JPH0463099B2 - - Google Patents
Info
- Publication number
- JPH0463099B2 JPH0463099B2 JP61255835A JP25583586A JPH0463099B2 JP H0463099 B2 JPH0463099 B2 JP H0463099B2 JP 61255835 A JP61255835 A JP 61255835A JP 25583586 A JP25583586 A JP 25583586A JP H0463099 B2 JPH0463099 B2 JP H0463099B2
- Authority
- JP
- Japan
- Prior art keywords
- rubber
- modified polystyrene
- microns
- weight
- gloss
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002245 particle Substances 0.000 claims description 74
- 239000004793 Polystyrene Substances 0.000 claims description 46
- 229920002223 polystyrene Polymers 0.000 claims description 46
- 229920001971 elastomer Polymers 0.000 claims description 32
- 239000005060 rubber Substances 0.000 claims description 29
- -1 polydimethylsiloxane Polymers 0.000 claims description 22
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 19
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 19
- 239000011342 resin composition Substances 0.000 claims description 16
- 241001237745 Salamis Species 0.000 claims description 8
- 235000015175 salami Nutrition 0.000 claims description 8
- 229920005990 polystyrene resin Polymers 0.000 claims description 6
- 238000009826 distribution Methods 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 16
- 229920002857 polybutadiene Polymers 0.000 description 11
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- 239000005062 Polybutadiene Substances 0.000 description 10
- 230000007423 decrease Effects 0.000 description 9
- 238000003756 stirring Methods 0.000 description 8
- 238000002156 mixing Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 238000006116 polymerization reaction Methods 0.000 description 5
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 229920005669 high impact polystyrene Polymers 0.000 description 4
- 239000004797 high-impact polystyrene Substances 0.000 description 4
- 230000000379 polymerizing effect Effects 0.000 description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 3
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 239000000314 lubricant Substances 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- OEVVKKAVYQFQNV-UHFFFAOYSA-N 1-ethenyl-2,4-dimethylbenzene Chemical compound CC1=CC=C(C=C)C(C)=C1 OEVVKKAVYQFQNV-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- QEDJMOONZLUIMC-UHFFFAOYSA-N 1-tert-butyl-4-ethenylbenzene Chemical compound CC(C)(C)C1=CC=C(C=C)C=C1 QEDJMOONZLUIMC-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- 239000005063 High cis polybutadiene Substances 0.000 description 1
- 239000005064 Low cis polybutadiene Substances 0.000 description 1
- 229920001890 Novodur Polymers 0.000 description 1
- 238000003917 TEM image Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- MPMBRWOOISTHJV-UHFFFAOYSA-N but-1-enylbenzene Chemical compound CCC=CC1=CC=CC=C1 MPMBRWOOISTHJV-UHFFFAOYSA-N 0.000 description 1
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 1
- 239000008116 calcium stearate Substances 0.000 description 1
- 235000013539 calcium stearate Nutrition 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 235000019646 color tone Nutrition 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- RKISUIUJZGSLEV-UHFFFAOYSA-N n-[2-(octadecanoylamino)ethyl]octadecanamide Chemical compound CCCCCCCCCCCCCCCCCC(=O)NCCNC(=O)CCCCCCCCCCCCCCCCC RKISUIUJZGSLEV-UHFFFAOYSA-N 0.000 description 1
- MMSLOZQEMPDGPI-UHFFFAOYSA-N p-Mentha-1,3,5,8-tetraene Chemical compound CC(=C)C1=CC=C(C)C=C1 MMSLOZQEMPDGPI-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010558 suspension polymerization method Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25583586A JPS63112646A (ja) | 1986-10-29 | 1986-10-29 | 高光沢耐衝撃性ポリスチレン樹脂組成物 |
KR1019890004774A KR920001046B1 (ko) | 1986-10-29 | 1989-04-11 | 고무-변성된 폴리스티렌 수지 조성물 |
TW078102842A TW197460B (sh) | 1986-10-29 | 1989-04-17 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP25583586A JPS63112646A (ja) | 1986-10-29 | 1986-10-29 | 高光沢耐衝撃性ポリスチレン樹脂組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS63112646A JPS63112646A (ja) | 1988-05-17 |
JPH0463099B2 true JPH0463099B2 (sh) | 1992-10-08 |
Family
ID=17284259
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP25583586A Granted JPS63112646A (ja) | 1986-10-29 | 1986-10-29 | 高光沢耐衝撃性ポリスチレン樹脂組成物 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS63112646A (sh) |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2676261B2 (ja) * | 1988-07-28 | 1997-11-12 | 出光石油化学 株式会社 | ゴム変性スチレン系樹脂組成物 |
JPH0238435A (ja) * | 1988-07-28 | 1990-02-07 | Idemitsu Petrochem Co Ltd | スチレン系樹脂組成物 |
JP2651491B2 (ja) * | 1988-07-28 | 1997-09-10 | 出光石油化学株式会社 | 高光沢耐衝撃性スチレン系樹脂組成物 |
JPH0689203B2 (ja) * | 1989-11-14 | 1994-11-09 | 出光石油化学株式会社 | スチレン系樹脂組成物 |
JPH0689202B2 (ja) * | 1989-11-14 | 1994-11-09 | 出光石油化学株式会社 | 難燃性スチレン系樹脂組成物 |
JPH0689204B2 (ja) * | 1989-11-29 | 1994-11-09 | 出光石油化学株式会社 | スチレン系樹脂組成物 |
JP2683613B2 (ja) * | 1990-01-30 | 1997-12-03 | 出光石油化学株式会社 | スチレン系樹脂から成る射出成形品 |
JP3686681B2 (ja) * | 1992-03-10 | 2005-08-24 | 住友化学株式会社 | ゴム変性スチレン系樹脂組成物 |
US5473014A (en) * | 1992-03-23 | 1995-12-05 | Mitsui Toatsu Chemicals, Incorporated | Rubber modified styrenic resin composition having high gloss and impact strength |
KR100384385B1 (ko) | 1998-03-23 | 2003-08-27 | 주식회사 엘지화학 | 고광택성및고충격성고무변성스티렌계수지의제조방법 |
KR100401325B1 (ko) * | 2000-12-18 | 2003-10-10 | 제일모직주식회사 | 괴상중합 연속공정으로 제조된 낙하충격강도와 내마모성이우수한 고충격 폴리스티렌 수지 |
ITMI20031420A1 (it) | 2003-07-11 | 2005-01-12 | Polimeri Europa Spa | Polimeri vinilaromatici rinforzati con gomma |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51139850A (en) * | 1975-05-15 | 1976-12-02 | Labofina Sa | High impact polystylene composition and process for production thereof |
JPS57170950A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Improved rubber-moldified styrene resin composition |
JPS57170949A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
JPS57187345A (en) * | 1981-05-12 | 1982-11-18 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
US4493922A (en) * | 1980-09-20 | 1985-01-15 | Basf Aktiengesellschaft | Impact-resistant thermoplastic molding material |
JPS60156709A (ja) * | 1984-01-25 | 1985-08-16 | Asahi Chem Ind Co Ltd | 外観特性、耐衝撃性に優れたゴム変性スチレン系樹脂組成物 |
JPS6185461A (ja) * | 1984-10-02 | 1986-05-01 | Asahi Chem Ind Co Ltd | 高光沢ポリスチレン樹脂組成物 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL8304029A (nl) * | 1983-11-23 | 1985-06-17 | Dow Chemical Nederland | Met rubber versterkte polymeren van monovinylideen-aromatische verbindingen met een zeer goede verhouding tussen glans en sterkteeigenschappen en een werkwijze voor hun bereiding. |
-
1986
- 1986-10-29 JP JP25583586A patent/JPS63112646A/ja active Granted
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS51139850A (en) * | 1975-05-15 | 1976-12-02 | Labofina Sa | High impact polystylene composition and process for production thereof |
US4493922A (en) * | 1980-09-20 | 1985-01-15 | Basf Aktiengesellschaft | Impact-resistant thermoplastic molding material |
JPS57170950A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Improved rubber-moldified styrene resin composition |
JPS57170949A (en) * | 1981-04-16 | 1982-10-21 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
JPS57187345A (en) * | 1981-05-12 | 1982-11-18 | Mitsui Toatsu Chem Inc | Rubber-modified styrene resin composition |
JPS60156709A (ja) * | 1984-01-25 | 1985-08-16 | Asahi Chem Ind Co Ltd | 外観特性、耐衝撃性に優れたゴム変性スチレン系樹脂組成物 |
JPS6185461A (ja) * | 1984-10-02 | 1986-05-01 | Asahi Chem Ind Co Ltd | 高光沢ポリスチレン樹脂組成物 |
Also Published As
Publication number | Publication date |
---|---|
JPS63112646A (ja) | 1988-05-17 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
LAPS | Cancellation because of no payment of annual fees |