JP7175889B2 - 進歩した多孔性炭素質材料およびそれらの調製方法 - Google Patents
進歩した多孔性炭素質材料およびそれらの調製方法 Download PDFInfo
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- JP7175889B2 JP7175889B2 JP2019528496A JP2019528496A JP7175889B2 JP 7175889 B2 JP7175889 B2 JP 7175889B2 JP 2019528496 A JP2019528496 A JP 2019528496A JP 2019528496 A JP2019528496 A JP 2019528496A JP 7175889 B2 JP7175889 B2 JP 7175889B2
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- vinylidene chloride
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- B01D2253/30—Physical properties of adsorbents
- B01D2253/34—Specific shapes
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001058807A (ja) | 1999-08-23 | 2001-03-06 | Kureha Chem Ind Co Ltd | ポリ塩化ビニリデン系樹脂粉末及び活性炭 |
JP2001089119A (ja) | 1999-04-30 | 2001-04-03 | Adchemco Corp | 炭素質材料およびその製造方法およびこれを用いた電気二重層キャパシタ |
JP2001110689A (ja) | 1999-10-04 | 2001-04-20 | Asahi Kasei Corp | 電気二重層キャパシタ電極用活性炭原料及び活性炭 |
JP2001114505A (ja) | 1999-10-15 | 2001-04-24 | Osaka Gas Co Ltd | 炭素材料、炭素材料の粒径制御方法、リチウム二次電池負極用炭素材料およびリチウム二次電池 |
JP2004529747A (ja) | 2001-01-24 | 2004-09-30 | ハネウェル・インターナショナル・インコーポレーテッド | 空気からco2と水を同時に除去するための強化・機能化されたカーボンモレキュラーシーブ |
JP2010095706A (ja) | 2008-09-22 | 2010-04-30 | Jsr Corp | 樹脂粒子 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2609150A (en) | 1949-11-05 | 1952-09-02 | Union Carbide & Carbon Corp | Mechanical pulverization of refrigerated plastics |
US2968651A (en) | 1957-02-08 | 1961-01-17 | Dow Chemical Co | Process for preparing normally crystalline vinylidene chloride polymers |
JPS57145017A (en) * | 1981-02-26 | 1982-09-07 | Mitsubishi Chem Ind Ltd | Preparation of porous carbonaceous particle |
US5292706A (en) | 1992-07-01 | 1994-03-08 | Allied-Signal Inc. | Preparing carbon molecular sieves of increased density |
JP3229033B2 (ja) * | 1992-08-19 | 2001-11-12 | 三井鉱山株式会社 | 水素精製用分子篩炭素材 |
US6171373B1 (en) | 1996-04-23 | 2001-01-09 | Applied Ceramics, Inc. | Adsorptive monolith including activated carbon, method for making said monolith, and method for adsorbing chemical agents from fluid streams |
US6294501B1 (en) | 1998-03-09 | 2001-09-25 | Alliedsignal Inc. | Special adsorbent for carbon dioxide acquisition on mars |
US6626981B2 (en) * | 2000-07-07 | 2003-09-30 | Advanced Fuel Research, Inc. | Microporous carbons for gas storage |
US20030217967A1 (en) * | 2001-08-23 | 2003-11-27 | The Procter & Gamble Company | Processes for manufacturing water filter materials and water filters |
US6743278B1 (en) | 2002-12-10 | 2004-06-01 | Advanced Technology Materials, Inc. | Gas storage and dispensing system with monolithic carbon adsorbent |
US7316323B2 (en) * | 2004-05-06 | 2008-01-08 | The Procter & Gamble Company | Filters having improved permeability and virus removal capabilities |
CN1281486C (zh) * | 2005-01-06 | 2006-10-25 | 北京化工大学 | 一种聚合物基炭球的制备方法 |
CN100509621C (zh) * | 2006-04-12 | 2009-07-08 | 中国科学院金属研究所 | 不同尺度纳米孔可控层次组合的碳材料及制备方法和应用 |
JP5021409B2 (ja) * | 2007-09-27 | 2012-09-05 | 公立大学法人大阪府立大学 | メタン吸着剤またはその製造方法 |
US8615812B2 (en) * | 2009-03-31 | 2013-12-31 | Advanced Fuel Research, Inc. | High-strength porous carbon and its multifunctional applications |
CN102811804B (zh) * | 2009-12-14 | 2015-04-15 | 特洛伊之海伦有限公司 | 含用pDADMAC涂布的活性炭颗粒的过滤器及其制造方法 |
US8679231B2 (en) | 2011-01-19 | 2014-03-25 | Advanced Technology Materials, Inc. | PVDF pyrolyzate adsorbent and gas storage and dispensing system utilizing same |
CA2825835A1 (en) | 2011-01-31 | 2012-08-09 | Advanced Technology Materials, Inc. | Carbon pyrolyzate adsorbent having utility for co2 capture and methods of making and using the same |
KR101404715B1 (ko) | 2013-02-04 | 2014-06-09 | 한국수력원자력 주식회사 | 유리 용융로 온도 측정장치 |
CN105283245B (zh) * | 2013-03-27 | 2019-04-19 | 陶氏环球技术有限责任公司 | 适用于c2-c3烷烃/烯烃分离的新颖碳分子筛和丸粒组合物 |
US9186650B2 (en) * | 2013-04-05 | 2015-11-17 | Entegris, Inc. | Adsorbent having utility for CO2 capture from gas mixtures |
WO2015081317A2 (en) | 2013-11-28 | 2015-06-04 | Entegris, Inc. | Carbon monoliths for adsorption refrigeration and heating applications |
CN103663450B (zh) * | 2013-12-19 | 2016-03-16 | 中国科学院过程工程研究所 | 一种高比表面积碳微球及其制备方法 |
WO2015109381A1 (en) | 2014-01-21 | 2015-07-30 | Her Majesty The Queen In Right Of Canada, As Represented By The Minister Of National Defence | Carbon monolith and method of producing same |
JP6651468B2 (ja) * | 2014-06-30 | 2020-02-19 | ダウ グローバル テクノロジーズ エルエルシー | 塩化ビニリデンコポリマー系炭素分子篩吸着剤組成物及びそれのためのプロセス |
-
2017
- 2017-11-17 EP EP17807776.4A patent/EP3548172B1/en active Active
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- 2017-11-17 WO PCT/EP2017/079648 patent/WO2018099739A1/en unknown
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Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001089119A (ja) | 1999-04-30 | 2001-04-03 | Adchemco Corp | 炭素質材料およびその製造方法およびこれを用いた電気二重層キャパシタ |
JP2001058807A (ja) | 1999-08-23 | 2001-03-06 | Kureha Chem Ind Co Ltd | ポリ塩化ビニリデン系樹脂粉末及び活性炭 |
JP2001110689A (ja) | 1999-10-04 | 2001-04-20 | Asahi Kasei Corp | 電気二重層キャパシタ電極用活性炭原料及び活性炭 |
JP2001114505A (ja) | 1999-10-15 | 2001-04-24 | Osaka Gas Co Ltd | 炭素材料、炭素材料の粒径制御方法、リチウム二次電池負極用炭素材料およびリチウム二次電池 |
JP2004529747A (ja) | 2001-01-24 | 2004-09-30 | ハネウェル・インターナショナル・インコーポレーテッド | 空気からco2と水を同時に除去するための強化・機能化されたカーボンモレキュラーシーブ |
JP2010095706A (ja) | 2008-09-22 | 2010-04-30 | Jsr Corp | 樹脂粒子 |
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US20190388872A1 (en) | 2019-12-26 |
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