JP7419245B2 - ウエットシート - Google Patents
ウエットシート Download PDFInfo
- Publication number
- JP7419245B2 JP7419245B2 JP2020545968A JP2020545968A JP7419245B2 JP 7419245 B2 JP7419245 B2 JP 7419245B2 JP 2020545968 A JP2020545968 A JP 2020545968A JP 2020545968 A JP2020545968 A JP 2020545968A JP 7419245 B2 JP7419245 B2 JP 7419245B2
- Authority
- JP
- Japan
- Prior art keywords
- sheet
- liquid composition
- magnesium
- sulfur odor
- wet sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 claims description 48
- 239000007788 liquid Substances 0.000 claims description 46
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- 229910052717 sulfur Inorganic materials 0.000 claims description 38
- 239000011593 sulfur Substances 0.000 claims description 38
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- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 10
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- 235000004611 garlic Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
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- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
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- 239000000077 insect repellent Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- UEGPKNKPLBYCNK-UHFFFAOYSA-L magnesium acetate Chemical compound [Mg+2].CC([O-])=O.CC([O-])=O UEGPKNKPLBYCNK-UHFFFAOYSA-L 0.000 description 1
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- 239000004753 textile Substances 0.000 description 1
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- SHWIJIJNPFXOFS-UHFFFAOYSA-N thiotaurine Chemical compound NCCS(O)(=O)=S SHWIJIJNPFXOFS-UHFFFAOYSA-N 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 229950009883 tocopheryl nicotinate Drugs 0.000 description 1
- JIVZKJJQOZQXQB-UHFFFAOYSA-N tolazoline Chemical compound C=1C=CC=CC=1CC1=NCCN1 JIVZKJJQOZQXQB-UHFFFAOYSA-N 0.000 description 1
- 229960002312 tolazoline Drugs 0.000 description 1
- GYDJEQRTZSCIOI-LJGSYFOKSA-N tranexamic acid Chemical compound NC[C@H]1CC[C@H](C(O)=O)CC1 GYDJEQRTZSCIOI-LJGSYFOKSA-N 0.000 description 1
- 229960000401 tranexamic acid Drugs 0.000 description 1
- PLSARIKBYIPYPF-UHFFFAOYSA-H trimagnesium dicitrate Chemical compound [Mg+2].[Mg+2].[Mg+2].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O PLSARIKBYIPYPF-UHFFFAOYSA-H 0.000 description 1
- 229960001722 verapamil Drugs 0.000 description 1
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- 238000005406 washing Methods 0.000 description 1
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- 238000002166 wet spinning Methods 0.000 description 1
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- 229940071104 xylenesulfonate Drugs 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- ZNVKGUVDRSSWHV-UHFFFAOYSA-L zinc;4-hydroxybenzenesulfonate Chemical compound [Zn+2].OC1=CC=C(S([O-])(=O)=O)C=C1.OC1=CC=C(S([O-])(=O)=O)C=C1 ZNVKGUVDRSSWHV-UHFFFAOYSA-L 0.000 description 1
- LYSLZRDZOBAUFL-UHFFFAOYSA-L zinc;4-tert-butylbenzoate Chemical compound [Zn+2].CC(C)(C)C1=CC=C(C([O-])=O)C=C1.CC(C)(C)C1=CC=C(C([O-])=O)C=C1 LYSLZRDZOBAUFL-UHFFFAOYSA-L 0.000 description 1
- JDLYKQWJXAQNNS-UHFFFAOYSA-L zinc;dibenzoate Chemical compound [Zn+2].[O-]C(=O)C1=CC=CC=C1.[O-]C(=O)C1=CC=CC=C1 JDLYKQWJXAQNNS-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- A—HUMAN NECESSITIES
- A47—FURNITURE; DOMESTIC ARTICLES OR APPLIANCES; COFFEE MILLS; SPICE MILLS; SUCTION CLEANERS IN GENERAL
- A47K—SANITARY EQUIPMENT NOT OTHERWISE PROVIDED FOR; TOILET ACCESSORIES
- A47K7/00—Body washing or cleaning implements
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/20—Halogens; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L9/00—Disinfection, sterilisation or deodorisation of air
- A61L9/01—Deodorant compositions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
Landscapes
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Veterinary Medicine (AREA)
- Animal Behavior & Ethology (AREA)
- Birds (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Cosmetics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Description
液状組成物が有機亜鉛化合物、有機マグネシウム化合物および無機マグネシウム化合物からなる群から選択される少なくとも1種の硫黄臭低減物質を、液状組成物の全量に対して1×10-6~2×10-2mol/L含有するものである。
程において分散性、均一性を確保することが可能である。
本発明のウエットシートは、レーヨンを含むシートと、シートに含浸される液状組成物とを含むウエットシートであって、液状組成物が有機亜鉛化合物、有機マグネシウム化合物および無機マグネシウム化合物からなる群から選択される少なくとも1種の硫黄臭低減物質を、液状組成物の全量に対して1×10-6~2×10-2mol/L含有するものである。
レーヨンを含むシートは、レーヨンを含んでいる繊維を含むシートであれば特に限定されるものではなく、不織布の他、繊維の編織布、和紙、多孔性フィルム、連続気孔を有する発泡体シートであってもよく、単層あるいはこれらの積層物であってもよい。また、これら単層または積層物は、さらに植毛により繊維で覆ったり、凹凸のエンボス加工したもの等の二次加工により、表面の特徴を変えたものやメッシュ状にしたもの等であってもよい。
シートの形状は特に限定されるものではなく、例えば、正方形、長方形の他、楕円形、円形、ハート形、半円形、半楕円形、台形、顔型等が挙げられる。
(硫黄臭低減物質)
液状組成物は、有機亜鉛化合物、有機マグネシウム化合物および無機マグネシウム化合物からなる群から選択される少なくとも1種の硫黄臭低減物質を含有する。ここで、有機亜鉛化合物、有機マグネシウム化合物、無機マグネシウム化合物の各化合物の、25℃における水への溶解性は好ましくは1×10-6mol/L以上、より好ましくは1×10-5mol/L以上、さらに好ましくは1×10-4mol/L以上、特に好ましくは1×10-3mol/L以上である。25℃における水への溶解性が1×10-6mol/L以上であることで、粉末がより凝集しにくく製造性が良くなる。
また、有機マグネシウム化合物としては、酢酸マグネシウム、プロピオン酸マグネシウム、乳酸マグネシウム、クエン酸マグネシウム、EDTAマグネシウム、リンゴ酸マグネシウム、グルコン酸マグネシウム、安息香酸マグネシウム、ベンゼンスルホン酸マグネシウム、トルエンスルホン酸マグネシウム、キシレンスルホン酸マグネシウム、クメンスルホン酸マグネシウム、リン酸アスコルビルマグネシウム等を挙げることができる。
無機マグネシウム化合物としては、塩化マグネシウム、硫酸マグネシウム、炭酸マグネシウム、リン酸マグネシウム等を、挙げることができる。
汎用性等の観点からすれば、フェノールスルホン酸亜鉛、塩化マグネシウムまたはリン酸アスコルビルマグネシウムが望ましい。これらの硫黄臭低減物質は1種のみを単独で用いてもよいし、2種以上を適宜組み合わせて用いてもよい。
硫黄臭低減物質が液状組成物の全量に対して1×10-6mol/L以上であることで、硫黄臭を効果的に低減することができる。また、硫黄臭低減物質が液状組成物の全量に対して2×10-2mol/L以下であることで、液状組成物に含まれる香料が相殺されることを抑制することができる。また、液状組成物に香料を含まない場合であっても、硫黄臭低減物質が液状組成物の全量に対して2×10-2mol/L以下であることで、金属イオンが液状組成物中に含まれる他成分と不溶性物質を生成することを防止でき、また、ウエットシートの適用対象部位に香水等の香料を適用している場合に、その香料を取り去ることを軽減することができる。
シートに含侵させる液状組成物の量は、シートの含浸前の自重に対して1~10倍であることが好ましい。清拭用シートの場合は、1~5倍が好ましく、2~4倍、特に3.5倍程度とすることが望ましい。1倍以上であることで、使用時に十分な液が放出され、清拭用の場合は5倍以下とすることで使用後に適度な液が肌上に残るため、べたつかない使用性となる。
本発明のウエットシートにおいて、シートへの液状組成物の含浸方法は公知の手段により行うことができ、例えば、滴下法、噴霧法、加圧法、ディッピング加工法が挙げられる。シートはそのままあるいは折りたたむなどして1枚または複数枚を用い、これに液状組成物を含浸させる。
本発明のウエットシートの使用形態は特に限定されないが、例えば、顔用汗拭きシート、身体用汗拭きシート、身体用デオドラントシート、足用拭き取りシート、介護用清拭シート、皮脂拭き取り用シート等の清拭シートや、化粧水や乳液等の化粧料を含侵させたスキンケア用シート、美容液等の化粧料を含侵させ、顔(全体、あるいは頬部、目元部、口元部等)、腕部、脚部、胸部、腹部、首部等の全体または局所の部位に密着させ、適当な時間放置後に剥離して使用するマスク用(パック用)シート等に用いることができる。
表1および2に示す処方により実施例および比較例の液状組成物を常法により調製した。各液状組成物を、レーヨンを80%含む不織布(レーヨン:疎水性繊維(PP/PE(50/50))=80:20で、目付40g/m2)に、不織布質量の約3倍量の液状組成物を含浸させた。
(硫黄臭低減効果)
上記含浸させた不織布について、4時間後にブラインドで3名により硫黄臭について、以下の基準で評価した。
A:硫黄臭を感じない
B:硫黄臭を感じにくい
C:硫黄臭は感じないが、香料の質がやや変化している
D:硫黄臭を感じる
実施例および比較例で用いた液状組成物を撹拌した後、撹拌停止1分後に粉末の分散状態を目視により、以下の基準で評価した。
A:溶解していて固体として分散しない
B:均一に分散している
C:ビーカーの底に沈殿物が観察される
液状組成物の処方とともに、評価結果を表1および2に示した。なお、表中のPPGはポリプロピレングリコール、PEGはポリエチレングリコールの略である。
Claims (6)
- レーヨンを含むシートと、該シートに含浸される液状組成物とを含むウエットシートであって、前記液状組成物がフェノールスルホン酸亜鉛、塩化マグネシウムおよびリン酸アスコルビルマグネシウムからなる群から選択される少なくとも1種の、レーヨンに起因する硫黄臭を抑制する硫黄臭低減物質を、前記液状組成物の全量に対して1×10-6~2×10-2mol/L含有するウエットシート。
- 前記硫黄臭低減物質が、25℃における水への溶解性が1×106mol/L以上である請求項1記載のウエットシート。
- 前記シートが不織布である請求項1または2記載のウエットシート。
- 前記シートのレーヨン含有量が50質量%以上である請求項1、2または3記載のウエットシート。
- 前記硫黄臭低減物質の含有量が前記液状組成物の全量に対して1×10-5~1×10-2mol/Lである請求項1~4のいずれか1項記載のウエットシート。
- ウエットシートが清拭用である請求項1~5いずれか1項記載のウエットシート。
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JP2016013475A (ja) | 2006-03-22 | 2016-01-28 | 高砂香料工業株式会社 | 消臭剤組成物 |
JP2010159513A (ja) | 2009-01-08 | 2010-07-22 | Lion Corp | ウエットシート用基材及びウエットシート |
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