JP7560452B2 - 骨格型mfiを有するゼオライト材料を含む成形品 - Google Patents

骨格型mfiを有するゼオライト材料を含む成形品 Download PDF

Info

Publication number
JP7560452B2
JP7560452B2 JP2021519721A JP2021519721A JP7560452B2 JP 7560452 B2 JP7560452 B2 JP 7560452B2 JP 2021519721 A JP2021519721 A JP 2021519721A JP 2021519721 A JP2021519721 A JP 2021519721A JP 7560452 B2 JP7560452 B2 JP 7560452B2
Authority
JP
Japan
Prior art keywords
range
molded article
zeolitic material
mfi
framework
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
JP2021519721A
Other languages
English (en)
Japanese (ja)
Other versions
JP2022512656A5 (https=
JP2022512656A (ja
Inventor
パルフレスク,アンドレイ-ニコラエ
リュッツェル,ハンス-ユルゲン
ミュラー,ウルリヒ
リーデル,ドミニク
ヘンリケ テレス,ジョアキム
ヴェーバー,マルクス
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BASF SE filed Critical BASF SE
Publication of JP2022512656A publication Critical patent/JP2022512656A/ja
Publication of JP2022512656A5 publication Critical patent/JP2022512656A5/ja
Application granted granted Critical
Publication of JP7560452B2 publication Critical patent/JP7560452B2/ja
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22CFOUNDRY MOULDING
    • B22C1/00Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/16Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
    • B22C1/18Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents
    • B22C1/181Cements, oxides or clays
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/89Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/6350.5-1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63Pore volume
    • B01J35/638Pore volume more than 1.0 ml/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • B01J37/10Heat treatment in the presence of water, e.g. steam
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001Calcining
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46Other types characterised by their X-ray diffraction pattern and their defined composition
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07DHETEROCYCLIC COMPOUNDS
    • C07D301/00Preparation of oxiranes
    • C07D301/02Synthesis of the oxirane ring
    • C07D301/03Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/22After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30After treatment, characterised by the means used
    • B01J2229/42Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
JP2021519721A 2018-10-09 2019-10-09 骨格型mfiを有するゼオライト材料を含む成形品 Active JP7560452B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP18199428 2018-10-09
EP18199428.6 2018-10-09
PCT/EP2019/077372 WO2020074586A1 (en) 2018-10-09 2019-10-09 A molding comprising a zeolitic material having framework type mfi

Publications (3)

Publication Number Publication Date
JP2022512656A JP2022512656A (ja) 2022-02-07
JP2022512656A5 JP2022512656A5 (https=) 2022-10-14
JP7560452B2 true JP7560452B2 (ja) 2024-10-02

Family

ID=63862001

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2021519721A Active JP7560452B2 (ja) 2018-10-09 2019-10-09 骨格型mfiを有するゼオライト材料を含む成形品

Country Status (9)

Country Link
US (1) US20210346942A1 (https=)
EP (1) EP3864010A1 (https=)
JP (1) JP7560452B2 (https=)
KR (1) KR102863394B1 (https=)
CN (1) CN112805272A (https=)
MX (1) MX2021004084A (https=)
SG (1) SG11202102455SA (https=)
WO (1) WO2020074586A1 (https=)
ZA (1) ZA202103028B (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20240326029A1 (en) 2021-11-22 2024-10-03 Basf Se Epoxidation catalyst and process for its preparation
EP4440743A1 (en) 2021-11-29 2024-10-09 Basf Se Catalyst for hydrogen peroxide activation
CN121039112A (zh) 2023-04-06 2025-11-28 巴斯夫欧洲公司 用于制备氧化烯烃的方法的启动方法
EP4719665A1 (en) 2023-05-31 2026-04-08 Basf Se Catalyst for epoxidation of propylene
KR20260018107A (ko) 2023-05-31 2026-02-06 바스프 에스이 과산화수소 활성화를 위한 촉매 성형체

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1132699C (zh) 1999-12-24 2003-12-31 中国石油化工集团公司 一种钛硅分子筛及其制备方法
JP2016529190A (ja) 2013-07-05 2016-09-23 ダンマークス・テクニスケ・ユニヴェルシテット ゼオライト及びゼオ型を製造する方法
JP2016535718A (ja) 2013-10-23 2016-11-17 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 疎水性のゼオライト系材料についての成形物及びその製造方法
JP2017531691A (ja) 2014-09-29 2017-10-26 中国石油化工股▲ふん▼有限公司 オレフィン類の酸化方法、反応装置及び反応系

