JPH0520874B2 - - Google Patents
Info
- Publication number
- JPH0520874B2 JPH0520874B2 JP58008686A JP868683A JPH0520874B2 JP H0520874 B2 JPH0520874 B2 JP H0520874B2 JP 58008686 A JP58008686 A JP 58008686A JP 868683 A JP868683 A JP 868683A JP H0520874 B2 JPH0520874 B2 JP H0520874B2
- Authority
- JP
- Japan
- Prior art keywords
- methyltetrahydrofuran
- lithium
- electrolyte
- propylene carbonate
- ethylene carbonate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- JWUJQDFVADABEY-UHFFFAOYSA-N 2-methyltetrahydrofuran Chemical compound CC1CCCO1 JWUJQDFVADABEY-UHFFFAOYSA-N 0.000 claims description 25
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 18
- 229910052744 lithium Inorganic materials 0.000 claims description 18
- 239000003792 electrolyte Substances 0.000 claims description 17
- 239000002904 solvent Substances 0.000 claims description 17
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 claims description 16
- 239000008151 electrolyte solution Substances 0.000 claims description 12
- 239000003960 organic solvent Substances 0.000 claims description 8
- 229910003002 lithium salt Inorganic materials 0.000 claims description 5
- 159000000002 lithium salts Chemical class 0.000 claims description 5
- 239000012046 mixed solvent Substances 0.000 claims description 3
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 21
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 21
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 19
- 238000007599 discharging Methods 0.000 description 14
- 239000000203 mixture Substances 0.000 description 11
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 9
- 238000006722 reduction reaction Methods 0.000 description 8
- 230000003647 oxidation Effects 0.000 description 7
- 238000007254 oxidation reaction Methods 0.000 description 7
- 229910001416 lithium ion Inorganic materials 0.000 description 6
- 239000007774 positive electrode material Substances 0.000 description 5
- 229910015027 LiAsF4 Inorganic materials 0.000 description 4
- 229910013684 LiClO 4 Inorganic materials 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000011255 nonaqueous electrolyte Substances 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 3
- 239000007773 negative electrode material Substances 0.000 description 3
- 125000004430 oxygen atom Chemical group O* 0.000 description 3
- -1 polypropylene Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 229910013063 LiBF 4 Inorganic materials 0.000 description 2
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 description 2
- 229910001486 lithium perchlorate Inorganic materials 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 230000003335 steric effect Effects 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 1
- 229910010238 LiAlCl 4 Inorganic materials 0.000 description 1
- 229910015015 LiAsF 6 Inorganic materials 0.000 description 1
- 229910013870 LiPF 6 Inorganic materials 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- KSECJOPEZIAKMU-UHFFFAOYSA-N [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] Chemical compound [S--].[S--].[S--].[S--].[S--].[V+5].[V+5] KSECJOPEZIAKMU-UHFFFAOYSA-N 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000006258 conductive agent Substances 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 150000002642 lithium compounds Chemical class 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- LTRVAZKHJRYLRJ-UHFFFAOYSA-N lithium;butan-1-olate Chemical compound [Li+].CCCC[O-] LTRVAZKHJRYLRJ-UHFFFAOYSA-N 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000005839 radical cations Chemical class 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 150000003346 selenoethers Chemical class 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- XSOKHXFFCGXDJZ-UHFFFAOYSA-N telluride(2-) Chemical compound [Te-2] XSOKHXFFCGXDJZ-UHFFFAOYSA-N 0.000 description 1
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
- H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
- H01M6/164—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by the solvent
Landscapes
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Primary Cells (AREA)
