JP7023232B2 - 乳酸ポリマーフィルム - Google Patents
乳酸ポリマーフィルム Download PDFInfo
- Publication number
- JP7023232B2 JP7023232B2 JP2018536095A JP2018536095A JP7023232B2 JP 7023232 B2 JP7023232 B2 JP 7023232B2 JP 2018536095 A JP2018536095 A JP 2018536095A JP 2018536095 A JP2018536095 A JP 2018536095A JP 7023232 B2 JP7023232 B2 JP 7023232B2
- Authority
- JP
- Japan
- Prior art keywords
- layer
- film
- lactic acid
- multilayer film
- acid polymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 title claims description 44
- 239000004310 lactic acid Substances 0.000 title claims description 22
- 235000014655 lactic acid Nutrition 0.000 title claims description 22
- 229920006254 polymer film Polymers 0.000 title description 2
- 229920000642 polymer Polymers 0.000 claims description 23
- 239000004014 plasticizer Substances 0.000 claims description 18
- 229920001169 thermoplastic Polymers 0.000 claims description 14
- 239000004416 thermosoftening plastic Substances 0.000 claims description 14
- 239000008035 bio-based plasticizer Substances 0.000 claims description 3
- 229920002472 Starch Polymers 0.000 description 20
- 235000019698 starch Nutrition 0.000 description 20
- 239000008107 starch Substances 0.000 description 19
- 239000000523 sample Substances 0.000 description 11
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- 238000004806 packaging method and process Methods 0.000 description 10
- 238000000034 method Methods 0.000 description 7
- 239000004626 polylactic acid Substances 0.000 description 7
- 239000011800 void material Substances 0.000 description 7
- 229920000747 poly(lactic acid) Polymers 0.000 description 6
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 5
- 238000012360 testing method Methods 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229920000881 Modified starch Polymers 0.000 description 3
- 230000006378 damage Effects 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 238000009863 impact test Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000004368 Modified starch Substances 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 229920000704 biodegradable plastic Polymers 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 235000019426 modified starch Nutrition 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- GUOCOOQWZHQBJI-UHFFFAOYSA-N 4-oct-7-enoxy-4-oxobutanoic acid Chemical compound OC(=O)CCC(=O)OCCCCCCC=C GUOCOOQWZHQBJI-UHFFFAOYSA-N 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- 239000004370 Bleached starch Substances 0.000 description 1
- 229920000858 Cyclodextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 239000001073 acetylated oxidized starch Substances 0.000 description 1
- 235000013770 acetylated oxidized starch Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 229920013724 bio-based polymer Polymers 0.000 description 1
- 235000019428 bleached starch Nutrition 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 229920006237 degradable polymer Polymers 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 239000001245 distarch phosphate Substances 0.000 description 1
- 235000013804 distarch phosphate Nutrition 0.000 description 1
- 239000001341 hydroxy propyl starch Substances 0.000 description 1
- -1 hydroxypropyl Chemical group 0.000 description 1
- 235000013828 hydroxypropyl starch Nutrition 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005464 sample preparation method Methods 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/22—Layered products comprising a layer of synthetic resin characterised by the use of special additives using plasticisers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
- B32B27/26—Layered products comprising a layer of synthetic resin characterised by the use of special additives using curing agents
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0016—Plasticisers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/24—All layers being polymeric
- B32B2250/244—All polymers belonging to those covered by group B32B27/36
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/44—Number of layers variable across the laminate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/40—Properties of the layers or laminate having particular optical properties
- B32B2307/412—Transparent
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/716—Degradable
- B32B2307/7163—Biodegradable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Laminated Bodies (AREA)
- Wrappers (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201562234114P | 2015-09-29 | 2015-09-29 | |
| US62/234,114 | 2015-09-29 | ||
| PCT/US2016/054548 WO2017059138A1 (en) | 2015-09-29 | 2016-09-29 | Lactic acid polymer films |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2018535132A JP2018535132A (ja) | 2018-11-29 |
| JP2018535132A5 JP2018535132A5 (https=) | 2019-11-07 |
