JPH0568555B2 - - Google Patents
Info
- Publication number
- JPH0568555B2 JPH0568555B2 JP59112151A JP11215184A JPH0568555B2 JP H0568555 B2 JPH0568555 B2 JP H0568555B2 JP 59112151 A JP59112151 A JP 59112151A JP 11215184 A JP11215184 A JP 11215184A JP H0568555 B2 JPH0568555 B2 JP H0568555B2
- Authority
- JP
- Japan
- Prior art keywords
- reaction
- squaric acid
- electrolytic
- products
- catholyte
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- PWEBUXCTKOWPCW-UHFFFAOYSA-N squaric acid Chemical compound OC1=C(O)C(=O)C1=O PWEBUXCTKOWPCW-UHFFFAOYSA-N 0.000 claims description 45
- 238000000034 method Methods 0.000 claims description 30
- 239000002904 solvent Substances 0.000 claims description 24
- 239000000047 product Substances 0.000 claims description 22
- 239000000203 mixture Substances 0.000 claims description 18
- 238000006243 chemical reaction Methods 0.000 claims description 17
- 239000003792 electrolyte Substances 0.000 claims description 17
- LRDFRRGEGBBSRN-UHFFFAOYSA-N isobutyronitrile Chemical compound CC(C)C#N LRDFRRGEGBBSRN-UHFFFAOYSA-N 0.000 claims description 15
- -1 aliphatic nitrile Chemical class 0.000 claims description 13
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims description 10
- 229910002091 carbon monoxide Inorganic materials 0.000 claims description 10
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 8
- 239000007795 chemical reaction product Substances 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 238000000926 separation method Methods 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 6
- 239000011777 magnesium Substances 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 238000005119 centrifugation Methods 0.000 claims description 5
- 150000002825 nitriles Chemical class 0.000 claims description 5
- 230000002829 reductive effect Effects 0.000 claims description 5
- 150000003839 salts Chemical class 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 238000010349 cathodic reaction Methods 0.000 claims description 4
- 239000007788 liquid Substances 0.000 claims description 4
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 claims description 4
- KVNRLNFWIYMESJ-UHFFFAOYSA-N butyronitrile Chemical compound CCCC#N KVNRLNFWIYMESJ-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 230000009972 noncorrosive effect Effects 0.000 claims description 3
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 238000009835 boiling Methods 0.000 claims description 2
- 238000007710 freezing Methods 0.000 claims description 2
- 230000008014 freezing Effects 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims description 2
- 238000002048 anodisation reaction Methods 0.000 claims 2
- 239000011541 reaction mixture Substances 0.000 claims 2
- 239000004020 conductor Substances 0.000 claims 1
- 239000012429 reaction media Substances 0.000 claims 1
- 239000011135 tin Substances 0.000 claims 1
- 239000007787 solid Substances 0.000 description 18
- 238000004458 analytical method Methods 0.000 description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 5
- 239000008151 electrolyte solution Substances 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- PWEBUXCTKOWPCW-UHFFFAOYSA-L squarate Chemical compound [O-]C1=C([O-])C(=O)C1=O PWEBUXCTKOWPCW-UHFFFAOYSA-L 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 239000010936 titanium Substances 0.000 description 4
- 229910052719 titanium Inorganic materials 0.000 description 4
