³ãã
ã³ããªãªãã·ãšãã¬ã³ ãœã«ãã¿ã³ ããªãªã¬ãŒ
ãã®èèªé žãšã¹ãã«ããŸãé©åœãªéã€ãªã³æ§çé¢
掻æ§å€ã§ããã ã«ãªãã³æ§çé¢æŽ»æ§å€ã¯ã奜ãŸããã¯ïŒ®â眮æ
åºãšããŠå°ãªããšãäžã€ã®ççŽ ååæ°ïŒãªãã22
ã®ã¢ã«ãã«åºãšãä»ã®çœ®æåºãšããŠäœçŽé眮æãŸ
ãã¯ããã²ã³åã¢ã«ãã«åºããã³ãžã«åºãŸãã¯äœ
çŽããããã·ã¢ã«ãã«åºãšãå«ã第åã¢ã³ã¢ããŠ
ã å¡©ã§ããã該塩ã¯å¥œãŸããã¯ããã²ã³åç©ãã¡
ãã«ç¡«é žå¡©ãŸãã¯ãšãã«ç¡«é žå¡©ã®åœ¢æ ã«ãããäŸ
ãã°ã¹ãã¢ãªã«ããªã¡ãã«ã¢ã³ã¢ããŠã ã¯ããª
ããŸãã¯ãã³ãžã« ãžâïŒïŒâã¯ãããšãã«ïŒãš
ãã«ã¢ã³ã¢ããŠã ããããã§ããã 補å€æ¥çã§æ £çšã®çé¢æŽ»æ§å€ã¯äŸãã°H.Staâ
cheïŒâTensidâTaschenbuchâïŒ2nd.editionïŒC.
Hanser VerlagïŒMunichããã³ViennaïŒ1981ïŒ
ããã³ïŒïŒJ.AshïŒâEncyclopedia of
SurfactantsâïŒVol.ãïŒChemical
Publishing Co.New YorkïŒ1980ã81äžã«èšèŒ
ãããŠããã 蟲è¬è£œå€ã¯éåžžãåŒã®ååç©0.1ãªãã95ïŒ ã
奜ãŸããã¯0.1ãªãã80ïŒ ãåºäœãŸãã¯æ¶²äœè£å©
å€ïŒãªãã99.9ïŒ ãããã³çé¢æŽ»æ§å€ïŒãªãã25
ïŒ ïŒå¥œãŸããã¯0.1ãªãã25ïŒ ãå«ãã 奜ãŸãã補å€ãšããŠã¯ç¹ã«äžèšã®æåãããªã
ãã®ãæããããïŒïŒ ã¯ééçŸåçã瀺ããïŒïŒä¹³
å€å液 匊å¹æåïŒ ïŒãªãã20ïŒ ã奜ãŸããã¯ïŒãªãã
10ïŒ çé¢æŽ»æ§å€ïŒ ïŒãªãã30ïŒ ã奜ãŸããã¯10ãªã
ã20ïŒ æ¶²äœæ äœïŒ 50ãªãã94ïŒ ã奜ãŸããã¯70ãªãã
85ïŒ ç² å€ æå¹æåïŒ 0.1ãªãã10ïŒ ã奜ãŸããã¯0.1ãªã
ãïŒïŒ åºäœæ äœïŒ 99.9ãªãã90ïŒ ã奜ãŸããã¯99.9ãª
ãã99ïŒ æžæ¿å液 æå¹æåïŒ ïŒãªãã75ïŒ ã奜ãŸããã¯10ãªãã
50ïŒ æ°Ž ïŒ 94ãªãã25ïŒ ã奜ãŸããã¯90ãªãã
30ïŒ çé¢æŽ»æ§å€ïŒ ïŒãªãã40ïŒ ã奜ãŸããã¯ïŒãªã
ã30ïŒ æ°Ž å å€ æå¹æåïŒ 0.5ãªãã90ïŒ ã奜ãŸããã¯10ãªã
ã80ïŒ çé¢æŽ»æ§å€ïŒ 0.5ãªãã20ïŒ ã奜ãŸããã¯ïŒãª
ãã15ïŒ åºäœæ äœïŒ ïŒãªãã90ïŒ ã奜ãŸããã¯15ãªãã
90ïŒ ç² å€ æå¹æåïŒ 0.5ãªãã30ïŒ ã奜ãŸããã¯ïŒãªã
ã15ïŒ åºäœæ äœïŒ 99.5ãªãã70ïŒ ã奜ãŸããã¯97ãªã
ã85ïŒ åžè²©åã¯å¥œãŸããã¯æ¿åç©ãšããŠè£œå€åããã
ããæ¶è²»è ã¯éåžžåžé補å€ã䜿çšããã補æã¯
0.001ïŒ ã®ãããªäœæ¿åºŠã«åžéããããšãã§ããã
æœçšæ¯çã¯éåžž0.01ãªãã10Kgæå¹æåïŒa.
i.ïŒïŒhaã奜ãŸããã¯0.025ãªããïŒKga.i.ïŒhaã§
ããã ãã®çµæç©ã¯ãŸãä»ã®æåäŸãã°å®å®å€ãæ¶æ³¡
å€ãç²åºŠèª¿ç¯å€ãçµåå€ãç²çä»äžå€äžŠã³ã«è¥æ
ãŸãã¯ãç¹å¥ãªå¹æã®ããã«ä»ã®æå¹æåãå«æ
ããŠãããã æ¬çºæãäžèšå®æœäŸã«ãã詳现ã«èª¬æããã å®æœäŸïŒïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«âïŒïŒïŒïŒïŒâã
ãªã¢ãžã³âïŒâã€ã«ïŒå°¿çŽ æ°ŽïŒmläžã®äºç¡é žãããªãŠã ïŒïœã®æº¶æ¶²ã0°ãª
ããïŒâã§ãâïŒïŒâã¢ããããšãã«ã¹ã«ãã
ã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«âïŒïŒïŒïŒ
ïŒâããªã¢ãžã³âïŒâã€ã«ïŒå°¿çŽ 3.4ïœãæ°·10ïœ
ããã³36ïŒ å¡©é žïŒmlã®æ··åç©ã«ãã€ããå ããã
åå¿æ··åç©ãïŒâã§ïŒæéæªæããåŸãæ°ŽïŒmläž
ã®ããã«ãŠã ã¢ãžãïŒïœã®æº¶æ¶²ã滎å ãã次ãã§
枩床ã20âã«äžæãããŸã§æŸçœ®ãããåå¿æ··åç©
ãå¡©åã³ã¡ãã¬ã³å20mlã§ïŒåæœåºãããæ··åã
ãææ©çžã也ç¥ãã次ãã§æ¿çž®ãããæ®éšã®åçµ
æ¶ã«ãã175âã§å解ãããâïŒïŒâã¢ãžãããš
ãã«ã¹ã«ããã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡
ãã«âïŒïŒïŒïŒïŒâããªã¢ãžã³âïŒâã€ã«ïŒå°¿çŽ
1.0ïœãåŸãã å®æœäŸïŒïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒïŒïŒâãžã¡ããã·ããªããžã³âïŒâã€ã«ïŒ
å°¿çŽ æ°ŽïŒmläžã®äºç¡é žãããªãŠã 1.0ïœã®æº¶æ¶²ãïŒ
âãªããïŒâã§ãâïŒïŒâã¢ããããšãã«ã¹ã«
ããã«ïŒâNâ²âïŒãžã¡ããã·ããªããžã³âïŒâã€
ã«ïŒå°¿çŽ 3.5ïœãæ°·10ïœããã³36ïŒ å¡©é žïŒmlã®æ··
åç©ã«ãã€ããå ãããåå¿æ··åç©ãïŒâã§ïŒæ
éæªæããåŸãæ°ŽïŒmläžã®ãããªãŠã ã¢ãžãïŒïœ
ã®æº¶æ¶²ã滎å ãã次ãã§æž©åºŠã20床ã«äžæãããŸ
ã§æŸçœ®ãããåå¿æ··åç©ãå¡©åã¡ãã¬ã³å20mlã§
ïŒåæœåºãããæ··åããææ©å±€ã也ç¥ãã次ãã§
æ¿çž®ãããæ®éšã®åçµæ¶ã«ãã190âã§å解ãã
