JP7036514B2 - テトラフルオロエチレン及び１つ以上のペルフルオロアルキルアリルエーテルコモノマーを含むフルオロポリマー - Google Patents
テトラフルオロエチレン及び１つ以上のペルフルオロアルキルアリルエーテルコモノマーを含むフルオロポリマー Download PDFInfo
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- JP7036514B2 JP7036514B2 JP2019508833A JP2019508833A JP7036514B2 JP 7036514 B2 JP7036514 B2 JP 7036514B2 JP 2019508833 A JP2019508833 A JP 2019508833A JP 2019508833 A JP2019508833 A JP 2019508833A JP 7036514 B2 JP7036514 B2 JP 7036514B2
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- tetrafluoroethylene copolymer
- tetrafluoroethylene
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- polymer
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- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 title claims description 43
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 title claims description 15
- 229920002313 fluoropolymer Polymers 0.000 title description 21
- 239000004811 fluoropolymer Substances 0.000 title description 20
- 229920001577 copolymer Polymers 0.000 claims description 88
- 229920000642 polymer Polymers 0.000 claims description 62
- 239000006185 dispersion Substances 0.000 claims description 45
- 125000004432 carbon atom Chemical group C* 0.000 claims description 24
- 238000002844 melting Methods 0.000 claims description 23
- 230000008018 melting Effects 0.000 claims description 23
- -1 perfluoroalkyl vinyl ether Chemical compound 0.000 claims description 20
- 239000000155 melt Substances 0.000 claims description 14
- HCDGVLDPFQMKDK-UHFFFAOYSA-N hexafluoropropylene Chemical compound FC(F)=C(F)C(F)(F)F HCDGVLDPFQMKDK-UHFFFAOYSA-N 0.000 claims description 13
- 125000005003 perfluorobutyl group Chemical group FC(F)(F)C(F)(F)C(F)(F)C(F)(F)* 0.000 claims description 7
- 125000005004 perfluoroethyl group Chemical group FC(F)(F)C(F)(F)* 0.000 claims description 7
- 125000005009 perfluoropropyl group Chemical group FC(C(C(F)(F)F)(F)F)(F)* 0.000 claims description 7
- 239000004711 α-olefin Substances 0.000 claims description 7
- 125000005010 perfluoroalkyl group Chemical group 0.000 claims description 6
- 125000002023 trifluoromethyl group Chemical group FC(F)(F)* 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 description 39
- 239000002245 particle Substances 0.000 description 34
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 27
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- 238000006116 polymerization reaction Methods 0.000 description 24
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- SNGREZUHAYWORS-UHFFFAOYSA-N perfluorooctanoic acid Chemical compound OC(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F SNGREZUHAYWORS-UHFFFAOYSA-N 0.000 description 13
- 238000006243 chemical reaction Methods 0.000 description 12
- 238000004519 manufacturing process Methods 0.000 description 12
- 125000000896 monocarboxylic acid group Chemical group 0.000 description 11
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- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 239000002736 nonionic surfactant Substances 0.000 description 9
- 239000007787 solid Substances 0.000 description 9
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- 125000001931 aliphatic group Chemical group 0.000 description 8
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
- 150000007513 acids Chemical class 0.000 description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 6
- 150000002170 ethers Chemical class 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
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- 239000004810 polytetrafluoroethylene Substances 0.000 description 6
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
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- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000000470 constituent Substances 0.000 description 4