- RFFFKMOABOFIDF-UHFFFAOYSA-N Pentanenitrile Chemical compound CCCCC#N RFFFKMOABOFIDF-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000002452 interceptive effect Effects 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- JAMNHZBIQDNHMM-UHFFFAOYSA-N pivalonitrile Chemical compound CC(C)(C)C#N JAMNHZBIQDNHMM-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000007858 starting material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- PKAUICCNAWQPAU-UHFFFAOYSA-N 2-(4-chloro-2-methylphenoxy)acetic acid;n-methylmethanamine Chemical compound CNC.CC1=CC(Cl)=CC=C1OCC(O)=O PKAUICCNAWQPAU-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 125000001047 cyclobutenyl group Chemical class C1(=CCC1)* 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000006798 ring closing metathesis reaction Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B3/00—Electrolytic production of organic compounds
- C25B3/20—Processes
- C25B3/29—Coupling reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/499,575 US4461681A (en) | 1983-05-31 | 1983-05-31 | Process for the preparation of squaric acid by the electrolysis of carbon monoxide in anhydrous aliphatic nitrile solvent media |
US499575 | 1995-07-07 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS605889A JPS605889A (ja) | 1985-01-12 |
JPH0568555B2 true JPH0568555B2 (US20030199744A1-20031023-C00003.png) | 1993-09-29 |
Family
ID=23985794
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP59112151A Granted JPS605889A (ja) | 1983-05-31 | 1984-05-31 | スクアリン酸の製造方法 |
Country Status (9)
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4523980A (en) * | 1984-08-31 | 1985-06-18 | The Halcon Sd Group, Inc. | Process for the recovery of high purity squaric acid |
IE65907B1 (en) * | 1990-02-26 | 1995-11-29 | Lonza Ag | New 3-hydroxy-2-cyclobuten-1-one salts their preparation and use |
US7164507B2 (en) * | 2002-10-25 | 2007-01-16 | Xerox Corporation | Image input terminal |
US7445884B2 (en) * | 2004-06-09 | 2008-11-04 | Konica Minolta Medical & Graphic, Inc. | Photothermographic material, development method and thermal development device thereof |
JP4433918B2 (ja) * | 2004-07-15 | 2010-03-17 | コニカミノルタエムジー株式会社 | 画像形成方法 |
US7220536B2 (en) * | 2004-10-22 | 2007-05-22 | Konica Minolta Medical & Graphic, Inc. | Silver salt photothermographic dry imaging material, thermal development method of the same, and thermal development apparatus for the same |
EP1906235A4 (en) | 2005-07-20 | 2008-07-30 | Konica Minolta Med & Graphic | IMAGE FORMING METHOD |
US7504200B2 (en) | 2007-02-02 | 2009-03-17 | Konica Minolta Medical & Graphic, Inc. | Photothermographic material |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3290350A (en) * | 1960-05-16 | 1966-12-06 | Du Pont | Alpha, alpha, alpha', alpha'-tetramethyl-xylylene diisocyanates and alpha, alpha-dimethylisopropenylbenzyl isocyanates and the preparation thereof from isocyanic acid and olefins |
US3502475A (en) * | 1967-07-13 | 1970-03-24 | Du Pont | Highly adherent coated films and method of producing same |
US3833489A (en) * | 1971-07-24 | 1974-09-03 | R Ercoli | Process for the preparation of squaric acid by reductive cyclotetramerization of carbon monoxide |
JPS5239612A (en) * | 1975-09-22 | 1977-03-28 | Asahi Chem Ind Co Ltd | Process for preparation of unsaturated glycol diesters |
JPS5579883A (en) * | 1978-12-13 | 1980-06-16 | Mitsui Petrochem Ind Ltd | Preparation of 3,4-dialkoxyphenol |
JPS5579882A (en) * | 1978-12-13 | 1980-06-16 | Mitsui Petrochem Ind Ltd | Electrolytic acyloxylation method |
JPS57212152A (en) * | 1981-06-05 | 1982-12-27 | Shell Int Research | Manufacture of isocyanate and/or derivative |
-
1983
- 1983-05-31 US US06/499,575 patent/US4461681A/en not_active Expired - Lifetime
-
1984
- 1984-05-25 IT IT48259/84A patent/IT1177750B/it active
- 1984-05-30 BE BE0/213038A patent/BE899792A/fr not_active IP Right Cessation
- 1984-05-30 CA CA000455434A patent/CA1241290A/en not_active Expired
