KR102863394B1 - 골격 유형 mfi를 갖는 제올라이트 물질을 포함하는 몰딩 - Google Patents

골격 유형 mfi를 갖는 제올라이트 물질을 포함하는 몰딩

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Publication number
KR102863394B1
KR102863394B1 KR1020217013715A KR20217013715A KR102863394B1 KR 102863394 B1 KR102863394 B1 KR 102863394B1 KR 1020217013715 A KR1020217013715 A KR 1020217013715A KR 20217013715 A KR20217013715 A KR 20217013715A KR 102863394 B1 KR102863394 B1 KR 102863394B1
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KR
South Korea
Prior art keywords
molding
range
zeolite material
precursor
mixture
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KR1020217013715A
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English (en)
Korean (ko)
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KR20210066913A (ko
Inventor
안드레이-니콜라이 파블레스쿠
한스-위르겐 뤼첼
울리히 뮐러
도미닉 라이델
요아큄 헨리케 텔레스
마르쿠스 베버
Original Assignee
바스프 에스이
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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B22—CASTING; POWDER METALLURGY
    • B22C—FOUNDRY MOULDING
    • B22C1/00—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds
    • B22C1/16—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents
    • B22C1/18—Compositions of refractory mould or core materials; Grain structures thereof; Chemical or physical features in the formation or manufacture of moulds characterised by the use of binding agents; Mixtures of binding agents of inorganic agents
    • B22C1/181—Cements, oxides or clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/89—Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/635—0.5-1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/638—Pore volume more than 1.0 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J6/00—Heat treatments such as Calcining; Fusing ; Pyrolysis
    • B01J6/001—Calcining
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/46—Other types characterised by their X-ray diffraction pattern and their defined composition
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/12—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with hydrogen peroxide or inorganic peroxides or peracids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/22—After treatment, characterised by the effect to be obtained to destroy the molecular sieve structure or part thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Catalysts (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
KR1020217013715A 2018-10-09 2019-10-09 골격 유형 mfi를 갖는 제올라이트 물질을 포함하는 몰딩 Active KR102863394B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP18199428 2018-10-09
EP18199428.6 2018-10-09
PCT/EP2019/077372 WO2020074586A1 (en) 2018-10-09 2019-10-09 A molding comprising a zeolitic material having framework type mfi

Publications (2)

Publication Number Publication Date
KR20210066913A KR20210066913A (ko) 2021-06-07
KR102863394B1 true KR102863394B1 (ko) 2025-09-22

Family

ID=63862001

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020217013715A Active KR102863394B1 (ko) 2018-10-09 2019-10-09 골격 유형 mfi를 갖는 제올라이트 물질을 포함하는 몰딩

Country Status (9)

Country Link
US (1) US20210346942A1 (https=)
EP (1) EP3864010A1 (https=)
JP (1) JP7560452B2 (https=)
KR (1) KR102863394B1 (https=)
CN (1) CN112805272A (https=)
MX (1) MX2021004084A (https=)
SG (1) SG11202102455SA (https=)
WO (1) WO2020074586A1 (https=)
ZA (1) ZA202103028B (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20240326029A1 (en) 2021-11-22 2024-10-03 Basf Se Epoxidation catalyst and process for its preparation
EP4440743A1 (en) 2021-11-29 2024-10-09 Basf Se Catalyst for hydrogen peroxide activation
CN121039112A (zh) 2023-04-06 2025-11-28 巴斯夫欧洲公司 用于制备氧化烯烃的方法的启动方法
EP4719665A1 (en) 2023-05-31 2026-04-08 Basf Se Catalyst for epoxidation of propylene
KR20260018107A (ko) 2023-05-31 2026-02-06 바스프 에스이 과산화수소 활성화를 위한 촉매 성형체

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016529190A (ja) 2013-07-05 2016-09-23 ダンマークス・テクニスケ・ユニヴェルシテット ゼオライト及びゼオ型を製造する方法
CN108250161A (zh) 2016-12-28 2018-07-06 中国石油化工股份有限公司 烯丙醇氧化方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19939416A1 (de) * 1999-08-20 2001-02-22 Basf Ag Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs
CN1132699C (zh) 1999-12-24 2003-12-31 中国石油化工集团公司 一种钛硅分子筛及其制备方法
EP2504098B1 (en) * 2009-11-27 2016-07-06 Basf Se Process for the preparation of a titanium zeolite catalyst
US8785670B2 (en) * 2010-12-07 2014-07-22 Basf Se Process for the production of propylene oxide
US10434503B2 (en) * 2013-10-23 2019-10-08 Basf Se Molding for a hydrophobic zeolitic material and process for its production
CN103708493A (zh) * 2013-11-26 2014-04-09 华东师范大学 具有mfi结构钛硅分子筛及其制备方法
CN105461661B (zh) 2014-09-29 2018-07-31 中国石油化工股份有限公司 一种烯烃氧化方法
US20200139357A1 (en) * 2017-04-24 2020-05-07 Basf Se A molding comprising a zeolitic material, phosphorous, one or more metals and a binder

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016529190A (ja) 2013-07-05 2016-09-23 ダンマークス・テクニスケ・ユニヴェルシテット ゼオライト及びゼオ型を製造する方法
CN108250161A (zh) 2016-12-28 2018-07-06 中国石油化工股份有限公司 烯丙醇氧化方法

Also Published As

Publication number Publication date
MX2021004084A (es) 2021-06-04
US20210346942A1 (en) 2021-11-11
ZA202103028B (en) 2025-09-25
EP3864010A1 (en) 2021-08-18
JP7560452B2 (ja) 2024-10-02
CN112805272A (zh) 2021-05-14
SG11202102455SA (en) 2021-04-29
BR112021005279A2 (pt) 2021-06-15
WO2020074586A1 (en) 2020-04-16
JP2022512656A (ja) 2022-02-07
KR20210066913A (ko) 2021-06-07

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