JP7049894B2 - ボロン系膜の成膜方法および成膜装置 - Google Patents
ボロン系膜の成膜方法および成膜装置 Download PDFInfo
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- JP7049894B2 JP7049894B2 JP2018072625A JP2018072625A JP7049894B2 JP 7049894 B2 JP7049894 B2 JP 7049894B2 JP 2018072625 A JP2018072625 A JP 2018072625A JP 2018072625 A JP2018072625 A JP 2018072625A JP 7049894 B2 JP7049894 B2 JP 7049894B2
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- Prior art keywords
- boron
- based film
- plasma
- forming
- gas
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- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 title claims description 229
- 229910052796 boron Inorganic materials 0.000 title claims description 223
- 238000000034 method Methods 0.000 title claims description 53
- 239000007789 gas Substances 0.000 claims description 205
- 239000000758 substrate Substances 0.000 claims description 74
- 230000015572 biosynthetic process Effects 0.000 claims description 24
- 238000005268 plasma chemical vapour deposition Methods 0.000 claims description 20
- 125000004429 atom Chemical group 0.000 claims description 18
- 150000002500 ions Chemical class 0.000 claims description 18
- 238000012545 processing Methods 0.000 claims description 17
- 238000009832 plasma treatment Methods 0.000 claims description 12
- 230000007246 mechanism Effects 0.000 claims description 11
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 10
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 9
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229910052786 argon Inorganic materials 0.000 claims description 5
- 239000012535 impurity Substances 0.000 claims description 5
- 238000004544 sputter deposition Methods 0.000 claims description 4
- 239000010410 layer Substances 0.000 claims 9
- 239000012790 adhesive layer Substances 0.000 claims 2
- 125000004430 oxygen atom Chemical group O* 0.000 claims 2
- 239000010408 film Substances 0.000 description 240
- 239000000463 material Substances 0.000 description 17
- 230000005540 biological transmission Effects 0.000 description 14
- 230000008569 process Effects 0.000 description 9
- 239000004065 semiconductor Substances 0.000 description 8
- 229910052710 silicon Inorganic materials 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 239000010703 silicon Substances 0.000 description 6
- 239000004020 conductor Substances 0.000 description 5
- 238000005530 etching Methods 0.000 description 5
- 239000007769 metal material Substances 0.000 description 5
- 238000010926 purge Methods 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 4
- -1 alkyl borane Chemical compound 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 4
- 230000006378 damage Effects 0.000 description 4
- 230000006870 function Effects 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- 230000009471 action Effects 0.000 description 3
- 229910003481 amorphous carbon Inorganic materials 0.000 description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 description 3
- 229910000085 borane Inorganic materials 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- ZOCHARZZJNPSEU-UHFFFAOYSA-N diboron Chemical compound B#B ZOCHARZZJNPSEU-UHFFFAOYSA-N 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 238000001312 dry etching Methods 0.000 description 3
- 230000005284 excitation Effects 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 238000004381 surface treatment Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- FAQYAMRNWDIXMY-UHFFFAOYSA-N trichloroborane Chemical compound ClB(Cl)Cl FAQYAMRNWDIXMY-UHFFFAOYSA-N 0.000 description 3
- UORVGPXVDQYIDP-UHFFFAOYSA-N trihydridoboron Substances B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 3
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- 229910052581 Si3N4 Inorganic materials 0.000 description 2
- 239000000956 alloy Substances 0.000 description 2
- 229910045601 alloy Inorganic materials 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 230000001965 increasing effect Effects 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000002093 peripheral effect Effects 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- 239000010453 quartz Substances 0.000 description 2
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 2
- 230000003746 surface roughness Effects 0.000 description 2
- 238000002230 thermal chemical vapour deposition Methods 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 2
- 229910052721 tungsten Inorganic materials 0.000 description 2
- 239000010937 tungsten Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000004642 Polyimide Substances 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 229910052756 noble gas Inorganic materials 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229910052814 silicon oxide Inorganic materials 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
- WXRGABKACDFXMG-UHFFFAOYSA-N trimethylborane Chemical compound CB(C)C WXRGABKACDFXMG-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/27—Relating to heating, ventilation or air conditioning [HVAC] technologies
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- Chemical Vapour Deposition (AREA)
- Formation Of Insulating Films (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2018072625A JP7049894B2 (ja) | 2018-04-04 | 2018-04-04 | ボロン系膜の成膜方法および成膜装置 |
US17/041,767 US11615957B2 (en) | 2018-04-04 | 2019-02-26 | Method for forming boron-based film, formation apparatus |
PCT/JP2019/007273 WO2019193872A1 (ja) | 2018-04-04 | 2019-02-26 | ボロン系膜の成膜方法および成膜装置 |
KR1020207030966A KR102493031B1 (ko) | 2018-04-04 | 2019-02-26 | 보론계 막의 성막 방법 및 성막 장치 |
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JP2018072625A JP7049894B2 (ja) | 2018-04-04 | 2018-04-04 | ボロン系膜の成膜方法および成膜装置 |
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JP2019186306A JP2019186306A (ja) | 2019-10-24 |
JP2019186306A5 JP2019186306A5 (enrdf_load_stackoverflow) | 2021-03-04 |
JP7049894B2 true JP7049894B2 (ja) | 2022-04-07 |
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001302218A (ja) | 1999-12-27 | 2001-10-31 | National Institute For Materials Science | 立方晶窒化ホウ素及びその気相合成法 |
JP2006237478A (ja) | 2005-02-28 | 2006-09-07 | Mitsubishi Heavy Ind Ltd | 窒化ホウ素膜の成膜方法及び成膜装置 |
JP2009099583A (ja) | 2007-10-12 | 2009-05-07 | Ulvac Japan Ltd | 半導体装置の製造方法及び半導体装置の製造装置 |
WO2011083869A1 (ja) | 2010-01-11 | 2011-07-14 | 国立大学法人九州大学 | 立方晶窒化ホウ素コーティング法およびそれにより得られる材料 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05213695A (ja) * | 1992-02-03 | 1993-08-24 | Matsushita Electric Ind Co Ltd | ダイヤモンド薄膜の堆積方法 |
JPH07300665A (ja) * | 1994-05-02 | 1995-11-14 | Yuken Kogyo Kk | 金属基材のホウ素拡散浸透層・ホウ素膜形成方法 |
-
2018
- 2018-04-04 JP JP2018072625A patent/JP7049894B2/ja active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001302218A (ja) | 1999-12-27 | 2001-10-31 | National Institute For Materials Science | 立方晶窒化ホウ素及びその気相合成法 |
JP2006237478A (ja) | 2005-02-28 | 2006-09-07 | Mitsubishi Heavy Ind Ltd | 窒化ホウ素膜の成膜方法及び成膜装置 |
JP2009099583A (ja) | 2007-10-12 | 2009-05-07 | Ulvac Japan Ltd | 半導体装置の製造方法及び半導体装置の製造装置 |
WO2011083869A1 (ja) | 2010-01-11 | 2011-07-14 | 国立大学法人九州大学 | 立方晶窒化ホウ素コーティング法およびそれにより得られる材料 |
Non-Patent Citations (1)
Title |
---|
Seiichiro Matsumoto and Wenjun Zhang,High-Rate Deposition of High-Quality, Thick Cubic Boron Nitride Films by Bias-Assisted DC Jet Plasma Chemical Vapor Deposition ,JAPANESE JOURNAL OF APPLIED PHYSICS ,日本,The Japan Society of Applied Physics,2000年,Vol.39、No.5B,pp.L442-L444 |
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JP2019186306A (ja) | 2019-10-24 |
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