JPH0475931B2 - - Google Patents
Info
- Publication number
- JPH0475931B2 JPH0475931B2 JP59173772A JP17377284A JPH0475931B2 JP H0475931 B2 JPH0475931 B2 JP H0475931B2 JP 59173772 A JP59173772 A JP 59173772A JP 17377284 A JP17377284 A JP 17377284A JP H0475931 B2 JPH0475931 B2 JP H0475931B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- rubber
- nbr
- oil
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920001971 elastomer Polymers 0.000 claims description 45
- 150000002825 nitriles Chemical class 0.000 claims description 45
- 239000005060 rubber Substances 0.000 claims description 43
- 239000000203 mixture Substances 0.000 claims description 40
- 229920003244 diene elastomer Polymers 0.000 claims description 29
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 230000009477 glass transition Effects 0.000 claims description 10
- 229920001577 copolymer Polymers 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 229920001194 natural rubber Polymers 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- 238000009826 distribution Methods 0.000 claims description 6
- 244000043261 Hevea brasiliensis Species 0.000 claims description 4
- 229920003052 natural elastomer Polymers 0.000 claims description 4
- 229920000468 styrene butadiene styrene block copolymer Polymers 0.000 claims description 3
- 238000002844 melting Methods 0.000 claims 1
- 230000008018 melting Effects 0.000 claims 1
- 229920000459 Nitrile rubber Polymers 0.000 description 24
- 238000006116 polymerization reaction Methods 0.000 description 14
- 238000000034 method Methods 0.000 description 13
- 239000003921 oil Substances 0.000 description 10
- 229920002943 EPDM rubber Polymers 0.000 description 9
- 239000004816 latex Substances 0.000 description 8
- 229920000126 latex Polymers 0.000 description 8
- 230000000704 physical effect Effects 0.000 description 7
- 238000009472 formulation Methods 0.000 description 6
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000001938 differential scanning calorimetry curve Methods 0.000 description 5
- 229920005989 resin Polymers 0.000 description 5
- 239000011347 resin Substances 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 108010047588 NBR-A isoenzyme Proteins 0.000 description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 description 4
- 238000004073 vulcanization Methods 0.000 description 4
- 239000002174 Styrene-butadiene Substances 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- 150000001993 dienes Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- -1 methylene norbornene Chemical compound 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- 108010091834 NBR-B isoenzyme Proteins 0.000 description 2
- 239000005062 Polybutadiene Substances 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000001112 coagulating effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- ZSWFCLXCOIISFI-UHFFFAOYSA-N cyclopentadiene Chemical compound C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- DMBHHRLKUKUOEG-UHFFFAOYSA-N diphenylamine Chemical compound C=1C=CC=CC=1NC1=CC=CC=C1 DMBHHRLKUKUOEG-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000806 elastomer Substances 0.000 description 2
- 238000007720 emulsion polymerization reaction Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000004898 kneading Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920003245 polyoctenamer Polymers 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 229920003051 synthetic elastomer Polymers 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical compound C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 1
- OJOWICOBYCXEKR-KRXBUXKQSA-N (5e)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C/C)/CC1C=C2 OJOWICOBYCXEKR-KRXBUXKQSA-N 0.000 description 1
- YAJYJWXEWKRTPO-UHFFFAOYSA-N 2,3,3,4,4,5-hexamethylhexane-2-thiol Chemical compound CC(C)C(C)(C)C(C)(C)C(C)(C)S YAJYJWXEWKRTPO-UHFFFAOYSA-N 0.000 description 1
- BWGNESOTFCXPMA-UHFFFAOYSA-N Dihydrogen disulfide Chemical compound SS BWGNESOTFCXPMA-UHFFFAOYSA-N 0.000 description 1
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 1
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 1
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 1
- 229920001893 acrylonitrile styrene Polymers 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 150000004659 dithiocarbamates Chemical class 0.000 description 1
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000002140 halogenating effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- CFJYNSNXFXLKNS-UHFFFAOYSA-N p-menthane Chemical compound CC(C)C1CCC(C)CC1 CFJYNSNXFXLKNS-UHFFFAOYSA-N 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920003246 polypentenamer Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000346 polystyrene-polyisoprene block-polystyrene Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L7/00—Compositions of natural rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Ethene-propene or ethene-propene-diene copolymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/02—Copolymers with acrylonitrile
