JPH0327563B2 - - Google Patents
Info
- Publication number
- JPH0327563B2 JPH0327563B2 JP1256892A JP25689289A JPH0327563B2 JP H0327563 B2 JPH0327563 B2 JP H0327563B2 JP 1256892 A JP1256892 A JP 1256892A JP 25689289 A JP25689289 A JP 25689289A JP H0327563 B2 JPH0327563 B2 JP H0327563B2
- Authority
- JP
- Japan
- Prior art keywords
- polymer
- water
- cation
- molecular weight
- acidic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229920000642 polymer Polymers 0.000 claims description 109
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 33
- 150000001768 cations Chemical class 0.000 claims description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 230000002378 acidificating effect Effects 0.000 claims description 28
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 239000000178 monomer Substances 0.000 claims description 27
- 238000006386 neutralization reaction Methods 0.000 claims description 25
- 239000000203 mixture Substances 0.000 claims description 21
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 16
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 12
- 239000012071 phase Substances 0.000 claims description 12
- 229910052708 sodium Inorganic materials 0.000 claims description 12
- 239000011734 sodium Substances 0.000 claims description 12
- 229920003169 water-soluble polymer Polymers 0.000 claims description 11
- 239000012074 organic phase Substances 0.000 claims description 10
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 8
- 229910052744 lithium Inorganic materials 0.000 claims description 8
- 229910052700 potassium Inorganic materials 0.000 claims description 8
- 239000011591 potassium Substances 0.000 claims description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 7
- 239000003513 alkali Substances 0.000 claims description 7
- 239000008346 aqueous phase Substances 0.000 claims description 6
- 239000002798 polar solvent Substances 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 5
- 239000002253 acid Substances 0.000 claims description 4
- 159000000000 sodium salts Chemical class 0.000 claims description 4
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 3
- 125000004432 carbon atom Chemical group C* 0.000 claims description 3
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 claims description 2
- 230000000379 polymerizing effect Effects 0.000 claims 2
- 125000003158 alcohol group Chemical group 0.000 claims 1
- 239000000049 pigment Substances 0.000 description 26
- 239000002270 dispersing agent Substances 0.000 description 24
- 229920002125 Sokalan® Polymers 0.000 description 23
- 239000004584 polyacrylic acid Substances 0.000 description 22
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 20
- 239000006185 dispersion Substances 0.000 description 19
- 239000000243 solution Substances 0.000 description 19
- 239000000047 product Substances 0.000 description 16
- 230000000694 effects Effects 0.000 description 11
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 description 11
- 238000000926 separation method Methods 0.000 description 11
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 10
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 9
- 229910000019 calcium carbonate Inorganic materials 0.000 description 9
- 238000005194 fractionation Methods 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 9
- 238000005191 phase separation Methods 0.000 description 8
- 150000003839 salts Chemical class 0.000 description 7
- 239000002904 solvent Substances 0.000 description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 238000002474 experimental method Methods 0.000 description 6
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 6
- 239000004579 marble Substances 0.000 description 6
- 238000003801 milling Methods 0.000 description 6
- 239000003960 organic solvent Substances 0.000 description 6
- IRLPACMLTUPBCL-KQYNXXCUSA-N 5'-adenylyl sulfate Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@@H]1O[C@H](COP(O)(=O)OS(O)(=O)=O)[C@@H](O)[C@H]1O IRLPACMLTUPBCL-KQYNXXCUSA-N 0.000 description 5
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000005498 polishing Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 4