âïŒã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²âïŒïŒïŒïŒ
âãžã¡ããã·ããªããžã³âïŒâã€ã«ïŒå°¿çŽ 0.52ïœ
ãåŸãã å®æœäŸïŒïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããžã³âïŒâ
ã€ã«ïŒå°¿çŽ æ°ŽïŒmläžã®äºç¡é žãããªãŠã ïŒïœã®æº¶æ¶²ã0°ãª
ããïŒâã§ãâïŒïŒâã¢ããããšãã«ã¹ã«ãã
ã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããž
ã³âïŒâã€ã«ïŒå°¿çŽ 3.4ïœãæ°·10ïœããã³36ïŒ å¡©
é žïŒmlã®æ··åç©ã«ãã€ããå ãããåå¿æ··åç©ã
ïŒâã§ïŒæéæªæããåŸãæ°ŽïŒmläžã®ããã«ãŠã
ã¢ãžãïŒïœã®æº¶æ¶²ã滎å ãã次ãã§æž©åºŠã20âã«
äžæãããŸã§æŸçœ®ãããåå¿æ··åç©ãå¡©åã¡ãã¬
ã³å20mlã§ïŒåæœåºãããæ··åããææ©çžã也ç¥
ãã次ãã§æ¿çž®ãããæ®éšã®åçµæ¶ã«ãã178°ãª
ãã179âã§å解ããâïŒïŒâã¢ãžãããšãã«ã¹
ã«ããã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«ã
ãªããžã³âïŒâã€ã«ïŒå°¿çŽ 0.85ïœãåŸãã å®æœäŸïŒïŒ âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²â
ïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããžã³âïŒâ
ã€ã«ïŒå°¿çŽ ãžãªããµã³10mläžã®ïŒ®âïŒïŒâã¡ããã·âïŒâ
ã¡ãã«ããªããžã³âïŒâã€ã«ïŒããšãã«ã«ã«ãã¡
ãŒã2.9ïœã®æº¶æ¶²ã20°ãªãã25âã§ããžãªããµã³
20mläžã®ïŒâã¢ãžãããšãã«ã¹ã«ãã³ã¢ããïŒïœ
ããã³ïŒïŒïŒâãžã¢ã¶ãã·ã¯ã ïŒïŒïŒïŒïŒïŒïŒ
ãŠã³ãã»ã³âïŒ 1.6mlã®æº¶æ¶²ã«æ»Žå ããã次ã
ã§åå¿æ··åç©ãæ°Ž200mläžã«æå ¥ãã次ãã§æ°Žæ§
æ··åç©ãå¡©é žã«ãã€ãŠé žæ§åãpH2ãšãããæ²æ®¿
ããçæç©ãåé¢ããé ¢é žãšãã«ã§æž æµãã次ã
ã§ä¹Ÿç¥ããŠãèç¹192âã®ç·å³ããã³ãçµæ¶ã®åœ¢
æ ã§ïŒ®âïŒïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâ
Nâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«ããªããžã³âïŒ
âã€ã«ïŒå°¿çŽ ãåç67ïŒ ã§åŸãã äžèšè¡šäžã«èšèŒãããäžéäœããã³æçµçæç©
ã¯åæ§ã®æ¹æ³ã«ãã€ãŠåŸãããã
ãè¡šã
ãè¡šã
ãè¡šã
補å€äŸ
å®æœäŸïŒïŒ
åŒã§è¡šããããååç©ã«å¯Ÿãã補å€äŸïŒããŒ
ã»ã³ãã¯ééåºæºïŒ
ã»ã³ãã¯ééåºæºïŒ
ãè¡šã
æå¹æåãå©å€ãšãšãã«ååã«æ··åããåŸã該
æ··åç©ãé©åœãªãã«ã§è¯ã磚ç ãããšãæ°Žã§åžé
ããŠææã®æ¿åºŠã®æžæ¿æ¶²ãåŸãããšã®ã§ããæ°Žå
å€ãåŸãããã
æ··åç©ãé©åœãªãã«ã§è¯ã磚ç ãããšãæ°Žã§åžé
ããŠææã®æ¿åºŠã®æžæ¿æ¶²ãåŸãããšã®ã§ããæ°Žå
å€ãåŸãããã
ãè¡šã
ãè¡šã
ãè¡šã
æå¹æåãæ
äœãšãšãã«æ··åããé©åœãªãã«äž
ã§ãã®æ··åç©ã磚ç ããããšã«ããããã®ãŸãŸäœ¿
çšããããšã®ã§ããç²æ«ãåŸãã
ã§ãã®æ··åç©ã磚ç ããããšã«ããããã®ãŸãŸäœ¿
çšããããšã®ã§ããç²æ«ãåŸãã
ãè¡šã
æå¹æåãå©å€ãšãšãã«æ··åã»ç£šç ããç¶ããŠ
ãã®æ··åç©ãæ°Žã§æ¹¿ãããæ··åç©ãæŒãåºãã空
æ°æµäžã§ä¹Ÿç¥ãããã ïœ è¢«èŠç²å€ åŒã®ååç© ïŒïŒ ãããšãã¬ã³ã°ãªã³ãŒã«200 ïŒïŒ ã«ãªãªã³ 94ïŒ çŽ°ããç²ç ããæå¹æåãããããµãŒäžã§ãã
ãªãšãã¬ã³ã°ãªã³ãŒã«ã§æ¹¿ããããã«ãªãªã³ã«å
äžã«æœçšããããã®æ¹æ³ã«ããéç²å¡µæ§éèŠç²å€
ãåŸãããã
ãã®æ··åç©ãæ°Žã§æ¹¿ãããæ··åç©ãæŒãåºãã空
æ°æµäžã§ä¹Ÿç¥ãããã ïœ è¢«èŠç²å€ åŒã®ååç© ïŒïŒ ãããšãã¬ã³ã°ãªã³ãŒã«200 ïŒïŒ ã«ãªãªã³ 94ïŒ çŽ°ããç²ç ããæå¹æåãããããµãŒäžã§ãã
ãªãšãã¬ã³ã°ãªã³ãŒã«ã§æ¹¿ããããã«ãªãªã³ã«å
äžã«æœçšããããã®æ¹æ³ã«ããéç²å¡µæ§éèŠç²å€
ãåŸãããã
ãè¡šã
ãè¡šã
现ããç²ç ããæå¹æåãå©å€ãšãšãã«åäžã«
æ··åããæ°Žã§åžéããããšã«ããææã®æ¿åºŠã®æž
æ¿æ¶²ãåŸãããšã®ã§ããæžæ¿æ¶²æ§æ¿åç©ãåŸãã
ãã ïœ å¡©ã®æº¶æ¶² åŒã®ååç© ïŒïŒ ã€ãœãããã«ã¢ãã³ ïŒïŒ ãªã¯ãã«ããšããŒã«ããªãšãã¬ã³ã°ãªã³ãŒã«ãš
ãŒãã«ïŒãšãã¬ã³ãªãã·ã78ã¢ã«ïŒ ïŒïŒ æ°Ž 91ïŒ çç©è©ŠéšäŸ å®æœäŸïŒïŒçºèœåã®é€èäœçš ãã©ã¹ããã¯å®¹åšãçºæ³¡ããŒãããŠã©ã€ãïŒå¯
床ïŒ0.135ïœïŒcm3ïŒæ°Žåžå容éïŒ0.5651ïŒïŒïŒã§
æºããã70.8ppmã®æ¿åºŠã§è©Šéšååç©ãå«ãè±ã€
ãªã³æ°Žäžã®æ°Žæ§ä¹³å€ã«ããéåžçæ§ããŒãããŠã©
ã€ãã飜åãããåŸãäžèšæ€ç©ã®çš®åããã®è¡šé¢
ã«æãïŒãã¹ãã«ããŠã ãªãã€ã·ããªã¹
