JPH04502271A - 廃ガスから窒素酸化物を除去する触媒の製造方法 - Google Patents
廃ガスから窒素酸化物を除去する触媒の製造方法Info
- Publication number
- JPH04502271A JPH04502271A JP2501021A JP50102190A JPH04502271A JP H04502271 A JPH04502271 A JP H04502271A JP 2501021 A JP2501021 A JP 2501021A JP 50102190 A JP50102190 A JP 50102190A JP H04502271 A JPH04502271 A JP H04502271A
- Authority
- JP
- Japan
- Prior art keywords
- halogen
- carbon
- gas
- nitrogen oxides
- catalyst
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- MWUXSHHQAYIFBG-UHFFFAOYSA-N nitrogen oxide Inorganic materials O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 title claims description 27
- 239000003054 catalyst Substances 0.000 title claims description 17
- 239000002912 waste gas Substances 0.000 title claims description 7
- 238000004519 manufacturing process Methods 0.000 title claims description 5
- 229910052736 halogen Inorganic materials 0.000 claims description 27
- 150000002367 halogens Chemical class 0.000 claims description 27
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 17
- 238000000034 method Methods 0.000 claims description 17
- 150000002366 halogen compounds Chemical class 0.000 claims description 14
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 12
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 12
- 229910052794 bromium Inorganic materials 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 9
- 239000007789 gas Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- 239000011261 inert gas Substances 0.000 claims description 7
- -1 bromine compound Chemical class 0.000 claims description 5
- 229910021529 ammonia Inorganic materials 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 2
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims 1
- 239000000571 coke Substances 0.000 description 10
- 230000003197 catalytic effect Effects 0.000 description 8
- CPELXLSAUQHCOX-UHFFFAOYSA-N Hydrogen bromide Chemical compound Br CPELXLSAUQHCOX-UHFFFAOYSA-N 0.000 description 6
- 239000003463 adsorbent Substances 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 238000006243 chemical reaction Methods 0.000 description 5
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 3
- CAMXVZOXBADHNJ-UHFFFAOYSA-N ammonium nitrite Chemical compound [NH4+].[O-]N=O CAMXVZOXBADHNJ-UHFFFAOYSA-N 0.000 description 3
- 229910000042 hydrogen bromide Inorganic materials 0.000 description 3
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000002349 favourable effect Effects 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- 241000257465 Echinoidea Species 0.000 description 1
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 235000019270 ammonium chloride Nutrition 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000004939 coking Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 229910000040 hydrogen fluoride Inorganic materials 0.000 description 1
- XMBWDFGMSWQBCA-UHFFFAOYSA-N hydrogen iodide Chemical compound I XMBWDFGMSWQBCA-UHFFFAOYSA-N 0.000 description 1
- 229910000043 hydrogen iodide Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
- B01D53/8621—Removing nitrogen compounds
- B01D53/8625—Nitrogen oxides
- B01D53/8628—Processes characterised by a specific catalyst
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/22—Halogenating
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Environmental & Geological Engineering (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Catalysts (AREA)
- Exhaust Gas Treatment By Means Of Catalyst (AREA)
- Treating Waste Gases (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3842526A DE3842526A1 (de) | 1988-12-17 | 1988-12-17 | Verfahren zur herstellung eines katalysators zur entfernung von stickstoffoxiden aus abgasen |
| DE3842526.2 | 1988-12-17 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH04502271A true JPH04502271A (ja) | 1992-04-23 |
Family
ID=6369396
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2501021A Pending JPH04502271A (ja) | 1988-12-17 | 1989-12-14 | 廃ガスから窒素酸化物を除去する触媒の製造方法 |
Country Status (6)
Families Citing this family (24)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4125913C1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1991-08-05 | 1993-01-07 | Bergwerksverband Gmbh, 4300 Essen, De | |
| US5372619A (en) * | 1992-10-14 | 1994-12-13 | Ucar Carbon Technology Corporation | Method for storing methane using a halogenating agent treated activated carbon |
| US6475461B1 (en) | 1995-03-30 | 2002-11-05 | Nippon Sanso Corporation | Porous carbonaceous material, manufacturing method therefor and use thereof |
