JPH0422897B2 - - Google Patents

Info

Publication number
JPH0422897B2
JPH0422897B2 JP57064202A JP6420282A JPH0422897B2 JP H0422897 B2 JPH0422897 B2 JP H0422897B2 JP 57064202 A JP57064202 A JP 57064202A JP 6420282 A JP6420282 A JP 6420282A JP H0422897 B2 JPH0422897 B2 JP H0422897B2
Authority
JP
Japan
Prior art keywords
catalyst
benzene
reaction
gas phase
gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP57064202A
Other languages
English (en)
Japanese (ja)
Other versions
JPS58180460A (ja
Inventor
Hiroshi Sato
Shuzo Nakamura
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Priority to JP57064202A priority Critical patent/JPS58180460A/ja
Priority to DE8383302083T priority patent/DE3360768D1/de
Priority to EP83302083A priority patent/EP0092372B1/en
Priority to US06/485,453 priority patent/US4551568A/en
Publication of JPS58180460A publication Critical patent/JPS58180460A/ja
Publication of JPH0422897B2 publication Critical patent/JPH0422897B2/ja
Granted legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C201/00Preparation of esters of nitric or nitrous acid or of compounds containing nitro or nitroso groups bound to a carbon skeleton
    • C07C201/06Preparation of nitro compounds
    • C07C201/08Preparation of nitro compounds by substitution of hydrogen atoms by nitro groups
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/0093Microreactors, e.g. miniaturised or microfabricated reactors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063Titanium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066Zirconium or hafnium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781Aspects relating to microreactors
    • B01J2219/00819Materials of construction
    • B01J2219/00824Ceramic
    • B01J2219/00826Quartz
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00781Aspects relating to microreactors
    • B01J2219/00819Materials of construction
    • B01J2219/00835Comprising catalytically active material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP57064202A 1982-04-16 1982-04-16 ニトロ化方法 Granted JPS58180460A (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP57064202A JPS58180460A (ja) 1982-04-16 1982-04-16 ニトロ化方法
DE8383302083T DE3360768D1 (en) 1982-04-16 1983-04-13 Process for nitration of benzene
EP83302083A EP0092372B1 (en) 1982-04-16 1983-04-13 Process for nitration of benzene
US06/485,453 US4551568A (en) 1982-04-16 1983-04-15 Process for nitration of benzene

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57064202A JPS58180460A (ja) 1982-04-16 1982-04-16 ニトロ化方法

Publications (2)

Publication Number Publication Date
JPS58180460A JPS58180460A (ja) 1983-10-21
JPH0422897B2 true JPH0422897B2 (enExample) 1992-04-20

Family

ID=13251241

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57064202A Granted JPS58180460A (ja) 1982-04-16 1982-04-16 ニトロ化方法

Country Status (4)

Country Link
US (1) US4551568A (enExample)
EP (1) EP0092372B1 (enExample)
JP (1) JPS58180460A (enExample)
DE (1) DE3360768D1 (enExample)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4754083A (en) * 1986-04-24 1988-06-28 Amoco Corporation Para selectivity in catalyzed disubstitutions of monosubstituted benzenes containing meta-directing substituents
JPH0249755A (ja) * 1988-05-18 1990-02-20 Sumitomo Chem Co Ltd ニトロベンゼン類の製造法
US5354924A (en) * 1988-06-22 1994-10-11 Olin Corporation Process for the production of dinitrotoluene
US5488187A (en) * 1988-06-22 1996-01-30 Olin Corporation Process for the production of dinitrobenzene and mononitrobenzene
US5001272A (en) * 1988-06-22 1991-03-19 Olin Corporation Process for the production of dinitrotoluene
US4918250A (en) * 1989-04-21 1990-04-17 Olin Corporation Process for the production of dinitrotoluene using an inorganic salt as a phase separation agent
JPH0311042A (ja) * 1989-06-08 1991-01-18 Sumitomo Chem Co Ltd 接触的ニトロ化方法
CH683918A5 (de) * 1991-12-04 1994-06-15 Uetikon Chemie Ag Verfahren zur Herstellung von Nitrobenzol.
CH683919A5 (de) * 1992-01-15 1994-06-15 Uetikon Chemie Ag Verfahren zur Herstellung von Nitrobenzol.
DE19935691A1 (de) * 1999-07-29 2001-02-01 Merck Patent Gmbh Friedel-Crafts-Acylierung im statischen Mikromischer
DE19935692A1 (de) * 1999-07-29 2001-02-01 Merck Patent Gmbh Nitrierung in einem statischen Mikromischer
DE10047163A1 (de) * 2000-09-22 2002-04-11 Basf Ag Verfahren zur Nitrierung aromatischer Kohlenwasserstoffe
US6991678B2 (en) * 2002-07-31 2006-01-31 Council Of Scientific And Industrial Research Process for preparing microporous crystalline titanium silicate
EP1386907B1 (en) * 2002-07-31 2011-10-05 Council of Scientific and Industrial Research Process for vapor phase nitration of benzene using nitric acid over molybdenum silica catalyst
KR101183822B1 (ko) * 2009-12-18 2012-09-19 한국화학연구원 고체 산촉매를 이용한 니트로파라핀의 제조방법
CN102093222A (zh) * 2010-12-23 2011-06-15 南京大学扬州化学化工研究院 固体酸催化剂SO42-/TiO2-HNbMoO6催化甲苯选择性硝化的方法
CN103781756B (zh) * 2011-08-17 2016-08-17 韩国化学研究院 由气相硝基化反应的硝基石蜡的制备方法
KR101282735B1 (ko) * 2011-08-17 2013-07-05 금호석유화학 주식회사 고체 염기촉매를 이용하는 기체상 니트로화 반응에 의한 니트로파라핀의 제조방법
KR101282734B1 (ko) * 2011-08-17 2013-07-05 금호석유화학 주식회사 고체산 촉매를 이용한 니트로파라핀의 제조방법
CN102432471B (zh) * 2011-11-07 2013-12-18 常州大学 一种利用微通道反应器进行氯苯硝基反应的方法
US9409854B2 (en) 2013-06-03 2016-08-09 Council Of Scientific & Industrial Research Liquid phase nitration of aromatics using solid acid catalyst
CN103922940B (zh) * 2013-12-02 2016-04-20 刘凤能 一种生产硝基苯的工艺
CN106431930B (zh) * 2015-08-05 2018-07-17 湘潭大学 从苯制备硝基苯的方法
CN109320423B (zh) * 2018-11-22 2021-08-10 四川金象赛瑞化工股份有限公司 一种微通道反应器合成硝基化合物的方法
CN109675508B (zh) * 2018-12-11 2021-05-07 浙江工业大学 全氟磺酸树脂/固体酸微纤化微通道反应器的制备方法和应用

