JP7438133B2 - 青みを帯びた外観を有する青色光カット光学材料 - Google Patents
青みを帯びた外観を有する青色光カット光学材料 Download PDFInfo
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- JP7438133B2 JP7438133B2 JP2020560357A JP2020560357A JP7438133B2 JP 7438133 B2 JP7438133 B2 JP 7438133B2 JP 2020560357 A JP2020560357 A JP 2020560357A JP 2020560357 A JP2020560357 A JP 2020560357A JP 7438133 B2 JP7438133 B2 JP 7438133B2
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- GWVMLCQWXVFZCN-UHFFFAOYSA-N isoindoline Chemical compound C1=CC=C2CNCC2=C1 GWVMLCQWXVFZCN-UHFFFAOYSA-N 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- 239000004973 liquid crystal related substance Substances 0.000 description 1
- OVPVVOAYSGVQSZ-UHFFFAOYSA-L lucifer yellow carbohydrazide dye(2-) Chemical compound [O-]S(=O)(=O)C1=CC(C(N(NC(=O)NN)C2=O)=O)=C3C2=CC(S([O-])(=O)=O)=CC3=C1N OVPVVOAYSGVQSZ-UHFFFAOYSA-L 0.000 description 1
- 235000012680 lutein Nutrition 0.000 description 1
- KBPHJBAIARWVSC-RGZFRNHPSA-N lutein Chemical compound C([C@H](O)CC=1C)C(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\[C@H]1C(C)=C[C@H](O)CC1(C)C KBPHJBAIARWVSC-RGZFRNHPSA-N 0.000 description 1
- 229960005375 lutein Drugs 0.000 description 1
- 239000001656 lutein Substances 0.000 description 1
- ORAKUVXRZWMARG-WZLJTJAWSA-N lutein Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2C(=CC(O)CC2(C)C)C ORAKUVXRZWMARG-WZLJTJAWSA-N 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- NYGZLYXAPMMJTE-UHFFFAOYSA-M metanil yellow Chemical group [Na+].[O-]S(=O)(=O)C1=CC=CC(N=NC=2C=CC(NC=3C=CC=CC=3)=CC=2)=C1 NYGZLYXAPMMJTE-UHFFFAOYSA-M 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- 125000002080 perylenyl group Chemical group C1(=CC=C2C=CC=C3C4=CC=CC5=CC=CC(C1=C23)=C45)* 0.000 description 1
- CSHWQDPOILHKBI-UHFFFAOYSA-N peryrene Natural products C1=CC(C2=CC=CC=3C2=C2C=CC=3)=C3C2=CC=CC3=C1 CSHWQDPOILHKBI-UHFFFAOYSA-N 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 150000004986 phenylenediamines Chemical class 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 125000003367 polycyclic group Chemical group 0.000 description 1
- 229920005906 polyester polyol Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000582 polyisocyanurate Polymers 0.000 description 1
- 239000011495 polyisocyanurate Substances 0.000 description 1
- 229920000307 polymer substrate Polymers 0.000 description 1
- 239000002685 polymerization catalyst Substances 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000000276 potassium ferrocyanide Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 229960000286 proflavine Drugs 0.000 description 1
- 230000000750 progressive effect Effects 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- NCNISYUOWMIOPI-UHFFFAOYSA-N propane-1,1-dithiol Chemical compound CCC(S)S NCNISYUOWMIOPI-UHFFFAOYSA-N 0.000 description 1
- ZJLMKPKYJBQJNH-UHFFFAOYSA-N propane-1,3-dithiol Chemical compound SCCCS ZJLMKPKYJBQJNH-UHFFFAOYSA-N 0.000 description 1
- HMPSOEYFMTWOFC-UHFFFAOYSA-N propane-2,2-dithiol Chemical compound CC(C)(S)S HMPSOEYFMTWOFC-UHFFFAOYSA-N 0.000 description 1
- 235000019260 propionic acid Nutrition 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- KIDHWZJUCRJVML-UHFFFAOYSA-N putrescine Chemical compound NCCCCN KIDHWZJUCRJVML-UHFFFAOYSA-N 0.000 description 1
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 description 1
- 239000002516 radical scavenger Substances 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 238000007151 ring opening polymerisation reaction Methods 0.000 description 1
- 230000004296 scotopic vision Effects 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- ORFSSYGWXNGVFB-UHFFFAOYSA-N sodium 4-amino-6-[[4-[4-[(8-amino-1-hydroxy-5,7-disulfonaphthalen-2-yl)diazenyl]-3-methoxyphenyl]-2-methoxyphenyl]diazenyl]-5-hydroxynaphthalene-1,3-disulfonic acid Chemical compound COC1=C(C=CC(=C1)C2=CC(=C(C=C2)N=NC3=C(C4=C(C=C3)C(=CC(=C4N)S(=O)(=O)O)S(=O)(=O)O)O)OC)N=NC5=C(C6=C(C=C5)C(=CC(=C6N)S(=O)(=O)O)S(=O)(=O)O)O.[Na+] ORFSSYGWXNGVFB-UHFFFAOYSA-N 0.000 description 1
- 238000000527 sonication Methods 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000000859 sublimation Methods 0.000 description 1
- 230000008022 sublimation Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- WTSBJMAOQNCZBF-UHFFFAOYSA-N sulfanylmethylsulfanylmethanethiol Chemical compound SCSCS WTSBJMAOQNCZBF-UHFFFAOYSA-N 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- HEKQWIORQJRILW-UHFFFAOYSA-N tetrakis(prop-2-enyl) benzene-1,2,4,5-tetracarboxylate Chemical compound C=CCOC(=O)C1=CC(C(=O)OCC=C)=C(C(=O)OCC=C)C=C1C(=O)OCC=C HEKQWIORQJRILW-UHFFFAOYSA-N 0.000 description 1
- XOGGUFAVLNCTRS-UHFFFAOYSA-N tetrapotassium;iron(2+);hexacyanide Chemical compound [K+].[K+].[K+].[K+].[Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] XOGGUFAVLNCTRS-UHFFFAOYSA-N 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 150000003573 thiols Chemical class 0.000 description 1
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- GRPURDFRFHUDSP-UHFFFAOYSA-N tris(prop-2-enyl) benzene-1,2,4-tricarboxylate Chemical compound C=CCOC(=O)C1=CC=C(C(=O)OCC=C)C(C(=O)OCC=C)=C1 GRPURDFRFHUDSP-UHFFFAOYSA-N 0.000 description 1
- 235000013799 ultramarine blue Nutrition 0.000 description 1
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 1
- 238000002211 ultraviolet spectrum Methods 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical class NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 208000029257 vision disease Diseases 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 230000004393 visual impairment Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- FJHBOVDFOQMZRV-XQIHNALSSA-N xanthophyll Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CC(O)CC1(C)C)C=CC=C(/C)C=CC2C=C(C)C(O)CC2(C)C FJHBOVDFOQMZRV-XQIHNALSSA-N 0.000 description 1
- 239000001052 yellow pigment Substances 0.000 description 1
- 235000010930 zeaxanthin Nutrition 0.000 description 1