| US8124036B1 (en) | 2005-10-27 | 2012-02-28 | ADA-ES, Inc. | Additives for mercury oxidation in coal-fired power plants |
| JP4723240B2 (ja) * | 2002-05-06 | 2011-07-13 | アルベマール コーポレイション | 燃焼ガスからの水銀除去のための吸着材とその方法 |
| US8617492B2 (en) * | 2008-01-08 | 2013-12-31 | Carbonxt Group Limited | System and method for making low volatile carboneaceous matter with supercritical CO2 |
| US8628707B2 (en) * | 2008-01-08 | 2014-01-14 | Carbonxt Group Limited | System and method for making carbon foam anodes |
| US20090172998A1 (en) * | 2008-01-08 | 2009-07-09 | Carbonxt Group Limited | System and method for refining carbonaceous material |
| UA109399C2 (uk) | 2009-04-01 | 2015-08-25 | Термічно активоване вугілля, стійке до самозапалювання | |
| US8496894B2 (en) | 2010-02-04 | 2013-07-30 | ADA-ES, Inc. | Method and system for controlling mercury emissions from coal-fired thermal processes |
| US8524179B2 (en) | 2010-10-25 | 2013-09-03 | ADA-ES, Inc. | Hot-side method and system |
| CN107866141A (zh) * | 2010-02-04 | 2018-04-03 | Ada-Es股份有限公司 | 控制从烧煤的热工艺释放汞的方法和系统 |
| US8951487B2 (en) | 2010-10-25 | 2015-02-10 | ADA-ES, Inc. | Hot-side method and system |
| WO2011112854A1 (en) | 2010-03-10 | 2011-09-15 | Ada Environmental Solutions, Llc | Process for dilute phase injection or dry alkaline materials |
| US8784757B2 (en) | 2010-03-10 | 2014-07-22 | ADA-ES, Inc. | Air treatment process for dilute phase injection of dry alkaline materials |
| AU2011296402B2 (en) | 2010-08-30 | 2015-01-22 | Albemarle Corporation | Improved brominated sorbents for removing mercury from emissions produced during fuel combustion |
| AU2011296403A1 (en) | 2010-08-30 | 2013-03-14 | Albemarle Corporation | Improved sorbents for removing mercury from emissions produced during fuel combustion |
| US8845986B2 (en) | 2011-05-13 | 2014-09-30 | ADA-ES, Inc. | Process to reduce emissions of nitrogen oxides and mercury from coal-fired boilers |
| US9017452B2 (en) | 2011-11-14 | 2015-04-28 | ADA-ES, Inc. | System and method for dense phase sorbent injection |
| US8883099B2 (en) | 2012-04-11 | 2014-11-11 | ADA-ES, Inc. | Control of wet scrubber oxidation inhibitor and byproduct recovery |
| US8974756B2 (en) | 2012-07-25 | 2015-03-10 | ADA-ES, Inc. | Process to enhance mixing of dry sorbents and flue gas for air pollution control |
| US9957454B2 (en) | 2012-08-10 | 2018-05-01 | ADA-ES, Inc. | Method and additive for controlling nitrogen oxide emissions |
| US10350545B2 (en) | 2014-11-25 | 2019-07-16 | ADA-ES, Inc. | Low pressure drop static mixing system |
| CN110523265A (zh) * | 2018-05-24 | 2019-12-03 | 中国石油化工股份有限公司 | 一种氮氧化物消除方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1989108A (en) * | 1933-05-22 | 1935-01-29 | Jacque C Morrell | Process of producing nonstructural activated carbon |
| JPS477687B1 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) * | 1967-01-13 | 1972-03-04 | ||
| US3662523A (en) * | 1970-12-15 | 1972-05-16 | American Optical Corp | Adsorbents for removal of mercury vapor from air or gas |
| US3961020A (en) * | 1972-10-09 | 1976-06-01 | Hitachi, Ltd. | Process for removing sulfur oxides and nitrogen oxides from flue gases using halogen-impregnated actuated carbon with simultaneous injection of ammonia |
| GB1460240A (en) * | 1974-11-12 | 1976-12-31 | Exxon Research Engineering Co | Lewis acid-fluorine compounds of carbon |
| US3962133A (en) * | 1974-12-12 | 1976-06-08 | Mobil Oil Corporation | Graphite intercalation |
| US4031185A (en) * | 1975-02-03 | 1977-06-21 | Hitachi, Ltd. | Process for making nitrogen oxides contained in flue gas harmless |
| DE3715526A1 (de) * | 1987-05-09 | 1988-11-17 | Bergwerksverband Gmbh | Verfahren zur entfernung von quecksilber aus gasen |
-
1988
- 1988-12-17 DE DE3842526A patent/DE3842526A1/de active Granted
-
1989
- 1989-12-14 DE DE9090900190T patent/DE58902470D1/de not_active Expired - Fee Related
- 1989-12-14 AT AT90900190T patent/ATE81475T1/de active
- 1989-12-14 JP JP2501021A patent/JPH04502271A/ja active Pending
- 1989-12-14 WO PCT/EP1989/001537 patent/WO1990006803A1/de active IP Right Grant
- 1989-12-14 EP EP90900190A patent/EP0448585B1/de not_active Expired - Lifetime
-
1991
- 1991-05-30 US US07/707,571 patent/US5179058A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| EP0448585B1 (de) | 1992-10-14 |
| DE3842526A1 (de) | 1990-06-21 |
| ATE81475T1 (de) | 1992-10-15 |
| EP0448585A1 (de) | 1991-10-02 |
| US5179058A (en) | 1993-01-12 |
| WO1990006803A1 (de) | 1990-06-28 |
| DE3842526C2 (GUID-C5D7CC26-194C-43D0-91A1-9AE8C70A9BFF.html) | 1992-05-21 |
| DE58902470D1 (de) | 1992-11-19 |
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