JP7719368B2 - ニッケルコバルト複合酸化物の製造方法、ニッケルコバルト複合酸化物、正極活物質、全固体リチウムイオン二次電池用正極および全固体リチウムイオン二次電池 - Google Patents
ニッケルコバルト複合酸化物の製造方法、ニッケルコバルト複合酸化物、正極活物質、全固体リチウムイオン二次電池用正極および全固体リチウムイオン二次電池Info
- Publication number
- JP7719368B2 JP7719368B2 JP2021535438A JP2021535438A JP7719368B2 JP 7719368 B2 JP7719368 B2 JP 7719368B2 JP 2021535438 A JP2021535438 A JP 2021535438A JP 2021535438 A JP2021535438 A JP 2021535438A JP 7719368 B2 JP7719368 B2 JP 7719368B2
- Authority
- JP
- Japan
- Prior art keywords
- nickel
- solution
- composite oxide
- cobalt
- positive electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
- H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/40—Complex oxides containing nickel and at least one other metal element
- C01G53/42—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2
- C01G53/44—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese
- C01G53/50—Complex oxides containing nickel and at least one other metal element containing alkali metals, e.g. LiNiO2 containing manganese of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G53/00—Compounds of nickel
- C01G53/80—Compounds containing nickel, with or without oxygen or hydrogen, and containing one or more other elements
- C01G53/82—Compounds containing nickel, with or without oxygen or hydrogen, and containing two or more other elements
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0562—Solid materials
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/04—Processes of manufacture in general
- H01M4/0402—Methods of deposition of the material
- H01M4/0407—Methods of deposition of the material by coating on an electrolyte layer
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M4/139—Processes of manufacture
- H01M4/1391—Processes of manufacture of electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/45—Aggregated particles or particles with an intergrown morphology
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/51—Particles with a specific particle size distribution
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/11—Powder tap density
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/028—Positive electrodes
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Dispersion Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2025075309A JP2025108772A (ja) | 2019-07-31 | 2025-04-30 | ニッケルコバルト複合酸化物の製造方法、ニッケルコバルト複合酸化物、正極活物質、全固体リチウムイオン二次電池用正極および全固体リチウムイオン二次電池 |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2019141366 | 2019-07-31 | ||
| JP2019141366 | 2019-07-31 | ||
| PCT/JP2020/029327 WO2021020531A1 (ja) | 2019-07-31 | 2020-07-30 | ニッケルコバルト複合酸化物の製造方法、ニッケルコバルト複合酸化物、正極活物質、全固体リチウムイオン二次電池用正極および全固体リチウムイオン二次電池 |
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2025075309A Division JP2025108772A (ja) | 2019-07-31 | 2025-04-30 | ニッケルコバルト複合酸化物の製造方法、ニッケルコバルト複合酸化物、正極活物質、全固体リチウムイオン二次電池用正極および全固体リチウムイオン二次電池 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPWO2021020531A1 JPWO2021020531A1 (enExample) | 2021-02-04 |
| JP7719368B2 true JP7719368B2 (ja) | 2025-08-06 |
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2021535438A Active JP7719368B2 (ja) | 2019-07-31 | 2020-07-30 | ニッケルコバルト複合酸化物の製造方法、ニッケルコバルト複合酸化物、正極活物質、全固体リチウムイオン二次電池用正極および全固体リチウムイオン二次電池 |
| JP2025075309A Pending JP2025108772A (ja) | 2019-07-31 | 2025-04-30 | ニッケルコバルト複合酸化物の製造方法、ニッケルコバルト複合酸化物、正極活物質、全固体リチウムイオン二次電池用正極および全固体リチウムイオン二次電池 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2025075309A Pending JP2025108772A (ja) | 2019-07-31 | 2025-04-30 | ニッケルコバルト複合酸化物の製造方法、ニッケルコバルト複合酸化物、正極活物質、全固体リチウムイオン二次電池用正極および全固体リチウムイオン二次電池 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20220259066A1 (enExample) |
| EP (1) | EP4007014A4 (enExample) |
| JP (2) | JP7719368B2 (enExample) |
| KR (1) | KR20220042359A (enExample) |
| WO (1) | WO2021020531A1 (enExample) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022122448A2 (en) * | 2020-12-08 | 2022-06-16 | Basf Se | Process for making an electrode active material |
| JP7722002B2 (ja) * | 2021-07-20 | 2025-08-13 | 日産自動車株式会社 | リチウムイオン二次電池用正極 |
| CN113644272B (zh) * | 2021-08-12 | 2023-01-24 | 巴斯夫杉杉电池材料有限公司 | 一种铈铋复合氧化物掺杂锂离子电池正极材料及其制备方法 |
| DE112023002844T5 (de) * | 2022-06-30 | 2025-04-17 | Nichia Corporation | Aktivmaterial für eine positive elektrode für sekundärbatterien, verfahren zu seiner herstellung, positive elektrode für sekundärbatterien die dieses verwendet und sekundärbatterie |
| CN115911358B (zh) * | 2022-08-23 | 2025-11-14 | 欣旺达动力科技股份有限公司 | 正极活性材料、电池及其制备方法 |
| CN116375104A (zh) * | 2023-03-09 | 2023-07-04 | 宜宾光原锂电材料有限公司 | 一种大颗粒高镍三元前驱体材料的制备方法及大颗粒高镍三元前驱体材料 |
| DE102023116756A1 (de) * | 2023-06-26 | 2025-01-02 | Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg, Stiftung des bürgerlichen Rechts | Verfahren zur Herstellung eines Übergangsmetallcarbonats in einem kontinuierlich betriebenen Reaktor |
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| CN102916177A (zh) | 2012-11-06 | 2013-02-06 | 中国科学院宁波材料技术与工程研究所 | 镍钴锰氢氧化物前驱体及其制备方法 |
| CN103280575A (zh) | 2013-06-06 | 2013-09-04 | 南通瑞翔新材料有限公司 | 锂离子二次电池正极材料镍钴锰酸锂的制备方法 |
| JP2015056307A (ja) | 2013-09-12 | 2015-03-23 | トヨタ自動車株式会社 | 活物質複合粉体及びリチウム電池並びにその製造方法 |
| JP2015147689A (ja) | 2014-02-04 | 2015-08-20 | 旭硝子株式会社 | 共沈物の製造方法およびリチウム含有複合酸化物の製造方法 |
| WO2016143844A1 (ja) | 2015-03-10 | 2016-09-15 | 日本化学産業株式会社 | 非水電解質リチウム二次電池用正極活物質及びその製造方法 |
| JP2016210674A (ja) | 2015-04-28 | 2016-12-15 | 日亜化学工業株式会社 | ニッケルコバルト複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、ならびに、非水系電解質二次電池 |
| JP2018116817A (ja) | 2017-01-17 | 2018-07-26 | 日立金属株式会社 | リチウムイオン二次電池用正極活物質およびその製造方法ならびにリチウムイオン二次電池 |
| CN108356286A (zh) | 2018-04-10 | 2018-08-03 | 宇辰新能源材料科技无锡有限公司 | 一种球形亚微米镍钴合金粉的制备方法 |
| CN109768248A (zh) | 2018-12-29 | 2019-05-17 | 桂林电器科学研究院有限公司 | 包覆改性LiNi0.8Co0.1Mn0.1O2三元正极材料及其制备方法和电池 |
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| JP2002075367A (ja) | 2000-09-04 | 2002-03-15 | Mitsui Chemicals Inc | リチウム電池用正極活物質、その製法およびそれを用いた二次電池 |
| US7393476B2 (en) * | 2001-11-22 | 2008-07-01 | Gs Yuasa Corporation | Positive electrode active material for lithium secondary cell and lithium secondary cell |
| US7384706B2 (en) * | 2003-04-17 | 2008-06-10 | Seimi Chemical Co., Ltd. | Lithium-nickel-cobalt-maganese containing composite oxide, material for positive electrode active material for lithium secondary battery, and methods for producing these |
| JP2006012433A (ja) | 2004-06-22 | 2006-01-12 | Nichia Chem Ind Ltd | 非水電解質二次電池用正極活物質および非水電解質二次電池 |
| WO2007004590A1 (ja) | 2005-07-01 | 2007-01-11 | National Institute For Materials Science | 全固体リチウム電池 |
| CN103299452B (zh) * | 2011-01-13 | 2015-10-14 | 株式会社村田制作所 | 蓄电设备用分隔物及蓄电设备 |
| JP5382025B2 (ja) | 2011-02-16 | 2014-01-08 | 日亜化学工業株式会社 | 非水電解質二次電池、非水電解質二次電池用正極活物質および非水電解質二次電池用正極合剤 |
| US9882204B2 (en) | 2012-06-06 | 2018-01-30 | Sumitomo Metal Mining Co., Ltd. | Nickel composite hydroxide, cathode active material for non-aqueous electrolyte secondary battery, and methods for producing these |
| CN104934595B (zh) | 2015-05-08 | 2017-08-08 | 广州锂宝新材料有限公司 | 制备具有铝元素梯度分布的镍钴铝前驱材料和正极材料的方法 |
| JP6855752B2 (ja) * | 2016-10-31 | 2021-04-07 | 住友金属鉱山株式会社 | ニッケルマンガン複合水酸化物とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、および非水系電解質二次電池 |
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2020
- 2020-07-30 WO PCT/JP2020/029327 patent/WO2021020531A1/ja not_active Ceased
- 2020-07-30 EP EP20847957.6A patent/EP4007014A4/en active Pending
- 2020-07-30 JP JP2021535438A patent/JP7719368B2/ja active Active
- 2020-07-30 US US17/631,317 patent/US20220259066A1/en active Pending
- 2020-07-30 KR KR1020227003165A patent/KR20220042359A/ko active Pending
-
2025
- 2025-04-30 JP JP2025075309A patent/JP2025108772A/ja active Pending
Patent Citations (9)
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| CN102916177A (zh) | 2012-11-06 | 2013-02-06 | 中国科学院宁波材料技术与工程研究所 | 镍钴锰氢氧化物前驱体及其制备方法 |
| CN103280575A (zh) | 2013-06-06 | 2013-09-04 | 南通瑞翔新材料有限公司 | 锂离子二次电池正极材料镍钴锰酸锂的制备方法 |
| JP2015056307A (ja) | 2013-09-12 | 2015-03-23 | トヨタ自動車株式会社 | 活物質複合粉体及びリチウム電池並びにその製造方法 |
| JP2015147689A (ja) | 2014-02-04 | 2015-08-20 | 旭硝子株式会社 | 共沈物の製造方法およびリチウム含有複合酸化物の製造方法 |
| WO2016143844A1 (ja) | 2015-03-10 | 2016-09-15 | 日本化学産業株式会社 | 非水電解質リチウム二次電池用正極活物質及びその製造方法 |
| JP2016210674A (ja) | 2015-04-28 | 2016-12-15 | 日亜化学工業株式会社 | ニッケルコバルト複合水酸化物粒子とその製造方法、非水系電解質二次電池用正極活物質とその製造方法、ならびに、非水系電解質二次電池 |
| JP2018116817A (ja) | 2017-01-17 | 2018-07-26 | 日立金属株式会社 | リチウムイオン二次電池用正極活物質およびその製造方法ならびにリチウムイオン二次電池 |
| CN108356286A (zh) | 2018-04-10 | 2018-08-03 | 宇辰新能源材料科技无锡有限公司 | 一种球形亚微米镍钴合金粉的制备方法 |
| CN109768248A (zh) | 2018-12-29 | 2019-05-17 | 桂林电器科学研究院有限公司 | 包覆改性LiNi0.8Co0.1Mn0.1O2三元正极材料及其制备方法和电池 |
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| WO2021020531A1 (ja) | 2021-02-04 |
| EP4007014A4 (en) | 2024-08-14 |
| JPWO2021020531A1 (enExample) | 2021-02-04 |
| KR20220042359A (ko) | 2022-04-05 |
| JP2025108772A (ja) | 2025-07-23 |
| EP4007014A1 (en) | 2022-06-01 |
| US20220259066A1 (en) | 2022-08-18 |
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