JPH01238932A - Composite one side face metal laminated plate - Google Patents

Composite one side face metal laminated plate

Info

Publication number
JPH01238932A
JPH01238932A JP6615888A JP6615888A JPH01238932A JP H01238932 A JPH01238932 A JP H01238932A JP 6615888 A JP6615888 A JP 6615888A JP 6615888 A JP6615888 A JP 6615888A JP H01238932 A JPH01238932 A JP H01238932A
Authority
JP
Japan
Prior art keywords
resin
impregnated
metal foil
foil
paper
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP6615888A
Other languages
Japanese (ja)
Inventor
Shigeo Suzuki
鈴木 重夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Panasonic Electric Works Co Ltd
Original Assignee
Matsushita Electric Works Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Matsushita Electric Works Ltd filed Critical Matsushita Electric Works Ltd
Priority to JP6615888A priority Critical patent/JPH01238932A/en
Publication of JPH01238932A publication Critical patent/JPH01238932A/en
Pending legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0313Organic insulating material
    • H05K1/0353Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/036Multilayers with layers of different types
    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05KPRINTED CIRCUITS; CASINGS OR CONSTRUCTIONAL DETAILS OF ELECTRIC APPARATUS; MANUFACTURE OF ASSEMBLAGES OF ELECTRICAL COMPONENTS
    • H05K1/00Printed circuits
    • H05K1/02Details
    • H05K1/03Use of materials for the substrate
    • H05K1/0313Organic insulating material
    • H05K1/0353Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement
    • H05K1/0366Organic insulating material consisting of two or more materials, e.g. two or more polymers, polymer + filler, + reinforcement reinforced, e.g. by fibres, fabrics

Landscapes

  • Laminated Bodies (AREA)

Abstract

PURPOSE:To obtain a printed circuit board or the like having small warpage by employing as resin-impregnated sheets predetermined number of resin- impregnated kraft paper at the side near a metal foil and predetermined number of resin-impregnated linter sheets at the side farthest from the foil. CONSTITUTION:A composite one side face metal laminated plate is combined to be laminated sequentially from above with a metal foil 1, a resin-impregnated glass cloth 2, a resin-impregnated kraft paper 3, a resin-impregnated linter sheet 4 and a resin-impregnated glass cloth 2 in this order. As the foil 1 to become the outermost layer of the laminated plate, copper, aluminium, nickel, zinc, iron, etc., are listed solely or as a metal foil of an alloy thereof, but it is not limited thereto. An adhesive layer may be provided on one side face (rear face) of the foil as required.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 この発明は、プリント配線板等に使用されるコンポジッ
ト片面金属張積層板に関する。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a composite single-sided metal-clad laminate used for printed wiring boards and the like.

〔従来の技術〕[Conventional technology]

近年、電子機器の高密度化、高性能化、低価格化等が急
速に進み、こうした趨勢に対応できるプリント配線板材
料として、電気絶縁性、打抜加工性、耐熱性などに優れ
、価格面でも有利なコンポジット基板が注目されている
In recent years, the density, performance, and price of electronic devices have rapidly increased, and printed wiring board materials that can respond to these trends have excellent electrical insulation, punching workability, heat resistance, etc., and are becoming more affordable. However, advantageous composite substrates are attracting attention.

このコンポジフト基板とは、2種または2種以上の基材
を用いた積層板であって、異なる特性を有する両基材の
それぞれの短所を改善し、長所を生かすように構成され
ている。代表的なコンポジット基板としては、たとえば
、芯材としてエポキシ樹脂含浸紙、その外側の表層材と
して同樹脂含浸ガラス布が用いられた銅張積層板(CE
M−1)、芯材としてエポキシ樹脂含浸ガラス不織布、
表層材として同樹脂含浸ガラス布が用いられた銅張積層
板(OEM−3)等が挙げられる。
This composite substrate is a laminated board using two or more types of base materials, and is configured to improve the respective disadvantages and take advantage of the advantages of both base materials having different characteristics. A typical composite board is, for example, a copper-clad laminate (CE), which uses epoxy resin-impregnated paper as the core material and glass cloth impregnated with the same resin as the outer surface layer material.
M-1), epoxy resin-impregnated glass nonwoven fabric as core material,
Examples include a copper-clad laminate (OEM-3) in which the same resin-impregnated glass cloth is used as a surface layer material.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

ところが、上記OEM−l等のように、芯材として紙基
材が用いられたコンポジット基板のうち、とりわけ片面
金属張の積層板においては、従来から、金属箔面が凹と
なるような反り(マイナス反り、あるいは単に反りとい
う)が大きい、という問題があった。紙基材としては、
通常、リンター紙が用いられているが、この場合、主と
してプリント加工工程時、特にエソチング工程時にマイ
ナス反りが大きい、という欠点がある。このことは、最
近のパターンサイズの大型化においては、致命的な欠陥
になってしまう。そこで、リンター紙に代えてクラフト
紙を用いることが試みられたが、こちらは、エツチング
加工、パンチング加工時等における反り挙動は小さいが
、積層板成形直後の反り、または保管時における経時的
な反りが大きいため、加工直前に反り直しを行う必要が
ある、という別の難点を有していた。
However, among composite substrates that use a paper base material as a core material, such as the OEM-1 mentioned above, especially in single-sided metal-clad laminates, warping (such as a concave metal foil surface) has traditionally occurred. The problem was that there was a large amount of negative warpage (or simply warpage). As a paper base material,
Usually, linter paper is used, but in this case, there is a drawback that negative warpage is large mainly during the printing process, especially during the etching process. This becomes a fatal flaw in the recent increase in pattern size. Therefore, attempts were made to use kraft paper in place of linter paper, but although this paper has less warping behavior during etching and punching processes, it does not warp immediately after forming the laminate or warp over time during storage. Another problem was that since the curve was large, it was necessary to correct the warpage immediately before processing.

このような事情に鑑み、この発明は、最終的に反りの少
ないプリント配線板等が得られるようなコンポジット片
面金属張積層板を提供することを課題とする。
In view of these circumstances, it is an object of the present invention to provide a composite single-sided metal-clad laminate that can ultimately yield a printed wiring board or the like with less warpage.

〔課題を解決するための手段〕[Means to solve the problem]

上記課題を解決するため、この発明は、芯材として樹脂
含浸紙、表層材として樹脂含浸ガラス布が用いられ、片
面に金属箔が配されてなるコンポジット片面金属張積層
板において、前記樹脂含浸紙として、前記金属箔に近い
側に所定枚数の樹脂含浸クラフト紙を、前記金属箔から
遠い側に所定枚数の樹脂含浸リンター紙をそれぞれ用い
るようにした。
In order to solve the above problems, the present invention provides a composite single-sided metal-clad laminate in which resin-impregnated paper is used as a core material, resin-impregnated glass cloth is used as a surface material, and metal foil is arranged on one side. As such, a predetermined number of resin-impregnated kraft paper was used on the side closer to the metal foil, and a predetermined number of resin-impregnated linter paper was used on the side farther from the metal foil.

〔作   用〕[For production]

このコンポジット片面金属張積層板では、上記のように
、金属箔に近い側に所定枚数の樹脂含浸クラフト紙が配
設されており、クラフト紙の長所、すなわちプリント配
線板への加工時の反りが起こりにくい、という特性が生
かされている。他方、積層板成形後および保管時におけ
る反り挙動が大きい、というクラフト紙の短所は、併用
されているリンター紙の該段階における安定性にカバー
されるため、いずれの段階における反り挙動にも対応で
きる、反りの少ない積層板となる。
As mentioned above, in this composite single-sided metal-clad laminate, a predetermined number of resin-impregnated kraft paper is placed on the side closer to the metal foil, and the advantage of kraft paper is that it does not warp when processed into a printed wiring board. It takes advantage of the characteristic that it is difficult to occur. On the other hand, the disadvantage of kraft paper is that it exhibits large warping behavior after forming the laminate and during storage, but this is covered by the stability of the linter paper that is used in combination, so it can handle warping behavior at any stage. , resulting in a laminate with less warpage.

〔実 施 例〕〔Example〕

以下に、この発明にかかるコンポジット片面金属張積層
板について、図面を参照しつつ詳しく説明する。
EMBODIMENT OF THE INVENTION Below, the composite single-sided metal clad laminate according to the present invention will be explained in detail with reference to the drawings.

第1図は、コンポジット片面金属張積層板の一実施例を
模式的にあられす断面図であり、上から、金属箔l、樹
脂含浸ガラス布2.樹脂含浸クラフト紙3.樹脂含浸リ
ンター紙4.樹脂含浸ガラス布2という順に積層された
組み合わせになっている。
FIG. 1 is a schematic cross-sectional view of an embodiment of a composite single-sided metal-clad laminate, in which, from the top, metal foil 1, resin-impregnated glass cloth 2. Resin impregnated kraft paper 3. Resin-impregnated linter paper4. The resin-impregnated glass cloth 2 is laminated in this order.

この発明における樹脂含浸紙3,4および樹脂含浸ガラ
ス布2に用いられる樹脂としては、特に限定はされず、
たとえば、フェノール樹脂、メラミン樹脂、エポキシ樹
脂、ジアリルフタレート樹脂、不飽和ポリエステル樹脂
、クレゾール樹脂。
The resin used for the resin-impregnated papers 3 and 4 and the resin-impregnated glass cloth 2 in this invention is not particularly limited,
For example, phenolic resins, melamine resins, epoxy resins, diallyl phthalate resins, unsaturated polyester resins, cresol resins.

ビニルエステル樹脂、ポリイミド樹脂、ポリアミド樹脂
、ポリアミドイミド樹脂、フッ素樹脂、シリコーン樹脂
、ポリブタジェン樹脂、ポリエチレンテレフタレート樹
脂、ポリブチレンテレフタレート樹脂、ポリフェニレン
スルフィド樹脂等の一般的な各種熱硬化性樹脂、および
それらの変性物等が、単独で、あるいは複数種を併せて
用いられる。なかでも、耐熱性1強度等のバランスがよ
いことからエポキシ樹脂を用いることが好ましく、たと
えば、ビスフェノールA型、ノボラック型。
Various general thermosetting resins such as vinyl ester resins, polyimide resins, polyamide resins, polyamideimide resins, fluororesins, silicone resins, polybutadiene resins, polyethylene terephthalate resins, polybutylene terephthalate resins, polyphenylene sulfide resins, and their modifications. These items can be used singly or in combination. Among them, it is preferable to use epoxy resins because they have a good balance of heat resistance, strength, etc., such as bisphenol A type and novolak type.

グリシジルエステル型等の各エポキシ樹脂や、ハロゲン
化エポキシ樹脂、高分子型エポキシ樹脂。
Various epoxy resins such as glycidyl ester type, halogenated epoxy resin, and polymer type epoxy resin.

可撓性エポキシ樹脂など、エポキシ樹脂全般を用いるこ
とができる。
Any epoxy resin can be used, including flexible epoxy resins.

各基材への上記樹脂の含浸、乾燥方法等についても、特
に限定されず、上記樹脂および溶剤に、必要に応じて硬
化剤(架橋剤)、硬化促進剤9重合開始剤等の添加剤を
配合してフェスを調製し、これを通常の方法で基材に含
浸させ、その後、乾燥しつつ半硬化状態にまで樹脂の硬
化を進めればよい。
There are no particular limitations on the method of impregnating each base material with the above resin, drying method, etc. Additives such as a curing agent (crosslinking agent), a curing accelerator, and a polymerization initiator are added to the resin and solvent as necessary. The resin may be blended to prepare a face, impregnated into a base material by a normal method, and then dried to proceed with curing of the resin to a semi-cured state.

積層板の最外層となる金属箔1としては、たとえば、銅
、アルミニウム、ニッケル、亜鉛、鉄等の単独あるいは
合金の金属箔が挙げられるが、これらに限定されること
はない。また、必要に応じて、金属箔の片面(裏面)に
接着剤層が設けられていてもよい。
Examples of the metal foil 1 serving as the outermost layer of the laminate include, but are not limited to, metal foils made of copper, aluminum, nickel, zinc, iron, etc. alone or in alloys. Moreover, an adhesive layer may be provided on one side (back side) of the metal foil, if necessary.

以上の各構成要素を、第1図に示したような順に積層し
て積層体とし、通常の積層成形等を行って、この発明に
かかる積層板が製造される。
The above-mentioned components are laminated in the order shown in FIG. 1 to form a laminate, and the laminate plate according to the present invention is manufactured by performing ordinary lamination molding or the like.

なお、この発明にかかるコンポジフト片面金属張積層板
の構成は、ここに図示されたものに限定されないことは
言うまでもない。たとえば、樹脂含浸紙3.4および樹
脂含浸ガラス布2の積層枚数は、それぞれの配設位置に
おいて各1枚以上が、全体厚みとの関係上、任意に選択
されうるちのである。また、必要に応じては、上記樹脂
含浸基材2,3.4とともに、電気絶縁性、耐熱性等を
有する熱溶着性プラスチックフィルム(たとえば、ポリ
フェニレンオキシド、ポリフェニレンスルフィド、エポ
キシ樹脂、ポリイミド樹脂等)などが併用されていても
よい。
It goes without saying that the structure of the composite single-sided metal-clad laminate according to the present invention is not limited to that shown here. For example, the number of laminated sheets of resin-impregnated paper 3.4 and resin-impregnated glass cloth 2 can be arbitrarily selected such that one or more sheets of each are stacked at each arrangement position, depending on the overall thickness. If necessary, a heat-fusible plastic film (for example, polyphenylene oxide, polyphenylene sulfide, epoxy resin, polyimide resin, etc.) having electrical insulation, heat resistance, etc. may be used together with the resin-impregnated base materials 2, 3.4. etc. may be used together.

つぎに、さらに具体的な実施例および比較例について説
明する。
Next, more specific examples and comparative examples will be described.

一実施例1〜3および比較例1〜3− 基材として、ガラスクロス(日東紡績部製9品名誉E1
8に−104,厚み0.18mm)、クラフト紙(重陽
国策バルブ■製、厚み0.2龍)およびリンター紙(阿
部用製紙■製、厚み0.2wm)を使用し、これらに下
記成分からなるエポキシ樹脂フェスをレジンコンテント
50重量%になるよう含浸させ、乾燥してプリプレグを
得た。
Examples 1 to 3 and Comparative Examples 1 to 3 - Glass cloth (9 products manufactured by Nitto Boseki Department, Honor E1) was used as the base material.
8-104, thickness 0.18mm), kraft paper (manufactured by Chūyō Kokusaku Valve ■, thickness 0.2wm) and linter paper (manufactured by Abeyo Paper Manufacturing ■, thickness 0.2wm), and added the following ingredients to these. The epoxy resin face was impregnated with a resin content of 50% by weight and dried to obtain a prepreg.

※エポキシ樹脂フェスの組成 得られたプリプレグおよび銅箔(厚さ0.018鶴)を
用い、第1表に示した構成の各積層体を積層成形してコ
ンポジット片面銅張積層板(縦横250龍、厚み1.6
mm)を得た。なお、成形条件は、温度160℃、圧力
100kg/cd、時間60分間であった。
*Composition of epoxy resin face Using the obtained prepreg and copper foil (thickness: 0.018mm), each laminate with the configuration shown in Table 1 was laminated and molded to form a composite single-sided copper-clad laminate (250 mm in length and width). , thickness 1.6
mm) was obtained. The molding conditions were a temperature of 160° C., a pressure of 100 kg/cd, and a time of 60 minutes.

得られた各積層板について、成形直後、10日間保管(
温度20℃、湿度60%)後、続いて全面エツチング後
におけるそれぞれの反りを測定した(JIS C648
1に準じる)。なお、上記全面エツチングは、温度約3
0℃、40°ボーメの塩化第二鉄溶液を用い、この中に
約3分間浸漬させて行った。
Immediately after forming, each laminate obtained was stored for 10 days (
The warpage was measured after etching (temperature: 20°C, humidity: 60%) and then after etching the entire surface (JIS C648
1). Note that the above-mentioned entire surface etching is performed at a temperature of approximately 3.
A ferric chloride solution at 0° C. and 40° Baume was used, and the samples were immersed in this solution for about 3 minutes.

以上の結果を、第1表に示す。The above results are shown in Table 1.

第1表にみるように、実施例のコンポジット片面銅張積
層板では、比較例に比べ、全面エツチング後においても
、大幅にマイナス反りが減少していることが判明した。
As shown in Table 1, it was found that the negative warpage of the composite single-sided copper-clad laminate of the example was significantly reduced compared to the comparative example even after the entire surface was etched.

〔発明の効果〕〔Effect of the invention〕

この発明にかかるコンポジット片面金属張積層板では、
芯材となる樹脂含浸紙として、金属箔に近い側に所定枚
数の樹脂含浸クラフト紙が、金属箔から遠い側に所定枚
数の樹脂含浸リンター紙がそれぞれ用いられているため
、従来の問題点が解決され、マイナス反りの小さなガラ
ス布基材/紙基材コンボジフト片面金属張積層板の実現
を可能としている。
In the composite single-sided metal-clad laminate according to the present invention,
As the resin-impregnated paper that serves as the core material, a predetermined number of resin-impregnated kraft paper is used on the side closer to the metal foil, and a predetermined number of resin-impregnated linter paper is used on the side farther from the metal foil, which eliminates the problems of conventional methods. This problem has been solved, making it possible to create a single-sided metal-clad laminate made of a glass cloth base/paper base combo with a small amount of negative warpage.

【図面の簡単な説明】 第1図は、この発明にかかるコンポジット片面金属張積
層板の一実施例を模式的にあられす断面図である。 1・・・金属箔 2・・・樹脂含浸ガラス布 3・・・
樹脂含浸クラフト紙 4・・・樹脂含浸リンター紙代理
人 弁理士  松 本 武 彦 第1図
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a schematic cross-sectional view of an embodiment of a composite single-sided metal-clad laminate according to the present invention. 1... Metal foil 2... Resin-impregnated glass cloth 3...
Resin-impregnated kraft paper 4...Resin-impregnated linter paper Agent Patent attorney Takehiko Matsumoto Figure 1

Claims (1)

【特許請求の範囲】[Claims] 1 芯材として樹脂含浸紙、表層材として樹脂含浸ガラ
ス布が用いられ、片面に金属箔が配されてなるコンポジ
ット片面金属張積層板であって、前記樹脂含浸紙として
、前記金属箔に近い側に所定枚数の樹脂含浸クラフト紙
が、前記金属箔から遠い側に所定枚数の樹脂含浸リンタ
ー紙がそれぞれ用いられていることを特徴とするコンポ
ジット片面金属張積層板。
1 A composite single-sided metal-clad laminate in which resin-impregnated paper is used as a core material, resin-impregnated glass cloth is used as a surface material, and metal foil is arranged on one side, and the resin-impregnated paper is used on the side closer to the metal foil. A composite single-sided metal-clad laminate, characterized in that a predetermined number of resin-impregnated kraft paper is used on the side farthest from the metal foil, and a predetermined number of resin-impregnated linter paper is used on the side far from the metal foil.
JP6615888A 1988-03-19 1988-03-19 Composite one side face metal laminated plate Pending JPH01238932A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP6615888A JPH01238932A (en) 1988-03-19 1988-03-19 Composite one side face metal laminated plate

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP6615888A JPH01238932A (en) 1988-03-19 1988-03-19 Composite one side face metal laminated plate

Publications (1)

Publication Number Publication Date
JPH01238932A true JPH01238932A (en) 1989-09-25

Family

ID=13307773

Family Applications (1)

Application Number Title Priority Date Filing Date
JP6615888A Pending JPH01238932A (en) 1988-03-19 1988-03-19 Composite one side face metal laminated plate

Country Status (1)

Country Link
JP (1) JPH01238932A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003055486A (en) * 2001-05-24 2003-02-26 Hitachi Chem Co Ltd Prepreg and laminate

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5649257A (en) * 1979-09-28 1981-05-02 Shin Kobe Electric Machinery Manufacture of copper lined laminated board
JPS62221535A (en) * 1986-03-24 1987-09-29 新神戸電機株式会社 Single-sided metallic-foil lined composite laminated board

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5649257A (en) * 1979-09-28 1981-05-02 Shin Kobe Electric Machinery Manufacture of copper lined laminated board
JPS62221535A (en) * 1986-03-24 1987-09-29 新神戸電機株式会社 Single-sided metallic-foil lined composite laminated board

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003055486A (en) * 2001-05-24 2003-02-26 Hitachi Chem Co Ltd Prepreg and laminate

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