JP7188922B2 - プロトン性イオン液体を有する水系電解質及び前記電解質を用いた電池 - Google Patents
プロトン性イオン液体を有する水系電解質及び前記電解質を用いた電池 Download PDFInfo
- Publication number
- JP7188922B2 JP7188922B2 JP2018131580A JP2018131580A JP7188922B2 JP 7188922 B2 JP7188922 B2 JP 7188922B2 JP 2018131580 A JP2018131580 A JP 2018131580A JP 2018131580 A JP2018131580 A JP 2018131580A JP 7188922 B2 JP7188922 B2 JP 7188922B2
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- Japan
- Prior art keywords
- lithium
- group
- formula
- fluoroalkylsulfonyl
- ionic liquid
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- 239000003792 electrolyte Substances 0.000 title claims description 60
- 239000002608 ionic liquid Substances 0.000 title claims description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 45
- 150000001450 anions Chemical class 0.000 claims description 34
- 229910001416 lithium ion Inorganic materials 0.000 claims description 30
- 229910003002 lithium salt Inorganic materials 0.000 claims description 29
- 159000000002 lithium salts Chemical class 0.000 claims description 29
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 27
- 150000001768 cations Chemical class 0.000 claims description 19
- 229910052744 lithium Inorganic materials 0.000 claims description 19
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 17
- 238000009831 deintercalation Methods 0.000 claims description 13
- 238000009830 intercalation Methods 0.000 claims description 13
- 150000003839 salts Chemical group 0.000 claims description 11
- DOYSIZKQWJYULQ-UHFFFAOYSA-N 1,1,2,2,2-pentafluoro-n-(1,1,2,2,2-pentafluoroethylsulfonyl)ethanesulfonamide Chemical compound FC(F)(F)C(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)C(F)(F)F DOYSIZKQWJYULQ-UHFFFAOYSA-N 0.000 claims description 10
- ACFSQHQYDZIPRL-UHFFFAOYSA-N lithium;bis(1,1,2,2,2-pentafluoroethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)C(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)C(F)(F)F ACFSQHQYDZIPRL-UHFFFAOYSA-N 0.000 claims description 8
- QSZMZKBZAYQGRS-UHFFFAOYSA-N lithium;bis(trifluoromethylsulfonyl)azanide Chemical compound [Li+].FC(F)(F)S(=O)(=O)[N-]S(=O)(=O)C(F)(F)F QSZMZKBZAYQGRS-UHFFFAOYSA-N 0.000 claims description 8
- 239000011149 active material Substances 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 7
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 7
- ZXMGHDIOOHOAAE-UHFFFAOYSA-N 1,1,1-trifluoro-n-(trifluoromethylsulfonyl)methanesulfonamide Chemical compound FC(F)(F)S(=O)(=O)NS(=O)(=O)C(F)(F)F ZXMGHDIOOHOAAE-UHFFFAOYSA-N 0.000 claims description 5
- 125000006165 cyclic alkyl group Chemical group 0.000 claims description 5
- 239000006183 anode active material Substances 0.000 claims description 4
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 claims description 4
- 229910011279 LiCoPO4 Inorganic materials 0.000 claims description 3
- 229910014089 LiMn1/3Ni1/3Co1/3O2 Inorganic materials 0.000 claims description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 claims description 3
- 229910032387 LiCoO2 Inorganic materials 0.000 claims description 2
- 229910010592 LiFe2 Inorganic materials 0.000 claims description 2
- 229910002097 Lithium manganese(III,IV) oxide Inorganic materials 0.000 claims description 2
- AFVFQIVMOAPDHO-UHFFFAOYSA-M Methanesulfonate Chemical compound CS([O-])(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-M 0.000 claims 2
- 229910017267 Mo 6 S 8 Inorganic materials 0.000 claims 2
- 229910012764 LiNi0.5Mn1 Inorganic materials 0.000 claims 1
- 150000001875 compounds Chemical class 0.000 claims 1
- 150000003871 sulfonates Chemical class 0.000 claims 1
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims 1
- -1 salt ions Chemical class 0.000 description 18
- 239000000203 mixture Substances 0.000 description 16
- 229910015643 LiMn 2 O 4 Inorganic materials 0.000 description 9
- 239000011230 binding agent Substances 0.000 description 8
- 229920001577 copolymer Polymers 0.000 description 8
- 238000010586 diagram Methods 0.000 description 8
- 239000000463 material Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 6
- 239000010405 anode material Substances 0.000 description 5
- 150000003949 imides Chemical class 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- 229920001780 ECTFE Polymers 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 239000002033 PVDF binder Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- MCVFFRWZNYZUIJ-UHFFFAOYSA-M lithium;trifluoromethanesulfonate Chemical compound [Li+].[O-]S(=O)(=O)C(F)(F)F MCVFFRWZNYZUIJ-UHFFFAOYSA-M 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 239000002245 particle Substances 0.000 description 4
- 229920002493 poly(chlorotrifluoroethylene) Polymers 0.000 description 4
- 239000005023 polychlorotrifluoroethylene (PCTFE) polymer Substances 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- 229910002099 LiNi0.5Mn1.5O4 Inorganic materials 0.000 description 3
- 239000010406 cathode material Substances 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000002484 cyclic voltammetry Methods 0.000 description 2
- 230000001351 cycling effect Effects 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- QHSJIZLJUFMIFP-UHFFFAOYSA-N ethene;1,1,2,2-tetrafluoroethene Chemical compound C=C.FC(F)=C(F)F QHSJIZLJUFMIFP-UHFFFAOYSA-N 0.000 description 2
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910018039 Cu2V2O7 Inorganic materials 0.000 description 1
- 229910002986 Li4Ti5O12 Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910011573 LiFe Inorganic materials 0.000 description 1
- 229910013246 LiNiMnO Inorganic materials 0.000 description 1
- 229910018095 Ni-MH Inorganic materials 0.000 description 1
- 229910018477 Ni—MH Inorganic materials 0.000 description 1
- 241000150258 Prospect Hill orthohantavirus Species 0.000 description 1
- FDLZQPXZHIFURF-UHFFFAOYSA-N [O-2].[Ti+4].[Li+] Chemical compound [O-2].[Ti+4].[Li+] FDLZQPXZHIFURF-UHFFFAOYSA-N 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000006182 cathode active material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 150000004292 cyclic ethers Chemical class 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001747 exhibiting effect Effects 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- FRMOHNDAXZZWQI-UHFFFAOYSA-N lithium manganese(2+) nickel(2+) oxygen(2-) Chemical compound [O-2].[Mn+2].[Ni+2].[Li+] FRMOHNDAXZZWQI-UHFFFAOYSA-N 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000011255 nonaqueous electrolyte Substances 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 229920000218 poly(hydroxyvalerate) Polymers 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0561—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of inorganic materials only
- H01M10/0563—Liquid materials, e.g. for Li-SOCl2 cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0005—Acid electrolytes
- H01M2300/0008—Phosphoric acid-based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0005—Acid electrolytes
- H01M2300/0011—Sulfuric acid-based
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
- H01M2300/0014—Alkaline electrolytes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US15/663,262 | 2017-07-28 | ||
| US15/663,262 US11133523B2 (en) | 2017-07-28 | 2017-07-28 | Aqueous electrolytes with protonic ionic liquid and batteries using the electrolyte |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019050183A JP2019050183A (ja) | 2019-03-28 |
| JP2019050183A5 JP2019050183A5 (cg-RX-API-DMAC7.html) | 2021-08-26 |
| JP7188922B2 true JP7188922B2 (ja) | 2022-12-13 |
Family
ID=65137944
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018131580A Active JP7188922B2 (ja) | 2017-07-28 | 2018-07-11 | プロトン性イオン液体を有する水系電解質及び前記電解質を用いた電池 |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US11133523B2 (cg-RX-API-DMAC7.html) |
| JP (1) | JP7188922B2 (cg-RX-API-DMAC7.html) |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP6874605B2 (ja) * | 2017-08-30 | 2021-05-19 | トヨタ自動車株式会社 | 水系電解液及び水系リチウムイオン二次電池 |
| JP6911774B2 (ja) | 2018-01-09 | 2021-07-28 | トヨタ自動車株式会社 | 水系電解液及び水系リチウムイオン二次電池 |
| KR102702443B1 (ko) | 2019-03-19 | 2024-09-04 | 고쿠리츠다이가쿠호우진 도쿄다이가쿠 | 축전 디바이스용 수계 전해액 및 이 수계 전해액을 포함하는 축전 디바이스 |
| CN113994506A (zh) * | 2019-06-07 | 2022-01-28 | 株式会社半导体能源研究所 | 二次电池、电子设备及车辆 |
| CN111244540B (zh) * | 2020-01-17 | 2021-11-09 | 中国科学院兰州化学物理研究所 | 一种水系高电压窗口防冻电解液及其应用 |
| CN113540563B (zh) * | 2020-04-17 | 2023-04-07 | 中国石油化工股份有限公司 | 一种添加剂以及锂电池电解液的改性方法 |
| US20220200295A1 (en) * | 2020-12-23 | 2022-06-23 | Medtronic, Inc. | Systems and method for charging batteries |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006344433A (ja) | 2005-06-07 | 2006-12-21 | Nissan Motor Co Ltd | イオン伝導体及びこれを用いたエネルギーデバイス |
| WO2016114141A1 (ja) | 2015-01-14 | 2016-07-21 | 国立大学法人 東京大学 | 蓄電装置用水系電解液、及び当該水系電解液を含む蓄電装置 |
| JP2017059551A (ja) | 2004-08-30 | 2017-03-23 | トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ,インコーポレイティド | 電池 |
| WO2017105578A2 (en) | 2015-09-28 | 2017-06-22 | University Of Maryland, College Park | Aqueous and hybrid electrolytes with wide electrochemical stability windows |
| JP2018049819A (ja) | 2016-08-31 | 2018-03-29 | トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ,インコーポレイティド | エーテルを含む水性電解液及び当該電解液を使用した電池 |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101501329B1 (ko) * | 2010-01-12 | 2015-03-10 | 도요타지도샤가부시키가이샤 | 액상의 소수성 상전이 물질 및 그것을 사용한 전지 |
| KR101155913B1 (ko) * | 2010-02-02 | 2012-06-20 | 삼성에스디아이 주식회사 | 리튬 이차 전지용 음극 활물질 및 이를 포함하는 리튬 이차 전지 |
| KR101561188B1 (ko) * | 2013-02-20 | 2015-10-16 | 에스케이이노베이션 주식회사 | 리튬 이차전지용 음극, 그 제조방법 및 이를 포함하는 리튬 에어 배터리 |
| AU2014229001A1 (en) * | 2013-03-15 | 2015-10-15 | Materials Modification Inc. | Functionalized ionic liquids and their applacations |
| FR3052598B1 (fr) * | 2016-06-10 | 2018-06-01 | Universite De Rennes 1 | Utilisation de liquides ioniques comme adjuvant en electrochimie |
-
2017
- 2017-07-28 US US15/663,262 patent/US11133523B2/en not_active Expired - Fee Related
-
2018
- 2018-07-11 JP JP2018131580A patent/JP7188922B2/ja active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2017059551A (ja) | 2004-08-30 | 2017-03-23 | トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ,インコーポレイティド | 電池 |
| JP2006344433A (ja) | 2005-06-07 | 2006-12-21 | Nissan Motor Co Ltd | イオン伝導体及びこれを用いたエネルギーデバイス |
| WO2016114141A1 (ja) | 2015-01-14 | 2016-07-21 | 国立大学法人 東京大学 | 蓄電装置用水系電解液、及び当該水系電解液を含む蓄電装置 |
| WO2017105578A2 (en) | 2015-09-28 | 2017-06-22 | University Of Maryland, College Park | Aqueous and hybrid electrolytes with wide electrochemical stability windows |
| JP2018049819A (ja) | 2016-08-31 | 2018-03-29 | トヨタ モーター エンジニアリング アンド マニュファクチャリング ノース アメリカ,インコーポレイティド | エーテルを含む水性電解液及び当該電解液を使用した電池 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20190036151A1 (en) | 2019-01-31 |
| JP2019050183A (ja) | 2019-03-28 |
| US11133523B2 (en) | 2021-09-28 |
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