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2109873A (en) * 1938-03-01 Process of nitrating hydrocarbons
GB578044A (en) * 1943-04-23 1946-06-13 Malcolm Percival Appleby Improvements in and relating to the production of nitroparaffins
GB586732A (en) * 1944-06-29 1947-03-28 Alfred Edgar Rout Improvements in the nitration of aromatic hydrocarbons
GB866162A (en) * 1956-12-31 1961-04-26 English Electric Co Ltd Improvements in and relating to electric fusegear
US3792099A (en) * 1972-07-31 1974-02-12 Standard Oil Co Branched polyphenylenes
DE2632234C3 (de) * 1976-07-17 1978-12-21 Hoechst Ag, 6000 Frankfurt Verfahren zur Herstellung von Nitrotoluolgemischen mit einem überwiegenden Gehalt an Nitrotoluol
EP0053031B1 (en) * 1980-11-26 1984-09-12 Monsanto Company A process for the vapor phase nitration of aromatic compounds
US4415744A (en) * 1981-10-21 1983-11-15 Monsanto Company Vapor phase nitration of aromatic compounds
EP0078247B1 (en) * 1981-10-21 1985-11-27 Monsanto Company Process and catalysts for vapor phase nitration of aromatic compounds

Also Published As

Publication number Publication date
EP0092372A1 (en) 1983-10-26
JPS58180460A (ja) 1983-10-21
DE3360768D1 (en) 1985-10-17
US4551568A (en) 1985-11-05
EP0092372B1 (en) 1985-09-11

Similar Documents

Publication Publication Date Title
JPH0422897B2 (enExample)
WO1997020630A1 (de) Amorphe mikroporöse mischoxidkatalysatoren mit kontrollierter oberflächenpolarität für die selektive heterogene katalyse, adsorption und stofftrennung
CA2933484C (en) Improved catalyst for ethane odh
JP4090885B2 (ja) シクロヘキサノンオキシムの製造方法
Sato et al. Vapor phase nitration of benzene over solid acid catalysts: II. Nitration with nitric acid (1); montmorillonite and mixed metal oxide catalysts
US11040336B2 (en) Catalyst of platinum/zirconium dioxide/SBA-15 and method for preparing p-chloroaniline using the same
KR100995756B1 (ko) 방향족 화합물의 알킬화 공정
EP0343048B1 (en) Process for producing nitrobenzenes
CA2048017A1 (en) One step synthesis of methyl t-butyl ether from t-butanol plus methanol using group iv oxides treated with sulfates or sulfuric acid
Mao et al. A clean method for solvent-free nitration of toluene over sulfated titania promoted by ceria catalysts
JPWO2003010133A1 (ja) シクロヘキサノンオキシムの製造方法
US6114274A (en) Preparation of aliphatic carboxylic acids in the presence of heteropolyacid catalysts
JPH1135497A (ja) クメンの製造方法
EP3801889B1 (en) Catalysts for single step double dehydrogenation of butadiene from n-butane
EP1386907B1 (en) Process for vapor phase nitration of benzene using nitric acid over molybdenum silica catalyst
Maurya et al. Solid acid catalysts for fluorotoluene nitration using nitric acid
EP0911309A1 (en) Process for producing fluorene or its derivatives
JPS58162557A (ja) ニトロ化方法
JP4760917B2 (ja) 固体酸触媒の調製方法、及び該触媒を用いたラクタム化合物の製造方法
JP2944463B2 (ja) メタクリル酸製造用触媒およびこの触媒を用いたメタクリル酸の製造方法
JPS6229556A (ja) ベンゼンの気相ニトロ化方法
Kemdeo MoO3/SiO2-ZrO2 Catalyst: Eeffect of Calcination Temperature on Physico-chemical Properties and Activities in Nitration of Toluene
JPH02300149A (ja) ニトロベンゼン類の製造方法
JP3020153B2 (ja) エタノール合成用触媒
JP2006272217A (ja) 硫酸化処理された固体酸触媒およびその使用