| JP7023232B2 true JP7023232B2 (ja) | 2022-02-21 |
Family
ID=58427973
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2018536095A Active JP7023232B2 (ja) | 2015-09-29 | 2016-09-29 | 乳酸ポリマーフィルム |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US11260632B2 (https=) |
| EP (1) | EP3356143B1 (https=) |
| JP (1) | JP7023232B2 (https=) |
| CN (1) | CN108349227A (https=) |
| WO (1) | WO2017059138A1 (https=) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2024011693A (ja) * | 2022-07-15 | 2024-01-25 | 王子ホールディングス株式会社 | 積層フィルム及び包装材用フィルム |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004143432A (ja) | 2002-10-03 | 2004-05-20 | Toray Ind Inc | ポリ乳酸系樹脂延伸フィルムおよびその製造方法 |
| JP2008265118A (ja) | 2007-04-19 | 2008-11-06 | Dainippon Printing Co Ltd | 多層積層フィルム |
| JP2014005330A (ja) | 2012-06-22 | 2014-01-16 | Toray Ind Inc | フィルム |
Family Cites Families (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS503222B2 (https=) | 1971-09-01 | 1975-02-01 | ||
| JPS5138735A (ja) | 1974-09-27 | 1976-03-31 | Sanko Kinzoku Kogyo Kk | Kenchikuyoban |
| US5849401A (en) * | 1995-09-28 | 1998-12-15 | Cargill, Incorporated | Compostable multilayer structures, methods for manufacture, and articles prepared therefrom |
| US6114495A (en) * | 1998-04-01 | 2000-09-05 | Cargill Incorporated | Lactic acid residue containing polymer composition and product having improved stability, and method for preparation and use thereof |
| JP4122915B2 (ja) * | 2001-10-03 | 2008-07-23 | 東レ株式会社 | 柔軟化ポリ乳酸系樹脂延伸フィルム及びその製造方法 |
| JP2004090608A (ja) * | 2002-07-11 | 2004-03-25 | Mitsubishi Plastics Ind Ltd | 折り曲げ罫線入り積層シート、及びこの折り曲げ罫線入り積層シートを用いた成形加工品 |
| JP4080953B2 (ja) * | 2003-06-05 | 2008-04-23 | 三菱樹脂株式会社 | ポリ乳酸系熱折り曲げ成形体及びその製造方法 |
| JP2005144694A (ja) | 2003-11-11 | 2005-06-09 | C I Kasei Co Ltd | ポリ乳酸積層フィルム |
| US7879440B2 (en) * | 2003-11-25 | 2011-02-01 | Asahi Kasei Life & Living Corporation | Matte film |
| JP2007269995A (ja) * | 2006-03-31 | 2007-10-18 | Three M Innovative Properties Co | ポリ乳酸含有樹脂組成物、ポリ乳酸含有樹脂フィルム及びポリ乳酸含有樹脂繊維 |
| MX2008012653A (es) * | 2006-03-31 | 2008-10-13 | Treofan Germany Gmbh & Co Kg | Pelicula descortezable y sellable de acido polilactico. |
| AU2007239514B2 (en) * | 2006-04-14 | 2010-09-23 | Biotec Biologische Naturverpackungen Gmbh & Co. Kg | Multilayered film and method for manufacturing same |
| JP2008221733A (ja) | 2007-03-15 | 2008-09-25 | Dainippon Printing Co Ltd | バリア性を有するヒ−トシ−ル性フィルム |
| JP5003222B2 (ja) | 2007-03-16 | 2012-08-15 | 大日本印刷株式会社 | バリア性を有するヒ−トシ−ル性フィルム |
| JP5309456B2 (ja) | 2007-03-16 | 2013-10-09 | 大日本印刷株式会社 | バリア性を有するヒ−トシ−ル性フィルム |
| JP5374826B2 (ja) | 2007-04-19 | 2013-12-25 | 大日本印刷株式会社 | 多層積層フィルム |
| DE102007038473C5 (de) | 2007-08-14 | 2013-11-07 | Huhtamaki Films Germany Gmbh & Co. Kg | Folienanordnung, Verfahren zu deren Herstellung und Verwendung |
| US20100015420A1 (en) * | 2008-03-24 | 2010-01-21 | Michael Riebel | Biolaminate composite assembly and related methods |
| US8188185B2 (en) * | 2008-06-30 | 2012-05-29 | Kimberly-Clark Worldwide, Inc. | Biodegradable packaging film |
| US20110135912A1 (en) | 2009-06-16 | 2011-06-09 | Meadwestvaco Corporation | Biodegradable packaging materials with enhanced oxygen barrier performance |
| US20110200844A1 (en) * | 2010-02-17 | 2011-08-18 | Frito-Lay North America, Inc. | Composition for facilitating environmental degradation of a film |
| WO2011140019A1 (en) | 2010-05-07 | 2011-11-10 | 3M Innovative Properties Company | Apparatus for manufacturing multilayer polymeric films |
| WO2011139618A2 (en) | 2010-05-07 | 2011-11-10 | 3M Innovative Properties Company | Feedblock for manufacturing multilayer polymeric films |
| US20120016328A1 (en) * | 2010-07-19 | 2012-01-19 | Bo Shi | Biodegradable films |
| CN103384702B (zh) * | 2011-02-24 | 2015-02-18 | 东丽株式会社 | 聚乳酸系膜 |
-
2016
- 2016-09-29 CN CN201680061922.0A patent/CN108349227A/zh active Pending
- 2016-09-29 US US15/764,451 patent/US11260632B2/en active Active
- 2016-09-29 EP EP16852639.0A patent/EP3356143B1/en active Active
- 2016-09-29 WO PCT/US2016/054548 patent/WO2017059138A1/en not_active Ceased
- 2016-09-29 JP JP2018536095A patent/JP7023232B2/ja active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004143432A (ja) | 2002-10-03 | 2004-05-20 | Toray Ind Inc | ポリ乳酸系樹脂延伸フィルムおよびその製造方法 |
| JP2008265118A (ja) | 2007-04-19 | 2008-11-06 | Dainippon Printing Co Ltd | 多層積層フィルム |
| JP2014005330A (ja) | 2012-06-22 | 2014-01-16 | Toray Ind Inc | フィルム |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2017059138A1 (en) | 2017-04-06 |
| US20180272668A1 (en) | 2018-09-27 |
| JP2018535132A (ja) | 2018-11-29 |
| US11260632B2 (en) | 2022-03-01 |
| EP3356143A4 (en) | 2019-04-24 |
| CN108349227A (zh) | 2018-07-31 |
| EP3356143B1 (en) | 2023-06-21 |
| EP3356143A1 (en) | 2018-08-08 |
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