JPH0524089B2 - - Google Patents
Info
- Publication number
- JPH0524089B2 JPH0524089B2 JP60013910A JP1391085A JPH0524089B2 JP H0524089 B2 JPH0524089 B2 JP H0524089B2 JP 60013910 A JP60013910 A JP 60013910A JP 1391085 A JP1391085 A JP 1391085A JP H0524089 B2 JPH0524089 B2 JP H0524089B2
- Authority
- JP
- Japan
- Prior art keywords
- ions
- aqueous solution
- ethanol
- titanium
- solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 72
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 claims description 64
- 239000010936 titanium Substances 0.000 claims description 56
- 238000000034 method Methods 0.000 claims description 39
- 239000007864 aqueous solution Substances 0.000 claims description 37
- 150000002500 ions Chemical class 0.000 claims description 35
- 229910052719 titanium Inorganic materials 0.000 claims description 27
- 239000000460 chlorine Substances 0.000 claims description 24
- LLZRNZOLAXHGLL-UHFFFAOYSA-J titanic acid Chemical compound O[Ti](O)(O)O LLZRNZOLAXHGLL-UHFFFAOYSA-J 0.000 claims description 19
- 235000006408 oxalic acid Nutrition 0.000 claims description 18
- 229910052801 chlorine Inorganic materials 0.000 claims description 17
- -1 chlorine ions Chemical class 0.000 claims description 16
- 238000004519 manufacturing process Methods 0.000 claims description 16
- 239000002243 precursor Substances 0.000 claims description 16
- 239000002244 precipitate Substances 0.000 claims description 15
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 11
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 11
- 229910017604 nitric acid Inorganic materials 0.000 claims description 11
- 150000003839 salts Chemical class 0.000 claims description 8
- 238000005406 washing Methods 0.000 claims description 6
- 229910002651 NO3 Inorganic materials 0.000 claims description 5
- 150000001805 chlorine compounds Chemical class 0.000 claims description 5
- 229910052745 lead Inorganic materials 0.000 claims description 5
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 5
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 4
- 229910052788 barium Inorganic materials 0.000 claims description 4
- 230000003301 hydrolyzing effect Effects 0.000 claims description 4
- 229910052712 strontium Inorganic materials 0.000 claims description 4
- 229910052726 zirconium Inorganic materials 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 239000000843 powder Substances 0.000 description 35
- 239000000243 solution Substances 0.000 description 26
- 239000002245 particle Substances 0.000 description 24
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- NKZSPGSOXYXWQA-UHFFFAOYSA-N dioxido(oxo)titanium;lead(2+) Chemical compound [Pb+2].[O-][Ti]([O-])=O NKZSPGSOXYXWQA-UHFFFAOYSA-N 0.000 description 10
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 9
- 239000000203 mixture Substances 0.000 description 9
- 150000001875 compounds Chemical class 0.000 description 8
- 230000004927 fusion Effects 0.000 description 8
- 235000012970 cakes Nutrition 0.000 description 7
- 239000013078 crystal Substances 0.000 description 7
- 150000003891 oxalate salts Chemical class 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 230000008569 process Effects 0.000 description 6
- 238000005245 sintering Methods 0.000 description 6
- 150000004703 alkoxides Chemical class 0.000 description 5
- 238000001354 calcination Methods 0.000 description 5
- 238000000975 co-precipitation Methods 0.000 description 5
- 238000010304 firing Methods 0.000 description 5
- 238000000227 grinding Methods 0.000 description 5
- RLJMLMKIBZAXJO-UHFFFAOYSA-N lead nitrate Chemical compound [O-][N+](=O)O[Pb]O[N+]([O-])=O RLJMLMKIBZAXJO-UHFFFAOYSA-N 0.000 description 5
- 239000011259 mixed solution Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000010419 fine particle Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- UJVRJBAUJYZFIX-UHFFFAOYSA-N nitric acid;oxozirconium Chemical compound [Zr]=O.O[N+]([O-])=O.O[N+]([O-])=O UJVRJBAUJYZFIX-UHFFFAOYSA-N 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 150000003608 titanium Chemical class 0.000 description 4
- 238000001132 ultrasonic dispersion Methods 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000011109 contamination Methods 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- ANBZWDBEKOZNHY-UHFFFAOYSA-N ethanol;oxalic acid Chemical compound CCO.OC(=O)C(O)=O ANBZWDBEKOZNHY-UHFFFAOYSA-N 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000005755 formation reaction Methods 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 3
- 239000012535 impurity Substances 0.000 description 3
- 229910021645 metal ion Inorganic materials 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 239000012452 mother liquor Substances 0.000 description 3
- 238000011160 research Methods 0.000 description 3
- 239000006104 solid solution Substances 0.000 description 3