- 239000007864 aqueous solution Substances 0.000 description 4
- 238000004821 distillation Methods 0.000 description 4
- 238000005227 gel permeation chromatography Methods 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- 238000001556 precipitation Methods 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 239000003999 initiator Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 125000000542 sulfonic acid group Chemical group 0.000 description 3
- 239000004408 titanium dioxide Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 238000000227 grinding Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- DZSVIVLGBJKQAP-UHFFFAOYSA-N 1-(2-methyl-5-propan-2-ylcyclohex-2-en-1-yl)propan-1-one Chemical compound CCC(=O)C1CC(C(C)C)CC=C1C DZSVIVLGBJKQAP-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 239000012670 alkaline solution Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 1
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 1
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000003042 antagnostic effect Effects 0.000 description 1
- 239000012223 aqueous fraction Substances 0.000 description 1
- 239000012736 aqueous medium Substances 0.000 description 1
- 239000002152 aqueous-organic solution Substances 0.000 description 1
- 238000003556 assay Methods 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 150000007514 bases Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000002843 carboxylic acid group Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000010419 fine particle Substances 0.000 description 1
- 238000001030 gas--liquid chromatography Methods 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 239000012456 homogeneous solution Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000006053 organic reaction Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L persulfate group Chemical group S(=O)(=O)([O-])OOS(=O)(=O)[O-] JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000002954 polymerization reaction product Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000004576 sand Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D17/00—Pigment pastes, e.g. for mixing in paints
- C09D17/004—Pigment pastes, e.g. for mixing in paints containing an inorganic pigment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F6/00—Post-polymerisation treatments
- C08F6/04—Fractionation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Pigments, Carbon Blacks, Or Wood Stains (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Extraction Or Liquid Replacement (AREA)
- Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB838313976A GB8313976D0 (en) | 1983-05-20 | 1983-05-20 | Water soluble polymers |
| GB8313976 | 1983-05-20 | ||
| GB838321731A GB8321731D0 (en) | 1983-08-12 | 1983-08-12 | Water soluble polymers |
| GB8321731 | 1983-08-12 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59103554A Division JPS59223702A (ja) | 1983-05-20 | 1984-05-21 | 顔料用分散剤 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02139005A JPH02139005A (ja) | 1990-05-29 |
| JPH0327563B2 true JPH0327563B2 (enExample) | 1991-04-16 |
Family
ID=26286181
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1256892A Granted JPH02139005A (ja) | 1983-05-20 | 1989-09-28 | 水溶性ポリマーの分離方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (4) | US4507422A (enExample) |
| EP (2) | EP0129329B2 (enExample) |
| JP (1) | JPH02139005A (enExample) |
| CA (1) | CA1265635A (enExample) |
| DE (2) | DE3461810D1 (enExample) |
| FI (1) | FI77674C (enExample) |
| NO (1) | NO841997L (enExample) |
Families Citing this family (102)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2531444A1 (fr) * | 1982-08-06 | 1984-02-10 | Coatex Sa | Agent de broyage a base de polymeres et/ou copolymeres acryliques pour suspension aqueuse de materiaux mineraux grossiers en vue d'applications pigmentaires |
| FR2539137A1 (fr) * | 1982-08-06 | 1984-07-13 | Coatex Sa | Agent de broyage a base de polymeres et/ou copolymeres acryliques neutralises pour suspension aqueuse de materiaux mineraux grossiers en vue d'applications pigmentaires |
| GB8419805D0 (en) * | 1984-08-03 | 1984-09-05 | Allied Colloids Ltd | Aqueous drilling and packer fluids |