ïŒNasturtium officinalisïŒãã¢ã°ãã¹ãã¹ããã€
ã¹ïŒAgrostis tenuisïŒïŒã¹ãã©ãªã¢ ã¡ãã€ã¢
ïŒStellaria mediaïŒããã³ãžã®ã¿ãªã¢ãµã³ã°ã€ã
ã«ã€ã¹ïŒDigitaria sanguinalisïŒã次ãã§å®¹åšã
20âãç §å°çŽ20ã«ã¯ã¹ããã³çžå¯Ÿæ¹¿åºŠ70ïŒ ã®æ°å
宀äžã«ä¿æãããïŒæ¥ãªããïŒæ¥ã®çºèœæã®éã
å±éšçãªæ¹¿åºŠãå¢å ãããããã«å ééæ§ç©è³ªã§
ãããããããŠè±ã€ãªã³æ°Žã§çæ°ŽãããïŒæ¥ç®ã®
åŸãåžè²©ã®æ¶²äœè¥æïŒGreenzit ïŒã®0.5ïŒ ãã
ã®æ°Žã«å ãããæçš®åŸ12æ¥ç®ã«è©Šéšçµæãè©äŸ¡
ããããæ€ç©ã«å¯Ÿããäœçšãäžèšã®ççŽã«åŸã€ãŠ
è©äŸ¡ããïŒ ïŒïŒæ€ç©ãçºèœããªãããŸãã¯å šãæ¯ãã ïŒãïŒïŒéåžžã«èããäœçš ïŒãïŒïŒäžãããã®äœçš ïŒãïŒïŒåŒ±ãäœçš ïŒïŒå šãäœçšãªãïŒæªåŠçã®å¯Ÿç §ç©ãšåçïŒã çºèœåã®äœçšïŒ è©Šéšååç©ä¹³å€ã®æ¿åºŠïŒ70.8ppm
æ··åããæ°Žã§åžéããããšã«ããææã®æ¿åºŠã®æž
æ¿æ¶²ãåŸãããšã®ã§ããæžæ¿æ¶²æ§æ¿åç©ãåŸãã
ãã ïœ å¡©ã®æº¶æ¶² åŒã®ååç© ïŒïŒ ã€ãœãããã«ã¢ãã³ ïŒïŒ ãªã¯ãã«ããšããŒã«ããªãšãã¬ã³ã°ãªã³ãŒã«ãš
ãŒãã«ïŒãšãã¬ã³ãªãã·ã78ã¢ã«ïŒ ïŒïŒ æ°Ž 91ïŒ çç©è©ŠéšäŸ å®æœäŸïŒïŒçºèœåã®é€èäœçš ãã©ã¹ããã¯å®¹åšãçºæ³¡ããŒãããŠã©ã€ãïŒå¯
床ïŒ0.135ïœïŒcm3ïŒæ°Žåžå容éïŒ0.5651ïŒïŒïŒã§
æºããã70.8ppmã®æ¿åºŠã§è©Šéšååç©ãå«ãè±ã€
ãªã³æ°Žäžã®æ°Žæ§ä¹³å€ã«ããéåžçæ§ããŒãããŠã©
ã€ãã飜åãããåŸãäžèšæ€ç©ã®çš®åããã®è¡šé¢
ã«æãïŒãã¹ãã«ããŠã ãªãã€ã·ããªã¹
ïŒNasturtium officinalisïŒãã¢ã°ãã¹ãã¹ããã€
ã¹ïŒAgrostis tenuisïŒïŒã¹ãã©ãªã¢ ã¡ãã€ã¢
ïŒStellaria mediaïŒããã³ãžã®ã¿ãªã¢ãµã³ã°ã€ã
ã«ã€ã¹ïŒDigitaria sanguinalisïŒã次ãã§å®¹åšã
20âãç §å°çŽ20ã«ã¯ã¹ããã³çžå¯Ÿæ¹¿åºŠ70ïŒ ã®æ°å
宀äžã«ä¿æãããïŒæ¥ãªããïŒæ¥ã®çºèœæã®éã
å±éšçãªæ¹¿åºŠãå¢å ãããããã«å ééæ§ç©è³ªã§
ãããããããŠè±ã€ãªã³æ°Žã§çæ°ŽãããïŒæ¥ç®ã®
åŸãåžè²©ã®æ¶²äœè¥æïŒGreenzit ïŒã®0.5ïŒ ãã
ã®æ°Žã«å ãããæçš®åŸ12æ¥ç®ã«è©Šéšçµæãè©äŸ¡
ããããæ€ç©ã«å¯Ÿããäœçšãäžèšã®ççŽã«åŸã€ãŠ
è©äŸ¡ããïŒ ïŒïŒæ€ç©ãçºèœããªãããŸãã¯å šãæ¯ãã ïŒãïŒïŒéåžžã«èããäœçš ïŒãïŒïŒäžãããã®äœçš ïŒãïŒïŒåŒ±ãäœçš ïŒïŒå šãäœçšãªãïŒæªåŠçã®å¯Ÿç §ç©ãšåçïŒã çºèœåã®äœçšïŒ è©Šéšååç©ä¹³å€ã®æ¿åºŠïŒ70.8ppm
ãè¡šã
âïŒè©Šéšãã
å®æœäŸïŒïŒçºèœåŸã®é€èäœçšïŒæ¥è§ŠäœçšïŒ å€æ°ã®éèããã³æ œå¹æ€ç©ïŒååèæ€ç©ããã³
ååèæ€ç©ã®äž¡æ¹ãå«ããïŒã«ãçºèœåŸïŒâãªã
ãïŒâèæã«ïŒKga.i.ïŒha ã®æœçšæ¯çã§è©Šéšå
åç©ã®æ°Žæ§æžæ¿æ¶²ãåŽé§ãã次ãã§24°ãªãã26
âããã³çžå¯Ÿæ¹¿åºŠ45ãªãã60ïŒ ã§ä¿æãããåŠç
åŸ15æ¥ç®ã«ãçºèœåã®è©Šéšã«ãããå Žåãšåãç
çŽã䜿çšããŠè©äŸ¡ããã å®æœäŸïŒïŒç±åž¯éäœã®çé·é²æ¢ è©Šéšæ€ç©ãã»ã³ããã»ã ãã«ããšãª
ïŒCentrosema plumieriïŒããã³ã»ã³ããã»ãã
ãã¹ã»ã³ã¹ïŒCentrosma plumieriïŒããå åçé·
ãããŸã§æ œå¹ãã次ãã§60cmã®é«ããŸã§åã蟌
ããïŒæ¥åŸã«ããã®æ€ç©ã«è©Šéšååç©ã®æ°Žæ§ä¹³å€
ãåŽé§ãããè©Šéšæ€ç©ããçžå¯Ÿæ¹¿åºŠ70ïŒ ããã³æ¯
æ¥14æé6000ã«ã¯ã¹ã®äººå£å ç·äžãæŒã®æž©åºŠ27â
ããã³å€ã®æž©åºŠ21âã§ä¿æãããæœçšåŸïŒé±éç®
ã«ãå¯Ÿç §ç©ãšæ¯ã¹ãæ°ããªçé·ã®ééã調ã¹ãã
ããŠæ€ç©æ¯æ§ã決ããããšã«ããè©Šéšãè©äŸ¡ã
ãã æ¬è©Šéšã«ãããŠãè©Šéšæ€ç©ã«æå·ãçããããš
ãªããåŒã§è¡šããããååç©ã«ããåŠçããæ€
ç©ã®æ°ããªçé·ã¯èããæžå°ããããšãå€ã€ã
ïŒæªåŠçã®å¯Ÿç §æ€ç©ã®æ°ããªçé·ã®20ïŒ ããå°ãª
ããïŒã å®æœäŸïŒïŒå€§è±ã®çé·æå¶ âãã«ã¯ïŒHerkïŒâçš®ã®å€§è±ããã©ã¹ããã¯å®¹
åšå ã®åïŒæ³¥çïŒç æ··åç©ïŒïŒïŒïŒïŒïŒïŒäžã«æ
ãããã®å®¹åšãæ°å宀äžã«çœ®ãããããŠæž©åºŠã
å ãè¥æã®æ·»å ããã³çµŠæ°Žãæé©ã«å¶åŸ¡ããããš
ã«ããçŽïŒé±éåŸã«æ€ç©ã¯ïŒãªããïŒæã®äžã€è
ç¶èæã«çé·ããã次ãã§åŒã§è¡šããããåå
ç©ã®æ°Žæ§æ··åç©ãååã«æ¹¿ããŸã§åŽé§ãããæœçš
æ¯çã¯ãã¯ã¿ãŒã«åœã100ïœa.i.ã«çžåœãããæœçš
åŸçŽïŒé±éç®ã«è©äŸ¡ãè¡ããæªåŠçã®å¯Ÿç §ç©ãšæ¯