- 238000005979 thermal decomposition reaction Methods 0.000 description 3
- 239000011882 ultra-fine particle Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000003985 ceramic capacitor Substances 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- CMOAHYOGLLEOGO-UHFFFAOYSA-N oxozirconium;dihydrochloride Chemical compound Cl.Cl.[Zr]=O CMOAHYOGLLEOGO-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- PXDRFTPXHTVDFR-UHFFFAOYSA-N propane;titanium(4+) Chemical compound [Ti+4].C[CH-]C.C[CH-]C.C[CH-]C.C[CH-]C PXDRFTPXHTVDFR-UHFFFAOYSA-N 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000005060 rubber Substances 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 238000003746 solid phase reaction Methods 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- QDZRBIRIPNZRSG-UHFFFAOYSA-N titanium nitrate Chemical compound [O-][N+](=O)O[Ti](O[N+]([O-])=O)(O[N+]([O-])=O)O[N+]([O-])=O QDZRBIRIPNZRSG-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- 230000004580 weight loss Effects 0.000 description 2
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000002033 PVDF binder Substances 0.000 description 1
- 229930040373 Paraformaldehyde Natural products 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910002367 SrTiO Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000005280 amorphization Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 235000015173 baked goods and baking mixes Nutrition 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 229910021523 barium zirconate Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000036772 blood pressure Effects 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000007416 differential thermogravimetric analysis Methods 0.000 description 1
- 235000021463 dry cake Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000004442 gravimetric analysis Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- HWSZZLVAJGOAAY-UHFFFAOYSA-L lead(II) chloride Chemical compound Cl[Pb]Cl HWSZZLVAJGOAAY-UHFFFAOYSA-L 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- GBNDTYKAOXLLID-UHFFFAOYSA-N zirconium(4+) ion Chemical compound [Zr+4] GBNDTYKAOXLLID-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60013910A JPS61174116A (ja) | 1985-01-28 | 1985-01-28 | ペロブスカイト型酸化物の製造法 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP60013910A JPS61174116A (ja) | 1985-01-28 | 1985-01-28 | ペロブスカイト型酸化物の製造法 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS61174116A JPS61174116A (ja) | 1986-08-05 |
| JPH0524089B2 true JPH0524089B2 (de) | 1993-04-06 |
Family
ID=11846322
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP60013910A Granted JPS61174116A (ja) | 1985-01-28 | 1985-01-28 | ペロブスカイト型酸化物の製造法 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS61174116A (de) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0237081B1 (de) * | 1986-03-14 | 1992-01-22 | Matsushita Electric Industrial Co., Ltd. | Verfahren zur Herstellung von komplexen Perovskittypverbindungen |
| US4874598A (en) * | 1987-01-20 | 1989-10-17 | Mitsubishi Petrochemical Co., Ltd. | Process for producing perovskite-type oxides of the ABO3 type |
| US6572793B2 (en) * | 2000-03-30 | 2003-06-03 | Tdk Corporation | Method of producing ceramic composition and method of producing electronic device |
| JP2010202641A (ja) * | 2009-02-06 | 2010-09-16 | Ngk Insulators Ltd | セラミックス前駆体の製造方法 |
| JP6686444B2 (ja) | 2016-01-07 | 2020-04-22 | 株式会社リコー | Ｐｚｔ膜積層構造体、液体吐出ヘッド、液体吐出ユニット、液体を吐出する装置及びｐｚｔ膜積層構造体の製造方法 |
-
1985
- 1985-01-28 JP JP60013910A patent/JPS61174116A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS61174116A (ja) | 1986-08-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP3963962B2 (ja) | ペロブスカイト化合物の結晶性セラミック粉体の合成方法 | |
| JP5361190B2 (ja) | 微粉末のチタン酸ジルコニウム酸鉛、ジルコンチタン水和物及びチタン酸ジルコニウム及びその製法 | |
| JPH04502303A (ja) | 化学量及び粒子の大きさが制御されているペロブスカイト化合物のサブミクロンセラミック粉末を製造する方法 | |
| JP3800651B2 (ja) | 複合金属酸化物粉末の製造方法 | |
| US8715614B2 (en) | High-gravity reactive precipitation process for the preparation of barium titanate powders | |
| US8431109B2 (en) | Process for production of composition | |
| JP3319807B2 (ja) | ペロブスカイト型化合物微細粒子粉末およびその製造法 | |
| JPH0524089B2 (de) | ||
| JP3772354B2 (ja) | セラミック粉体の製造方法 | |
| JPH0246531B2 (de) | ||
| JPH0249251B2 (de) | ||
| US20060275201A1 (en) | Production of perovskite particles | |
| JPS61251516A (ja) | ペロブスカイト型酸化物の製造法 | |
| KR100395218B1 (ko) | ＢａＴｉＯ3계 분말 제조 방법 | |
| JPS63151673A (ja) | ジルコン酸チタン酸鉛系圧電磁器の製造方法 | |
| JP3319795B2 (ja) | ペロブスカイト型化合物微細粒子粉末 | |
| JPH05116943A (ja) | チタン酸バリウム粉末の製造方法 | |
| JP3041411B2 (ja) | 圧電セラミックス用原料粉体の製造方法 | |
| JPS6259529A (ja) | チタン含有易焼結性ペロブスカイトおよびその固溶体の原料粉末の製造方法 | |
| JP3210992B2 (ja) | チタン変成ジルコニアの製造方法 | |
| JP2694851B2 (ja) | Ｐｌｚｔセラミック原料粉末の製造方法 | |
| JPH0471848B2 (de) | ||
| JPH0524090B2 (de) | ||
| JPH0524859B2 (de) | ||
| JPH0472770B2 (de) |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |