JP7312181B2 - 嫌気硬化性組成物のための硬化促進剤 - Google Patents
嫌気硬化性組成物のための硬化促進剤 Download PDFInfo
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- JP7312181B2 JP7312181B2 JP2020540676A JP2020540676A JP7312181B2 JP 7312181 B2 JP7312181 B2 JP 7312181B2 JP 2020540676 A JP2020540676 A JP 2020540676A JP 2020540676 A JP2020540676 A JP 2020540676A JP 7312181 B2 JP7312181 B2 JP 7312181B2
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- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
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- C08K5/00—Use of organic ingredients
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- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
- C08K5/3432—Six-membered rings
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- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
- C08F20/20—Esters of polyhydric alcohols or polyhydric phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
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- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
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- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/10—Esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/14—Peroxides
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0025—Crosslinking or vulcanising agents; including accelerators
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K2003/1034—Materials or components characterised by specific properties
- C09K2003/1065—Anaerobically hardenable materials
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Epoxy Resins (AREA)
- Polymerization Catalysts (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Description
嫌気性接着剤組成物は、一般によく知られている。例えば、R.D.Rich,“Anaerobic Adhesives” Handbook of Adhesive Technology,29,467-79,A.PizziおよびK.L.Mittal編,MarcelDekker,Inc.,NewYork(1994)、およびそこで引用されている参考文献を参照されたい。それらの用途は多く、また新しい用途が開発され続けている。
サッカリンおよびAPHは、嫌気性接着剤硬化系において標準的な硬化促進剤成分として使用される。しかしながら、これらの成分は、世界の特定の地域では規制当局の監視下にあるため、その代替候補を同定するための努力がなされてきた。
(a)下記に包含される化合物:
(b)少なくとも1種のイソシアネート官能基材料。
本発明は、嫌気性接着剤に、従来の嫌気性硬化促進剤[トルイジン、THQ、および/またはアセチルフェニルヒドラジン(“APH”)など]の量の一部または全部に代えて硬化促進剤を添加することに関し、これは、驚くべきことに、従来の嫌気硬化性組成物で観察されたものと比べて少なくとも同等の硬化速度および物理的特性を、それから形成された反応生成物に提供する。
述べたように、フリーラジカル重合の従来の促進剤も、本発明で使用される硬化促進剤と組み合わせて、ただし過去に使用されていた量より少ない量で使用してもよい。このような促進剤(本明細書では共促進剤と呼ばれる)は、典型的には、米国特許第4,287,350号(Rich)および第4,321,349号(Rich)に開示されているように、多様なヒドラジン(例えば、APH)である。本明細書で使用するための共促進剤としてAPHを選択した場合、通常、マレイン酸も添加されることとなる。本発明の1つの利点は、本発明の嫌気性硬化促進剤が、嫌気性接着剤組成物の調製においてそのような酸の使用を不要にすることである。
有機アミドおよびイミド、例えば安息香酸スルフィミド(サッカリンとしても知られている)などが挙げられる(米国特許第4,324,349号を参照されたい)。当然ながら、THQも共促進剤として使用することができる。
Claims (8)
- 嫌気性硬化誘導組成物が、t-ブチルヒドロペルオキシド、p-メタンヒドロペルオキシド、クメンヒドロペルオキシド、ジイソプロピルベンゼンヒドロペルオキシド、およびそれらの混合物からなる群から選択されるヒドロペルオキシドを含む、請求項1に記載の組成物。
- 少なくとも1種の共促進剤をさらに含む、請求項1に記載の組成物。
- 共促進剤が、アミン、アミンオキシド、スルホンアミド、金属源、酸、およびそれらの混合物からなる群から選択される、請求項3に記載の組成物。
- 共促進剤が、トリアジン、エタノールアミン、ジエタノールアミン、トリエタノールアミン、N,Nジメチルアニリン、ベンゼンスルファンイミド、シクロヘキシルアミン、トリエチルアミン、ブチルアミン、サッカリン、N,N-ジエチル-p-トルイジン、N,N-ジメチル-o-トルイジン、アセチルフェニルヒドラジン、マレイン酸、およびそれらの混合物からなる群から選択される、請求項3に記載の組成物。
- 少なくとも1種の安定剤をさらに含む、請求項1に記載の組成物。
- 安定剤が、ベンゾキノン、ナフトキノン、アントラキノン、ヒドロキノン、メトキシヒドロキノン、ブチル化ヒドロキシトルエン、エチレンジアミン四酢酸またはその塩、およびそれらの混合物からなる群から選択される、請求項6に記載の組成物。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1716517.6 | 2017-10-09 | ||
GB1716517.6A GB2567242B (en) | 2017-10-09 | 2017-10-09 | Anaerobically curable compositions comprising 1, 2, 3, 4-tetrahydro benzo(h)quinolin-3-ol or derivatives thereof |
PCT/EP2018/077044 WO2019072686A1 (en) | 2017-10-09 | 2018-10-04 | CURING ACCELERATORS FOR ANAEROBICALLY CURABLE COMPOSITIONS |
Publications (2)
Publication Number | Publication Date |
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JP2020537029A JP2020537029A (ja) | 2020-12-17 |
JP7312181B2 true JP7312181B2 (ja) | 2023-07-20 |
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JP2020540676A Active JP7312181B2 (ja) | 2017-10-09 | 2018-10-04 | 嫌気硬化性組成物のための硬化促進剤 |
Country Status (11)
Country | Link |
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US (1) | US11274190B2 (ja) |
EP (1) | EP3694942B1 (ja) |
JP (1) | JP7312181B2 (ja) |
KR (1) | KR102601879B1 (ja) |
CN (1) | CN111417693B (ja) |
BR (1) | BR112020006459A2 (ja) |
CA (1) | CA3077392A1 (ja) |
GB (1) | GB2567242B (ja) |
MX (1) | MX2020004122A (ja) |
TW (1) | TWI770291B (ja) |
WO (1) | WO2019072686A1 (ja) |
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CN116323723A (zh) | 2020-08-18 | 2023-06-23 | 汉高股份有限及两合公司 | 用于可厌氧固化组合物的固化促进剂 |
WO2023165850A1 (en) * | 2022-03-04 | 2023-09-07 | Henkel Ag & Co. Kgaa | Cure accelerator for anaerobic curable composition |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2012525417A (ja) | 2009-05-01 | 2012-10-22 | ヘンケル コーポレイション | 嫌気硬化性組成物用の硬化促進剤 |
JP2013508476A (ja) | 2009-10-15 | 2013-03-07 | ヘンケル コーポレイション | 嫌気硬化性組成物 |
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JPS59207977A (ja) * | 1983-05-12 | 1984-11-26 | Okura Ind Co Ltd | 嫌気硬化性接着剤 |
IE882227L (en) * | 1988-07-21 | 1990-01-21 | Loctite Ireland Ltd | Sealant composition |
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- 2018-10-04 BR BR112020006459-9A patent/BR112020006459A2/pt not_active Application Discontinuation
- 2018-10-04 WO PCT/EP2018/077044 patent/WO2019072686A1/en unknown
- 2018-10-04 CA CA3077392A patent/CA3077392A1/en active Pending
- 2018-10-04 KR KR1020207010797A patent/KR102601879B1/ko active IP Right Grant
- 2018-10-04 CN CN201880076133.3A patent/CN111417693B/zh active Active
- 2018-10-04 JP JP2020540676A patent/JP7312181B2/ja active Active
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- 2018-10-08 TW TW107135451A patent/TWI770291B/zh not_active IP Right Cessation
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Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2012525417A (ja) | 2009-05-01 | 2012-10-22 | ヘンケル コーポレイション | 嫌気硬化性組成物用の硬化促進剤 |
JP2013508476A (ja) | 2009-10-15 | 2013-03-07 | ヘンケル コーポレイション | 嫌気硬化性組成物 |
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MX2020004122A (es) | 2020-08-13 |
TW201922906A (zh) | 2019-06-16 |
KR20200067151A (ko) | 2020-06-11 |
EP3694942A1 (en) | 2020-08-19 |
JP2020537029A (ja) | 2020-12-17 |
GB201716517D0 (en) | 2017-11-22 |
TWI770291B (zh) | 2022-07-11 |
KR102601879B1 (ko) | 2023-11-14 |
WO2019072686A1 (en) | 2019-04-18 |
GB2567242B (en) | 2021-08-11 |
GB2567242A (en) | 2019-04-10 |
CN111417693B (zh) | 2022-05-27 |
US11274190B2 (en) | 2022-03-15 |
BR112020006459A2 (pt) | 2020-10-06 |
CA3077392A1 (en) | 2019-04-18 |
CN111417693A (zh) | 2020-07-14 |
EP3694942B1 (en) | 2021-09-29 |
US20200299485A1 (en) | 2020-09-24 |
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