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L65/00—Compositions of macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain; Compositions of derivatives of such polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (5)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59173772A JPS6153340A (ja) | 1984-08-21 | 1984-08-21 | 耐油性ゴム組成物 |
| KR1019850005955A KR890003359B1 (ko) | 1984-08-21 | 1985-08-19 | 내유성 고무 조성물 |
| EP85305957A EP0173546B1 (en) | 1984-08-21 | 1985-08-21 | Oil-resistant rubber composition |
| DE8585305957T DE3580326D1 (de) | 1984-08-21 | 1985-08-21 | Oelbestaendige kautschukmischung. |
| US07/158,037 US4849478A (en) | 1984-08-21 | 1988-02-16 | Oil-resistant rubber composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59173772A JPS6153340A (ja) | 1984-08-21 | 1984-08-21 | 耐油性ゴム組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6153340A JPS6153340A (ja) | 1986-03-17 |
| JPH0475931B2 true JPH0475931B2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-12-02 |
Family
ID=15966858
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59173772A Granted JPS6153340A (ja) | 1984-08-21 | 1984-08-21 | 耐油性ゴム組成物 |
Country Status (5)
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007100064A1 (ja) | 2006-03-01 | 2007-09-07 | Jsr Corporation | ゴム組成物、架橋ゴム、及び成形品 |
Families Citing this family (20)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3501697A1 (de) * | 1985-01-19 | 1986-07-24 | Bayer Ag, 5090 Leverkusen | Kautschukmischungen und ihre covulkanisate |
| US4894420A (en) * | 1988-09-14 | 1990-01-16 | The Goodyear Tire & Rubber Company | Tire with tread of selective rubber blend |
| US5216066A (en) * | 1991-03-28 | 1993-06-01 | The Goodyear Tire & Rubber Company | Tread compounds containing modified EPDM which exhibit good abrasion resistance and improved hysteresis properties |
| JP2558559B2 (ja) * | 1991-05-10 | 1996-11-27 | 住友ゴム工業株式会社 | 無圧テニスボール |
| JP2956344B2 (ja) * | 1992-02-08 | 1999-10-04 | 日本ゼオン株式会社 | ゴム組成物 |
| JP3035075B2 (ja) * | 1992-05-20 | 2000-04-17 | 住友ゴム工業株式会社 | グリップ |
| RU2165440C2 (ru) * | 1998-05-05 | 2001-04-20 | Закрытое акционерное общество "Тульский завод резиновых технических изделий" | Полимерная композиция |
| DE60229748D1 (de) * | 2001-06-15 | 2008-12-18 | Pirelli | Verfahren zur herstellung und lagerung eines nichtvulkanisierten gummiprodukts |
| US20080188621A1 (en) * | 2004-04-28 | 2008-08-07 | Mitsui Chemicals, Inc. | Rubber Composition and Use Thereof |
| FR2910905B1 (fr) * | 2006-12-27 | 2010-08-20 | Michelin Soc Tech | Systeme plastifiant et composition de caoutchouc pour pneumatique incorporant ledit systeme |
| US8110266B2 (en) | 2007-02-08 | 2012-02-07 | Allegiance Corporation | Glove coating and manufacturing process |
| US20080306200A1 (en) * | 2007-06-11 | 2008-12-11 | Seong Fong Chen | Antistatic gloves and process for making same |
| US20090234064A1 (en) | 2008-03-14 | 2009-09-17 | Allegiance Corporation | Water-based resin composition and articles made therefrom |
| CN104448432B (zh) * | 2014-12-18 | 2017-05-17 | 山东玲珑轮胎股份有限公司 | 耐油胎面胶料及其制法和应用 |
| TWI618749B (zh) * | 2015-03-30 | 2018-03-21 | 科騰聚合物美國有限責任公司 | 可固化透明橡膠組合物，由其製得之固化透明橡膠組合物及其製法 |
| EP3416796B1 (en) * | 2016-03-29 | 2019-12-25 | Kraton Polymers U.S. LLC | A curable transparent rubber composition, a cured transparent rubber composition made thereof, and manufacturing process for the same |
| CN110041574A (zh) * | 2019-05-05 | 2019-07-23 | 蚌埠创特新材料科技有限公司 | 一种耐腐蚀耐高温油底壳密封橡胶材料 |
| JP7360883B2 (ja) * | 2019-09-30 | 2023-10-13 | 株式会社ブリヂストン | ゴム組成物、複合体、ホース、コンベヤベルト、クローラおよびタイヤ |
| WO2022190998A1 (ja) * | 2021-03-10 | 2022-09-15 | バンドー化学株式会社 | ゴム組成物、及びゴム製品 |
| CN114854107B (zh) * | 2022-05-05 | 2023-09-01 | 广东联塑科技实业有限公司 | 一种耐油耐低温橡胶材料及其制备方法与应用 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB672992A (en) * | 1948-10-01 | 1952-05-28 | Standard Oil Dev Co | Improvements in or relating to synthetic rubber |
| US3179718A (en) * | 1960-10-28 | 1965-04-20 | Exxon Research Engineering Co | Composition comprising butadiene-acrylonitrile copolymer, ethylene-propylene copolymer, peroxide, and sulfur |
| US3400086A (en) * | 1965-06-21 | 1968-09-03 | Polymer Corp | Rubber blend |
| NL146192B (nl) * | 1966-05-09 | 1975-06-16 | Copolymer Rubber & Chem Corp | Werkwijze voor de bereiding van een homogeen, met zwavel vulcaniseerbaar rubbermengsel. |
| US3963665A (en) * | 1974-09-25 | 1976-06-15 | Sun Oil Company Of Pennsylvania | Novel conveyor belts for transporting tar sands |
-
1984
- 1984-08-21 JP JP59173772A patent/JPS6153340A/ja active Granted
-
1985
- 1985-08-19 KR KR1019850005955A patent/KR890003359B1/ko not_active Expired
- 1985-08-21 EP EP85305957A patent/EP0173546B1/en not_active Expired - Lifetime
- 1985-08-21 DE DE8585305957T patent/DE3580326D1/de not_active Expired - Lifetime
-
1988
- 1988-02-16 US US07/158,037 patent/US4849478A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007100064A1 (ja) | 2006-03-01 | 2007-09-07 | Jsr Corporation | ゴム組成物、架橋ゴム、及び成形品 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP0173546A3 (en) | 1986-06-11 |
| JPS6153340A (ja) | 1986-03-17 |
| EP0173546A2 (en) | 1986-03-05 |
| KR870002184A (ko) | 1987-03-30 |
| EP0173546B1 (en) | 1990-10-31 |
| US4849478A (en) | 1989-07-18 |
| DE3580326D1 (de) | 1990-12-06 |
| KR890003359B1 (ko) | 1989-09-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |