JP7447738B2 - 光触媒 - Google Patents
光触媒 Download PDFInfo
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- JP7447738B2 JP7447738B2 JP2020146555A JP2020146555A JP7447738B2 JP 7447738 B2 JP7447738 B2 JP 7447738B2 JP 2020146555 A JP2020146555 A JP 2020146555A JP 2020146555 A JP2020146555 A JP 2020146555A JP 7447738 B2 JP7447738 B2 JP 7447738B2
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- photocatalyst
- molar amount
- tio
- caba
- ratio
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- 239000011941 photocatalyst Substances 0.000 title claims description 31
- 239000013078 crystal Substances 0.000 claims description 5
- 229910010252 TiO3 Inorganic materials 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 description 23
- 229910052739 hydrogen Inorganic materials 0.000 description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 22
- 239000007789 gas Substances 0.000 description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 12
- 230000000694 effects Effects 0.000 description 8
- 229910052786 argon Inorganic materials 0.000 description 6
- 238000000354 decomposition reaction Methods 0.000 description 6
- 239000000843 powder Substances 0.000 description 5
- 238000010586 diagram Methods 0.000 description 4
- 239000006104 solid solution Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 239000002002 slurry Substances 0.000 description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000000919 ceramic Substances 0.000 description 2
- 239000003426 co-catalyst Substances 0.000 description 2
- VSQYNPJPULBZKU-UHFFFAOYSA-N mercury xenon Chemical compound [Xe].[Hg] VSQYNPJPULBZKU-UHFFFAOYSA-N 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 229910019899 RuO Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000002250 progressing effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
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Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
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- Catalysts (AREA)
Description
前記(CaBa)TiO3に含まれるCaとBaの合計モル量に対するBaのモル量の比Ba/(Ca+Ba)が0.2より大きく、かつ、0.8未満であることを特徴とする。
TiO2、CaCO3、および、BaCO3の原料粉を所望の組成比で調合し、ボールミルで5時間撹拌して乾燥させた後、1100℃で仮焼することによって、セラミック粉体を得た。得られたセラミック粉体を硝酸Ni水溶液に浸漬して撹拌した後、150℃に設定したホットプレートで加熱して乾燥物を得た。その後、乾燥物を、大気中500℃で熱処理することによって硝酸を揮発させた後、水素中800℃で還元することにより、助触媒であるNiを1重量%担持させた(CaBa)TiO3粉からなる光触媒を作製した。
11 (CaBa)TiO3を含む酸化物
12 助触媒
21 シャーレ
22 密封容器
23 蓋
24 パック
25 送風ポンプ
Claims (3)
- (CaBa)TiO3を含む酸化物を備え、
前記(CaBa)TiO3に含まれるCaとBaの合計モル量に対するBaのモル量の比Ba/(Ca+Ba)が0.2より大きく、かつ、0.8未満であり、
前記(CaBa)TiO 3 を含む酸化物には、CaTiO 3 の結晶相とBaTiO 3 の結晶相が混在していることを特徴とする光触媒。 - 前記モル量の比Ba/(Ca+Ba)は、0.3以上0.7以下であることを特徴とする請求項1に記載の光触媒。
- 前記モル量の比Ba/(Ca+Ba)は、0.37以上0.7以下であることを特徴とする請求項2に記載の光触媒。
Priority Applications (1)
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JP2020146555A JP7447738B2 (ja) | 2020-09-01 | 2020-09-01 | 光触媒 |
Applications Claiming Priority (1)
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JP2020146555A JP7447738B2 (ja) | 2020-09-01 | 2020-09-01 | 光触媒 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2022041394A JP2022041394A (ja) | 2022-03-11 |
JP7447738B2 true JP7447738B2 (ja) | 2024-03-12 |
Family
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Family Applications (1)
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JP2020146555A Active JP7447738B2 (ja) | 2020-09-01 | 2020-09-01 | 光触媒 |
Country Status (1)
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JP (1) | JP7447738B2 (ja) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002306963A (ja) | 2001-04-13 | 2002-10-22 | Toshiba Corp | 可視光吸収性光触媒物質、水分解方法および炭素固定化方法 |
JP2015006974A (ja) | 2013-05-29 | 2015-01-15 | Toto株式会社 | 金属酸化物粒子の製造方法 |
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2020
- 2020-09-01 JP JP2020146555A patent/JP7447738B2/ja active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002306963A (ja) | 2001-04-13 | 2002-10-22 | Toshiba Corp | 可視光吸収性光触媒物質、水分解方法および炭素固定化方法 |
JP2015006974A (ja) | 2013-05-29 | 2015-01-15 | Toto株式会社 | 金属酸化物粒子の製造方法 |
US20160121319A1 (en) | 2013-05-29 | 2016-05-05 | Toto Ltd. | Method for producing metal oxide particles |
Non-Patent Citations (1)
Title |
---|
LIN Enzhu et al.,Enhanced piezocatalytic, photocatalytic and piezo-/photocatalytic performance of diphasic Ba1?xCaxTiO3 nanowires near a solubility limit,Catal. Sci. Technol,英国,The Royal Society of Chemistry,2019年10月14日,9,6863-6874,DOI: 10.1039/c9cy01713e |
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