- Secondary Cells (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58008686A JPS59134568A (ja) | 1983-01-24 | 1983-01-24 | リチウム電池用電解液 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP58008686A JPS59134568A (ja) | 1983-01-24 | 1983-01-24 | リチウム電池用電解液 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59134568A JPS59134568A (ja) | 1984-08-02 |
| JPH0520874B2 true JPH0520874B2 (de) | 1993-03-22 |
Family
ID=11699799
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP58008686A Granted JPS59134568A (ja) | 1983-01-24 | 1983-01-24 | リチウム電池用電解液 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59134568A (de) |
Families Citing this family (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS62105375A (ja) * | 1985-11-01 | 1987-05-15 | Nippon Telegr & Teleph Corp <Ntt> | リチウム二次電池 |
| JPS63119170A (ja) * | 1986-11-07 | 1988-05-23 | Nippon Telegr & Teleph Corp <Ntt> | リチウム二次電池用電解液 |
| JPS63148572A (ja) * | 1986-12-10 | 1988-06-21 | Fuji Elelctrochem Co Ltd | 非水電解液電池 |
| JPS63148570A (ja) * | 1986-12-10 | 1988-06-21 | Fuji Elelctrochem Co Ltd | 非水電解液電池 |
| JPS63148569A (ja) * | 1986-12-10 | 1988-06-21 | Fuji Elelctrochem Co Ltd | 非水電解液電池 |
| JPS63148571A (ja) * | 1986-12-10 | 1988-06-21 | Fuji Elelctrochem Co Ltd | 非水電解液電池 |
| JPS63168969A (ja) * | 1986-12-27 | 1988-07-12 | Sanyo Electric Co Ltd | 非水電解液電池 |
| JPS646382A (en) * | 1987-06-29 | 1989-01-10 | Showa Denko Kk | Secondary cell |
| JPS63307669A (ja) * | 1987-06-08 | 1988-12-15 | Sanyo Electric Co Ltd | 非水電解液電池 |
| JPH0715820B2 (ja) * | 1988-05-09 | 1995-02-22 | 三洋電機株式会社 | 非水電解液電池 |
| JPH01313861A (ja) * | 1988-06-14 | 1989-12-19 | Sanyo Electric Co Ltd | 有機電解質二次電池 |
| JP2698103B2 (ja) * | 1988-07-01 | 1998-01-19 | 三洋電機株式会社 | 非水系電解液一次電池 |
| JPH0677465B2 (ja) * | 1988-08-01 | 1994-09-28 | 富士電気化学株式会社 | 非水電解液電池 |
| US5079109A (en) * | 1989-05-16 | 1992-01-07 | Kabushiki Kaisha Toshiba | Nonaqueous electrolyte secondary battery |
| JPH0760705B2 (ja) * | 1990-12-28 | 1995-06-28 | 富士電気化学株式会社 | 非水電解液電池 |
| JP5549516B2 (ja) * | 2010-10-06 | 2014-07-16 | 日本電気株式会社 | 二次電池およびそれに用いる電解液並びに膜 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4887338A (de) * | 1972-01-31 | 1973-11-16 | ||
| JPS52153118A (en) * | 1976-06-15 | 1977-12-20 | Matsushita Electric Ind Co Ltd | Battery |
| JPS5389941A (en) * | 1977-01-19 | 1978-08-08 | Accumulateurs Fixes | Electrolyte for lithium primary cell |
-
1983
- 1983-01-24 JP JP58008686A patent/JPS59134568A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4887338A (de) * | 1972-01-31 | 1973-11-16 | ||
| JPS52153118A (en) * | 1976-06-15 | 1977-12-20 | Matsushita Electric Ind Co Ltd | Battery |
| JPS5389941A (en) * | 1977-01-19 | 1978-08-08 | Accumulateurs Fixes | Electrolyte for lithium primary cell |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59134568A (ja) | 1984-08-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Hayashi et al. | Mixed solvent electrolyte for high voltage lithium metal secondary cells | |
| EP1722430B1 (de) | Sekundärbatterie mit radikalischer Verbindung als aktives Elektrodenmaterial | |
| US7468224B2 (en) | Battery having improved positive electrode and method of manufacturing the same | |
| US7416813B2 (en) | Lithium secondary battery | |
| US7635542B2 (en) | Non-aqueous electrolyte secondary battery | |
| EP1995817A1 (de) | Wiederaufladbare lithiumbatterie mit ionischer flüssigkeit | |
| EP1209754B1 (de) | Nichtwässrige elektrolytische zelle | |
| RU2330354C1 (ru) | Неводный электролит, содержащий оксианион, и литиевая аккумуляторная батарея, в которой он применяется | |
| JPH0520874B2 (de) | ||
| JP2011228052A (ja) | リチウムイオン二次電池 | |
| EP1170814A1 (de) | Nichtwässriger elektrolyt und nichtwässrige elektrolytische zelle | |
| JPH07211351A (ja) | 二次電池用非水電解液 | |
| JPH0636370B2 (ja) | リチウム二次電池用電解液 | |
| US8372541B2 (en) | Non-aqueous electrolyte secondary battery | |
| JPH053112B2 (de) | ||
| KR20020055572A (ko) | 비수성 전해질 이차 전지 | |
| JPH0351068B2 (de) | ||
| JPH08162154A (ja) | 非水溶媒電解液を有する二次電池 | |
| JPH08190932A (ja) | 非水溶媒電解液を有する二次電池 | |
| JPH0377626B2 (de) | ||
| JPH0477426B2 (de) | ||
| JPH0564429B2 (de) | ||
| JP4134556B2 (ja) | 非水電解質二次電池 | |
| JP4313982B2 (ja) | 非水電解質二次電池 | |
| JPH01286263A (ja) | リチウム二次電池用電解液 |