| GB8428984D0 (en) * | 1984-11-16 | 1984-12-27 | Allied Colloids Ltd | Water soluble polymers |
| AU581417B2 (en) | 1984-11-16 | 1989-02-23 | Ciba Specialty Chemicals Water Treatments Limited | Water soluble polymers and dispersions containing them |
| AU618032B2 (en) * | 1984-11-16 | 1991-12-12 | Ciba Specialty Chemicals Water Treatments Limited | Separating water soluble polymers |
| FR2577568B1 (fr) * | 1985-02-19 | 1987-12-18 | Coatex Sa | Agent fluidifiant non polluant pour fluides de forage a base d'eau douce ou saline |
| US4680128A (en) * | 1985-04-26 | 1987-07-14 | Exxon Chemical Patents Inc. | Anionic copolymers for improved control of drilling fluid rheology |
| FR2581651B1 (fr) * | 1985-05-13 | 1988-02-26 | Rhone Poulenc Spec Chim | Dispersants pour fluides de forage et fluides de forage les contenant |
| US5039433A (en) * | 1985-09-10 | 1991-08-13 | The Lubrizol Corporation | Method of using polymers of amido-sulfonic acid containing monomers and salts as drilling additive |
| US4715971A (en) * | 1985-12-09 | 1987-12-29 | Engineering & Colloid, Ltd. | Well drilling and completion composition |
| US4826611A (en) * | 1985-12-09 | 1989-05-02 | Engineering & Colloid, Ltd. | Well drilling and completion composition |
| US4721576A (en) * | 1985-12-13 | 1988-01-26 | Hale Arthur H | Well drilling fluids and process for drilling wells |
| US4812244A (en) * | 1985-12-13 | 1989-03-14 | Pony Industries, Inc. | Well drilling fluids and process for drilling wells |
| US4728445A (en) * | 1985-12-13 | 1988-03-01 | Pony Industries, Inc. | Well drilling fluids and process for drilling wells |
| US4740318A (en) * | 1985-12-13 | 1988-04-26 | Great Lakes Research Corp. | Well drilling fluids and process for drilling wells |
| US4711731A (en) * | 1986-02-06 | 1987-12-08 | Diamond Shamrock Chemicals Company | Drilling fluid dispersant |
| US4814389A (en) * | 1986-02-06 | 1989-03-21 | Diamond Shamrock Chemicals Company | Drilling fluid dispersant |
| US4745154A (en) * | 1986-04-14 | 1988-05-17 | Alco Chemical Corporation | Water soluble polymers, their preparation and their uses |
| US4891401A (en) * | 1986-09-30 | 1990-01-02 | E. I. Du Pont De Nemours And Company | Pigment dispersant resin with P-containing acid |
| WO1988002381A1 (en) * | 1986-09-30 | 1988-04-07 | E.I. Du Pont De Nemours And Company | Pigment dispersant resin with s-containing acid |
| FR2610637B1 (fr) * | 1987-02-11 | 1989-05-12 | Coatex Sa | Agent de pretraitement de materiaux mineraux grossiers en vue d'applications pigmentaires |
| US4976997A (en) * | 1987-06-15 | 1990-12-11 | Chemco Technologies, Inc. | Surface composition for a substrate and method of preparation |
| US4935463A (en) * | 1987-06-15 | 1990-06-19 | Chemco Technologies, Inc. | Surface composition for a substrate and method of preparation |
| US4770795A (en) * | 1987-08-24 | 1988-09-13 | Nalco Chemical Company | Calcium tolerant deflocculant for drilling fluids |
| IL88054A0 (en) * | 1987-10-19 | 1989-06-30 | Union Carbide Corp | Stable aqueous dispersions of water-insoluble particulate solids and processes for the preparation thereof |
| US5275650A (en) * | 1987-10-23 | 1994-01-04 | Coatex S.A. | Agent for grinding lime to augment its reactivity |
| US5693692A (en) * | 1988-05-02 | 1997-12-02 | Huntsman Petrochemical Corp. | Depressant for flotation separation of polymetallic sulphide ores |
| DE3833045A1 (de) * | 1988-09-29 | 1990-04-05 | Henkel Kgaa | Bohrspueladditive auf basis eines polymergemiches, deren verwendung sowie verfahren zur herstellung derselben |
| US5032295A (en) * | 1989-04-25 | 1991-07-16 | National Starch And Chemical Investment Holding Corporation | Polymers for use in drilling muds |
| US5023368A (en) * | 1989-06-08 | 1991-06-11 | National Starch And Chemical Investment Holding Corporation | Aminophosphonate-containing polymers |
| US4995982A (en) * | 1989-11-01 | 1991-02-26 | Marathon Oil Company | Process for recovering and purifying a high molecular weight sulfonate |
| US5008025A (en) * | 1989-11-16 | 1991-04-16 | Mobil Oil Corporation | Sulfonate-containing polymer/polyanionic cellulose combination for high temperature/high pressure filtration control in water base drilling fluids |