- 239000001775 zeaxanthin Substances 0.000 description 1
- 229940043269 zeaxanthin Drugs 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
- G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
- G02B1/041—Lenses
- G02B1/043—Contact lenses
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
- C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/16—Catalysts
- C08G18/22—Catalysts containing metal compounds
- C08G18/24—Catalysts containing metal compounds of tin
- C08G18/242—Catalysts containing metal compounds of tin organometallic compounds containing tin-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
- C08G18/3863—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms
- C08G18/3865—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms
- C08G18/3868—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing groups having sulfur atoms between two carbon atoms, the sulfur atoms being directly linked to carbon atoms or other sulfur atoms containing groups having one sulfur atom between two carbon atoms the sulfur atom belonging to a sulfide group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7678—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing condensed aromatic rings
-
- G—PHYSICS
- G02—OPTICS
- G02C—SPECTACLES; SUNGLASSES OR GOGGLES INSOFAR AS THEY HAVE THE SAME FEATURES AS SPECTACLES; CONTACT LENSES
- G02C7/00—Optical parts
- G02C7/02—Lenses; Lens systems ; Methods of designing lenses
- G02C7/04—Contact lenses for the eyes
Description
- 2mmの光学材料厚さについて、6以下である、CIE(1976)L*a*b*国際表色系で定義される比色係数b*を有し、
- 2mmの光学材料厚さについて、120°以上且つ180°以下である、CIE(1976)L*a*b*国際表色系で定義される色相角hを有する。
- 400~450nmの範囲の波長を有する光を少なくとも部分的にブロックする少なくとも1つのUV吸収剤と、少なくとも1つの吸収色素Aであって、520nm~640nmの範囲内にその極大吸収波長を有する少なくとも1つの吸収色素Aと、ポリチオウレタン材料、又はその前駆体、ポリウレタンウレア材料、又はその前駆体、ポリエピスルフィドモノマー、若しくはオリゴマーの重合、若しくは共重合から得られる材料、又はその前駆体、及びアリルモノマー、若しくはオリゴマーの重合、若しくは共重合から得られる材料、又はその前駆体から選択される材料、又は化合物とを混合することによって光学材料組成物を調製するステップと、
- 前記光学材料組成物を好ましくは金型中で硬化させて、ポリマーマトリクスと前記少なくとも1つのUV吸収剤及び吸収色素Aとを含む光学材料を形成するステップと
を含む。
- 400~450nmの範囲の波長を有する光を少なくとも部分的にブロックする少なくとも1つのUV吸収剤と、
- 少なくとも1つの吸収色素Aであって、520nm~640nmの範囲内にその極大吸収波長を有する少なくとも1つの吸収色素Aと
を含む光学材料で製作され、光学材料は、
- ポリチオウレタン材料、ポリウレタンウレア材料、ポリエピスルフィドモノマー、又はオリゴマーの重合、又は共重合から得られる材料、及びアリルモノマー、又はオリゴマーの重合、又は共重合から得られる材料から選択される材料で製作され、
- 2mmの光学材料厚さについて、6以下、好ましくは以下の値:5.5、5、4、3の何れか1つ以下である、CIE(1976)L*a*b*国際表色系で定義される比色係数b*を有し、
- 120°以上且つ180°以下である、CIE(1976)L*a*b*国際表色系で定義される色相角hを有する。
光学材料は、重合性モノマー、触媒としてジメチルすずジクロリド(CAS No.753-73-1)、吸収色素AとしてDiaresin Blue J(登録商標)(三菱ケミカル株式会社が販売する、Solvent Violet 33、CAS No.86090-40-6としても知られる青み剤)又はSolvent Violet 13(Clariantが販売するCAS No.81-48-1)、離型剤としてZelec UN(登録商標)、400~450nmの範囲の波長を有する光を少なくとも部分的に阻止する1つ、又は複数のUV吸収剤及び任意選択により、吸収色素Bであって、410nm~450nmの範囲にその極大吸収波長を有する吸収色素BとしてABS-420(登録商標)(Exciton社が販売する、421nm付近に中心をおく狭い吸収ピークを有する選択的黄色色素)を含む組成物から調製された。
タイピングプロセスにより凸及び凹型を組み立てる。中央厚さ調整を行って、2mm厚さのサンプルを得た。
Hunter社のCary 4000分光光度計を用いて、レンズの光学特性を特定した。可視スペクトル中の光透過率Tvは、装用者の視野角からの透過モードにおいて、レンズ(中央厚さ2mm)の後(凹)面を検出器に向け、光がレンズの前面から入射する状態で測定した。Tvは、D65光源条件(日昼光)で測定した。光カットオフ波長を透過スペクトルから特定した。
調製した調合物並びにこれらの調合物及び最終レンズの特性を下表に示す。
行った試験により、本発明によるレンズがより受け入れられることが確認された。
5人のグループについて、本発明によるレンズを白いプラスチックポリマーの基板マットの上に置き、蛍光増白剤を用いず、レンズ表面での光の反射ができるだけ見えないように非直接蛍光光源下での透過中にそれらの色合いを観察した。
本発明のレンズを比較用レンズ、すなわち以下の特徴を有する市販の青色光カットレンズと共に、第一の試験と同様に置いて観察した。
a*=-1.9、b*=3.6 h=118° C=4.1 BVC=28% Tv(D65)=95%
Claims (16)
- - 400~450nmの範囲の波長を有する光を少なくとも部分的にブロックする少なくとも1つのUV吸収剤と、
- 少なくとも1つの吸収色素Aであって、550nm~640nmの範囲内にその極大吸収波長を有する少なくとも1つの吸収色素Aと、を含む光学材料であって、前記光学材料は、500nm以上且つ550nm未満の極大吸収波長を有するいかなる吸収色素も含まず、
- ポリチオウレタン材料、ポリウレタンウレア材料、ポリエピスルフィドモノマー、又はオリゴマーの重合、又は共重合から得られる材料、及びアリルモノマー、又はオリゴマーの重合、又は共重合から得られる材料から選択される材料で製作され、
- 2mmの光学材料厚さについて、6以下である、CIE(1976)L*a*b*国際表色系で定義される比色係数b*を有し、
- 2mmの光学材料厚さについて、120°以上且つ180°以下である、CIE(1976)L*a*b*国際表色系で定義される色相角hを有する、光学材料。 - 2mmの光学材料厚さについて、120°以上且つ145°以下である、CIE(1976)L*a*b*国際表色系で定義される色相角hを有するとしてさらに定義される、請求項1に記載の光学材料。
- 前記吸収色素Aは、550nm~610nmの範囲にその極大吸収波長を有する、請求項1又は2に記載の光学材料。
- 前記吸収色素Aは、アントラキノン色素である、請求項1~3の何れか一項に記載の光学材料。
- 82%以上である、可視スペクトルでの相対光透過率Tvを有するとしてさらに定義される、請求項1~4の何れか一項に記載の光学材料。
- 2mmの光学材料厚さについて、3以下である、CIE(1976)L*a*b*国際表色系で定義される比色係数a*を有するとしてさらに定義される、請求項1~5の何れか一項に記載の光学材料。
- 2mmの光学材料厚さについて、5.5以下である、CIE(1976)L*a*b*国際表色系で定義される比色係数b*を有するとしてさらに定義される、請求項1~6の何れか一項に記載の光学材料。
- ポリチオウレタン材料及びポリエピスルフィドモノマー又はオリゴマーの重合又は共重合から得られる材料から選択される材料で製作されるとしてさらに定義される、請求項1~7の何れか一項に記載の光学材料。
- 前記吸収色素Aは、前記光学材料の総重量に対して0.1~1000重量ppmの範囲の量で存在する、請求項1~8の何れか一項に記載の光学材料。
- 前記UV吸収剤は、前記光学材料の総重量に対して0.05~4重量%の範囲の量で存在する、請求項1~9の何れか一項に記載の光学材料。
- 2mmの光学材料厚さについて、5以下である、CIE(1976)L*a*b*国際表色系で定義される比色係数b*を有するとしてさらに定義される、請求項1~10の何れか一項に記載の光学材料。
- 少なくとも1つの吸収色素Bであって、410nm~450nmの範囲内にその極大吸収波長を有する少なくとも1つの吸収色素Bをさらに含む、請求項1~11の何れか一項に記載の光学材料。
- 主前面と主後面とを有する母材を含む光学物品であって、前記母材は、請求項1~12の何れか一項に記載の光学材料を含む、光学物品。
- 光学レンズとしてさらに定義される、請求項13に記載の光学物品。
- 主前面と主後面とを有する母材を含む光学物品であって、前記母材は、400~450nmの範囲の波長を有する光を少なくとも部分的にブロックする少なくとも1つのUV吸収剤、少なくとも1つの吸収色素Aであって、550nm~640nmの範囲内にその極大吸収波長を有する少なくとも1つの吸収色素Aを含む光学材料を含み、前記光学材料は、500nm以上且つ550nm未満の極大吸収波長を有するいかなる吸収色素も含まず、ポリチオウレタン材料、ポリウレタンウレア材料、ポリエピスルフィドモノマー、又はオリゴマーの重合、又は共重合から得られる材料、及びアリルモノマー、又はオリゴマーの重合、又は共重合から得られる材料から選択される材料で製作され、前記光学物品は、
- 2mmの光学材料厚さについて、6以下である、CIE(1976)L*a*b*国際表色系で定義される比色係数b*を有し、
- 2mmの光学材料厚さについて、120°以上且つ180°以下である、CIE(1976)L*a*b*国際表色系で定義される色相角hを有する、光学物品。 - 請求項1~12の何れか一項に記載の光学材料を製造する方法であって、
- 400~450nmの範囲の波長を有する光を少なくとも部分的にブロックする少なくとも1つのUV吸収剤と、少なくとも1つの吸収色素Aであって、550nm~640nmの範囲内にその極大吸収波長を有する少なくとも1つの吸収色素Aと、ポリチオウレタン材料、又はその前駆体、ポリウレタンウレア材料、又はその前駆体、ポリエピスルフィドモノマー、若しくはオリゴマーの重合、若しくは共重合から得られる材料、又はその前駆体、及びアリルモノマー、若しくはオリゴマーの重合、若しくは共重合から得られる材料、又はその前駆体から選択される材料、又は化合物とを混合することによって光学材料組成物を調製するステップと、
- 前記光学材料組成物を硬化させるステップと
を含み、
前記光学材料は、500nm以上且つ550nm未満の極大吸収波長を有するいかなる吸収色素も含まない方法。
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AU2021283398A1 (en) | 2020-06-01 | 2023-01-05 | Icares Medicus, Inc. | Double-sided aspheric diffractive multifocal lens, manufacture, and uses thereof |
CN113189792A (zh) * | 2021-04-28 | 2021-07-30 | 江苏海一比真光学镜片有限公司 | 一种透明度高的蓝光吸收型镜片及其制备方法 |
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