JPH026777B2 - - Google Patents
Info
- Publication number
- JPH026777B2 JPH026777B2 JP22824982A JP22824982A JPH026777B2 JP H026777 B2 JPH026777 B2 JP H026777B2 JP 22824982 A JP22824982 A JP 22824982A JP 22824982 A JP22824982 A JP 22824982A JP H026777 B2 JPH026777 B2 JP H026777B2
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- rubber
- parts
- weight
- nitrogen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 229920001971 elastomer Polymers 0.000 claims description 27
- 239000005060 rubber Substances 0.000 claims description 27
- 239000000203 mixture Substances 0.000 claims description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 12
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- 125000000217 alkyl group Chemical group 0.000 claims description 8
- 229910052759 nickel Inorganic materials 0.000 claims description 7
- 239000012991 xanthate Substances 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 6
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 claims description 6
- BQHTWZRFOSRCCH-UHFFFAOYSA-L nickel(2+);dicarbamodithioate Chemical compound [Ni+2].NC([S-])=S.NC([S-])=S BQHTWZRFOSRCCH-UHFFFAOYSA-L 0.000 claims description 5
- 150000001993 dienes Chemical class 0.000 claims description 4
- 150000002815 nickel Chemical class 0.000 claims description 4
- 229920003051 synthetic elastomer Polymers 0.000 claims description 4
- 239000005061 synthetic rubber Substances 0.000 claims description 4
- 244000043261 Hevea brasiliensis Species 0.000 claims description 3
- 229920003052 natural elastomer Polymers 0.000 claims description 3
- 229920001194 natural rubber Polymers 0.000 claims description 3
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 2
- 230000006835 compression Effects 0.000 description 11
- 238000007906 compression Methods 0.000 description 11
- 229960002447 thiram Drugs 0.000 description 11
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 10
- -1 thiuram compound Chemical class 0.000 description 10
- 238000004073 vulcanization Methods 0.000 description 10
- 238000012360 testing method Methods 0.000 description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 7
- 230000032683 aging Effects 0.000 description 7
- 229910052717 sulfur Inorganic materials 0.000 description 7
- 239000011593 sulfur Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 6
- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 6
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 239000003431 cross linking reagent Substances 0.000 description 5
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 5
- 229920003048 styrene butadiene rubber Polymers 0.000 description 5
- 239000011787 zinc oxide Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- AUZONCFQVSMFAP-UHFFFAOYSA-N disulfiram Chemical compound CCN(CC)C(=S)SSC(=S)N(CC)CC AUZONCFQVSMFAP-UHFFFAOYSA-N 0.000 description 4
- 229920000459 Nitrile rubber Polymers 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 238000004132 cross linking Methods 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 239000002174 Styrene-butadiene Substances 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- SDGKUVSVPIIUCF-UHFFFAOYSA-N 2,6-dimethylpiperidine Chemical compound CC1CCCC(C)N1 SDGKUVSVPIIUCF-UHFFFAOYSA-N 0.000 description 1
- CPGFMWPQXUXQRX-UHFFFAOYSA-N 3-amino-3-(4-fluorophenyl)propanoic acid Chemical compound OC(=O)CC(N)C1=CC=C(F)C=C1 CPGFMWPQXUXQRX-UHFFFAOYSA-N 0.000 description 1
- BUZICZZQJDLXJN-UHFFFAOYSA-N 3-azaniumyl-4-hydroxybutanoate Chemical compound OCC(N)CC(O)=O BUZICZZQJDLXJN-UHFFFAOYSA-N 0.000 description 1
- HLBZWYXLQJQBKU-UHFFFAOYSA-N 4-(morpholin-4-yldisulfanyl)morpholine Chemical compound C1COCCN1SSN1CCOCC1 HLBZWYXLQJQBKU-UHFFFAOYSA-N 0.000 description 1
- QNTARNCGFNQQRP-UHFFFAOYSA-N 5-carbamothioylsulfanylpentyl carbamodithioate Chemical compound NC(=S)SCCCCCSC(N)=S QNTARNCGFNQQRP-UHFFFAOYSA-N 0.000 description 1
- DGJWKLOHCHFWAF-UHFFFAOYSA-N C(C)(C)[Ni] Chemical compound C(C)(C)[Ni] DGJWKLOHCHFWAF-UHFFFAOYSA-N 0.000 description 1
- KOKOYYJFGZIZPY-UHFFFAOYSA-N CCCC[Ni] Chemical compound CCCC[Ni] KOKOYYJFGZIZPY-UHFFFAOYSA-N 0.000 description 1
- QBRKLGSYMHHFTE-UHFFFAOYSA-N CC[Ni] Chemical compound CC[Ni] QBRKLGSYMHHFTE-UHFFFAOYSA-N 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- RLULIUSIDLLCSW-UHFFFAOYSA-N diethylcarbamothioylsulfanylselanyl n,n-diethylcarbamodithioate Chemical compound CCN(CC)C(=S)S[Se]SC(=S)N(CC)CC RLULIUSIDLLCSW-UHFFFAOYSA-N 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 description 1
- ZVFKOPAELLPDTR-UHFFFAOYSA-L n,n-dibenzylcarbamodithioate;nickel(2+) Chemical compound [Ni+2].C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1 ZVFKOPAELLPDTR-UHFFFAOYSA-L 0.000 description 1
- HPOWMHUJHHIQGP-UHFFFAOYSA-L n,n-dibutylcarbamodithioate;nickel(2+) Chemical compound [Ni+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC HPOWMHUJHHIQGP-UHFFFAOYSA-L 0.000 description 1
- NCLUCMXMAPDFGT-UHFFFAOYSA-L n,n-diethylcarbamodithioate;nickel(2+) Chemical compound [Ni+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S NCLUCMXMAPDFGT-UHFFFAOYSA-L 0.000 description 1
- BLCKKNLGFULNRC-UHFFFAOYSA-L n,n-dimethylcarbamodithioate;nickel(2+) Chemical compound [Ni+2].CN(C)C([S-])=S.CN(C)C([S-])=S BLCKKNLGFULNRC-UHFFFAOYSA-L 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 238000009864 tensile test Methods 0.000 description 1
- 239000004636 vulcanized rubber Substances 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22824982A JPS59124942A (ja) | 1982-12-30 | 1982-12-30 | ゴム組成物 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP22824982A JPS59124942A (ja) | 1982-12-30 | 1982-12-30 | ゴム組成物 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS59124942A JPS59124942A (ja) | 1984-07-19 |
| JPH026777B2 true JPH026777B2 (enrdf_load_stackoverflow) | 1990-02-13 |
Family
ID=16873498
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP22824982A Granted JPS59124942A (ja) | 1982-12-30 | 1982-12-30 | ゴム組成物 |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS59124942A (enrdf_load_stackoverflow) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE3709313A1 (de) * | 1987-03-21 | 1988-09-29 | Freudenberg Carl Fa | Vulkanisationsbeschleuniger |
| JPH0299667A (ja) * | 1988-09-29 | 1990-04-11 | Mitsuboshi Belting Ltd | ゴム補強用処理繊維及び同繊維により補強した補強ゴム製品 |
| WO2015159934A1 (ja) * | 2014-04-16 | 2015-10-22 | 株式会社ブリヂストン | ゴム組成物 |
-
1982
- 1982-12-30 JP JP22824982A patent/JPS59124942A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS59124942A (ja) | 1984-07-19 |
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