| US5075164A (en) * | 1989-12-05 | 1991-12-24 | Eastman Kodak Company | Print retaining coatings |
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| DK2143688T3 (en) | 2008-07-07 | 2017-01-09 | Omya Int Ag | A process for the preparation of aqueous suspensions of calcium carbonate, and the resulting suspensions as well as uses thereof |
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| SI2910609T1 (sl) | 2014-02-21 | 2017-11-30 | Omya International Ag | Postopek za pripravo polnilnega proizvoda na osnovi kalcijevega karbonata |
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| JP2019536840A (ja) * | 2016-10-07 | 2019-12-19 | ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ | 二酸化チタン顔料を含有するラテックス塗料 |
| CN116694142A (zh) * | 2023-08-07 | 2023-09-05 | 晋江厚德印花有限公司 | 着色效果好的转印膜打印用颜料及其制备方法 |
| EP4613816A1 (de) * | 2024-03-05 | 2025-09-10 | Gebrüder Dorfner GmbH & Co. KG | Partikel mit einer polymer-beschichtung sowie verfahren zur herstellung dieser beschichteten partikel und deren anwendung |
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| NL104335C (enExample) * | 1953-08-11 | |||
| US3296172A (en) * | 1963-02-28 | 1967-01-03 | Du Pont | Preparing aqueous polymer dispersions in presence of polar liquids |
| GB1375731A (enExample) * | 1971-06-03 | 1974-11-27 | ||
| GB1414964A (en) * | 1971-10-19 | 1975-11-19 | English Clays Lovering Pochin | Copolymers and their use in the treatment of materials |
| DE2225317C3 (de) * | 1972-05-25 | 1978-06-01 | Basf Ag, 6700 Ludwigshafen | Papierstreichmassen |
| US3759860A (en) * | 1972-06-19 | 1973-09-18 | Uniroyal Inc | Coating compositions and coated articles |
| AU473121B2 (en) * | 1973-02-01 | 1976-06-10 | Bayer Aktiengesellschaft | Pulverizable acrylic resins |
| US3794608A (en) * | 1973-05-11 | 1974-02-26 | Dow Chemical Co | Aqueous coating compositions thickened by a terpolymer of an alkenyl aromatic compound,an unsaturated dicarboxylic acid,and an ether of vinyl benzyl alcohol and an oxyalkylated compound |
| GB1505555A (en) * | 1975-03-04 | 1978-03-30 | Allied Colloids Ltd | Water based surface coatings |
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| US4419466A (en) * | 1981-06-25 | 1983-12-06 | The Lubrizol Corporation | Method for continuous production of invert emulsion polymers |
| US4681918A (en) * | 1981-06-30 | 1987-07-21 | E. I. Du Pont De Nemours And Company | "Living" polymers and process for their preparation |
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-
1984
- 1984-05-16 DE DE8484303332T patent/DE3461810D1/de not_active Expired
- 1984-05-16 EP EP84303333A patent/EP0129329B2/en not_active Expired - Lifetime
- 1984-05-16 EP EP84303332A patent/EP0127388B1/en not_active Expired
- 1984-05-16 DE DE8484303333T patent/DE3479223D1/de not_active Expired
- 1984-05-17 CA CA000454568A patent/CA1265635A/en not_active Expired - Lifetime
- 1984-05-17 FI FI841990A patent/FI77674C/fi not_active IP Right Cessation
- 1984-05-18 NO NO841997A patent/NO841997L/no unknown
- 1984-05-21 US US06/612,516 patent/US4507422A/en not_active Expired - Lifetime
- 1984-05-21 US US06/612,185 patent/US4503172A/en not_active Expired - Lifetime
- 1984-11-16 US US06/672,308 patent/US4554307A/en not_active Expired - Lifetime
- 1984-11-16 US US06/672,312 patent/US4554298A/en not_active Expired - Lifetime
-
1989
- 1989-09-28 JP JP1256892A patent/JPH02139005A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| EP0127388B1 (en) | 1986-12-30 |
| EP0129329B2 (en) | 1998-04-01 |
| JPH02139005A (ja) | 1990-05-29 |
| US4507422A (en) | 1985-03-26 |
| FI77674B (fi) | 1988-12-30 |
| EP0129329B1 (en) | 1989-08-02 |
| FI841990L (fi) | 1984-11-21 |
| NO841997L (no) | 1984-11-21 |
| DE3479223D1 (en) | 1989-09-07 |
| US4503172A (en) | 1985-03-05 |
| DE3461810D1 (en) | 1987-02-05 |
| EP0129329A2 (en) | 1984-12-27 |
| US4554298A (en) | 1985-11-19 |
| EP0129329A3 (en) | 1986-04-16 |
| FI77674C (fi) | 1989-04-10 |
| US4554307A (en) | 1985-11-19 |
| CA1265635A (en) | 1990-02-06 |
| FI841990A0 (fi) | 1984-05-17 |
| EP0127388A1 (en) | 1984-12-05 |
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