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- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 3
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- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- 150000001335 aliphatic alkanes Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 3
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- PLFJWWUZKJKIPZ-UHFFFAOYSA-N 2-[2-[2-(2,6,8-trimethylnonan-4-yloxy)ethoxy]ethoxy]ethanol Chemical compound CC(C)CC(C)CC(CC(C)C)OCCOCCOCCO PLFJWWUZKJKIPZ-UHFFFAOYSA-N 0.000 description 2
- LCGLNKUTAGEVQW-UHFFFAOYSA-N Dimethyl ether Chemical compound COC LCGLNKUTAGEVQW-UHFFFAOYSA-N 0.000 description 2
- 238000004566 IR spectroscopy Methods 0.000 description 2
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- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- ZUQAPLKKNAQJAU-UHFFFAOYSA-N acetylenediol Chemical class OC#CO ZUQAPLKKNAQJAU-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000002318 adhesion promoter Substances 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- 125000000129 anionic group Chemical group 0.000 description 2
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- 239000012752 auxiliary agent Substances 0.000 description 2
- 230000002902 bimodal effect Effects 0.000 description 2
- 239000000872 buffer Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
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- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 description 2
- 238000002296 dynamic light scattering Methods 0.000 description 2
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- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N n-hexadecanoic acid Natural products CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 239000012875 nonionic emulsifier Substances 0.000 description 2
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
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- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 2
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 2
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 2
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 2
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 2
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 2
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- 125000002572 propoxy group Chemical group [*]OC([H])([H])C(C([H])([H])[H])([H])[H] 0.000 description 2
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- BLTXWCKMNMYXEA-UHFFFAOYSA-N 1,1,2-trifluoro-2-(trifluoromethoxy)ethene Chemical compound FC(F)=C(F)OC(F)(F)F BLTXWCKMNMYXEA-UHFFFAOYSA-N 0.000 description 1
- BQCIDUSAKPWEOX-UHFFFAOYSA-N 1,1-Difluoroethene Chemical compound FC(F)=C BQCIDUSAKPWEOX-UHFFFAOYSA-N 0.000 description 1
- WUMVZXWBOFOYAW-UHFFFAOYSA-N 1,2,3,3,4,4,4-heptafluoro-1-(1,2,3,3,4,4,4-heptafluorobut-1-enoxy)but-1-ene Chemical compound FC(F)(F)C(F)(F)C(F)=C(F)OC(F)=C(F)C(F)(F)C(F)(F)F WUMVZXWBOFOYAW-UHFFFAOYSA-N 0.000 description 1
- OWEIAGSMFHSSES-UHFFFAOYSA-N 1-[1,1,1,3,3,3-hexafluoro-2-(4-methylphenyl)propan-2-yl]-4-methylbenzene Chemical compound C1=CC(C)=CC=C1C(C(F)(F)F)(C(F)(F)F)C1=CC=C(C)C=C1 OWEIAGSMFHSSES-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical group CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- VJGCZWVJDRIHNC-UHFFFAOYSA-N 1-fluoroprop-1-ene Chemical compound CC=CF VJGCZWVJDRIHNC-UHFFFAOYSA-N 0.000 description 1
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- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 239000006228 supernatant Substances 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 238000001721 transfer moulding Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- 125000000876 trifluoromethoxy group Chemical group FC(F)(F)O* 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
- C08F214/18—Monomers containing fluorine
- C08F214/26—Tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/12—Polymerisation in non-solvents