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19939416A1 (de) * 1999-08-20 2001-02-22 Basf Ag Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs
EP2504098B1 (en) * 2009-11-27 2016-07-06 Basf Se Process for the preparation of a titanium zeolite catalyst
US8785670B2 (en) * 2010-12-07 2014-07-22 Basf Se Process for the production of propylene oxide
CN103708493A (zh) * 2013-11-26 2014-04-09 华东师范大学 具有mfi结构钛硅分子筛及其制备方法
CN108250161B (zh) 2016-12-28 2022-01-04 中国石油化工股份有限公司 烯丙醇氧化方法
US20200139357A1 (en) * 2017-04-24 2020-05-07 Basf Se A molding comprising a zeolitic material, phosphorous, one or more metals and a binder

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1132699C (zh) 1999-12-24 2003-12-31 中国石油化工集团公司 一种钛硅分子筛及其制备方法
JP2016529190A (ja) 2013-07-05 2016-09-23 ダンマークス・テクニスケ・ユニヴェルシテット ゼオライト及びゼオ型を製造する方法
JP2016535718A (ja) 2013-10-23 2016-11-17 ビーエーエスエフ ソシエタス・ヨーロピアBasf Se 疎水性のゼオライト系材料についての成形物及びその製造方法
JP2017531691A (ja) 2014-09-29 2017-10-26 中国石油化工股▲ふん▼有限公司 オレフィン類の酸化方法、反応装置及び反応系

Also Published As

Publication number Publication date
MX2021004084A (es) 2021-06-04
KR102863394B1 (ko) 2025-09-22
US20210346942A1 (en) 2021-11-11
ZA202103028B (en) 2025-09-25
EP3864010A1 (en) 2021-08-18
CN112805272A (zh) 2021-05-14
SG11202102455SA (en) 2021-04-29
BR112021005279A2 (pt) 2021-06-15
WO2020074586A1 (en) 2020-04-16
JP2022512656A (ja) 2022-02-07
KR20210066913A (ko) 2021-06-07

Similar Documents

Publication Publication Date Title
JP7560452B2 (ja) 骨格型mfiを有するゼオライト材料を含む成形品
CA2621400C (en) Preparation of titanosilicate zeolite ts-1
JP6461807B2 (ja) ゼオライト材料の製造方法及び酸素含有物質のオレフィンへの転化方法におけるゼオライト材料の使用
JP6775491B2 (ja) ホウ素およびチタンを含むmwwゼオライト系材料の製造のための方法
EP1453603A1 (en) Catalyst containing microporous zeolite in mesoporous support and method for making same
RU2563648C2 (ru) Улучшенный способ получения катализатора на основе цеолита для превращения метанола в олефины
US12478959B2 (en) Continuous synthesis of a titanosilicate zeolitic material, said zeolitic material, molding prepared thereof, and their use
EP4249115A2 (en) Molding for a hydrophobic zeolitic material
KR20140124393A (ko) Ti 및 Zn을 함유하는 제올라이트 물질을 포함하는 마이크로분말 및 몰딩
RU2706014C2 (ru) Способы дегидратации-гидролиза и катализаторы для них
JP7574216B2 (ja) 骨格型mfiを有するゼオライト材料を含む成形品
CN106794453A (zh) 脱水‑水解方法及其催化剂
Feng et al. Liquid-phase xylene isomerization on nano-sized ZSM-5
JP2023055845A (ja) 亜鉛とチタン含有ゼオライトとを含む成形物の製造方法
RU2808562C2 (ru) Формованное изделие, содержащее цеолитный материал, имеющий тип каркасной структуры mfi
US9636668B2 (en) Production and use of a zeolitic material in a process for the conversion of oxygenates to olefins
BR112021005279B1 (pt) Moldagem, processo para preparar uma moldagem, e, uso de uma moldagem
Othman et al. Synthesis of mesoporous sodalite by mixed quaternary ammonium cation templates for knoevenagel condensation reaction
BR112021019270B1 (pt) Moldagem química, processo para preparar uma moldagem química, usos de uma moldagem, de uma dispersão coloidal de sílica em água e da mistura, e, mistura

Legal Events

Date Code Title Description
A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20221005

A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20221005

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20230809

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20230905

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20231127

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20240206

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20240507

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20240820

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20240919

R150 Certificate of patent or registration of utility model

Ref document number: 7560452

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R150