- 1984-05-30 DE DE19843420333 patent/DE3420333A1/de active Granted
- 1984-05-30 FR FR8408588A patent/FR2546910B1/fr not_active Expired
- 1984-05-30 NL NL8401733A patent/NL192457C/nl not_active IP Right Cessation
- 1984-05-31 GB GB08413890A patent/GB2141708B/en not_active Expired
- 1984-05-31 JP JP59112151A patent/JPS605889A/ja active Granted
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3290350A (en) * | 1960-05-16 | 1966-12-06 | Du Pont | Alpha, alpha, alpha', alpha'-tetramethyl-xylylene diisocyanates and alpha, alpha-dimethylisopropenylbenzyl isocyanates and the preparation thereof from isocyanic acid and olefins |
US3502475A (en) * | 1967-07-13 | 1970-03-24 | Du Pont | Highly adherent coated films and method of producing same |
US3833489A (en) * | 1971-07-24 | 1974-09-03 | R Ercoli | Process for the preparation of squaric acid by reductive cyclotetramerization of carbon monoxide |
JPS5239612A (en) * | 1975-09-22 | 1977-03-28 | Asahi Chem Ind Co Ltd | Process for preparation of unsaturated glycol diesters |
JPS5579883A (en) * | 1978-12-13 | 1980-06-16 | Mitsui Petrochem Ind Ltd | Preparation of 3,4-dialkoxyphenol |
JPS5579882A (en) * | 1978-12-13 | 1980-06-16 | Mitsui Petrochem Ind Ltd | Electrolytic acyloxylation method |
JPS57212152A (en) * | 1981-06-05 | 1982-12-27 | Shell Int Research | Manufacture of isocyanate and/or derivative |
Also Published As
Publication number | Publication date |
---|---|
GB2141708A (en) | 1985-01-03 |
CA1241290A (en) | 1988-08-30 |
US4461681A (en) | 1984-07-24 |
NL192457C (nl) | 1997-08-04 |
FR2546910A1 (fr) | 1984-12-07 |
JPS605889A (ja) | 1985-01-12 |
NL8401733A (nl) | 1984-12-17 |
FR2546910B1 (fr) | 1988-10-14 |
IT8448259A0 (it) | 1984-05-25 |
GB2141708B (en) | 1986-12-10 |
IT1177750B (it) | 1987-08-26 |
NL192457B (nl) | 1997-04-01 |
DE3420333C2 (US20030199744A1-20031023-C00003.png) | 1993-02-04 |
DE3420333A1 (de) | 1984-12-06 |
GB8413890D0 (en) | 1984-07-04 |
BE899792A (fr) | 1984-11-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
FR2807072A1 (fr) | Electrolyse a basse temperature de metaux alcalins | |
FI74945C (fi) | Foerfarande foer framstaellning av hydroksifoereningar genom elektrokemisk reduktion. | |
JPH0568555B2 (US20030199744A1-20031023-C00003.png) | ||
CA1243686A (en) | Process for the manufacture of an aldehyde | |
JP2633244B2 (ja) | 水性有機溶液中でメタンスルホン酸セリウムを使用する有機化合物の酸化 | |
EP0189120B1 (en) | Process for the electrocarboxylation of carbonyl compounds for producing alpha-hydroxycarboxylic acids | |
EP0905282A1 (en) | Process for the electrochemical synthesis of n-acetylcysteine from cystine | |
JP2509206B2 (ja) | セリウム酸化剤 | |
MX2015000244A (es) | Metodo para la produccion de vainillina. | |
US3833489A (en) | Process for the preparation of squaric acid by reductive cyclotetramerization of carbon monoxide | |
JPS60211088A (ja) | シアノピリジン塩基の電気化学的還元法 | |
JPS6157818B2 (US20030199744A1-20031023-C00003.png) | ||
US3969200A (en) | Manufacture of propiolic acid | |
US3994788A (en) | Electrochemical oxidation of phenol | |
JPH0564936B2 (US20030199744A1-20031023-C00003.png) | ||
EP0618312A1 (en) | Process for obtaining n-acetyl homocysteine thiolactone from DL-homocystine by electrochemical methods | |
JP3806181B2 (ja) | ナフタレンアルデヒド類の製造方法 | |
EP0226319B1 (en) | Electrochemical dimerizations of pyridinium salts | |
IE46752B1 (en) | A process for the production of ferrocenes | |
JP2674767B2 (ja) | ポリフルオロ芳香族アルデヒドの製造方法 | |
JP2632832B2 (ja) | ポリフルオロベンジルアルコールの製造方法 | |
CA1284650C (en) | Process for the preparation of 5-nitro-1,4-naphthoquinone | |
JPS6131191B2 (US20030199744A1-20031023-C00003.png) | ||
JPH02133590A (ja) | 2―アリールヒドロキノンの電気化学的合成法 | |
FR2688519A1 (fr) | Procede d'electrosynthese de fluorobiphenyles symetriques. |