- C08F2/16—Aqueous medium
- C08F2/22—Emulsion polymerisation
- C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
- C08F2/26—Emulsion polymerisation with the aid of emulsifying agents anionic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C09D127/18—Homopolymers or copolymers of tetrafluoroethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/24—Polymer with special particle form or size
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2800/00—Copolymer characterised by the proportions of the comonomers expressed
- C08F2800/20—Copolymer characterised by the proportions of the comonomers expressed as weight or mass percentages
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP16184503.7A EP3284762A1 (en) | 2016-08-17 | 2016-08-17 | Fluoropolymers comprising tetrafluoroethene and one or more perfluorinated alkyl allyl ether comonomers |
| EP16184503.7 | 2016-08-17 | ||
| PCT/US2017/044951 WO2018034838A1 (en) | 2016-08-17 | 2017-08-01 | Fluoropolymers comprising tetrafluoroethylene and one or more perfluorinated alkyl allyl ether comonomers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2019524968A JP2019524968A (ja) | 2019-09-05 |
| JP2019524968A5 JP2019524968A5 (enExample) | 2020-09-10 |
| JP7036514B2 true JP7036514B2 (ja) | 2022-03-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2019508833A Active JP7036514B2 (ja) | 2016-08-17 | 2017-08-01 | テトラフルオロエチレン及び１つ以上のペルフルオロアルキルアリルエーテルコモノマーを含むフルオロポリマー |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US20190185599A1 (enExample) |
| EP (2) | EP3284762A1 (enExample) |
| JP (1) | JP7036514B2 (enExample) |
| CN (1) | CN109641991A (enExample) |
| WO (1) | WO2018034838A1 (enExample) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3896052A1 (en) | 2017-05-19 | 2021-10-20 | 3M Innovative Properties Co. | Methods of making a polyfluorinated allyl ether and compounds relating to the methods |
| WO2018229659A1 (en) * | 2017-06-13 | 2018-12-20 | 3M Innovative Properties Company | Modified polytetrafluoroethylene and aqueous dispersion containing the same |
| CN110389147A (zh) * | 2018-04-18 | 2019-10-29 | 中昊晨光化工研究院有限公司 | 一种基于核磁共振测定全氟聚醚的结构和分子量的方法 |
| EP3824001A1 (en) | 2018-07-20 | 2021-05-26 | 3M Innovative Properties Company | Tetrafluroethylene fluoropolymers containing perfluorinated allyl ethers |
| CN112703178B (zh) * | 2018-08-30 | 2022-02-22 | 3M创新有限公司 | 支链全氟乙烯基醚化合物、其制备方法以及来源于支链全氟乙烯基醚化合物的含氟聚合物 |
| WO2020132213A1 (en) | 2018-12-20 | 2020-06-25 | 3M Innovative Properties Company | Latex blends of amorphous perfluorinated polymers and articles derived therefrom |
| CN113195628A (zh) | 2018-12-20 | 2021-07-30 | 3M创新有限公司 | 非晶态全氟化聚合物的干粉共混物、其制备方法以及衍生自干粉共混物的制品 |
| CN109762091B (zh) * | 2018-12-29 | 2021-01-15 | 山东华夏神舟新材料有限公司 | 四氟乙烯基共聚物及其制备方法 |
| WO2020162623A1 (ja) * | 2019-02-07 | 2020-08-13 | ダイキン工業株式会社 | 組成物、延伸体及びその製造方法 |
| WO2020250919A1 (ja) * | 2019-06-13 | 2020-12-17 | Ａｇｃ株式会社 | 収容体の製造方法及び液状組成物 |
| WO2023042005A1 (en) | 2021-09-16 | 2023-03-23 | 3M Innovative Properties Company | Core shell fluoropolmyers with functional groups suitable for copper and electronic telecommunications articles |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004244504A (ja) | 2003-02-13 | 2004-09-02 | Yunimatekku Kk | 含フッ素共重合体およびその製造方法 |
| JP2009516005A (ja) | 2004-12-21 | 2009-04-16 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロエラストマーを製造するためのフルオロポリマー |
| JP2013532740A (ja) | 2010-07-23 | 2013-08-19 | スリーエム イノベイティブ プロパティズ カンパニー | 溶融加工用の高融点ｐｔｆｅポリマー |
| JP2016501311A (ja) | 2012-12-19 | 2016-01-18 | スリーエム イノベイティブ プロパティズ カンパニー | ポリヨウ化物を用いたフルオロポリマーの製造方法、これらの組成物及び物品 |
| JP2018510235A (ja) | 2015-02-12 | 2018-04-12 | スリーエム イノベイティブ プロパティズ カンパニー | テトラフルオロエチレンとペルフッ素化アリルエーテルとのコポリマー |
Family Cites Families (45)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3037953A (en) | 1961-04-26 | 1962-06-05 | Du Pont | Concentration of aqueous colloidal dispersions of polytetrafluoroethylene |