ã¹ãŠãåŒã§è¡šããããååç©ã¯çé·ããè¥æã
ãåç©«ãããé·è§æã®æ°ããã³ééãèããå¢å
ãããã å®æœäŸ10ïŒç©ç©ã®çé·é²æ¢ å€å€§éºŠããã«ããŠã ãã«ã¬ã¬ïŒHordeum
vulgareïŒãããã³å€ã©ã€éºŠãã»ã«ã¬ïŒSecaleïŒã
ã枩宀å ã®ãã€ã©ã¹ããã¯ããŒã«å ã®æ» èããå
å£äžã«æãã次ãã§å¿ èŠãªãã°æ°Žããããæçš®åŸ
çŽ21æ¥ç®ã«ãåŒã§è¡šããããååç©ã®æ°Žæ§åŽé§
æ··åç©ã«ããç©ç©ã®è¥æãåŠçãããæ¿åºŠã¯ãã¯
ã¿ãŒã«åœãæå¹æå100ïœã«çžåœãããç©ç©ã®ç
é·ã®è©äŸ¡ã¯æœçšåŸ21æ¥ç®ã«è©äŸ¡ãããæªåŠçã®å¯Ÿ
ç §ç©ãšã®æ¯èŒã«ãããåŒã§è¡šããããååç©ã§
åŠçããç©ç©ã®çé·ã¯ååã«æžå°ãïŒå¯Ÿç §ç©ã®60
ãªãã90ïŒ ïŒããããŠèã®çŽåŸã¯ããªãã®å Žåã«
ãããŠå¢å ããã å®æœäŸ11ïŒç§èã®çé·é²æ¢ ããªãŠã ãã¬ãïŒLolium pereneïŒããã¢ã
ã©ãã³ã·ã¹ïŒPoa pratensisïŒïŒããšã¹ãã«ãªãã
ïŒFestuca ovinaïŒããã³ã·ããã³ ãã¯ããã³
ïŒCynodon dactylonïŒçš®ã®ç§èã®çš®ã枩宀å ã®ã
åïŒæ³¥çïŒç æ··åç©ïŒïŒïŒïŒïŒïŒïŒã«ãã€ãŠæºã
ãããã©ã¹ããã¯ç¿äžã«æãã次ãã§å¿ èŠãªãã°
æ°Žããããçºèœããç§èãæ¯é±ïŒcmäžã«åã蟌
ã¿ããããŠæçš®åŸçŽ50æ¥ç®ã§æåŸã®å蟌ã¿ã®ïŒæ¥
åŸã«åŒã§è¡šããããååç©ã®æ°Žæ§åŽé§æ··åç©ã
åŽé§ãããè©Šéšååç©ã®æ¿åºŠã¯ãã¯ã¿ãŒã«åœã
100ïœa.i.ãŸã§ã®æœçšæ¯çã«çžåœãããç§èã®çé·
ã¯æœçšåŸ21æ¥ç®ã«è©äŸ¡ãããåŒã§è¡šããããå
åç©ã¯æªåŠçã®å¯Ÿç §ç©ãšæ¯ã¹ãŠ10ãªãã30ïŒ ã®ç¯
å²ã«ãããŠæ°ããªçé·ãæžå°ãããå¹æã瀺ãã
å®æœäŸïŒïŒçºèœåŸã®é€èäœçšïŒæ¥è§ŠäœçšïŒ å€æ°ã®éèããã³æ œå¹æ€ç©ïŒååèæ€ç©ããã³
ååèæ€ç©ã®äž¡æ¹ãå«ããïŒã«ãçºèœåŸïŒâãªã
ãïŒâèæã«ïŒKga.i.ïŒha ã®æœçšæ¯çã§è©Šéšå
åç©ã®æ°Žæ§æžæ¿æ¶²ãåŽé§ãã次ãã§24°ãªãã26
âããã³çžå¯Ÿæ¹¿åºŠ45ãªãã60ïŒ ã§ä¿æãããåŠç
åŸ15æ¥ç®ã«ãçºèœåã®è©Šéšã«ãããå Žåãšåãç
çŽã䜿çšããŠè©äŸ¡ããã å®æœäŸïŒïŒç±åž¯éäœã®çé·é²æ¢ è©Šéšæ€ç©ãã»ã³ããã»ã ãã«ããšãª
ïŒCentrosema plumieriïŒããã³ã»ã³ããã»ãã
ãã¹ã»ã³ã¹ïŒCentrosma plumieriïŒããå åçé·
ãããŸã§æ œå¹ãã次ãã§60cmã®é«ããŸã§åã蟌
ããïŒæ¥åŸã«ããã®æ€ç©ã«è©Šéšååç©ã®æ°Žæ§ä¹³å€
ãåŽé§ãããè©Šéšæ€ç©ããçžå¯Ÿæ¹¿åºŠ70ïŒ ããã³æ¯
æ¥14æé6000ã«ã¯ã¹ã®äººå£å ç·äžãæŒã®æž©åºŠ27â
ããã³å€ã®æž©åºŠ21âã§ä¿æãããæœçšåŸïŒé±éç®
ã«ãå¯Ÿç §ç©ãšæ¯ã¹ãæ°ããªçé·ã®ééã調ã¹ãã
ããŠæ€ç©æ¯æ§ã決ããããšã«ããè©Šéšãè©äŸ¡ã
ãã æ¬è©Šéšã«ãããŠãè©Šéšæ€ç©ã«æå·ãçããããš
ãªããåŒã§è¡šããããååç©ã«ããåŠçããæ€
ç©ã®æ°ããªçé·ã¯èããæžå°ããããšãå€ã€ã
ïŒæªåŠçã®å¯Ÿç §æ€ç©ã®æ°ããªçé·ã®20ïŒ ããå°ãª
ããïŒã å®æœäŸïŒïŒå€§è±ã®çé·æå¶ âãã«ã¯ïŒHerkïŒâçš®ã®å€§è±ããã©ã¹ããã¯å®¹
åšå ã®åïŒæ³¥çïŒç æ··åç©ïŒïŒïŒïŒïŒïŒïŒäžã«æ
ãããã®å®¹åšãæ°å宀äžã«çœ®ãããããŠæž©åºŠã
å ãè¥æã®æ·»å ããã³çµŠæ°Žãæé©ã«å¶åŸ¡ããããš
ã«ããçŽïŒé±éåŸã«æ€ç©ã¯ïŒãªããïŒæã®äžã€è
ç¶èæã«çé·ããã次ãã§åŒã§è¡šããããåå
ç©ã®æ°Žæ§æ··åç©ãååã«æ¹¿ããŸã§åŽé§ãããæœçš
æ¯çã¯ãã¯ã¿ãŒã«åœã100ïœa.i.ã«çžåœãããæœçš
åŸçŽïŒé±éç®ã«è©äŸ¡ãè¡ããæªåŠçã®å¯Ÿç §ç©ãšæ¯
ã¹ãŠãåŒã§è¡šããããååç©ã¯çé·ããè¥æã
ãåç©«ãããé·è§æã®æ°ããã³ééãèããå¢å
ãããã å®æœäŸ10ïŒç©ç©ã®çé·é²æ¢ å€å€§éºŠããã«ããŠã ãã«ã¬ã¬ïŒHordeum
vulgareïŒãããã³å€ã©ã€éºŠãã»ã«ã¬ïŒSecaleïŒã
ã枩宀å ã®ãã€ã©ã¹ããã¯ããŒã«å ã®æ» èããå
å£äžã«æãã次ãã§å¿ èŠãªãã°æ°Žããããæçš®åŸ
çŽ21æ¥ç®ã«ãåŒã§è¡šããããååç©ã®æ°Žæ§åŽé§
æ··åç©ã«ããç©ç©ã®è¥æãåŠçãããæ¿åºŠã¯ãã¯
ã¿ãŒã«åœãæå¹æå100ïœã«çžåœãããç©ç©ã®ç
é·ã®è©äŸ¡ã¯æœçšåŸ21æ¥ç®ã«è©äŸ¡ãããæªåŠçã®å¯Ÿ
ç §ç©ãšã®æ¯èŒã«ãããåŒã§è¡šããããååç©ã§
åŠçããç©ç©ã®çé·ã¯ååã«æžå°ãïŒå¯Ÿç §ç©ã®60
ãªãã90ïŒ ïŒããããŠèã®çŽåŸã¯ããªãã®å Žåã«
ãããŠå¢å ããã å®æœäŸ11ïŒç§èã®çé·é²æ¢ ããªãŠã ãã¬ãïŒLolium pereneïŒããã¢ã
ã©ãã³ã·ã¹ïŒPoa pratensisïŒïŒããšã¹ãã«ãªãã
ïŒFestuca ovinaïŒããã³ã·ããã³ ãã¯ããã³