| US3489595A (en) | 1966-12-22 | 1970-01-13 | Du Pont | Coating compositions containing perfluorohalocarbon polymer,phosphoric acid and aluminum oxide,boron oxide or aluminum phosphate |
| US3635926A (en) | 1969-10-27 | 1972-01-18 | Du Pont | Aqueous process for making improved tetrafluoroethylene / fluoroalkyl perfluorovinyl ether copolymers |
| DE2639109A1 (de) | 1976-08-31 | 1978-03-09 | Hoechst Ag | Copolymerisate des tetrafluoraethylens und verfahren zu deren herstellung |
| SE7712836L (sv) * | 1976-12-02 | 1978-06-03 | Du Pont | Polyfluoroallyloxiforeningar |
| CH616880A5 (en) | 1977-03-23 | 1980-04-30 | Crystalon Sa | Process and means for the coating of surfaces for protecting against abrasion and corrosion |
| DE2908001C2 (de) | 1979-03-01 | 1981-02-19 | Hoechst Ag, 6000 Frankfurt | Verfahren zur Herstellung konzentrierter Dispersionen von Fluorpolymeren |
| US4349650A (en) | 1979-03-14 | 1982-09-14 | E. I. Du Pont De Nemours And Company | Polyfluoroallyloxy compounds, their preparation and copolymers therefrom |
| IT1125484B (it) * | 1979-03-14 | 1986-05-14 | Du Pont | Composti polifluorallilossilici,loro preparazione e copolimeri da essi ottenuti |
| DE2949907A1 (de) | 1979-12-12 | 1981-06-19 | Hoechst Ag, 6230 Frankfurt | Fluorpolymere mit schalenmodifizierten teilchen und verfahren zu deren herstellung |
| JPS60135446A (ja) * | 1983-12-22 | 1985-07-18 | Otsuka Chem Co Ltd | 溶融成形可能なフツ素系樹脂組成物 |
| US4743658A (en) | 1985-10-21 | 1988-05-10 | E. I. Du Pont De Nemours And Company | Stable tetrafluoroethylene copolymers |
| US4675380A (en) | 1985-10-25 | 1987-06-23 | E. I. Du Pont De Nemours And Company | Melt-processible tetrafluoroethylene/perfluoroolefin copolymer granules and processes for preparing them |
| DE3585160D1 (de) | 1985-11-08 | 1992-02-20 | Du Pont | Verfahren zur behandlung von schmelzverarbeitbaren copolymeren von tetrafluoraethylen und perfluoralkylvinylaether. |
| IT1204903B (it) | 1986-06-26 | 1989-03-10 | Ausimont Spa | Processo di polimerizzazione in dispersione acquosa di monomeri florati |
| SE460274B (sv) | 1988-02-18 | 1989-09-25 | Perstorp Ab | Foerfarande foer framstaellning av ett noetningsbestaendigt, dekorativt haerdplastlaminat |
| WO1994014904A1 (en) | 1992-12-23 | 1994-07-07 | E.I. Du Pont De Nemours And Company | Coating composition for non-stick substrates |
| DE4340943A1 (de) | 1993-12-01 | 1995-06-08 | Hoechst Ag | Wäßrige Dispersion von Fluorpolymerisaten, ihre Herstellung und Verwendung für Beschichtungen |
| US5760151A (en) | 1995-08-17 | 1998-06-02 | E. I. Du Pont De Nemours And Company | Tetrafluoroethylene copolymer |
| DE19547909A1 (de) | 1995-12-21 | 1997-06-26 | Dyneon Gmbh | Verfahren zur Nachbehandlung von thermoplastischen Fluorpolymeren |
| DE19726802C1 (de) | 1997-06-24 | 1998-06-10 | Dyneon Gmbh | Wäßrige Dispersion von Fluorpolymeren unterschiedlicher Teilchengröße |
| ITMI981520A1 (it) | 1998-07-02 | 2000-01-02 | Ausimont Spa | Dispersioni di fluoropolimeri |
| DE19857111A1 (de) | 1998-12-11 | 2000-06-15 | Dyneon Gmbh | Wäßrige Dispersionen von Fluorpolymeren |
| CN1094840C (zh) | 1999-01-26 | 2002-11-27 | 克劳诺斯潘技术有限公司 | 制备地板的复合覆层的方法 |
| US6291054B1 (en) | 1999-02-19 | 2001-09-18 | E. I. Du Pont De Nemours And Company | Abrasion resistant coatings |
| US6395848B1 (en) | 1999-05-20 | 2002-05-28 | E. I. Du Pont De Nemours And Company | Polymerization of fluoromonomers |
| DE10048730A1 (de) | 2000-09-29 | 2002-04-18 | Dyneon Gmbh | Thermoplastisch oder sintertechnisch verarbeitbares Fluorpolymer |
| DE60121291T2 (de) | 2001-03-26 | 2008-01-03 | 3M Innovative Properties Co., Saint Paul | Verbessertes Verfahren zur Polymerisation von Fluor enthaltenden Monomeren in wässriger Emulsion |
| US6761964B2 (en) | 2001-04-02 | 2004-07-13 | E. I. Du Pont De Nemours And Company | Fluoropolymer non-stick coatings |