ïŒCynodon dactylonïŒçš®ã®ç§èã®çš®ã枩宀å ã®ã
åïŒæ³¥çïŒç æ··åç©ïŒïŒïŒïŒïŒïŒïŒã«ãã€ãŠæºã
ãããã©ã¹ããã¯ç¿äžã«æãã次ãã§å¿ èŠãªãã°
æ°Žããããçºèœããç§èãæ¯é±ïŒcmäžã«åã蟌
ã¿ããããŠæçš®åŸçŽ50æ¥ç®ã§æåŸã®å蟌ã¿ã®ïŒæ¥
åŸã«åŒã§è¡šããããååç©ã®æ°Žæ§åŽé§æ··åç©ã
åŽé§ãããè©Šéšååç©ã®æ¿åºŠã¯ãã¯ã¿ãŒã«åœã
100ïœa.i.ãŸã§ã®æœçšæ¯çã«çžåœãããç§èã®çé·
ã¯æœçšåŸ21æ¥ç®ã«è©äŸ¡ãããåŒã§è¡šããããå
åç©ã¯æªåŠçã®å¯Ÿç §ç©ãšæ¯ã¹ãŠ10ãªãã30ïŒ ã®ç¯
å²ã«ãããŠæ°ããªçé·ãæžå°ãããå¹æã瀺ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ æ¬¡åŒïŒ ãåã ãåŒäžã ã¯çªçŽ ååãŸãã¯ã¡ãã³æ©ãè¡šããã R1ã¯æ°ŽçŽ ååãããã²ã³ååããããåºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒâNR4R5 ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šãããã
ã§è¡šããããâã¢ãžãããšãã«ã¹ã«ããã«â
Nâ²âããªããžãã«âãŸãã¯âNâ²âããªã¢ãžãã«
å°¿çŽ ããã³ãã®å¡©ã ïŒ äžèšåŒã«ãããŠãã¢ãžãåºãã¹ã«ããã«åº
ã«å¯ŸããŠïŒâäœã«åšãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒ
ã®ååç©ã ïŒ äžèšåŒã«ãããŠãR1ãæ°ŽçŽ ååè¡šããç¹
èš±è«æ±ã®ç¯å²ïŒé èšèŒã®ååç©ã ïŒ äžèšåŒã«ãããŠãR2ããã³R3ãå ±ã«ççŽ
ååïŒåããå€ããå«ãŸãªãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®ååç©ã ïŒ äžèšåŒïŒã«ãããŠãR2ããã³R3ãã¡ãã«åºã
ã¡ããã·åºããžã¡ãã«ã¢ããåºããžãã«ãªãã¡ã
ãã·åºããã³ïŒïŒïŒïŒïŒâããªãã«ãªããšããã·
åºãããªã矀ããéžæãããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
é èšèŒã®ååç©ã ïŒ äžèšåŒã«ãããŠãR1ãççŽ ååæ°ïŒãªã
ãïŒã®ã¢ã«ã³ãã·ã«ã«ããã«åºãè¡šããç¹èš±è«æ±
ã®ç¯å²ïŒé èšèŒã®ååç©ã ïŒ äžèšåŒã«ãããŠãR1ãã¹ã«ããã«åºã«å¯Ÿ
ããŠïŒâäœã«åšãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã«ã«ããã«åºãè¡šããããããŠR2ããã³R3
ãã¡ãã«åºãã¡ããã·åºããžãã«ãªãã¡ããã·
åºããžã¡ãã«ã¢ããåºããã³ïŒïŒïŒïŒïŒâããªã
ã«ãªããšããã·åºãããªã矀ããéžæããããã
ãŠå ±ã«ççŽ ååïŒåããå€ããå«ãŸãªãç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒé èšèŒã®ååç©ã ïŒ R2ããã³R3ãã¡ãã«åºãã¡ããã·åºãŸãã¯
ãžãã«ãªãã¡ããã·åºãè¡šããç¹èš±è«æ±ã®ç¯å²ç¬¬
ïŒé èšèŒã®ååç©ã ïŒ äžèšåŒãâïŒïŒâã¡ããã·ã«ã«ããã«â
ïŒâã¢ãžãããšãã«ã¹ã«ããã«ïŒâNâ²âïŒïŒâãž
ãã«ãªãã¡ããã·âïŒâã¡ãã«ããªããžã³âïŒâ
ã€ã«ïŒå°¿çŽ ãè¡šããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®
ååç©ã ïŒïŒ äžèšåŒãâïŒïŒâã¢ãžãããšãã«ã¹ã«
ããã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«âïŒïŒ
ïŒïŒïŒâããªã¢ãžã³âïŒâã€ã«ïŒå°¿çŽ ãè¡šããç¹
èš±è«æ±ã®ç¯å²ç¬¬ïŒé èšèŒã®ååç©ã ïŒïŒ äžèšåŒãâïŒïŒâã¢ãžãããšãã«ã¹ã«
ããã«ïŒâNâ²âïŒïŒâã¡ããã·âïŒâã¡ãã«ããª
ããžã³âïŒâã€ã«ïŒå°¿çŽ ãè¡šããç¹èš±è«æ±ã®ç¯å²
第ïŒé èšèŒã®ååç©ã ïŒïŒ 次åŒïŒ ãåã ãåŒäžã R1ã¯æ°ŽçŽ ååãããã²ã³ååããããåºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããããã§è¡šããããã¢ãž
ãããšãã«ã¹ã«ãã³ã¢ããã次åŒïŒ ãåŒã ãåŒäžã ã¯çªçŽ ååãŸãã¯ã¡ãã³æ©ãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒ âNR4R5 ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šããã
ãã㊠ã¯ããšãã«åºãã¢ã«ãã«åºãŸãã¯çœ®æããšã
ã«åºãè¡šããããã§è¡šããããâããªããžãã«
âãŸãã¯ïŒ®âããªã¢ãžãã«ã«ã«ãã¡ãŒããšå¡©åºã®
ååšäžã§åå¿ããããããŠããææãªãã°åŸãã
ãã¹ã«ããã«å°¿çŽ ããã®å¡©ã«å€ããããšãããªã
次åŒïŒ ãåã ãåŒäžããR1ãR2ããã³R3ã¯äžèšåŒãã
ã³åŒã«ãããŠå®çŸ©ããããã®ãšåãæå³ãè¡šã
ãããã§è¡šããããååç©ã®è£œé æ¹æ³ã ïŒïŒ äžèšåŒã§è¡šããããã¹ã«ããã«å°¿çŽ ãã¢
ãã³ãã¢ã«ã«ãªéå±æ°Žé žåç©ãŸãã¯ã¢ã«ã«ãªåé¡
éå±æ°Žé žåç©ãŸãã¯ç¬¬åã¢ã³ã¢ããŠã å¡©åºãšåå¿
ãããããšãããªãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒ
ã®åŒã§è¡šããããååç©ã®ä»å å¡©ã®è£œé æ¹æ³ã ïŒïŒ 次åŒïŒ ãåã ãåŒäžã ã¯çªçŽ ååãŸãã¯ã¡ãã³æ©ãè¡šããã R1ã¯æ°ŽçŽ ååãããã²ã³ååããããåºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒâNR4R5ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šãããã
ã§è¡šããããã¢ããã¹ã«ããã«å°¿çŽ ããžã¢ãŸå
ãããããŠå ¬ç¥æ¹æ³ã«ããã¢ãžãåºãå°å ¥ããã
ããŠææããªãã°åŸãããã¹ã«ããã«å°¿çŽ ããã®
å¡©ã«å€ããããšãããªã次åŒïŒ ãåã ãåŒäžãïŒR1ïŒR2ããã³R3ã¯äžèšåŒã«ã
ããŠå®çŸ©ããããã®ãšåãæå³ãè¡šããããã§è¡š
ããããååç©ã®è£œé æ¹æ³ã ïŒïŒ äžèšåŒã§è¡šããããã¹ã«ããã«å°¿çŽ ãã¢
ãã³ãã¢ã«ã«ãªéå±æ°Žé žåç©ãŸãã¯ã¢ã«ã«ãªåé¡
éå±æ°Žé žåç©ãŸãã¯ç¬¬åã¢ã³ã¢ããŠã å¡©åºãšåå¿
ãããããšãããªãç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒ
ã®åŒã§è¡šããããååç©ã®ä»å å¡©ã®è£œé æ¹æ³ã ïŒïŒ æ äœããã³ïŒãŸãã¯ä»ã®å©å€ãšå ±ã«æ¬¡åŒ
ïŒ ãåã ãåŒäžã ã¯çªçŽ ååãŸãã¯ã¡ãã³æ©ãè¡šããã R1ã¯æ°ŽçŽ ååãããã²ã³ååããããåºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒâNR4R5ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šãããã
ã§è¡šããããâã¢ãžãããšãã«ã¹ã«ããã«â
Nâ²âããªã¢ãžãã«âãŸãã¯âNâ²âããªããžãã«
å°¿çŽ ã®ãã¡å°ãªããšãïŒã€ãå«ãé€èå€çµæç©ã ïŒïŒ 次åŒïŒ ãåã ãåŒäžã ã¯çªçŽ ååãŸãã¯ã¡ãã³æ©ãè¡šããã R1ã¯æ°ŽçŽ ååãããã²ã³ååããããåºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒâNR4R5ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šãããã
ã§è¡šããããâã¢ãžãããšãã«ã¹ã«ããã«â
Nâ²âããªã¢ãžãã«å°¿çŽ ãŸãã¯ââã¢ãžãããš
ãã«ã¹ã«ããã«âNâ²âããªããžãã«å°¿çŽ ããã
ã¯è©²ååç©ãå«ãçµæç©ã䜿çšããããšãããª
ããæãŸãªãæ€ç©ã®çé·ãæå¶ããæ¹æ³ã ïŒïŒ äžèšã«ãããŠåŒã§è¡šããããâã¢ãžã
ããšãã«ã¹ã«ããã«âNâ²âããªã¢ãžãã«å°¿çŽ ãŸ
ãã¯ââã¢ãžãããšãã«ã¹ã«ããã«âNâ²âã
ãªããžãã«å°¿çŽ ãããã¯è©²ååç©ãå«ãçµæç©ã
䜿çšããããšãããªããæçšæ€ç©ã®æ œå¹ã«ãããŠ
çºèœåãŸãã¯çºèœåŸã«éžæçã«éèã®çé·ãæå¶
ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ æ œå¹ãã¹ãæçšæ€ç©ãç ç³ãã³ãç©ç©ãã
ãŠã¢ãã³ã·ãçš²ã倧è±ããã³æ£ã§ããç¹èš±è«æ±ã®
ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ 次åŒïŒ ãåã ãåŒäžã ã¯çªçŽ ååãŸãã¯ã¡ãã³æ©ãè¡šããã R1ã¯æ°ŽçŽ ååãããã²ã³ååããããåºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒâNR4R5ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šãããã
ã§è¡šããããâã¢ãžãããšãã«ã¹ã«ããã«â
Nâ²âããªã¢ãžãã«å°¿çŽ ãŸãã¯ââã¢ãžãããš
ãã«ã¹ã«ããã«âNâ²âããªããžãã«å°¿çŽ ããã
ã¯è©²ååç©ãå«ãçµæç©ã䜿çšããããšãããªã
æ€ç©ã®çé·ãé²æ¢ããæ¹æ³ã ïŒïŒ äžèšã«ãããŠåŒã§è¡šããããâã¢ãžã
ããšãã«ã¹ã«ããã«âNâ²âããªã¢ãžãã«å°¿çŽ ãŸ
ãã¯ïŒ®âã¢ãžãããšãã«ã¹ã«ããã«âNâ²âããª
ããžãã«å°¿çŽ ãããã¯è©²ååç©ãå«ãçµæç©ã䜿
çšããããšãããªããçºèœåã«æœçšããŠïŒèæã
è¶ããæ€ç©ã®çé·ãé²æ¢ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒ
ïŒé èšèŒã®æ¹æ³ã ïŒïŒ çé·ãé²æ¢ãã¹ãæ€ç©ããã¡ç§ã®éäœäœç©
ã§ããç¹èš±è«æ±ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ 次åŒïŒ ãåã ãåŒäžã ã¯çªçŽ ååãŸãã¯ã¡ãã³æ©ãè¡šããã R1ã¯æ°ŽçŽ ååãããã²ã³ååããããåºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒâNR4R5ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šãããã
ã§è¡šããããâã¢ãžãããšãã«ã¹ã«ããã«â
Nâ²âããªã¢ãžãã«âãŸãã¯âNâ²âããªããžãã«
å°¿çŽ ãããã¯è©²ååç©ãå«ãçµæç©ã䜿çšããã
ãšãããªããåç©«éãå¢å ãããããã«æ œå¹æ€ç©
ã®çé·ãæå¶ããæ¹æ³ã ïŒïŒ åç©«ãã¹ãæçšæ€ç©ã倧è±ã§ããç¹èš±è«æ±
ã®ç¯å²ç¬¬ïŒïŒé èšèŒã®æ¹æ³ã ïŒïŒ æ äœããã³ïŒãŸãã¯ä»ã®å©å€ãšå ±ã«æ¬¡åŒ
ïŒ ãåã ãåŒäžã ã¯çªçŽ ååãŸãã¯ã¡ãã³æ©ãè¡šããã R1ã¯æ°ŽçŽ ååãããã²ã³ååããããåºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒ
ãªããïŒã®ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªãã
ïŒã®ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ãã
ã¢ã«ã³ãã·åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ã
ã·ã«ã«ããã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã
ã«ããªåºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹ã«
ãã€ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«ã¹
ã«ããã«åºãŸãã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·ã¢ã«ã³ãã·åºãè¡šããã R2ã¯ççŽ ååæ°ïŒãªããïŒã®ã¢ã«ãã«åºãç
çŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·åºãŸãã¯ççŽ å
åæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·åºãè¡šããã R3ã¯æ°ŽçŽ ååãããã²ã³ååãççŽ ååæ°ïŒ
ãªããïŒã®ã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®
ããã¢ã«ãã«åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³
ãã·åºãççŽ ååæ°ïŒãªããïŒã®ããã¢ã«ã³ãã·
åºãççŽ ååæ°ïŒãªããïŒã®ã¢ã«ã³ãã·ã¢ã«ã³ã
ã·åºãŸãã¯æ¬¡åŒïŒâNR4R5ïŒåŒäžã R4ã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºãè¡šããããã
㊠R5ã¯æ°ŽçŽ ååãã¡ãã«åºããšãã«åºãŸãã¯ã¡
ããã·åºãè¡šãããïŒã§è¡šããããåºãè¡šãããã
ã§è¡šããããâã¢ãžãããšãã«ã¹ã«ããã«â
Nâ²âããªã¢ãžãã«âãŸãã¯âNâ²âããªããžãã«
å°¿çŽ ã®ãã¡å°ãªããšãïŒã€ãå«ãæ€ç©çé·æå¶å€
çµæç©ã
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CH5196/82-0 | 1982-09-01 | ||
CH519682 | 1982-09-01 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5965083A JPS5965083A (ja) | 1984-04-13 |
JPH0587510B2 true JPH0587510B2 (ja) | 1993-12-16 |
Family
ID=4289541
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP58161168A Granted JPS5965083A (ja) | 1982-09-01 | 1983-09-01 | âã¢ãžãããšãã«ã¹ã«ããã«âïœâ²âããªããžãã«âããã³âïœâ²âããªã¢ãžãã«å°¿çŽ ããã®è£œæ³äžŠã³ã«ãã®çšé |
Country Status (6)
Country | Link |
---|---|
US (2) | US4555262A (ja) |
EP (1) | EP0102924B1 (ja) |
JP (1) | JPS5965083A (ja) |
AT (1) | ATE33330T1 (ja) |
CA (1) | CA1223011A (ja) |
DE (1) | DE3376190D1 (ja) |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4555262A (en) * | 1982-09-01 | 1985-11-26 | Ciba-Geigy Corporation | N-Azidophenylsulfonyl-N'-pyrimidinyl ureas |
US4606754A (en) * | 1982-10-28 | 1986-08-19 | E. I. Du Pont De Nemours And Company | Herbicidal ortho-(azinyl)-benzenesulfonamides |
US4693744A (en) * | 1982-10-28 | 1987-09-15 | E. I. Du Pont De Nemours And Company | Herbicidal ortho-(azinyl)-benzenesulfonamides |
US4585470A (en) * | 1984-09-13 | 1986-04-29 | E. I. Du Pont De Nemours And Company | Herbicidal azobenzenesulfonamides |
US6852341B2 (en) * | 2000-10-10 | 2005-02-08 | Auburn University | Azide method and composition for controlling deleterious organisms and for stimulating beneficial organisms |
US6932985B2 (en) * | 2000-10-10 | 2005-08-23 | Auburn University | Azide method and composition for controlling deleterious organisms |
BR0114553A (pt) * | 2000-10-10 | 2003-08-26 | Univ Auburn | Composição, métodos de controle de população de organismo deletérios e liberação de composição pesticida e conjunto |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL7703809A (nl) * | 1976-04-07 | 1977-10-11 | Du Pont | Herbicide sulfonamiden. |