| RU2294940C2 (ru) | 2001-09-05 | 2007-03-10 | Зм Инновейтив Пропертиз Компани | Дисперсия фторполимера, не содержащая либо содержащая малое количество низкомолекулярного фторированного поверхностно-активного вещества |
| US7060772B2 (en) | 2001-09-20 | 2006-06-13 | 3M Innovative Properties Company | Fluoropolymers from tetrafluoroethylene and perfluoro(alkoxyalkyl vinyl) ether |
| MXPA04006460A (es) | 2002-01-04 | 2004-10-04 | Du Pont | Dispersiones de fluoropolimeros concentradas. |
| JP4100431B2 (ja) | 2003-12-25 | 2008-06-11 | ダイキン工業株式会社 | フルオロポリマーの製造方法 |
| JP2005225816A (ja) * | 2004-02-13 | 2005-08-25 | Asahi Glass Co Ltd | 含フッ素アリルエーテルの製造方法 |
| US20060135681A1 (en) | 2004-12-22 | 2006-06-22 | Cavanaugh Robert J | Viscosity control for reduced fluorosurfactant aqueous fluoropolymer dispersions by the addition of cationic surfactant |
| US20070015937A1 (en) | 2005-07-15 | 2007-01-18 | 3M Innovative Properties Company | Process for recovery of fluorinated carboxylic acid surfactants from exhaust gas |
| US20080015304A1 (en) | 2006-07-13 | 2008-01-17 | Klaus Hintzer | Aqueous emulsion polymerization process for producing fluoropolymers |
| US7754287B2 (en) | 2006-05-31 | 2010-07-13 | E. I. Du Pont De Nemours And Company | Process for forming filled bearings from fluoropolymer dispersions stabilized with anionic polyelectrolyte dispersing agents |
| US7951795B2 (en) | 2006-12-08 | 2011-05-31 | Merck Sharp & Dohme Corp. | Constrained spirocyclic compounds as CGRP receptor antagonists |
| EP2284200A1 (en) * | 2009-07-31 | 2011-02-16 | 3M Innovative Properties Company | Aqueous fluoropolymer dispersions containing a polyol comprising at least one long chain residue and method for producing them |
| PL2459641T3 (pl) | 2009-07-31 | 2017-04-28 | 3M Innovative Properties Company | Kompozycje fluoropolimeru zawierającego związek poliolu oraz sposoby ich wytwarzania |
| PL2767557T3 (pl) * | 2013-02-14 | 2017-09-29 | 3M Innovative Properties Company | Kompozycje fluoropolimeru z mikrosferami |
| EP2803691B1 (en) * | 2013-05-17 | 2016-04-20 | 3M Innovative Properties Company | Fluoropolymer compositions containing a polyhydroxy surfactant |
| EP2803690B1 (en) * | 2013-05-17 | 2016-12-14 | 3M Innovative Properties Company | Method for reducing fluorinated emulsifiers from aqueous fluoropolymer dispersions using sugar-based emulsifiers |
| JP2016143487A (ja) | 2015-01-30 | 2016-08-08 | 株式会社オートネットワーク技術研究所 | 絶縁電線 |
-
2016
- 2016-08-17 EP EP16184503.7A patent/EP3284762A1/en not_active Withdrawn
-
2017
- 2017-08-01 EP EP17748618.0A patent/EP3500603B1/en active Active
- 2017-08-01 CN CN201780050792.5A patent/CN109641991A/zh active Pending
- 2017-08-01 WO PCT/US2017/044951 patent/WO2018034838A1/en not_active Ceased
- 2017-08-01 US US16/325,795 patent/US20190185599A1/en not_active Abandoned
- 2017-08-01 JP JP2019508833A patent/JP7036514B2/ja active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004244504A (ja) | 2003-02-13 | 2004-09-02 | Yunimatekku Kk | 含フッ素共重合体およびその製造方法 |
| JP2009516005A (ja) | 2004-12-21 | 2009-04-16 | スリーエム イノベイティブ プロパティズ カンパニー | フルオロエラストマーを製造するためのフルオロポリマー |
| JP2013532740A (ja) | 2010-07-23 | 2013-08-19 | スリーエム イノベイティブ プロパティズ カンパニー | 溶融加工用の高融点ｐｔｆｅポリマー |
| JP2016501311A (ja) | 2012-12-19 | 2016-01-18 | スリーエム イノベイティブ プロパティズ カンパニー | ポリヨウ化物を用いたフルオロポリマーの製造方法、これらの組成物及び物品 |
| JP2018510235A (ja) | 2015-02-12 | 2018-04-12 | スリーエム イノベイティブ プロパティズ カンパニー | テトラフルオロエチレンとペルフッ素化アリルエーテルとのコポリマー |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3500603B1 (en) | 2020-06-17 |
| CN109641991A (zh) | 2019-04-16 |
| WO2018034838A1 (en) | 2018-02-22 |
| EP3284762A1 (en) | 2018-02-21 |
| EP3500603A1 (en) | 2019-06-26 |
| US20190185599A1 (en) | 2019-06-20 |
| JP2019524968A (ja) | 2019-09-05 |
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