DK401978A (da) * | 1977-10-06 | 1979-04-07 | Du Pont | Herbicide sulfonamider |
US4555262A (en) * | 1982-09-01 | 1985-11-26 | Ciba-Geigy Corporation | N-Azidophenylsulfonyl-N'-pyrimidinyl ureas |
-
1983
- 1983-08-22 US US06/525,365 patent/US4555262A/en not_active Expired - Fee Related
- 1983-08-26 EP EP83810385A patent/EP0102924B1/de not_active Expired
- 1983-08-26 AT AT83810385T patent/ATE33330T1/de not_active IP Right Cessation
- 1983-08-26 DE DE8383810385T patent/DE3376190D1/de not_active Expired
- 1983-08-30 CA CA000435655A patent/CA1223011A/en not_active Expired
- 1983-09-01 JP JP58161168A patent/JPS5965083A/ja active Granted
-
1985
- 1985-08-07 US US06/763,175 patent/US4589912A/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
EP0102924A3 (en) | 1985-05-15 |
EP0102924A2 (de) | 1984-03-14 |
JPS5965083A (ja) | 1984-04-13 |
CA1223011A (en) | 1987-06-16 |
DE3376190D1 (de) | 1988-05-11 |
US4555262A (en) | 1985-11-26 |
EP0102924B1 (de) | 1988-04-06 |
US4589912A (en) | 1986-05-20 |
ATE33330T1 (de) | 1988-04-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
KR910000524B1 (ko) | N-ì늎ì€í¬ë-n'-íŒëŠ¬ë¯žëëì°ë ìì ì ì¡°ë°©ë² | |
US4671819A (en) | N-phenylsulfonyl-N'-triazinylureas | |
KR910005411B1 (ko) | N-ì¹íë ì°ë ìì ì ì¡°ë°©ë² | |
JPH0453861B2 (ja) | ||
JPH0660179B2 (ja) | çž®åïœâ²äžââŒããšãã«ã¹ã«ããã«â²äžââŒïœâ²â²äžââŒããªããžãã«å°¿çŽ ããã³ïœâ²äžââŒããšãã«ã¹ã«ããã«â²äžââŒïœâ²â²äžââŒããªã¢ãžãã«å°¿çŽ ããã®è£œé æ¹æ³ããã³ãã®çšé | |
JPH0680646A (ja) | ããšãã«ã¹ã«ãã³ã¢ãã | |
JPH0469143B2 (ja) | ||
JPS6316383B2 (ja) | ||
US4932997A (en) | N-heterocyclosulfonyl-N'-pyrimidinylureas and N-heterocyclosulfonyl-N'-triazinylureas | |
JPH0625160B2 (ja) | âããšãã«ã¹ã«ããã«âïœâ²âããªããžãã«å°¿çŽ ããã³ïœâããšãã«ã¹ã«ããã«âïœâ²âããªã¢ãžãã«å°¿çŽ ããã®è£œæ³äžŠã³ã«è©²ååç©ãå«ãæ€ç©ã®çé·æå¶å€ | |
US4944793A (en) | N-phenylsulfonyl-N-triazinylureas | |
JPS6222763A (ja) | æ°èŠãªïœâïŒïŒâãã«ãªãããšãã«ïŒâã¢ãŸãªãžã³åã³ãã®è£œé æ¹æ³ã䞊ã³ã«é€èåã³æ€ç©çé·èª¿ç¯çšçµæç© | |
JPS59205369A (ja) | âããšãã«ã¹ã«ããã«âïœâ²âããªããžãã«âããã³âããªã¢ãžãã«å°¿çŽ | |
JPH0587510B2 (ja) | ||
JPS6245228B2 (ja) | ||
US4923995A (en) | Pyridylsulfonamides | |
US4881964A (en) | N-heterocyclosulfonyl-N'-pyrimidinylureas | |
JPH0720960B2 (ja) | æ°èŠã¹ã«ããã«å°¿çŽ ïŒããã³é€èããã³ïŒåã¯çé·èª¿ç¯çšçµæç© | |
JPS6147470A (ja) | âã¢ãªãŒã«ã¹ã«ããã«âïœââããªã¢ãžãã«å°¿çŽ åã³ïœâã¢ãªãŒã«ã¹ã«ããã«âïœââããªããžãã«å°¿çŽ 䞊ã³ã«ãã®è£œé æ¹æ³åã³è©²ååç©ãå«æããçµæç© | |
JPH01308264A (ja) | é€èåã³æ€ç©çé·èª¿ç¯æŽ»æ§ãæããæ°èŠå°¿çŽ èªå°äœ | |
US4927450A (en) | N-heterocyclosulfonyl-n'-pyrimidinylureas | |
US4707177A (en) | Sulfonylureas | |
US4759792A (en) | Phenylsulfonylureas | |
JPS60188374A (ja) | ããšãã«ã¹ã«ãã³ã¢ããèªå°äœããã®è£œæ³åã³ãããå«æããçµæç© | |
JPS61291586A (ja) | âãããã·ã¯ãã¹ã«ããã«âïœââããªããžãã«å°¿çŽ ãïœâãããã·ã¯ãã¹ã«ããã«âïœââããªã¢ãŸãªã«å°¿çŽ åã³ïœâãããã·ã¯ãã¹ã«ããã«âïœââããªã¢ãžãã«å°¿çŽ |